Nitrogen, phosphorus co-doped carbon cloth as self-standing electrode for lithium-iodine batteries
Abstract Rechargeable lithium-iodine (Li-$ I_{2} $) battery is a promising energy storage system because of the high energy and power density. However, the shuttle effects of iodine species and the unstable features of $ I_{2} $ block the practical applications of Li-$ I_{2} $ batteries. Herein, a d...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Li, Kang [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2018 |
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| Schlagwörter: |
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| Anmerkung: |
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
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| Übergeordnetes Werk: |
Enthalten in: Nano research - [S.l.] : Tsinghua Press, 2008, 12(2018), 3 vom: 03. Dez., Seite 549-555 |
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| Übergeordnetes Werk: |
volume:12 ; year:2018 ; number:3 ; day:03 ; month:12 ; pages:549-555 |
| Links: |
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| DOI / URN: |
10.1007/s12274-018-2251-1 |
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| Katalog-ID: |
SPR024732087 |
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| 520 | |a Abstract Rechargeable lithium-iodine (Li-$ I_{2} $) battery is a promising energy storage system because of the high energy and power density. However, the shuttle effects of iodine species and the unstable features of $ I_{2} $ block the practical applications of Li-$ I_{2} $ batteries. Herein, a dual heteroatom doped porous carbon cloth is fabricated as the host material for lithium iodide (LiI). Specifically, the self-standing nitrogen, phosphorus co-doped carbon cloth with high LiI loading exhibits a large specific capacity (221 mAh·$ g^{−1} $ at 1 C), excellent rate capability (95.8% capacity retention at 5 C) and superior long cycling stability (2,000 cycles with a capacity retention of 96%). Electrochemical kinetic analysis confirms the dominant contribution of capacitive effects at high scan rates, which is responsible for the good high-rate performance. The improved electrochemical performance mainly stems from two unique features of nitrogen, phosphorus co-doped porous carbon cloth. Heteroatom doping provides extra active sites for strong adsorption of iodine species while the highly porous structure with large surface area favors the capacitive effects at high rates. This work provides a facile yet efficient approach to regulating both redox reaction and capacitive effects via adjusting surface composition and pore structure of carbon materials for enhanced battery performance. | ||
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| 650 | 4 | |a heteroatom doping |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a self-standing |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a capacitive effect |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a porous carbon |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Chen, Song |4 aut | |
| 700 | 1 | |a Chen, Si |4 aut | |
| 700 | 1 | |a Liu, Xien |4 aut | |
| 700 | 1 | |a Pan, Wei |4 aut | |
| 700 | 1 | |a Zhang, Jintao |4 aut | |
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10.1007/s12274-018-2251-1 doi (DE-627)SPR024732087 (SPR)s12274-018-2251-1-e DE-627 ger DE-627 rakwb eng Li, Kang verfasserin aut Nitrogen, phosphorus co-doped carbon cloth as self-standing electrode for lithium-iodine batteries 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Rechargeable lithium-iodine (Li-$ I_{2} $) battery is a promising energy storage system because of the high energy and power density. However, the shuttle effects of iodine species and the unstable features of $ I_{2} $ block the practical applications of Li-$ I_{2} $ batteries. Herein, a dual heteroatom doped porous carbon cloth is fabricated as the host material for lithium iodide (LiI). Specifically, the self-standing nitrogen, phosphorus co-doped carbon cloth with high LiI loading exhibits a large specific capacity (221 mAh·$ g^{−1} $ at 1 C), excellent rate capability (95.8% capacity retention at 5 C) and superior long cycling stability (2,000 cycles with a capacity retention of 96%). Electrochemical kinetic analysis confirms the dominant contribution of capacitive effects at high scan rates, which is responsible for the good high-rate performance. The improved electrochemical performance