Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells

Abstract The electron transport layer (ETL) plays a crucial role on the electron injection and extraction, resulting in balanced charge transporting and reducing the interfacial energy barrier. The interface compatibility and electrical contact via employing appropriate buffer layer at the surface o...
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Gespeichert in:

Autor*in:	Liu, Jikang [verfasserIn] Li, Junli Tu, Guoli

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2018

Schlagwörter:	interface compatibility functionalized fullerene derivatives tune energy alignment third compound ternary system

Anmerkung:	© Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Übergeordnetes Werk:	Enthalten in: Frontiers of optoelectronics in China - [Beijing] : Higher Education Press, 2008, 11(2018), 4 vom: Dez., Seite 348-359
Übergeordnetes Werk:	volume:11 ; year:2018 ; number:4 ; month:12 ; pages:348-359

Links:	Volltext

DOI / URN:	10.1007/s12200-018-0842-9

Katalog-ID:	SPR025212842

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allfields	10.1007/s12200-018-0842-9 doi (DE-627)SPR025212842 (SPR)s12200-018-0842-9-e DE-627 ger DE-627 rakwb eng Liu, Jikang verfasserin aut Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract The electron transport layer (ETL) plays a crucial role on the electron injection and extraction, resulting in balanced charge transporting and reducing the interfacial energy barrier. The interface compatibility and electrical contact via employing appropriate buffer layer at the surface of hydrophobic organic active layer and hydrophilic inorganic electrode are also essential for charge collections. Herein, an ether chain functionalized fullerene derivatives [6,6]-phenyl-$ C_{61} $-butyricacid-(3,5-bis(2-(2-ethoxyethoxy)-ethoxy)-phenyl)-methyl ester ($ C_{60} $-2EPM) was developed to modify zinc oxide (ZnO) in inverted structure organic solar cells (OSCs). The composited ZnO/$ C_{60} $-2EPM interface layer can help to overcome the low interface compatibility between ZnO and organic active layer. By introducing the $ C_{60} $-2EPM layer, the composited fullerene derivatives tune energy alignment and accelerated the electronic transfer, leading to increased photocurrent and power conversion efficiency (PCE) in the inverted OSCs. The PCE based on PTB7-Th: $ PC_{71} $BM was enhance from 8.11% on bare ZnO to 8.38% and 8.65% with increasing concentrations of 2.0 and 4.0 mg/mL, respectively. The fullerene derivatives $ C_{60} $-2EPM was also used as a third compound in P3HT:$ PC_{61} $BM blend to form ternary system, the devices with addition of $ C_{60} $-2EPM exhibited better values than the control device. interface compatibility (dpeaa)DE-He213 functionalized fullerene derivatives (dpeaa)DE-He213 tune energy alignment (dpeaa)DE-He213 third compound (dpeaa)DE-He213 ternary system (dpeaa)DE-He213 Li, Junli aut Tu, Guoli aut Enthalten in Frontiers of optoelectronics in China [Beijing] : Higher Education Press, 2008 11(2018), 4 vom: Dez., Seite 348-359 (DE-627)587886420 (DE-600)2468689-X 1674-4594 nnns volume:11 year:2018 number:4 month:12 pages:348-359 https://dx.doi.org/10.1007/s12200-018-0842-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 11 2018 4 12 348-359
spelling	10.1007/s12200-018-0842-9 doi (DE-627)SPR025212842 (SPR)s12200-018-0842-9-e DE-627 ger DE-627 rakwb eng Liu, Jikang verfasserin aut Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract The electron transport layer (ETL) plays a crucial role on the electron injection and extraction, resulting in balanced charge transporting and reducing the interfacial energy barrier. The interface compatibility and electrical contact via employing appropriate buffer layer at the surface of hydrophobic organic active layer and hydrophilic inorganic electrode are also essential for charge collections. Herein, an ether chain functionalized fullerene derivatives [6,6]-phenyl-$ C_{61} $-butyricacid-(3,5-bis(2-(2-ethoxyethoxy)-ethoxy)-phenyl)-methyl ester ($ C_{60} $-2EPM) was developed to modify zinc oxide (ZnO) in inverted structure organic solar cells (OSCs). The composited ZnO/$ C_{60} $-2EPM interface layer can help to overcome the low interface compatibility between ZnO and organic active layer. By introducing the $ C_{60} $-2EPM layer, the composited fullerene derivatives tune energy alignment and accelerated the electronic transfer, leading to increased photocurrent and power conversion efficiency (PCE) in the inverted OSCs. The PCE based on PTB7-Th: $ PC_{71} $BM was enhance from 8.11% on bare ZnO to 8.38% and 8.65% with increasing concentrations of 2.0 and 4.0 mg/mL, respectively. The fullerene derivatives $ C_{60} $-2EPM was also used as a third compound in P3HT:$ PC_{61} $BM blend to form ternary system, the devices with addition of $ C_{60} $-2EPM exhibited better values than the control device. interface compatibility (dpeaa)DE-He213 functionalized fullerene derivatives (dpeaa)DE-He213 tune energy alignment (dpeaa)DE-He213 third compound (dpeaa)DE-He213 ternary system (dpeaa)DE-He213 Li, Junli aut Tu, Guoli aut Enthalten in Frontiers of optoelectronics in China [Beijing] : Higher Education Press, 2008 11(2018), 4 vom: Dez., Seite 348-359 (DE-627)587886420 (DE-600)2468689-X 1674-4594 nnns volume:11 year:2018 number:4 month:12 pages:348-359 https://dx.doi.org/10.1007/s12200-018-0842-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 11 2018 4 12 348-359
allfields_unstemmed	10.1007/s12200-018-0842-9 doi (DE-627)SPR025212842 (SPR)s12200-018-0842-9-e DE-627 ger DE-627 rakwb eng Liu, Jikang verfasserin aut Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract The electron transport layer (ETL) plays a crucial role on the electron injection and extraction, resulting in balanced charge transporting and reducing the interfacial energy barrier. The interface compatibility and electrical contact via employing appropriate buffer layer at the surface of hydrophobic organic active layer and hydrophilic inorganic electrode are also essential for charge collections. Herein, an ether chain functionalized fullerene derivatives [6,6]-phenyl-$ C_{61} $-butyricacid-(3,5-bis(2-(2-ethoxyethoxy)-ethoxy)-phenyl)-methyl ester ($ C_{60} $-2EPM) was developed to modify zinc oxide (ZnO) in inverted structure organic solar cells (OSCs). The composited ZnO/$ C_{60} $-2EPM interface layer can help to overcome the low interface compatibility between ZnO and organic active layer. By introducing the $ C_{60} $-2EPM layer, the composited fullerene derivatives tune energy alignment and accelerated the electronic transfer, leading to increased photocurrent and power conversion efficiency (PCE) in the inverted OSCs. The PCE based on PTB7-Th: $ PC_{71} $BM was enhance from 8.11% on bare ZnO to 8.38% and 8.65% with increasing concentrations of 2.0 and 4.0 mg/mL, respectively. The fullerene derivatives $ C_{60} $-2EPM was also used as a third compound in P3HT:$ PC_{61} $BM blend to form ternary system, the devices with addition of $ C_{60} $-2EPM exhibited better values than the control device. interface compatibility (dpeaa)DE-He213 functionalized fullerene derivatives (dpeaa)DE-He213 tune energy alignment (dpeaa)DE-He213 third compound (dpeaa)DE-He213 ternary system (dpeaa)DE-He213 Li, Junli aut Tu, Guoli aut Enthalten in Frontiers of optoelectronics in China [Beijing] : Higher Education Press, 2008 11(2018), 4 vom: Dez., Seite 348-359 (DE-627)587886420 (DE-600)2468689-X 1674-4594 nnns volume:11 year:2018 number:4 month:12 pages:348-359 https://dx.doi.org/10.1007/s12200-018-0842-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 11 2018 4 12 348-359
allfieldsGer	10.1007/s12200-018-0842-9 doi (DE-627)SPR025212842 (SPR)s12200-018-0842-9-e DE-627 ger DE-627 rakwb eng Liu, Jikang verfasserin aut Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract The electron transport layer (ETL) plays a crucial role on the electron injection and extraction, resulting in balanced charge transporting and reducing the interfacial energy barrier. The interface compatibility and electrical contact via employing appropriate buffer layer at the surface of hydrophobic organic active layer and hydrophilic inorganic electrode are also essential for charge collections. Herein, an ether chain functionalized fullerene derivatives [6,6]-phenyl-$ C_{61} $-butyricacid-(3,5-bis(2-(2-ethoxyethoxy)-ethoxy)-phenyl)-methyl ester ($ C_{60} $-2EPM) was developed to modify zinc oxide (ZnO) in inverted structure organic solar cells (OSCs). The composited ZnO/$ C_{60} $-2EPM interface layer can help to overcome the low interface compatibility between ZnO and organic active layer. By introducing the $ C_{60} $-2EPM layer, the composited fullerene derivatives tune energy alignment and accelerated the electronic transfer, leading to increased photocurrent and power conversion efficiency (PCE) in the inverted OSCs. The PCE based on PTB7-Th: $ PC_{71} $BM was enhance from 8.11% on bare ZnO to 8.38% and 8.65% with increasing concentrations of 2.0 and 4.0 mg/mL, respectively. The fullerene derivatives $ C_{60} $-2EPM was also used as a third compound in P3HT:$ PC_{61} $BM blend to form ternary system, the devices with addition of $ C_{60} $-2EPM exhibited better values than the control device. interface compatibility (dpeaa)DE-He213 functionalized fullerene derivatives (dpeaa)DE-He213 tune energy alignment (dpeaa)DE-He213 third compound (dpeaa)DE-He213 ternary system (dpeaa)DE-He213 Li, Junli aut Tu, Guoli aut Enthalten in Frontiers of optoelectronics in China [Beijing] : Higher Education Press, 2008 11(2018), 4 vom: Dez., Seite 348-359 (DE-627)587886420 (DE-600)2468689-X 1674-4594 nnns volume:11 year:2018 number:4 month:12 pages:348-359 https://dx.doi.org/10.1007/s12200-018-0842-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 11 2018 4 12 348-359
