A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils
Abstract Based on the conclusions of the European Food Safety Authority (EFSA), the four polycyclic aromatic hydrocarbons (PAH4) chrysene (Chr), benzo(a)anthracene (BaA), benzo(a)pyrene (BaP), and benzo(b)fluoranthene (BbF) are new markers for the occurrence of PAHs in food. Vegetable oils are extre...
Ausführliche Beschreibung
Autor*in: |
Liu, Yi-Hong [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2016 |
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Schlagwörter: |
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Anmerkung: |
© Springer Science+Business Media New York 2016 |
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Übergeordnetes Werk: |
Enthalten in: Food analytical methods - New York, NY : Springer, 2008, 9(2016), 11 vom: 27. Apr., Seite 3209-3217 |
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Übergeordnetes Werk: |
volume:9 ; year:2016 ; number:11 ; day:27 ; month:04 ; pages:3209-3217 |
Links: |
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DOI / URN: |
10.1007/s12161-016-0515-5 |
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Katalog-ID: |
SPR025142526 |
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245 | 1 | 2 | |a A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils |
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520 | |a Abstract Based on the conclusions of the European Food Safety Authority (EFSA), the four polycyclic aromatic hydrocarbons (PAH4) chrysene (Chr), benzo(a)anthracene (BaA), benzo(a)pyrene (BaP), and benzo(b)fluoranthene (BbF) are new markers for the occurrence of PAHs in food. Vegetable oils are extremely easily contaminated by PAHs, due to the raw material pollution and the imperfections of processing techniques. Therefore, it is of great importance to establish an efficient method for the rapid determination of PAH4 in vegetable oils. In this research, second-derivative nonlinear variable-angle-matrix isopotential synchronous fluorescence spectroscopic approach has been proposed for the simultaneous and rapid determination of PAH4 in vegetable oils with ultrasonic-assisted extraction. This method is capable of resolving the spectra of these four PAHs well. The limits of detection (LODs) for Chr, BaA, BaP, and BbF were 13.0, 8.64, 0.16, and 7.68 μg $ kg^{−1} $, respectively. The recoveries in various oil samples for Chr, BaA, BaP, and BbF were 86.2 ± 15.3, 93.8 ± 11.7, 93.9 ± 12.1, and 94.3 ± 7.4 %, respectively, at the spiked levels of 10∼400 μg $ kg^{−1} $. The relative standard deviations (RSDs) achieved for Chr, BaA, BaP, and BbF were 3.0, 8.4, 6.3, and 7.2 %, respectively. The established method is simple, economical, and reliable, as well as provides an attractive alternative for the simultaneous and rapid determination of PAH4 in vegetable oils. | ||
650 | 4 | |a Synchronous fluorescence spectroscopy |7 (dpeaa)DE-He213 | |
650 | 4 | |a Vegetable oils |7 (dpeaa)DE-He213 | |
650 | 4 | |a Chrysene |7 (dpeaa)DE-He213 | |
650 | 4 | |a Benzo(a)anthracene |7 (dpeaa)DE-He213 | |
650 | 4 | |a Benzo(a)pyrene |7 (dpeaa)DE-He213 | |
650 | 4 | |a Benzo(b)fluoranthene |7 (dpeaa)DE-He213 | |
700 | 1 | |a Wu, Ping-Ping |4 aut | |
700 | 1 | |a Liu, Qian |4 aut | |
700 | 1 | |a Luo, He-Dong |4 aut | |
700 | 1 | |a Cao, Shuo-Hui |4 aut | |
700 | 1 | |a Lin, Guo-Chun |4 aut | |
700 | 1 | |a Fu, Dong-Sai |4 aut | |
700 | 1 | |a Zhong, Xiu-Di |4 aut | |
700 | 1 | |a Li, Yao-Qun |4 aut | |