mainly stems from two unique features of nitrogen, phosphorus co-doped porous carbon cloth. Heteroatom doping provides extra active sites for strong adsorption of iodine species while the highly porous structure with large surface area favors the capacitive effects at high rates. This work provides a facile yet efficient approach to regulating both redox reaction and capacitive effects via adjusting surface composition and pore structure of carbon materials for enhanced battery performance. iodine (dpeaa)DE-He213 heteroatom doping (dpeaa)DE-He213 self-standing (dpeaa)DE-He213 capacitive effect (dpeaa)DE-He213 porous carbon (dpeaa)DE-He213 Chen, Song aut Chen, Si aut Liu, Xien aut Pan, Wei aut Zhang, Jintao aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 12(2018), 3 vom: 03. Dez., Seite 549-555 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:12 year:2018 number:3 day:03 month:12 pages:549-555 https://dx.doi.org/10.1007/s12274-018-2251-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 12 2018 3 03 12 549-555 |
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10.1007/s12274-018-2251-1 doi (DE-627)SPR024732087 (SPR)s12274-018-2251-1-e DE-627 ger DE-627 rakwb eng Li, Kang verfasserin aut Nitrogen, phosphorus co-doped carbon cloth as self-standing electrode for lithium-iodine batteries 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Rechargeable lithium-iodine (Li-$ I_{2} $) battery is a promising energy storage system because of the high energy and power density. However, the shuttle effects of iodine species and the unstable features of $ I_{2} $ block the practical applications of Li-$ I_{2} $ batteries. Herein, a dual heteroatom doped porous carbon cloth is fabricated as the host material for lithium iodide (LiI). Specifically, the self-standing nitrogen, phosphorus co-doped carbon cloth with high LiI loading exhibits a large specific capacity (221 mAh·$ g^{−1} $ at 1 C), excellent rate capability (95.8% capacity retention at 5 C) and superior long cycling stability (2,000 cycles with a capacity retention of 96%). Electrochemical kinetic analysis confirms the dominant contribution of capacitive effects at high scan rates, which is responsible for the good high-rate performance. The improved electrochemical performance mainly stems from two unique features of nitrogen, phosphorus co-doped porous carbon cloth. Heteroatom doping provides extra active sites for strong adsorption of iodine species while the highly porous structure with large surface area favors the capacitive effects at high rates. This work provides a facile yet efficient approach to regulating both redox reaction and capacitive effects via adjusting surface composition and pore structure of carbon materials for enhanced battery performance. iodine (dpeaa)DE-He213 heteroatom doping (dpeaa)DE-He213 self-standing (dpeaa)DE-He213 capacitive effect (dpeaa)DE-He213 porous carbon (dpeaa)DE-He213 Chen, Song aut Chen, Si aut Liu, Xien aut Pan, Wei aut Zhang, Jintao aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 12(2018), 3 vom: 03. Dez., Seite 549-555 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:12 year:2018 number:3 day:03 month:12 pages:549-555 https://dx.doi.org/10.1007/s12274-018-2251-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 12 2018 3 03 12 549-555 |
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10.1007/s12274-018-2251-1 doi (DE-627)SPR024732087 (SPR)s12274-018-2251-1-e DE-627 ger DE-627 rakwb eng Li, Kang verfasserin aut Nitrogen, phosphorus co-doped carbon cloth as self-standing electrode for lithium-iodine batteries 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Rechargeable lithium-iodine (Li-$ I_{2} $) battery is a promising energy storage system because of the high energy and power density. However, the shuttle effects of iodine species and the unstable features of $ I_{2} $ block the practical applications of Li-$ I_{2} $ batteries. Herein, a dual heteroatom doped porous carbon cloth is fabricated as the host material for lithium iodide (LiI). Specifically, the self-standing nitrogen, phosphorus co-doped carbon cloth with high LiI loading exhibits a large specific capacity (221 mAh·$ g^{−1} $ at 1 C), excellent rate capability (95.8% capacity retention at 5 C) and superior long cycling stability (2,000 cycles with a capacity retention of 96%). Electrochemical kinetic analysis confirms the dominant contribution of capacitive effects at high scan rates, which is