Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides

Abstract A series of novel layered double hydroxide (LDH)-modified phosphate esters (LPPBs) flame retardants were synthesized by the reaction of flexible phosphate ester (PPB) and LDHs with different mass ratio and then well characterized by Fourier transform infrared spectroscopy (FTIR) and 1H nucl...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Xu, Zhisheng [verfasserIn] Deng, Nan [verfasserIn] Yan, Long [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Transparent fire-retardant coating Layered double hydroxides Flame retardancy Smoke suppression Synergistic effect

Übergeordnetes Werk:	Enthalten in: Journal of coatings technology and research - Blue Bell, Pa., 2004, 17(2019), 1 vom: 06. Aug., Seite 157-169
Übergeordnetes Werk:	volume:17 ; year:2019 ; number:1 ; day:06 ; month:08 ; pages:157-169

Links:	Volltext

DOI / URN:	10.1007/s11998-019-00249-8

Katalog-ID:	SPR02364513X

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520			\|a Abstract A series of novel layered double hydroxide (LDH)-modified phosphate esters (LPPBs) flame retardants were synthesized by the reaction of flexible phosphate ester (PPB) and LDHs with different mass ratio and then well characterized by Fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance spectroscopy (1H NMR). The obtained LPPBs were mixed with melamine formaldehyde resin to produce transparent fire-retardant coatings applied on wood substrates. The coatings containing LDHs exhibit a high degree of transparency even at high LDH contents due to the well dispersed and completely exfoliated state of LDHs in the amino matrix, as determined from the results of X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images. The fire protection tests show that the values of weight loss, char index, and flame spread rating of the coatings are remarkably decreased with the introduction of LDHs concomitant with an increase in the intumescent factor. The cone calorimeter and smoke density tests show that the flame retardancy and smoke suppression properties of the coatings are significantly improved with the introduction of LDHs due to the formation of a more compact, continuous, and intumescent char during combustion. The results of thermogravimetric (TG) analysis show that the thermal stability and residual weight of the coatings are gradually increased with increasing LDH content. Char residue analysis shows that the introduction of LDHs into the coatings contributes to generating more phosphorus-rich crosslinking structures and aromatic structures in the condensed phase that produce a more compact and thermally stable char against the release of heat and smoke, thus exhibiting excellent flame retardancy and smoke suppression properties.
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650		4	\|a Smoke suppression \|7 (dpeaa)DE-He213
650		4	\|a Synergistic effect \|7 (dpeaa)DE-He213
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700	1		\|a Yan, Long \|e verfasserin \|4 aut
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allfields	10.1007/s11998-019-00249-8 doi (DE-627)SPR02364513X (SPR)s11998-019-00249-8-e DE-627 ger DE-627 rakwb eng 600 ASE Xu, Zhisheng verfasserin aut Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A series of novel layered double hydroxide (LDH)-modified phosphate esters (LPPBs) flame retardants were synthesized by the reaction of flexible phosphate ester (PPB) and LDHs with different mass ratio and then well characterized by Fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance spectroscopy (1H NMR). The obtained LPPBs were mixed with melamine formaldehyde resin to produce transparent fire-retardant coatings applied on wood substrates. The coatings containing LDHs exhibit a high degree of transparency even at high LDH contents due to the well dispersed and completely exfoliated state of LDHs in the amino matrix, as determined from the results of X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images. The fire protection tests show that the values of weight loss, char index, and flame spread rating of the coatings are remarkably decreased with the introduction of LDHs concomitant with an increase in the intumescent factor. The cone calorimeter and smoke density tests show that the flame retardancy and smoke suppression properties of the coatings are significantly improved with the introduction of LDHs due to the formation of a more compact, continuous, and intumescent char during combustion. The results of thermogravimetric (TG) analysis show that the thermal stability and residual weight of the coatings are gradually increased with increasing LDH content. Char residue analysis shows that the introduction of LDHs into the coatings contributes to generating more phosphorus-rich crosslinking structures and aromatic structures in the condensed phase that produce a more compact and thermally stable char against the release of heat and smoke, thus exhibiting excellent flame retardancy and smoke suppression properties. Transparent fire-retardant coating (dpeaa)DE-He213 Layered double hydroxides (dpeaa)DE-He213 Flame retardancy (dpeaa)DE-He213 Smoke suppression (dpeaa)DE-He213 Synergistic effect (dpeaa)DE-He213 Deng, Nan verfasserin aut Yan, Long verfasserin aut Enthalten in Journal of coatings technology and research Blue Bell, Pa., 2004 17(2019), 1 vom: 06. Aug., Seite 157-169 (DE-627)51834584X (DE-600)2252471-X 1935-3804 nnns volume:17 year:2019 number:1 day:06 month:08 pages:157-169 https://dx.doi.org/10.1007/s11998-019-00249-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2019 1 06 08 157-169