allfieldsSound	10.1007/s12200-018-0842-9 doi (DE-627)SPR025212842 (SPR)s12200-018-0842-9-e DE-627 ger DE-627 rakwb eng Liu, Jikang verfasserin aut Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract The electron transport layer (ETL) plays a crucial role on the electron injection and extraction, resulting in balanced charge transporting and reducing the interfacial energy barrier. The interface compatibility and electrical contact via employing appropriate buffer layer at the surface of hydrophobic organic active layer and hydrophilic inorganic electrode are also essential for charge collections. Herein, an ether chain functionalized fullerene derivatives [6,6]-phenyl-$ C_{61} $-butyricacid-(3,5-bis(2-(2-ethoxyethoxy)-ethoxy)-phenyl)-methyl ester ($ C_{60} $-2EPM) was developed to modify zinc oxide (ZnO) in inverted structure organic solar cells (OSCs). The composited ZnO/$ C_{60} $-2EPM interface layer can help to overcome the low interface compatibility between ZnO and organic active layer. By introducing the $ C_{60} $-2EPM layer, the composited fullerene derivatives tune energy alignment and accelerated the electronic transfer, leading to increased photocurrent and power conversion efficiency (PCE) in the inverted OSCs. The PCE based on PTB7-Th: $ PC_{71} $BM was enhance from 8.11% on bare ZnO to 8.38% and 8.65% with increasing concentrations of 2.0 and 4.0 mg/mL, respectively. The fullerene derivatives $ C_{60} $-2EPM was also used as a third compound in P3HT:$ PC_{61} $BM blend to form ternary system, the devices with addition of $ C_{60} $-2EPM exhibited better values than the control device. interface compatibility (dpeaa)DE-He213 functionalized fullerene derivatives (dpeaa)DE-He213 tune energy alignment (dpeaa)DE-He213 third compound (dpeaa)DE-He213 ternary system (dpeaa)DE-He213 Li, Junli aut Tu, Guoli aut Enthalten in Frontiers of optoelectronics in China [Beijing] : Higher Education Press, 2008 11(2018), 4 vom: Dez., Seite 348-359 (DE-627)587886420 (DE-600)2468689-X 1674-4594 nnns volume:11 year:2018 number:4 month:12 pages:348-359 https://dx.doi.org/10.1007/s12200-018-0842-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 11 2018 4 12 348-359
language	English
source	Enthalten in Frontiers of optoelectronics in China 11(2018), 4 vom: Dez., Seite 348-359 volume:11 year:2018 number:4 month:12 pages:348-359
sourceStr	Enthalten in Frontiers of optoelectronics in China 11(2018), 4 vom: Dez., Seite 348-359 volume:11 year:2018 number:4 month:12 pages:348-359
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	interface compatibility functionalized fullerene derivatives tune energy alignment third compound ternary system
isfreeaccess_bool	false
container_title	Frontiers of optoelectronics in China
authorswithroles_txt_mv	Liu, Jikang @@aut@@ Li, Junli @@aut@@ Tu, Guoli @@aut@@
publishDateDaySort_date	2018-12-01T00:00:00Z
hierarchy_top_id	587886420
id	SPR025212842
language_de	englisch
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author	Liu, Jikang
spellingShingle	Liu, Jikang misc interface compatibility misc functionalized fullerene derivatives misc tune energy alignment misc third compound misc ternary system Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells
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topic_title	Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells interface compatibility (dpeaa)DE-He213 functionalized fullerene derivatives (dpeaa)DE-He213 tune energy alignment (dpeaa)DE-He213 third compound (dpeaa)DE-He213 ternary system (dpeaa)DE-He213
topic	misc interface compatibility misc functionalized fullerene derivatives misc tune energy alignment misc third compound misc ternary system
topic_unstemmed	misc interface compatibility misc functionalized fullerene derivatives misc tune energy alignment misc third compound misc ternary system
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title	Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells
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title_full	Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells
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title_sort	ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells
title_auth	Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells
abstract	Abstract The electron transport layer (ETL) plays a crucial role on the electron injection and extraction, resulting in balanced charge transporting and reducing the interfacial energy barrier. The interface compatibility and electrical contact via employing appropriate buffer layer at the surface of hydrophobic organic active layer and hydrophilic inorganic electrode are also essential for charge collections. Herein, an ether chain functionalized fullerene derivatives [6,6]-phenyl-$ C_{61} $-butyricacid-(3,5-bis(2-(2-ethoxyethoxy)-ethoxy)-phenyl)-methyl ester ($ C_{60} $-2EPM) was developed to modify zinc oxide (ZnO) in inverted structure organic solar cells (OSCs). The composited ZnO/$ C_{60} $-2EPM interface layer can help to overcome the low interface compatibility between ZnO and organic active layer. By introducing the $ C_{60} $-2EPM layer, the composited fullerene derivatives tune energy alignment and accelerated the electronic transfer, leading to increased photocurrent and power conversion efficiency (PCE) in the inverted OSCs. The PCE based on PTB7-Th: $ PC_{71} $BM was enhance from 8.11% on bare ZnO to 8.38% and 8.65% with increasing concentrations of 2.0 and 4.0 mg/mL, respectively. The fullerene derivatives $ C_{60} $-2EPM was also used as a third compound in P3HT:$ PC_{61} $BM blend to form ternary system, the devices with addition of $ C_{60} $-2EPM exhibited better values than the control device. © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018
abstractGer	Abstract The electron transport layer (ETL) plays a crucial role on the electron injection and extraction, resulting in balanced charge transporting and reducing the interfacial energy barrier. The interface compatibility and electrical contact via employing appropriate buffer layer at the surface of hydrophobic organic active layer and hydrophilic inorganic electrode are also essential for charge collections. Herein, an ether chain functionalized fullerene derivatives [6,6]-phenyl-$ C_{61} $-butyricacid-(3,5-bis(2-(2-ethoxyethoxy)-ethoxy)-phenyl)-methyl ester ($ C_{60} $-2EPM) was developed to modify zinc oxide (ZnO) in inverted structure organic solar cells (OSCs). The composited ZnO/$ C_{60} $-2EPM interface layer can help to overcome the low interface compatibility between ZnO and organic active layer. By introducing the $ C_{60} $-2EPM layer, the composited fullerene derivatives tune energy alignment and accelerated the electronic transfer, leading to increased photocurrent and power conversion efficiency (PCE) in the inverted OSCs. The PCE based on PTB7-Th: $ PC_{71} $BM was enhance from 8.11% on bare ZnO to 8.38% and 8.65% with increasing concentrations of 2.0 and 4.0 mg/mL, respectively. The fullerene derivatives $ C_{60} $-2EPM was also used as a third compound in P3HT:$ PC_{61} $BM blend to form ternary system, the devices with addition of $ C_{60} $-2EPM exhibited better values than the control device. © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018
abstract_unstemmed	Abstract The electron transport layer (ETL) plays a crucial role on the electron injection and extraction, resulting in balanced charge transporting and reducing the interfacial energy barrier. The interface compatibility and electrical contact via employing appropriate buffer layer at the surface of hydrophobic organic active layer and hydrophilic inorganic electrode are also essential for charge collections. Herein, an ether chain functionalized fullerene derivatives [6,6]-phenyl-$ C_{61} $-butyricacid-(3,5-bis(2-(2-ethoxyethoxy)-ethoxy)-phenyl)-methyl ester ($ C_{60} $-2EPM) was developed to modify zinc oxide (ZnO) in inverted structure organic solar cells (OSCs). The composited ZnO/$ C_{60} $-2EPM interface layer can help to overcome the low interface compatibility between ZnO and organic active layer. By introducing the $ C_{60} $-2EPM layer, the composited fullerene derivatives tune energy alignment and accelerated the electronic transfer, leading to increased photocurrent and power conversion efficiency (PCE) in the inverted OSCs. The PCE based on PTB7-Th: $ PC_{71} $BM was enhance from 8.11% on bare ZnO to 8.38% and 8.65% with increasing concentrations of 2.0 and 4.0 mg/mL, respectively. The fullerene derivatives $ C_{60} $-2EPM was also used as a third compound in P3HT:$ PC_{61} $BM blend to form ternary system, the devices with addition of $ C_{60} $-2EPM exhibited better values than the control device. © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018
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title_short	Ether chain functionalized fullerene derivatives as cathode interface materials for efficient organic solar cells
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