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10.1007/s12161-016-0515-5 doi (DE-627)SPR025142526 (SPR)s12161-016-0515-5-e DE-627 ger DE-627 rakwb eng Liu, Yi-Hong verfasserin aut A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media New York 2016 Abstract Based on the conclusions of the European Food Safety Authority (EFSA), the four polycyclic aromatic hydrocarbons (PAH4) chrysene (Chr), benzo(a)anthracene (BaA), benzo(a)pyrene (BaP), and benzo(b)fluoranthene (BbF) are new markers for the occurrence of PAHs in food. Vegetable oils are extremely easily contaminated by PAHs, due to the raw material pollution and the imperfections of processing techniques. Therefore, it is of great importance to establish an efficient method for the rapid determination of PAH4 in vegetable oils. In this research, second-derivative nonlinear variable-angle-matrix isopotential synchronous fluorescence spectroscopic approach has been proposed for the simultaneous and rapid determination of PAH4 in vegetable oils with ultrasonic-assisted extraction. This method is capable of resolving the spectra of these four PAHs well. The limits of detection (LODs) for Chr, BaA, BaP, and BbF were 13.0, 8.64, 0.16, and 7.68 μg $ kg^{−1} $, respectively. The recoveries in various oil samples for Chr, BaA, BaP, and BbF were 86.2 ± 15.3, 93.8 ± 11.7, 93.9 ± 12.1, and 94.3 ± 7.4 %, respectively, at the spiked levels of 10∼400 μg $ kg^{−1} $. The relative standard deviations (RSDs) achieved for Chr, BaA, BaP, and BbF were 3.0, 8.4, 6.3, and 7.2 %, respectively. The established method is simple, economical, and reliable, as well as provides an attractive alternative for the simultaneous and rapid determination of PAH4 in vegetable oils. Synchronous fluorescence spectroscopy (dpeaa)DE-He213 Vegetable oils (dpeaa)DE-He213 Chrysene (dpeaa)DE-He213 Benzo(a)anthracene (dpeaa)DE-He213 Benzo(a)pyrene (dpeaa)DE-He213 Benzo(b)fluoranthene (dpeaa)DE-He213 Wu, Ping-Ping aut Liu, Qian aut Luo, He-Dong aut Cao, Shuo-Hui aut Lin, Guo-Chun aut Fu, Dong-Sai aut Zhong, Xiu-Di aut Li, Yao-Qun aut Enthalten in Food analytical methods New York, NY : Springer, 2008 9(2016), 11 vom: 27. Apr., Seite 3209-3217 (DE-627)566007320 (DE-600)2424728-5 1936-976X nnns volume:9 year:2016 number:11 day:27 month:04 pages:3209-3217 https://dx.doi.org/10.1007/s12161-016-0515-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 9 2016 11 27 04 3209-3217 |
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10.1007/s12161-016-0515-5 doi (DE-627)SPR025142526 (SPR)s12161-016-0515-5-e DE-627 ger DE-627 rakwb eng Liu, Yi-Hong verfasserin aut A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media New York 2016 Abstract Based on the conclusions of the European Food Safety Authority (EFSA), the four polycyclic aromatic hydrocarbons (PAH4) chrysene (Chr), benzo(a)anthracene (BaA), benzo(a)pyrene (BaP), and benzo(b)fluoranthene (BbF) are new markers for the occurrence of PAHs in food. Vegetable oils are extremely easily contaminated by PAHs, due to the raw material pollution and the imperfections of processing techniques. Therefore, it is of great importance to establish an efficient method for the rapid determination of PAH4 in vegetable oils. In this research, second-derivative nonlinear variable-angle-matrix isopotential synchronous fluorescence spectroscopic approach has been proposed for the simultaneous and rapid determination of PAH4 in vegetable oils with ultrasonic-assisted extraction. This method is capable of resolving the spectra of these four PAHs well. The limits of detection (LODs) for Chr, BaA, BaP, and BbF were 13.0, 8.64, 0.16, and 7.68 μg $ kg^{−1} $, respectively. The recoveries in various oil samples for Chr, BaA, BaP, and BbF were 86.2 ± 15.3, 93.8 ± 11.7, 93.9 ± 12.1, and 94.3 ± 7.4 %, respectively, at the spiked levels of 10∼400 μg $ kg^{−1} $. The relative standard deviations (RSDs) achieved for Chr, BaA, BaP, and BbF were 3.0, 8.4, 6.3, and 7.2 %, respectively. The established method is simple, economical, and reliable, as well as provides an attractive alternative for the simultaneous and rapid determination of PAH4 in vegetable oils. Synchronous fluorescence spectroscopy (dpeaa)DE-He213 Vegetable oils (dpeaa)DE-He213 Chrysene (dpeaa)DE-He213 Benzo(a)anthracene (dpeaa)DE-He213 Benzo(a)pyrene (dpeaa)DE-He213 Benzo(b)fluoranthene (dpeaa)DE-He213 Wu, Ping-Ping aut Liu, Qian aut Luo, He-Dong aut Cao, Shuo-Hui aut Lin, Guo-Chun aut Fu, Dong-Sai aut Zhong, Xiu-Di aut Li, Yao-Qun aut Enthalten in Food analytical methods New York, NY : Springer, 2008 9(2016), 11 vom: 27. Apr., Seite 3209-3217 (DE-627)566007320 (DE-600)2424728-5 1936-976X nnns volume:9 year:2016 number:11 day:27 month:04 pages:3209-3217 https://dx.doi.org/10.1007/s12161-016-0515-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 9 2016 11 27 04 3209-3217 |
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10.1007/s12161-016-0515-5 doi (DE-627)SPR025142526 (SPR)s12161-016-0515-5-e DE-627 ger DE-627 rakwb eng Liu, Yi-Hong verfasserin aut A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media New York 2016 Abstract Based on the conclusions of the European Food Safety Authority (EFSA), the four polycyclic aromatic hydrocarbons (PAH4) chrysene (Chr), benzo(a)anthracene (BaA), benzo(a)pyrene (BaP), and benzo(b)fluoranthene (BbF) are new markers for the occurrence of PAHs in food. Vegetable oils are extremely easily contaminated by PAHs, due to the raw material pollution and the imperfections of processing techniques. Therefore, it is of great importance to establish an efficient method for the rapid determination of PAH4 in vegetable oils. In this research, second-derivative nonlinear variable-angle-matrix isopotential synchronous fluorescence spectroscopic approach has been proposed for the simultaneous and rapid determination of PAH4 in vegetable oils with ultrasonic-assisted extraction. This method is capable of resolving the spectra of these four PAHs well. The limits of detection (LODs) for Chr, BaA, BaP, and BbF were 13.0, 8.64, 0.16, and 7.68 μg $ kg^{−1} $, respectively. The recoveries in various oil samples for Chr, BaA, BaP, and BbF were 86.2 ± 15.3, 93.8 ± 11.7, 93.9 ± 12.1, and 94.3 ± 7.4 %, respectively, at the spiked levels of 10∼400 μg $ kg^{−1} $. The relative standard deviations (RSDs) achieved for Chr, BaA, BaP, and BbF were 3.0, 8.4, 6.3, and 7.2 %, respectively. The established method is simple, economical, and reliable, as well as provides an attractive alternative for the simultaneous and rapid determination of PAH4 in vegetable oils. Synchronous fluorescence spectroscopy (dpeaa)DE-He213 Vegetable oils (dpeaa)DE-He213 Chrysene (dpeaa)DE-He213 Benzo(a)anthracene (dpeaa)DE-He213 Benzo(a)pyrene (dpeaa)DE-He213 Benzo(b)fluoranthene (dpeaa)DE-He213 Wu, Ping-Ping aut Liu, Qian aut Luo, He-Dong aut Cao, Shuo-Hui aut Lin, Guo-Chun aut Fu, Dong-Sai aut Zhong, Xiu-Di aut Li, Yao-Qun aut Enthalten in Food analytical methods New York, NY : Springer, 2008 9(2016), 11 vom: 27. Apr., Seite 3209-3217 (DE-627)566007320 (DE-600)2424728-5 1936-976X nnns volume:9 year:2016 number:11 day:27 month:04 pages:3209-3217 https://dx.doi.org/10.1007/s12161-016-0515-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 9 2016 11 27 04 3209-3217 |