spelling	10.1007/s11998-019-00249-8 doi (DE-627)SPR02364513X (SPR)s11998-019-00249-8-e DE-627 ger DE-627 rakwb eng 600 ASE Xu, Zhisheng verfasserin aut Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A series of novel layered double hydroxide (LDH)-modified phosphate esters (LPPBs) flame retardants were synthesized by the reaction of flexible phosphate ester (PPB) and LDHs with different mass ratio and then well characterized by Fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance spectroscopy (1H NMR). The obtained LPPBs were mixed with melamine formaldehyde resin to produce transparent fire-retardant coatings applied on wood substrates. The coatings containing LDHs exhibit a high degree of transparency even at high LDH contents due to the well dispersed and completely exfoliated state of LDHs in the amino matrix, as determined from the results of X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images. The fire protection tests show that the values of weight loss, char index, and flame spread rating of the coatings are remarkably decreased with the introduction of LDHs concomitant with an increase in the intumescent factor. The cone calorimeter and smoke density tests show that the flame retardancy and smoke suppression properties of the coatings are significantly improved with the introduction of LDHs due to the formation of a more compact, continuous, and intumescent char during combustion. The results of thermogravimetric (TG) analysis show that the thermal stability and residual weight of the coatings are gradually increased with increasing LDH content. Char residue analysis shows that the introduction of LDHs into the coatings contributes to generating more phosphorus-rich crosslinking structures and aromatic structures in the condensed phase that produce a more compact and thermally stable char against the release of heat and smoke, thus exhibiting excellent flame retardancy and smoke suppression properties. Transparent fire-retardant coating (dpeaa)DE-He213 Layered double hydroxides (dpeaa)DE-He213 Flame retardancy (dpeaa)DE-He213 Smoke suppression (dpeaa)DE-He213 Synergistic effect (dpeaa)DE-He213 Deng, Nan verfasserin aut Yan, Long verfasserin aut Enthalten in Journal of coatings technology and research Blue Bell, Pa., 2004 17(2019), 1 vom: 06. Aug., Seite 157-169 (DE-627)51834584X (DE-600)2252471-X 1935-3804 nnns volume:17 year:2019 number:1 day:06 month:08 pages:157-169 https://dx.doi.org/10.1007/s11998-019-00249-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2019 1 06 08 157-169
allfields_unstemmed	10.1007/s11998-019-00249-8 doi (DE-627)SPR02364513X (SPR)s11998-019-00249-8-e DE-627 ger DE-627 rakwb eng 600 ASE Xu, Zhisheng verfasserin aut Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A series of novel layered double hydroxide (LDH)-modified phosphate esters (LPPBs) flame retardants were synthesized by the reaction of flexible phosphate ester (PPB) and LDHs with different mass ratio and then well characterized by Fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance spectroscopy (1H NMR). The obtained LPPBs were mixed with melamine formaldehyde resin to produce transparent fire-retardant coatings applied on wood substrates. The coatings containing LDHs exhibit a high degree of transparency even at high LDH contents due to the well dispersed and completely exfoliated state of LDHs in the amino matrix, as determined from the results of X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images. The fire protection tests show that the values of weight loss, char index, and flame spread rating of the coatings are remarkably decreased with the introduction of LDHs concomitant with an increase in the intumescent factor. The cone calorimeter and smoke density tests show that the flame retardancy and smoke suppression properties of the coatings are significantly improved with the introduction of LDHs due to the formation of a more compact, continuous, and intumescent char during combustion. The results of thermogravimetric (TG) analysis show that the thermal stability and residual weight of the coatings are gradually increased with increasing LDH content. Char residue analysis shows that the introduction of LDHs into the coatings contributes to generating more phosphorus-rich crosslinking structures and aromatic structures in the condensed phase that produce a more compact and thermally stable char against the release of heat and smoke, thus exhibiting excellent flame retardancy and smoke suppression properties. Transparent fire-retardant coating (dpeaa)DE-He213 Layered double hydroxides (dpeaa)DE-He213 Flame retardancy (dpeaa)DE-He213 Smoke suppression (dpeaa)DE-He213 Synergistic effect (dpeaa)DE-He213 Deng, Nan verfasserin aut Yan, Long verfasserin aut Enthalten in Journal of coatings technology and research Blue Bell, Pa., 2004 17(2019), 1 vom: 06. Aug., Seite 157-169 (DE-627)51834584X (DE-600)2252471-X 1935-3804 nnns volume:17 year:2019 number:1 day:06 month:08 pages:157-169 https://dx.doi.org/10.1007/s11998-019-00249-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2019 1 06 08 157-169