responsible for the good high-rate performance. The improved electrochemical performance mainly stems from two unique features of nitrogen, phosphorus co-doped porous carbon cloth. Heteroatom doping provides extra active sites for strong adsorption of iodine species while the highly porous structure with large surface area favors the capacitive effects at high rates. This work provides a facile yet efficient approach to regulating both redox reaction and capacitive effects via adjusting surface composition and pore structure of carbon materials for enhanced battery performance. iodine (dpeaa)DE-He213 heteroatom doping (dpeaa)DE-He213 self-standing (dpeaa)DE-He213 capacitive effect (dpeaa)DE-He213 porous carbon (dpeaa)DE-He213 Chen, Song aut Chen, Si aut Liu, Xien aut Pan, Wei aut Zhang, Jintao aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 12(2018), 3 vom: 03. Dez., Seite 549-555 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:12 year:2018 number:3 day:03 month:12 pages:549-555 https://dx.doi.org/10.1007/s12274-018-2251-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 12 2018 3 03 12 549-555 |
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10.1007/s12274-018-2251-1 doi (DE-627)SPR024732087 (SPR)s12274-018-2251-1-e DE-627 ger DE-627 rakwb eng Li, Kang verfasserin aut Nitrogen, phosphorus co-doped carbon cloth as self-standing electrode for lithium-iodine batteries 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Rechargeable lithium-iodine (Li-$ I_{2} $) battery is a promising energy storage system because of the high energy and power density. However, the shuttle effects of iodine species and the unstable features of $ I_{2} $ block the practical applications of Li-$ I_{2} $ batteries. Herein, a dual heteroatom doped porous carbon cloth is fabricated as the host material for lithium iodide (LiI). Specifically, the self-standing nitrogen, phosphorus co-doped carbon cloth with high LiI loading exhibits a large specific capacity (221 mAh·$ g^{−1} $ at 1 C), excellent rate capability (95.8% capacity retention at 5 C) and superior long cycling stability (2,000 cycles with a capacity retention of 96%). Electrochemical kinetic analysis confirms the dominant contribution of capacitive effects at high scan rates, which is responsible for the good high-rate performance. The improved electrochemical performance mainly stems from two unique features of nitrogen, phosphorus co-doped porous carbon cloth. Heteroatom doping provides extra active sites for strong adsorption of iodine species while the highly porous structure with large surface area favors the capacitive effects at high rates. This work provides a facile yet efficient approach to regulating both redox reaction and capacitive effects via adjusting surface composition and pore structure of carbon materials for enhanced battery performance. iodine (dpeaa)DE-He213 heteroatom doping (dpeaa)DE-He213 self-standing (dpeaa)DE-He213 capacitive effect (dpeaa)DE-He213 porous carbon (dpeaa)DE-He213 Chen, Song aut Chen, Si aut Liu, Xien aut Pan, Wei aut Zhang, Jintao aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 12(2018), 3 vom: 03. Dez., Seite 549-555 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:12 year:2018 number:3 day:03 month:12 pages:549-555 https://dx.doi.org/10.1007/s12274-018-2251-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 12 2018 3 03 12 549-555 |
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10.1007/s12274-018-2251-1 doi (DE-627)SPR024732087 (SPR)s12274-018-2251-1-e DE-627 ger DE-627 rakwb eng Li, Kang verfasserin aut Nitrogen, phosphorus co-doped carbon cloth as self-standing electrode for lithium-iodine batteries 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Rechargeable lithium-iodine (Li-$ I_{2} $) battery is a promising energy storage system because of the high energy and power density. However, the shuttle effects of iodine species and the unstable features of $ I_{2} $ block the practical applications of Li-$ I_{2} $ batteries. Herein, a dual heteroatom doped porous carbon cloth is fabricated as the host material for lithium iodide (LiI). Specifically, the self-standing nitrogen, phosphorus co-doped carbon cloth with high LiI loading exhibits a large specific capacity (221 mAh·$ g^{−1} $ at 1 C), excellent rate capability (95.8% capacity retention at 5 C) and superior long cycling stability (2,000 cycles with a capacity retention of 96%). Electrochemical kinetic analysis confirms