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10.1007/s12161-016-0515-5 doi (DE-627)SPR025142526 (SPR)s12161-016-0515-5-e DE-627 ger DE-627 rakwb eng Liu, Yi-Hong verfasserin aut A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media New York 2016 Abstract Based on the conclusions of the European Food Safety Authority (EFSA), the four polycyclic aromatic hydrocarbons (PAH4) chrysene (Chr), benzo(a)anthracene (BaA), benzo(a)pyrene (BaP), and benzo(b)fluoranthene (BbF) are new markers for the occurrence of PAHs in food. Vegetable oils are extremely easily contaminated by PAHs, due to the raw material pollution and the imperfections of processing techniques. Therefore, it is of great importance to establish an efficient method for the rapid determination of PAH4 in vegetable oils. In this research, second-derivative nonlinear variable-angle-matrix isopotential synchronous fluorescence spectroscopic approach has been proposed for the simultaneous and rapid determination of PAH4 in vegetable oils with ultrasonic-assisted extraction. This method is capable of resolving the spectra of these four PAHs well. The limits of detection (LODs) for Chr, BaA, BaP, and BbF were 13.0, 8.64, 0.16, and 7.68 μg $ kg^{−1} $, respectively. The recoveries in various oil samples for Chr, BaA, BaP, and BbF were 86.2 ± 15.3, 93.8 ± 11.7, 93.9 ± 12.1, and 94.3 ± 7.4 %, respectively, at the spiked levels of 10∼400 μg $ kg^{−1} $. The relative standard deviations (RSDs) achieved for Chr, BaA, BaP, and BbF were 3.0, 8.4, 6.3, and 7.2 %, respectively. The established method is simple, economical, and reliable, as well as provides an attractive alternative for the simultaneous and rapid determination of PAH4 in vegetable oils. Synchronous fluorescence spectroscopy (dpeaa)DE-He213 Vegetable oils (dpeaa)DE-He213 Chrysene (dpeaa)DE-He213 Benzo(a)anthracene (dpeaa)DE-He213 Benzo(a)pyrene (dpeaa)DE-He213 Benzo(b)fluoranthene (dpeaa)DE-He213 Wu, Ping-Ping aut Liu, Qian aut Luo, He-Dong aut Cao, Shuo-Hui aut Lin, Guo-Chun aut Fu, Dong-Sai aut Zhong, Xiu-Di aut Li, Yao-Qun aut Enthalten in Food analytical methods New York, NY : Springer, 2008 9(2016), 11 vom: 27. Apr., Seite 3209-3217 (DE-627)566007320 (DE-600)2424728-5 1936-976X nnns volume:9 year:2016 number:11 day:27 month:04 pages:3209-3217 https://dx.doi.org/10.1007/s12161-016-0515-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 9 2016 11 27 04 3209-3217 |
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10.1007/s12161-016-0515-5 doi (DE-627)SPR025142526 (SPR)s12161-016-0515-5-e DE-627 ger DE-627 rakwb eng Liu, Yi-Hong verfasserin aut A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Science+Business Media New York 2016 Abstract Based on the conclusions of the European Food Safety Authority (EFSA), the four polycyclic aromatic hydrocarbons (PAH4) chrysene (Chr), benzo(a)anthracene (BaA), benzo(a)pyrene (BaP), and benzo(b)fluoranthene (BbF) are new markers for the occurrence of PAHs in food. Vegetable oils are extremely easily contaminated by PAHs, due to the raw material pollution and the imperfections of processing techniques. Therefore, it is of great importance to establish an efficient method for the rapid determination of PAH4 in vegetable oils. In this research, second-derivative nonlinear variable-angle-matrix isopotential synchronous fluorescence spectroscopic approach has been proposed for the simultaneous and rapid determination of PAH4 in vegetable oils with ultrasonic-assisted extraction. This method is capable of resolving the spectra of these four PAHs well. The limits of detection (LODs) for Chr, BaA, BaP, and BbF were 13.0, 8.64, 0.16, and 7.68 μg $ kg^{−1} $, respectively. The recoveries in various oil samples for Chr, BaA, BaP, and