allfieldsGer	10.1007/s11998-019-00249-8 doi (DE-627)SPR02364513X (SPR)s11998-019-00249-8-e DE-627 ger DE-627 rakwb eng 600 ASE Xu, Zhisheng verfasserin aut Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A series of novel layered double hydroxide (LDH)-modified phosphate esters (LPPBs) flame retardants were synthesized by the reaction of flexible phosphate ester (PPB) and LDHs with different mass ratio and then well characterized by Fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance spectroscopy (1H NMR). The obtained LPPBs were mixed with melamine formaldehyde resin to produce transparent fire-retardant coatings applied on wood substrates. The coatings containing LDHs exhibit a high degree of transparency even at high LDH contents due to the well dispersed and completely exfoliated state of LDHs in the amino matrix, as determined from the results of X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images. The fire protection tests show that the values of weight loss, char index, and flame spread rating of the coatings are remarkably decreased with the introduction of LDHs concomitant with an increase in the intumescent factor. The cone calorimeter and smoke density tests show that the flame retardancy and smoke suppression properties of the coatings are significantly improved with the introduction of LDHs due to the formation of a more compact, continuous, and intumescent char during combustion. The results of thermogravimetric (TG) analysis show that the thermal stability and residual weight of the coatings are gradually increased with increasing LDH content. Char residue analysis shows that the introduction of LDHs into the coatings contributes to generating more phosphorus-rich crosslinking structures and aromatic structures in the condensed phase that produce a more compact and thermally stable char against the release of heat and smoke, thus exhibiting excellent flame retardancy and smoke suppression properties. Transparent fire-retardant coating (dpeaa)DE-He213 Layered double hydroxides (dpeaa)DE-He213 Flame retardancy (dpeaa)DE-He213 Smoke suppression (dpeaa)DE-He213 Synergistic effect (dpeaa)DE-He213 Deng, Nan verfasserin aut Yan, Long verfasserin aut Enthalten in Journal of coatings technology and research Blue Bell, Pa., 2004 17(2019), 1 vom: 06. Aug., Seite 157-169 (DE-627)51834584X (DE-600)2252471-X 1935-3804 nnns volume:17 year:2019 number:1 day:06 month:08 pages:157-169 https://dx.doi.org/10.1007/s11998-019-00249-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2019 1 06 08 157-169
allfieldsSound	10.1007/s11998-019-00249-8 doi (DE-627)SPR02364513X (SPR)s11998-019-00249-8-e DE-627 ger DE-627 rakwb eng 600 ASE Xu, Zhisheng verfasserin aut Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A series of novel layered double hydroxide (LDH)-modified phosphate esters (LPPBs) flame retardants were synthesized by the reaction of flexible phosphate ester (PPB) and LDHs with different mass ratio and then well characterized by Fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance spectroscopy (1H NMR). The obtained LPPBs were mixed with melamine formaldehyde resin to produce transparent fire-retardant coatings applied on wood substrates. The coatings containing LDHs exhibit a high degree of transparency even at high LDH contents due to the well dispersed and completely exfoliated state of LDHs in the amino matrix, as determined from the results of X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images. The fire protection tests show that the values of weight loss, char index, and flame spread rating of the coatings are remarkably decreased with the introduction of LDHs concomitant with an increase in the intumescent factor. The cone calorimeter and smoke density tests show that the flame retardancy and smoke suppression properties of the coatings are significantly improved with the introduction of LDHs due to the formation of a more compact, continuous, and intumescent char during combustion. The results of thermogravimetric (TG) analysis show that the thermal stability and residual weight of the coatings are gradually increased with increasing LDH content. Char residue analysis shows that the introduction of LDHs into the coatings contributes to generating more phosphorus-rich crosslinking structures and aromatic structures in the condensed phase that produce a more compact and thermally stable char against the release of heat and smoke, thus exhibiting excellent flame retardancy and smoke suppression properties. Transparent fire-retardant coating (dpeaa)DE-He213 Layered double hydroxides (dpeaa)DE-He213 Flame retardancy (dpeaa)DE-He213 Smoke suppression (dpeaa)DE-He213 Synergistic effect (dpeaa)DE-He213 Deng, Nan verfasserin aut Yan, Long verfasserin aut Enthalten in Journal of coatings technology and research Blue Bell, Pa., 2004 17(2019), 1 vom: 06. Aug., Seite 157-169 (DE-627)51834584X (DE-600)2252471-X 1935-3804 nnns volume:17 year:2019 number:1 day:06 month:08 pages:157-169 https://dx.doi.org/10.1007/s11998-019-00249-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 17 2019 1 06 08 157-169
