Structural disordering in Cr-doped $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinels
Abstract The processes of lithium redistribution in the structure of cubic $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinel, caused by both chromium doping and thermal activation, have been investigated by nuclear magnetic resonance. It is shown that Li ions migrate from tetra- to octahedral crystallographic p...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhuravlev, N. A. [verfasserIn] Mukhina, N. A. [verfasserIn] Kellerman, D. G. [verfasserIn] Gorshkov, V. S. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Bulletin of the Russian Academy of Sciences - New York, NY : Allerton Press, 2007, 73(2009), 11 vom: 15. Dez. |
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| Übergeordnetes Werk: |
volume:73 ; year:2009 ; number:11 ; day:15 ; month:12 |
| Links: |
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| DOI / URN: |
10.3103/S1062873809110239 |
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| Katalog-ID: |
SPR023149779 |
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| 520 | |a Abstract The processes of lithium redistribution in the structure of cubic $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinel, caused by both chromium doping and thermal activation, have been investigated by nuclear magnetic resonance. It is shown that Li ions migrate from tetra- to octahedral crystallographic positions with an increase in temperature. This process becomes more pronounced at temperatures above 400 K. In contrast, the fraction of tetrahedrally coordinated Li increases as a result of doping with chromium. | ||
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| 650 | 4 | |a Spinel Structure |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Nuclear Magnetic Resonance Spectroscopy |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Octahedral Position |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Broad Component |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Mukhina, N. A. |e verfasserin |4 aut | |
| 700 | 1 | |a Kellerman, D. G. |e verfasserin |4 aut | |
| 700 | 1 | |a Gorshkov, V. S. |e verfasserin |4 aut | |
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10.3103/S1062873809110239 doi (DE-627)SPR023149779 (SPR)S1062873809110239-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Zhuravlev, N. A. verfasserin aut Structural disordering in Cr-doped $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinels 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The processes of lithium redistribution in the structure of cubic $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinel, caused by both chromium doping and thermal activation, have been investigated by nuclear magnetic resonance. It is shown that Li ions migrate from tetra- to octahedral crystallographic positions with an increase in temperature. This process becomes more pronounced at temperatures above 400 K. In contrast, the fraction of tetrahedrally coordinated Li increases as a result of doping with chromium. Nuclear Magnetic Resonance (dpeaa)DE-He213 Spinel Structure (dpeaa)DE-He213 Nuclear Magnetic Resonance Spectroscopy (dpeaa)DE-He213 Octahedral Position (dpeaa)DE-He213 Broad Component (dpeaa)DE-He213 Mukhina, N. A. verfasserin aut Kellerman, D. G. verfasserin aut Gorshkov, V. S. verfasserin aut Enthalten in Bulletin of the Russian Academy of Sciences New York, NY : Allerton Press, 2007 73(2009), 11 vom: 15. Dez. (DE-627)556723872 (DE-600)2403169-0 1934-9432 nnns volume:73 year:2009 number:11 day:15 month:12 https://dx.doi.org/10.3103/S1062873809110239 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 73 2009 11 15 12 |
| spelling |
10.3103/S1062873809110239 doi (DE-627)SPR023149779 (SPR)S1062873809110239-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Zhuravlev, N. A. verfasserin aut Structural disordering in Cr-doped $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinels 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The processes of lithium redistribution in the structure of cubic $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinel, caused by both chromium doping and thermal activation, have been investigated by nuclear magnetic resonance. It is shown that Li ions migrate from tetra- to octahedral crystallographic positions with an increase in temperature. This process becomes more pronounced at temperatures above 400 K. In contrast, the fraction of tetrahedrally coordinated Li increases as a result of doping with chromium. Nuclear Magnetic Resonance (dpeaa)DE-He213 Spinel Structure (dpeaa)DE-He213 Nuclear Magnetic Resonance Spectroscopy (dpeaa)DE-He213 Octahedral Position (dpeaa)DE-He213 Broad Component (dpeaa)DE-He213 Mukhina, N. A. verfasserin aut Kellerman, D. G. verfasserin aut Gorshkov, V. S. verfasserin aut Enthalten in Bulletin of the Russian Academy of Sciences New York, NY : Allerton Press, 2007 73(2009), 11 vom: 15. Dez. (DE-627)556723872 (DE-600)2403169-0 1934-9432 nnns volume:73 year:2009 number:11 day:15 month:12 https://dx.doi.org/10.3103/S1062873809110239 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 73 2009 11 15 12 |
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10.3103/S1062873809110239 doi (DE-627)SPR023149779 (SPR)S1062873809110239-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Zhuravlev, N. A. verfasserin aut Structural disordering in Cr-doped $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinels 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The processes of lithium redistribution in the structure of cubic $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinel, caused by both chromium doping and thermal activation, have been investigated by nuclear magnetic resonance. It is shown that Li ions migrate from tetra- to octahedral crystallographic positions with an increase in temperature. This process becomes more pronounced at temperatures above 400 K. In contrast, the fraction of tetrahedrally coordinated Li increases as a result of doping with chromium. Nuclear Magnetic Resonance (dpeaa)DE-He213 Spinel Structure (dpeaa)DE-He213 Nuclear Magnetic Resonance Spectroscopy (dpeaa)DE-He213 Octahedral Position (dpeaa)DE-He213 Broad Component (dpeaa)DE-He213 Mukhina, N. A. verfasserin aut Kellerman, D. G. verfasserin aut Gorshkov, V. S. verfasserin aut Enthalten in Bulletin of the Russian Academy of Sciences New York, NY : Allerton Press, 2007 73(2009), 11 vom: 15. Dez. (DE-627)556723872 (DE-600)2403169-0 1934-9432 nnns volume:73 year:2009 number:11 day:15 month:12 https://dx.doi.org/10.3103/S1062873809110239 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 73 2009 11 15 12 |
