Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance
Abstract In this work, thin layers of $ MoO_{3} $ were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation ($ K^{+} $) into the $ MoO_{3} $ structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated f...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Szkoda, M. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s) 2019 |
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| Übergeordnetes Werk: |
Enthalten in: Electrocatalysis - New York, NY : Springer, 2010, 11(2019), 2 vom: 25. Okt., Seite 111-120 |
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| Übergeordnetes Werk: |
volume:11 ; year:2019 ; number:2 ; day:25 ; month:10 ; pages:111-120 |
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| DOI / URN: |
10.1007/s12678-019-00561-2 |
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SPR027178617 |
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| 520 | |a Abstract In this work, thin layers of $ MoO_{3} $ were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation ($ K^{+} $) into the $ MoO_{3} $ structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. $ MoO_{3} $ thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The Tauc and Mott–Schottky plots analysis were performed in order to determine the energy bands position of the investigated material. The photointercalation effect of $ K^{+} $ on photoelectrochemical properties of FTO/$ MoO_{3} $ photoanodes was studied using electrochemical techniques performed under simulated solar light illumination. It was proven that pristine $ MoO_{3} $ layers cannot act as effective photoanodes for water splitting due to the utilization of the photoexcited electrons in the intercalation process. The photochromic phenomenon related to $ Mo^{6+} $ centers reduction, and $ K^{+} $ intercalation occurs at a potential range in which the photoanode exhibits photoelectrochemical activity towards water photooxidation. Graphical AbstractSchematic presentation of the photointercalation phenomenon influence on the photocurrent generation | ||
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| 700 | 1 | |a Trzciński, K. |4 aut | |
| 700 | 1 | |a Łapiński, M. |4 aut | |
| 700 | 1 | |a Lisowska-Oleksiak, A. |4 aut | |
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10.1007/s12678-019-00561-2 doi (DE-627)SPR027178617 (SPR)s12678-019-00561-2-e DE-627 ger DE-627 rakwb eng Szkoda, M. verfasserin aut Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2019 Abstract In this work, thin layers of $ MoO_{3} $ were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation ($ K^{+} $) into the $ MoO_{3} $ structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. $ MoO_{3} $ thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The Tauc and Mott–Schottky plots analysis were performed in order to determine the energy bands position of the investigated material. The photointercalation effect of $ K^{+} $ on photoelectrochemical properties of FTO/$ MoO_{3} $ photoanodes was studied using electrochemical techniques performed under simulated solar light illumination. It was proven that pristine $ MoO_{3} $ layers cannot act as effective photoanodes for water splitting due to the utilization of the photoexcited electrons in the intercalation process. The photochromic phenomenon related to $ Mo^{6+} $ centers reduction, and $ K^{+} $ intercalation occurs at a potential range in which the photoanode exhibits photoelectrochemical activity towards water photooxidation. Graphical AbstractSchematic presentation of the photointercalation phenomenon influence on the photocurrent generation MoO (dpeaa)DE-He213 Photointercalation (dpeaa)DE-He213 Photoanodes (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Trzciński, K. aut Łapiński, M. aut Lisowska-Oleksiak, A. aut Enthalten in Electrocatalysis New York, NY : Springer, 2010 11(2019), 2 vom: 25. Okt., Seite 111-120 (DE-627)620775238 (DE-600)2543106-7 1868-5994 nnns volume:11 year:2019 number:2 day:25 month:10 pages:111-120 https://dx.doi.org/10.1007/s12678-019-00561-2 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 11 2019 2 25 10 111-120 |