language	English
source	Enthalten in Journal of coatings technology and research 17(2019), 1 vom: 06. Aug., Seite 157-169 volume:17 year:2019 number:1 day:06 month:08 pages:157-169
sourceStr	Enthalten in Journal of coatings technology and research 17(2019), 1 vom: 06. Aug., Seite 157-169 volume:17 year:2019 number:1 day:06 month:08 pages:157-169
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Transparent fire-retardant coating Layered double hydroxides Flame retardancy Smoke suppression Synergistic effect
dewey-raw	600
isfreeaccess_bool	false
container_title	Journal of coatings technology and research
authorswithroles_txt_mv	Xu, Zhisheng @@aut@@ Deng, Nan @@aut@@ Yan, Long @@aut@@
publishDateDaySort_date	2019-08-06T00:00:00Z
hierarchy_top_id	51834584X
dewey-sort	3600
id	SPR02364513X
language_de	englisch
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author	Xu, Zhisheng
spellingShingle	Xu, Zhisheng ddc 600 misc Transparent fire-retardant coating misc Layered double hydroxides misc Flame retardancy misc Smoke suppression misc Synergistic effect Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides
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topic_title	600 ASE Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides Transparent fire-retardant coating (dpeaa)DE-He213 Layered double hydroxides (dpeaa)DE-He213 Flame retardancy (dpeaa)DE-He213 Smoke suppression (dpeaa)DE-He213 Synergistic effect (dpeaa)DE-He213
topic	ddc 600 misc Transparent fire-retardant coating misc Layered double hydroxides misc Flame retardancy misc Smoke suppression misc Synergistic effect
topic_unstemmed	ddc 600 misc Transparent fire-retardant coating misc Layered double hydroxides misc Flame retardancy misc Smoke suppression misc Synergistic effect
topic_browse	ddc 600 misc Transparent fire-retardant coating misc Layered double hydroxides misc Flame retardancy misc Smoke suppression misc Synergistic effect
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title	Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides
ctrlnum	(DE-627)SPR02364513X (SPR)s11998-019-00249-8-e
title_full	Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides
author_sort	Xu, Zhisheng
journal	Journal of coatings technology and research
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author_browse	Xu, Zhisheng Deng, Nan Yan, Long
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author-letter	Xu, Zhisheng
doi_str_mv	10.1007/s11998-019-00249-8
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title_sort	flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides
title_auth	Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides
abstract	Abstract A series of novel layered double hydroxide (LDH)-modified phosphate esters (LPPBs) flame retardants were synthesized by the reaction of flexible phosphate ester (PPB) and LDHs with different mass ratio and then well characterized by Fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance spectroscopy (1H NMR). The obtained LPPBs were mixed with melamine formaldehyde resin to produce transparent fire-retardant coatings applied on wood substrates. The coatings containing LDHs exhibit a high degree of transparency even at high LDH contents due to the well dispersed and completely exfoliated state of LDHs in the amino matrix, as determined from the results of X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images. The fire protection tests show that the values of weight loss, char index, and flame spread rating of the coatings are remarkably decreased with the introduction of LDHs concomitant with an increase in the intumescent factor. The cone calorimeter and smoke density tests show that the flame retardancy and smoke suppression properties of the coatings are significantly improved with the introduction of LDHs due to the formation of a more compact, continuous, and intumescent char during combustion. The results of thermogravimetric (TG) analysis show that the thermal stability and residual weight of the coatings are gradually increased with increasing LDH content. Char residue analysis shows that the introduction of LDHs into the coatings contributes to generating more phosphorus-rich crosslinking structures and aromatic structures in the condensed phase that produce a more compact and thermally stable char against the release of heat and smoke, thus exhibiting excellent flame retardancy and smoke suppression properties.