BbF were 86.2 ± 15.3, 93.8 ± 11.7, 93.9 ± 12.1, and 94.3 ± 7.4 %, respectively, at the spiked levels of 10∼400 μg $ kg^{−1} $. The relative standard deviations (RSDs) achieved for Chr, BaA, BaP, and BbF were 3.0, 8.4, 6.3, and 7.2 %, respectively. The established method is simple, economical, and reliable, as well as provides an attractive alternative for the simultaneous and rapid determination of PAH4 in vegetable oils. Synchronous fluorescence spectroscopy (dpeaa)DE-He213 Vegetable oils (dpeaa)DE-He213 Chrysene (dpeaa)DE-He213 Benzo(a)anthracene (dpeaa)DE-He213 Benzo(a)pyrene (dpeaa)DE-He213 Benzo(b)fluoranthene (dpeaa)DE-He213 Wu, Ping-Ping aut Liu, Qian aut Luo, He-Dong aut Cao, Shuo-Hui aut Lin, Guo-Chun aut Fu, Dong-Sai aut Zhong, Xiu-Di aut Li, Yao-Qun aut Enthalten in Food analytical methods New York, NY : Springer, 2008 9(2016), 11 vom: 27. Apr., Seite 3209-3217 (DE-627)566007320 (DE-600)2424728-5 1936-976X nnns volume:9 year:2016 number:11 day:27 month:04 pages:3209-3217 https://dx.doi.org/10.1007/s12161-016-0515-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 9 2016 11 27 04 3209-3217 |
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Enthalten in Food analytical methods 9(2016), 11 vom: 27. Apr., Seite 3209-3217 volume:9 year:2016 number:11 day:27 month:04 pages:3209-3217 |
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Synchronous fluorescence spectroscopy Vegetable oils Chrysene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene |
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Liu, Yi-Hong @@aut@@ Wu, Ping-Ping @@aut@@ Liu, Qian @@aut@@ Luo, He-Dong @@aut@@ Cao, Shuo-Hui @@aut@@ Lin, Guo-Chun @@aut@@ Fu, Dong-Sai @@aut@@ Zhong, Xiu-Di @@aut@@ Li, Yao-Qun @@aut@@ |
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2016-04-27T00:00:00Z |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR025142526</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519221501.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201007s2016 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s12161-016-0515-5</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR025142526</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s12161-016-0515-5-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Liu, Yi-Hong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="2"><subfield code="a">A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2016</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media New York 2016</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Based on the conclusions of the European Food Safety Authority (EFSA), the four polycyclic aromatic hydrocarbons (PAH4) chrysene (Chr), benzo(a)anthracene (BaA), benzo(a)pyrene (BaP), and benzo(b)fluoranthene (BbF) are new markers for the occurrence of PAHs in food. Vegetable oils are extremely easily contaminated by PAHs, due to the raw material pollution and the imperfections of processing techniques. Therefore, it is of great importance to establish an efficient method for the rapid determination of PAH4 in vegetable oils. In this research, second-derivative nonlinear variable-angle-matrix isopotential synchronous fluorescence spectroscopic approach has been proposed for the simultaneous and rapid determination of PAH4 in vegetable oils with ultrasonic-assisted extraction. This method is capable of resolving the spectra of these four PAHs well. The limits of detection (LODs) for Chr, BaA, BaP, and BbF were 13.0, 8.64, 0.16, and 7.68 μg $ kg^{−1} $, respectively. The recoveries in various oil samples for Chr, BaA, BaP, and BbF were 86.2 ± 15.3, 93.8 ± 11.7, 93.9 ± 12.1, and 94.3 ± 7.4 %, respectively, at the spiked levels of 10∼400 μg $ kg^{−1} $. The relative standard deviations (RSDs) achieved for Chr, BaA, BaP, and BbF were 3.0, 8.4, 6.3, and 7.2 %, respectively. 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author |