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10.3103/S1062873809110239 doi (DE-627)SPR023149779 (SPR)S1062873809110239-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Zhuravlev, N. A. verfasserin aut Structural disordering in Cr-doped $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinels 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The processes of lithium redistribution in the structure of cubic $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinel, caused by both chromium doping and thermal activation, have been investigated by nuclear magnetic resonance. It is shown that Li ions migrate from tetra- to octahedral crystallographic positions with an increase in temperature. This process becomes more pronounced at temperatures above 400 K. In contrast, the fraction of tetrahedrally coordinated Li increases as a result of doping with chromium. Nuclear Magnetic Resonance (dpeaa)DE-He213 Spinel Structure (dpeaa)DE-He213 Nuclear Magnetic Resonance Spectroscopy (dpeaa)DE-He213 Octahedral Position (dpeaa)DE-He213 Broad Component (dpeaa)DE-He213 Mukhina, N. A. verfasserin aut Kellerman, D. G. verfasserin aut Gorshkov, V. S. verfasserin aut Enthalten in Bulletin of the Russian Academy of Sciences New York, NY : Allerton Press, 2007 73(2009), 11 vom: 15. Dez. (DE-627)556723872 (DE-600)2403169-0 1934-9432 nnns volume:73 year:2009 number:11 day:15 month:12 https://dx.doi.org/10.3103/S1062873809110239 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 73 2009 11 15 12 |
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Enthalten in Bulletin of the Russian Academy of Sciences 73(2009), 11 vom: 15. Dez. volume:73 year:2009 number:11 day:15 month:12 |
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Nuclear Magnetic Resonance Spinel Structure Nuclear Magnetic Resonance Spectroscopy Octahedral Position Broad Component |
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Zhuravlev, N. A. @@aut@@ Mukhina, N. A. @@aut@@ Kellerman, D. G. @@aut@@ Gorshkov, V. S. @@aut@@ |
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Zhuravlev, N. A. |
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Zhuravlev, N. A. ddc 530 bkl 33.00 misc Nuclear Magnetic Resonance misc Spinel Structure misc Nuclear Magnetic Resonance Spectroscopy misc Octahedral Position misc Broad Component Structural disordering in Cr-doped $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinels |
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530 ASE 33.00 bkl Structural disordering in Cr-doped $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinels Nuclear Magnetic Resonance (dpeaa)DE-He213 Spinel Structure (dpeaa)DE-He213 Nuclear Magnetic Resonance Spectroscopy (dpeaa)DE-He213 Octahedral Position (dpeaa)DE-He213 Broad Component (dpeaa)DE-He213 |
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Structural disordering in Cr-doped $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinels |
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Structural disordering in Cr-doped $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinels |
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structural disordering in cr-doped $ li_{4} %$ ti_{5} %$ o_{12} $ spinels |
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Structural disordering in Cr-doped $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinels |
| abstract |
Abstract The processes of lithium redistribution in the structure of cubic $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinel, caused by both chromium doping and thermal activation, have been investigated by nuclear magnetic resonance. It is shown that Li ions migrate from tetra- to octahedral crystallographic positions with an increase in temperature. This process becomes more pronounced at temperatures above 400 K. In contrast, the fraction of tetrahedrally coordinated Li increases as a result of doping with chromium. |
| abstractGer |
Abstract The processes of lithium redistribution in the structure of cubic $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinel, caused by both chromium doping and thermal activation, have been investigated by nuclear magnetic resonance. It is shown that Li ions migrate from tetra- to octahedral crystallographic positions with an increase in temperature. This process becomes more pronounced at temperatures above 400 K. In contrast, the fraction of tetrahedrally coordinated Li increases as a result of doping with chromium. |
| abstract_unstemmed |
Abstract The processes of lithium redistribution in the structure of cubic $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinel, caused by both chromium doping and thermal activation, have been investigated by nuclear magnetic resonance. It is shown that Li ions migrate from tetra- to octahedral crystallographic positions with an increase in temperature. This process becomes more pronounced at temperatures above 400 K. In contrast, the fraction of tetrahedrally coordinated Li increases as a result of doping with chromium. |
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Structural disordering in Cr-doped $ Li_{4} %$ Ti_{5} %$ O_{12} $ spinels |
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2024-07-03T17:10:56.742Z |
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