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10.1007/s12678-019-00561-2 doi (DE-627)SPR027178617 (SPR)s12678-019-00561-2-e DE-627 ger DE-627 rakwb eng Szkoda, M. verfasserin aut Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2019 Abstract In this work, thin layers of $ MoO_{3} $ were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation ($ K^{+} $) into the $ MoO_{3} $ structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. $ MoO_{3} $ thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The Tauc and Mott–Schottky plots analysis were performed in order to determine the energy bands position of the investigated material. The photointercalation effect of $ K^{+} $ on photoelectrochemical properties of FTO/$ MoO_{3} $ photoanodes was studied using electrochemical techniques performed under simulated solar light illumination. It was proven that pristine $ MoO_{3} $ layers cannot act as effective photoanodes for water splitting due to the utilization of the photoexcited electrons in the intercalation process. The photochromic phenomenon related to $ Mo^{6+} $ centers reduction, and $ K^{+} $ intercalation occurs at a potential range in which the photoanode exhibits photoelectrochemical activity towards water photooxidation. Graphical AbstractSchematic presentation of the photointercalation phenomenon influence on the photocurrent generation MoO (dpeaa)DE-He213 Photointercalation (dpeaa)DE-He213 Photoanodes (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Trzciński, K. aut Łapiński, M. aut Lisowska-Oleksiak, A. aut Enthalten in Electrocatalysis New York, NY : Springer, 2010 11(2019), 2 vom: 25. Okt., Seite 111-120 (DE-627)620775238 (DE-600)2543106-7 1868-5994 nnns volume:11 year:2019 number:2 day:25 month:10 pages:111-120 https://dx.doi.org/10.1007/s12678-019-00561-2 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 11 2019 2 25 10 111-120 |
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10.1007/s12678-019-00561-2 doi (DE-627)SPR027178617 (SPR)s12678-019-00561-2-e DE-627 ger DE-627 rakwb eng Szkoda, M. verfasserin aut Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2019 Abstract In this work, thin layers of $ MoO_{3} $ were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation ($ K^{+} $) into the $ MoO_{3} $ structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. $ MoO_{3} $ thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The Tauc and Mott–Schottky plots analysis were performed in order to determine the energy bands position of the investigated material. The photointercalation effect of $ K^{+} $ on photoelectrochemical properties of FTO/$ MoO_{3} $ photoanodes was studied using electrochemical techniques performed under simulated solar light illumination. It was proven that pristine $ MoO_{3} $ layers cannot act as effective photoanodes for water splitting due to the utilization of the photoexcited electrons in the intercalation process. The photochromic phenomenon related to $ Mo^{6+} $ centers reduction, and $ K^{+} $ intercalation occurs at a potential range in which the photoanode exhibits photoelectrochemical activity towards water photooxidation. Graphical AbstractSchematic presentation of the photointercalation phenomenon influence on the photocurrent generation MoO (dpeaa)DE-He213 Photointercalation (dpeaa)DE-He213 Photoanodes (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Trzciński, K. aut Łapiński, M. aut Lisowska-Oleksiak, A. aut Enthalten in Electrocatalysis New York, NY : Springer, 2010 11(2019), 2 vom: 25. Okt., Seite 111-120 (DE-627)620775238 (DE-600)2543106-7 1868-5994 nnns volume:11 year:2019 number:2 day:25 month:10 pages:111-120 https://dx.doi.org/10.1007/s12678-019-00561-2 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 11 2019 2 25 10 111-120 |
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10.1007/s12678-019-00561-2 doi (DE-627)SPR027178617 (SPR)s12678-019-00561-2-e DE-627 ger DE-627 rakwb eng Szkoda, M. verfasserin aut Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2019 Abstract In this work, thin layers of $ MoO_{3} $ were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation ($ K^{+} $) into the $ MoO_{3} $ structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. $ MoO_{3} $ thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The Tauc and Mott–Schottky plots analysis were performed in order to determine the energy bands position of the investigated material. The photointercalation effect of $ K^{+} $ on photoelectrochemical properties of FTO/$ MoO_{3} $ photoanodes was studied using electrochemical techniques performed under simulated solar light illumination. It was proven that pristine $ MoO_{3} $ layers cannot act as effective photoanodes for water splitting due to the utilization of the photoexcited electrons in the intercalation process. The photochromic phenomenon related to $ Mo^{6+} $ centers reduction, and $ K^{+} $ intercalation occurs at a potential range in which the photoanode exhibits photoelectrochemical activity towards water photooxidation. Graphical AbstractSchematic presentation of the photointercalation phenomenon influence on the photocurrent generation MoO (dpeaa)DE-He213 Photointercalation (dpeaa)DE-He213 Photoanodes (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Trzciński, K. aut Łapiński, M. aut Lisowska-Oleksiak, A. aut Enthalten in Electrocatalysis New York, NY : Springer, 2010 11(2019), 2 vom: 25. Okt., Seite 111-120 (DE-627)620775238 (DE-600)2543106-7 1868-5994 nnns volume:11 year:2019 number:2 day:25 month:10 pages:111-120 https://dx.doi.org/10.1007/s12678-019-00561-2 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 11 2019 2 25 10 111-120 |