Liu, Yi-Hong |
spellingShingle |
Liu, Yi-Hong misc Synchronous fluorescence spectroscopy misc Vegetable oils misc Chrysene misc Benzo(a)anthracene misc Benzo(a)pyrene misc Benzo(b)fluoranthene A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils |
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A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils Synchronous fluorescence spectroscopy (dpeaa)DE-He213 Vegetable oils (dpeaa)DE-He213 Chrysene (dpeaa)DE-He213 Benzo(a)anthracene (dpeaa)DE-He213 Benzo(a)pyrene (dpeaa)DE-He213 Benzo(b)fluoranthene (dpeaa)DE-He213 |
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misc Synchronous fluorescence spectroscopy misc Vegetable oils misc Chrysene misc Benzo(a)anthracene misc Benzo(a)pyrene misc Benzo(b)fluoranthene |
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misc Synchronous fluorescence spectroscopy misc Vegetable oils misc Chrysene misc Benzo(a)anthracene misc Benzo(a)pyrene misc Benzo(b)fluoranthene |
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A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils |
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A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils |
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Liu, Yi-Hong Wu, Ping-Ping Liu, Qian Luo, He-Dong Cao, Shuo-Hui Lin, Guo-Chun Fu, Dong-Sai Zhong, Xiu-Di Li, Yao-Qun |
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Liu, Yi-Hong |
doi_str_mv |
10.1007/s12161-016-0515-5 |
title_sort |
simple fluorescence spectroscopic approach for simultaneous and rapid detection of four polycyclic aromatic hydrocarbons (pah4) in vegetable oils |
title_auth |
A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils |
abstract |
Abstract Based on the conclusions of the European Food Safety Authority (EFSA), the four polycyclic aromatic hydrocarbons (PAH4) chrysene (Chr), benzo(a)anthracene (BaA), benzo(a)pyrene (BaP), and benzo(b)fluoranthene (BbF) are new markers for the occurrence of PAHs in food. Vegetable oils are extremely easily contaminated by PAHs, due to the raw material pollution and the imperfections of processing techniques. Therefore, it is of great importance to establish an efficient method for the rapid determination of PAH4 in vegetable oils. In this research, second-derivative nonlinear variable-angle-matrix isopotential synchronous fluorescence spectroscopic approach has been proposed for the simultaneous and rapid determination of PAH4 in vegetable oils with ultrasonic-assisted extraction. This method is capable of resolving the spectra of these four PAHs well. The limits of detection (LODs) for Chr, BaA, BaP, and BbF were 13.0, 8.64, 0.16, and 7.68 μg $ kg^{−1} $, respectively. The recoveries in various oil samples for Chr, BaA, BaP, and BbF were 86.2 ± 15.3, 93.8 ± 11.7, 93.9 ± 12.1, and 94.3 ± 7.4 %, respectively, at the spiked levels of 10∼400 μg $ kg^{−1} $. The relative standard deviations (RSDs) achieved for Chr, BaA, BaP, and BbF were 3.0, 8.4, 6.3, and 7.2 %, respectively. The established method is simple, economical, and reliable, as well as provides an attractive alternative for the simultaneous and rapid determination of PAH4 in vegetable oils. © Springer Science+Business Media New York 2016 |
abstractGer |