the dominant contribution of capacitive effects at high scan rates, which is responsible for the good high-rate performance. The improved electrochemical performance mainly stems from two unique features of nitrogen, phosphorus co-doped porous carbon cloth. Heteroatom doping provides extra active sites for strong adsorption of iodine species while the highly porous structure with large surface area favors the capacitive effects at high rates. This work provides a facile yet efficient approach to regulating both redox reaction and capacitive effects via adjusting surface composition and pore structure of carbon materials for enhanced battery performance. iodine (dpeaa)DE-He213 heteroatom doping (dpeaa)DE-He213 self-standing (dpeaa)DE-He213 capacitive effect (dpeaa)DE-He213 porous carbon (dpeaa)DE-He213 Chen, Song aut Chen, Si aut Liu, Xien aut Pan, Wei aut Zhang, Jintao aut Enthalten in Nano research [S.l.] : Tsinghua Press, 2008 12(2018), 3 vom: 03. Dez., Seite 549-555 (DE-627)57375361X (DE-600)2442216-2 1998-0000 nnns volume:12 year:2018 number:3 day:03 month:12 pages:549-555 https://dx.doi.org/10.1007/s12274-018-2251-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 12 2018 3 03 12 549-555 |
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Enthalten in Nano research 12(2018), 3 vom: 03. Dez., Seite 549-555 volume:12 year:2018 number:3 day:03 month:12 pages:549-555 |
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Enthalten in Nano research 12(2018), 3 vom: 03. Dez., Seite 549-555 volume:12 year:2018 number:3 day:03 month:12 pages:549-555 |
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Li, Kang @@aut@@ Chen, Song @@aut@@ Chen, Si @@aut@@ Liu, Xien @@aut@@ Pan, Wei @@aut@@ Zhang, Jintao @@aut@@ |
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However, the shuttle effects of iodine species and the unstable features of $ I_{2} $ block the practical applications of Li-$ I_{2} $ batteries. Herein, a dual heteroatom doped porous carbon cloth is fabricated as the host material for lithium iodide (LiI). Specifically, the self-standing nitrogen, phosphorus co-doped carbon cloth with high LiI loading exhibits a large specific capacity (221 mAh·$ g^{−1} $ at 1 C), excellent rate capability (95.8% capacity retention at 5 C) and superior long cycling stability (2,000 cycles with a capacity retention of 96%). Electrochemical kinetic analysis confirms the dominant contribution of capacitive effects at high scan rates, which is responsible for the good high-rate performance. The improved electrochemical performance mainly stems from two unique features of nitrogen, phosphorus co-doped porous carbon cloth. Heteroatom doping provides extra active sites for strong adsorption of iodine species while the highly porous structure with large surface area favors the capacitive effects at high rates. 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Li, Kang |
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Li, Kang misc iodine misc heteroatom doping misc self-standing misc capacitive effect misc porous carbon Nitrogen, phosphorus co-doped carbon cloth as self-standing electrode for lithium-iodine batteries |
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Nitrogen, phosphorus co-doped carbon cloth as self-standing electrode for lithium-iodine batteries iodine (dpeaa)DE-He213 heteroatom doping (dpeaa)DE-He213 self-standing (dpeaa)DE-He213 capacitive effect (dpeaa)DE-He213 porous carbon (dpeaa)DE-He213 |
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nitrogen, phosphorus co-doped carbon cloth as self-standing electrode for lithium-iodine batteries |
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Nitrogen, phosphorus co-doped carbon cloth as self-standing electrode for lithium-iodine batteries |
| abstract |
Abstract Rechargeable lithium-iodine (Li-$ I_{2} $) battery is a promising energy storage system because of the high energy and power density. However, the shuttle effects of iodine species and the unstable features of $ I_{2} $ block the practical applications of Li-$ I_{2} $ batteries. Herein, a dual heteroatom doped porous carbon cloth is fabricated as the host material for lithium iodide (LiI). Specifically, the self-standing nitrogen, phosphorus co-doped carbon cloth with high LiI loading exhibits a large specific capacity (221 mAh·$ g^{−1} $ at 1 C), excellent rate capability (95.8% capacity retention at 5 C) and superior long cycling stability (2,000 cycles with