abstractGer	Abstract A series of novel layered double hydroxide (LDH)-modified phosphate esters (LPPBs) flame retardants were synthesized by the reaction of flexible phosphate ester (PPB) and LDHs with different mass ratio and then well characterized by Fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance spectroscopy (1H NMR). The obtained LPPBs were mixed with melamine formaldehyde resin to produce transparent fire-retardant coatings applied on wood substrates. The coatings containing LDHs exhibit a high degree of transparency even at high LDH contents due to the well dispersed and completely exfoliated state of LDHs in the amino matrix, as determined from the results of X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images. The fire protection tests show that the values of weight loss, char index, and flame spread rating of the coatings are remarkably decreased with the introduction of LDHs concomitant with an increase in the intumescent factor. The cone calorimeter and smoke density tests show that the flame retardancy and smoke suppression properties of the coatings are significantly improved with the introduction of LDHs due to the formation of a more compact, continuous, and intumescent char during combustion. The results of thermogravimetric (TG) analysis show that the thermal stability and residual weight of the coatings are gradually increased with increasing LDH content. Char residue analysis shows that the introduction of LDHs into the coatings contributes to generating more phosphorus-rich crosslinking structures and aromatic structures in the condensed phase that produce a more compact and thermally stable char against the release of heat and smoke, thus exhibiting excellent flame retardancy and smoke suppression properties.
abstract_unstemmed	Abstract A series of novel layered double hydroxide (LDH)-modified phosphate esters (LPPBs) flame retardants were synthesized by the reaction of flexible phosphate ester (PPB) and LDHs with different mass ratio and then well characterized by Fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance spectroscopy (1H NMR). The obtained LPPBs were mixed with melamine formaldehyde resin to produce transparent fire-retardant coatings applied on wood substrates. The coatings containing LDHs exhibit a high degree of transparency even at high LDH contents due to the well dispersed and completely exfoliated state of LDHs in the amino matrix, as determined from the results of X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images. The fire protection tests show that the values of weight loss, char index, and flame spread rating of the coatings are remarkably decreased with the introduction of LDHs concomitant with an increase in the intumescent factor. The cone calorimeter and smoke density tests show that the flame retardancy and smoke suppression properties of the coatings are significantly improved with the introduction of LDHs due to the formation of a more compact, continuous, and intumescent char during combustion. The results of thermogravimetric (TG) analysis show that the thermal stability and residual weight of the coatings are gradually increased with increasing LDH content. Char residue analysis shows that the introduction of LDHs into the coatings contributes to generating more phosphorus-rich crosslinking structures and aromatic structures in the condensed phase that produce a more compact and thermally stable char against the release of heat and smoke, thus exhibiting excellent flame retardancy and smoke suppression properties.
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title_short	Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides
url	https://dx.doi.org/10.1007/s11998-019-00249-8
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author2	Deng, Nan Yan, Long
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doi_str	10.1007/s11998-019-00249-8
up_date	2024-07-03T20:20:41.307Z
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fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR02364513X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20220111103110.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2019 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11998-019-00249-8</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR02364513X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11998-019-00249-8-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">600</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Xu, Zhisheng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract A series of novel layered double hydroxide (LDH)-modified phosphate esters (LPPBs) flame retardants were synthesized by the reaction of flexible phosphate ester (PPB) and LDHs with different mass ratio and then well characterized by Fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance spectroscopy (1H NMR). The obtained LPPBs were mixed with melamine formaldehyde resin to produce transparent fire-retardant coatings applied on wood substrates. The coatings containing LDHs exhibit a high degree of transparency even at high LDH contents due to the well dispersed and completely exfoliated state of LDHs in the amino matrix, as determined from the results of X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images. The fire protection tests show that the values of weight loss, char index, and flame spread rating of the coatings are remarkably decreased with the introduction of LDHs concomitant with an increase in the intumescent factor. The cone calorimeter and smoke density tests show that the flame retardancy and smoke suppression properties of the coatings are significantly improved with the introduction of LDHs due to the formation of a more compact, continuous, and intumescent char during combustion. The results of thermogravimetric (TG) analysis show that the thermal stability and residual weight of the coatings are gradually increased with increasing LDH content. Char residue analysis shows that the introduction of LDHs into the coatings contributes to generating more phosphorus-rich crosslinking structures and aromatic structures in the condensed phase that produce a more compact and thermally stable char against the release of heat and smoke, thus exhibiting excellent flame retardancy and smoke suppression properties.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Transparent fire-retardant coating</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Layered double hydroxides</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Flame retardancy</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Smoke suppression</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Synergistic effect</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Deng, Nan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yan, Long</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of coatings technology and research</subfield><subfield code="d">Blue Bell, Pa., 2004</subfield><subfield code="g">17(2019), 1 vom: 06. 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Flame retardancy and smoke suppression properties of transparent intumescent fire-retardant coatings reinforced with layered double hydroxides

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