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10.1007/s12678-019-00561-2 doi (DE-627)SPR027178617 (SPR)s12678-019-00561-2-e DE-627 ger DE-627 rakwb eng Szkoda, M. verfasserin aut Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s) 2019 Abstract In this work, thin layers of $ MoO_{3} $ were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation ($ K^{+} $) into the $ MoO_{3} $ structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. $ MoO_{3} $ thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The Tauc and Mott–Schottky plots analysis were performed in order to determine the energy bands position of the investigated material. The photointercalation effect of $ K^{+} $ on photoelectrochemical properties of FTO/$ MoO_{3} $ photoanodes was studied using electrochemical techniques performed under simulated solar light illumination. It was proven that pristine $ MoO_{3} $ layers cannot act as effective photoanodes for water splitting due to the utilization of the photoexcited electrons in the intercalation process. The photochromic phenomenon related to $ Mo^{6+} $ centers reduction, and $ K^{+} $ intercalation occurs at a potential range in which the photoanode exhibits photoelectrochemical activity towards water photooxidation. Graphical AbstractSchematic presentation of the photointercalation phenomenon influence on the photocurrent generation MoO (dpeaa)DE-He213 Photointercalation (dpeaa)DE-He213 Photoanodes (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Trzciński, K. aut Łapiński, M. aut Lisowska-Oleksiak, A. aut Enthalten in Electrocatalysis New York, NY : Springer, 2010 11(2019), 2 vom: 25. Okt., Seite 111-120 (DE-627)620775238 (DE-600)2543106-7 1868-5994 nnns volume:11 year:2019 number:2 day:25 month:10 pages:111-120 https://dx.doi.org/10.1007/s12678-019-00561-2 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 11 2019 2 25 10 111-120 |
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Enthalten in Electrocatalysis 11(2019), 2 vom: 25. Okt., Seite 111-120 volume:11 year:2019 number:2 day:25 month:10 pages:111-120 |
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Szkoda, M. @@aut@@ Trzciński, K. @@aut@@ Łapiński, M. @@aut@@ Lisowska-Oleksiak, A. @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR027178617</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230331201513.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201007s2019 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s12678-019-00561-2</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR027178617</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s12678-019-00561-2-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Szkoda, M.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s) 2019</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract In this work, thin layers of $ MoO_{3} $ were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation ($ K^{+} $) into the $ MoO_{3} $ structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. $ MoO_{3} $ thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The Tauc and Mott–Schottky plots analysis were performed in order to determine the energy bands position of the investigated material. The photointercalation effect of $ K^{+} $ on photoelectrochemical properties of FTO/$ MoO_{3} $ photoanodes was studied using electrochemical techniques performed under simulated solar light illumination. It was proven that pristine $ MoO_{3} $ layers cannot act as effective photoanodes for water splitting due to the utilization of the photoexcited electrons in the intercalation process. The photochromic phenomenon related to $ Mo^{6+} $ centers reduction, and $ K^{+} $ intercalation occurs at a potential range in which the photoanode exhibits photoelectrochemical activity towards water photooxidation. 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Szkoda, M. |
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Szkoda, M. misc MoO misc Photointercalation misc Photoanodes misc Water splitting Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance |
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Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance MoO (dpeaa)DE-He213 Photointercalation (dpeaa)DE-He213 Photoanodes (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 |
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Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance |
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Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance |
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Szkoda, M. Trzciński, K. Łapiński, M. Lisowska-Oleksiak, A. |
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Szkoda, M. |
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10.1007/s12678-019-00561-2 |
| title_sort |
photoinduced $ k^{+} $ intercalation into $ moo_{3} $/fto photoanode—the impact on the photoelectrochemical performance |
| title_auth |
Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance |
| abstract |
Abstract In this work, thin layers of $ MoO_{3} $ were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation ($ K^{+} $) into the $ MoO_{3} $ structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. $ MoO_{3} $ thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The Tauc and Mott–Schottky plots analysis were performed in order to determine the energy bands position of the investigated material. The photointercalation effect of $ K^{+} $ on photoelectrochemical properties of FTO/$ MoO_{3} $ photoanodes was studied using electrochemical techniques performed under simulated solar light illumination. It was proven that pristine $ MoO_{3} $ layers cannot act as effective photoanodes for water splitting due to the utilization of the photoexcited electrons in the intercalation process. The photochromic phenomenon related to $ Mo^{6+} $ centers reduction, and $ K^{+} $ intercalation occurs at a potential range in which the photoanode exhibits photoelectrochemical activity towards water photooxidation. Graphical AbstractSchematic presentation of the photointercalation phenomenon influence on the photocurrent generation © The Author(s) 2019 |
| abstractGer |
Abstract In this work, thin layers of $ MoO_{3} $ were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation ($ K^{+} $) into the $ MoO_{3} $ structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. $ MoO_{3} $ thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The Tauc and Mott–Schottky plots analysis were performed in order to determine the energy bands position of the investigated material. The photointercalation effect of $ K^{+} $ on photoelectrochemical properties of FTO/$ MoO_{3} $ photoanodes was studied using electrochemical techniques performed under simulated solar light illumination. It was proven that pristine $ MoO_{3} $ layers cannot act as effective photoanodes for water splitting due to the utilization of the photoexcited electrons in the intercalation process. The photochromic phenomenon related to $ Mo^{6+} $ centers reduction, and $ K^{+} $ intercalation occurs at a potential range in which the photoanode exhibits photoelectrochemical activity towards water photooxidation. Graphical AbstractSchematic presentation of the photointercalation phenomenon influence on the photocurrent generation © The Author(s) 2019 |
| abstract_unstemmed |
Abstract In this work, thin layers of $ MoO_{3} $ were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation ($ K^{+} $) into the $ MoO_{3} $ structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. $ MoO_{3} $ thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The Tauc and Mott–Schottky plots analysis were performed in order to determine the energy bands position of the investigated material. The photointercalation effect of $ K^{+} $ on photoelectrochemical properties of FTO/$ MoO_{3} $ photoanodes was studied using electrochemical techniques performed under simulated solar light illumination. It was proven that pristine $ MoO_{3} $ layers cannot act as effective photoanodes for water splitting due to the utilization of the photoexcited electrons in the intercalation process. The photochromic phenomenon related to $ Mo^{6+} $ centers reduction, and $ K^{+} $ intercalation occurs at a potential range in which the photoanode exhibits photoelectrochemical activity towards water photooxidation. Graphical AbstractSchematic presentation of the photointercalation phenomenon influence on the photocurrent generation © The Author(s) 2019 |
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Photoinduced $ K^{+} $ Intercalation into $ MoO_{3} $/FTO Photoanode—the Impact on the Photoelectrochemical Performance |
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https://dx.doi.org/10.1007/s12678-019-00561-2 |
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Trzciński, K. Łapiński, M. Lisowska-Oleksiak, A. |
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Trzciński, K. Łapiński, M. Lisowska-Oleksiak, A. |
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10.1007/s12678-019-00561-2 |
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2024-07-04T00:45:05.947Z |
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| score |
7.3987474 |