a capacity retention of 96%). Electrochemical kinetic analysis confirms the dominant contribution of capacitive effects at high scan rates, which is responsible for the good high-rate performance. The improved electrochemical performance mainly stems from two unique features of nitrogen, phosphorus co-doped porous carbon cloth. Heteroatom doping provides extra active sites for strong adsorption of iodine species while the highly porous structure with large surface area favors the capacitive effects at high rates. This work provides a facile yet efficient approach to regulating both redox reaction and capacitive effects via adjusting surface composition and pore structure of carbon materials for enhanced battery performance. © Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
| abstractGer |
Abstract Rechargeable lithium-iodine (Li-$ I_{2} $) battery is a promising energy storage system because of the high energy and power density. However, the shuttle effects of iodine species and the unstable features of $ I_{2} $ block the practical applications of Li-$ I_{2} $ batteries. Herein, a dual heteroatom doped porous carbon cloth is fabricated as the host material for lithium iodide (LiI). Specifically, the self-standing nitrogen, phosphorus co-doped carbon cloth with high LiI loading exhibits a large specific capacity (221 mAh·$ g^{−1} $ at 1 C), excellent rate capability (95.8% capacity retention at 5 C) and superior long cycling stability (2,000 cycles with a capacity retention of 96%). Electrochemical kinetic analysis confirms the dominant contribution of capacitive effects at high scan rates, which is responsible for the good high-rate performance. The improved electrochemical performance mainly stems from two unique features of nitrogen, phosphorus co-doped porous carbon cloth. Heteroatom doping provides extra active sites for strong adsorption of iodine species while the highly porous structure with large surface area favors the capacitive effects at high rates. This work provides a facile yet efficient approach to regulating both redox reaction and capacitive effects via adjusting surface composition and pore structure of carbon materials for enhanced battery performance. © Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
| abstract_unstemmed |
Abstract Rechargeable lithium-iodine (Li-$ I_{2} $) battery is a promising energy storage system because of the high energy and power density. However, the shuttle effects of iodine species and the unstable features of $ I_{2} $ block the practical applications of Li-$ I_{2} $ batteries. Herein, a dual heteroatom doped porous carbon cloth is fabricated as the host material for lithium iodide (LiI). Specifically, the self-standing nitrogen, phosphorus co-doped carbon cloth with high LiI loading exhibits a large specific capacity (221 mAh·$ g^{−1} $ at 1 C), excellent rate capability (95.8% capacity retention at 5 C) and superior long cycling stability (2,000 cycles with a capacity retention of 96%). Electrochemical kinetic analysis confirms the dominant contribution of capacitive effects at high scan rates, which is responsible for the good high-rate performance. The improved electrochemical performance mainly stems from two unique features of nitrogen, phosphorus co-doped porous carbon cloth. Heteroatom doping provides extra active sites for strong adsorption of iodine species while the highly porous structure with large surface area favors the capacitive effects at high rates. This work provides a facile yet efficient approach to regulating both redox reaction and capacitive effects via adjusting surface composition and pore structure of carbon materials for enhanced battery performance. © Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
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Nitrogen, phosphorus co-doped carbon cloth as self-standing electrode for lithium-iodine batteries |
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https://dx.doi.org/10.1007/s12274-018-2251-1 |
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| author2 |
Chen, Song Chen, Si Liu, Xien Pan, Wei Zhang, Jintao |
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Chen, Song Chen, Si Liu, Xien Pan, Wei Zhang, Jintao |
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10.1007/s12274-018-2251-1 |
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2024-07-04T02:10:17.826Z |
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| score |
7.3972845 |