Abstract Based on the conclusions of the European Food Safety Authority (EFSA), the four polycyclic aromatic hydrocarbons (PAH4) chrysene (Chr), benzo(a)anthracene (BaA), benzo(a)pyrene (BaP), and benzo(b)fluoranthene (BbF) are new markers for the occurrence of PAHs in food. Vegetable oils are extremely easily contaminated by PAHs, due to the raw material pollution and the imperfections of processing techniques. Therefore, it is of great importance to establish an efficient method for the rapid determination of PAH4 in vegetable oils. In this research, second-derivative nonlinear variable-angle-matrix isopotential synchronous fluorescence spectroscopic approach has been proposed for the simultaneous and rapid determination of PAH4 in vegetable oils with ultrasonic-assisted extraction. This method is capable of resolving the spectra of these four PAHs well. The limits of detection (LODs) for Chr, BaA, BaP, and BbF were 13.0, 8.64, 0.16, and 7.68 μg $ kg^{−1} $, respectively. The recoveries in various oil samples for Chr, BaA, BaP, and BbF were 86.2 ± 15.3, 93.8 ± 11.7, 93.9 ± 12.1, and 94.3 ± 7.4 %, respectively, at the spiked levels of 10∼400 μg $ kg^{−1} $. The relative standard deviations (RSDs) achieved for Chr, BaA, BaP, and BbF were 3.0, 8.4, 6.3, and 7.2 %, respectively. The established method is simple, economical, and reliable, as well as provides an attractive alternative for the simultaneous and rapid determination of PAH4 in vegetable oils. © Springer Science+Business Media New York 2016 |
abstract_unstemmed |
Abstract Based on the conclusions of the European Food Safety Authority (EFSA), the four polycyclic aromatic hydrocarbons (PAH4) chrysene (Chr), benzo(a)anthracene (BaA), benzo(a)pyrene (BaP), and benzo(b)fluoranthene (BbF) are new markers for the occurrence of PAHs in food. Vegetable oils are extremely easily contaminated by PAHs, due to the raw material pollution and the imperfections of processing techniques. Therefore, it is of great importance to establish an efficient method for the rapid determination of PAH4 in vegetable oils. In this research, second-derivative nonlinear variable-angle-matrix isopotential synchronous fluorescence spectroscopic approach has been proposed for the simultaneous and rapid determination of PAH4 in vegetable oils with ultrasonic-assisted extraction. This method is capable of resolving the spectra of these four PAHs well. The limits of detection (LODs) for Chr, BaA, BaP, and BbF were 13.0, 8.64, 0.16, and 7.68 μg $ kg^{−1} $, respectively. The recoveries in various oil samples for Chr, BaA, BaP, and BbF were 86.2 ± 15.3, 93.8 ± 11.7, 93.9 ± 12.1, and 94.3 ± 7.4 %, respectively, at the spiked levels of 10∼400 μg $ kg^{−1} $. The relative standard deviations (RSDs) achieved for Chr, BaA, BaP, and BbF were 3.0, 8.4, 6.3, and 7.2 %, respectively. The established method is simple, economical, and reliable, as well as provides an attractive alternative for the simultaneous and rapid determination of PAH4 in vegetable oils. © Springer Science+Business Media New York 2016 |
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container_issue |
11 |
title_short |
A Simple Fluorescence Spectroscopic Approach for Simultaneous and Rapid Detection of Four Polycyclic Aromatic Hydrocarbons (PAH4) in Vegetable Oils |
url |
https://dx.doi.org/10.1007/s12161-016-0515-5 |
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author2 |
Wu, Ping-Ping Liu, Qian Luo, He-Dong Cao, Shuo-Hui Lin, Guo-Chun Fu, Dong-Sai Zhong, Xiu-Di Li, Yao-Qun |
author2Str |
Wu, Ping-Ping Liu, Qian Luo, He-Dong Cao, Shuo-Hui Lin, Guo-Chun Fu, Dong-Sai Zhong, Xiu-Di Li, Yao-Qun |
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score |
7.3995314 |