Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane)

Abstract 2-(Methoxymethyl)oxirane (MOMO) was used as a co-monomer for ring-opening polymerization, and four different samples of poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) (poly(ECH-co-MOMO)) were synthesized by cationic ring opening copolymerization in the presence of $ BF_{3} $-etherate and...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Cho, Bong-Sang [verfasserIn] Noh, Si-Tae

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2012

Schlagwörter:	ring opening polymerization ferrocene thermal analysis

Anmerkung:	© The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2013

Übergeordnetes Werk:	Enthalten in: Macromolecular research - Heidelberg : Springer, 2010, 21(2012), 2 vom: 28. Nov., Seite 221-227
Übergeordnetes Werk:	volume:21 ; year:2012 ; number:2 ; day:28 ; month:11 ; pages:221-227

Links:	Volltext

DOI / URN:	10.1007/s13233-013-1074-x

Katalog-ID:	SPR030961394

Internformat


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245	1	0	\|a Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane)
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520			\|a Abstract 2-(Methoxymethyl)oxirane (MOMO) was used as a co-monomer for ring-opening polymerization, and four different samples of poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) (poly(ECH-co-MOMO)) were synthesized by cationic ring opening copolymerization in the presence of $ BF_{3} $-etherate and 1,4-butandiol as an initiator system. Further, ferrocene modified copolymers were obtained by a substitution reaction of ferrocene methanol with the epichlorohydrin (ECH) unit in poly (ECH-co-MOMO) under mild conditions. Structural analysis of all products was performed using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly(ECH-co-MOMO) and ferrocene-modified poly(ECH-co-MOMO) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The glass transition temperatures (Tg) of PECH and PMOMO were −47 and −61 °C, respectively. As the contents of PMOMO increased, the Tg of the poly(ECH-co-MOMO)s were decreased and the onset of thermal decomposition shifted to a higher temperature. The decomposition temperature of poly(ECH-co-MOMO) was higher than that of the ferrocene-modified poly(ECH-co-MOMO).
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773	0	8	\|i Enthalten in \|t Macromolecular research \|d Heidelberg : Springer, 2010 \|g 21(2012), 2 vom: 28. Nov., Seite 221-227 \|w (DE-627)618327576 \|w (DE-600)2537708-5 \|x 2092-7673 \|7 nnns
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912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
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912			\|a GBV_ILN_95
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912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
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912			\|a GBV_ILN_2143
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912			\|a GBV_ILN_2152
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Indexfelder

author_variant	b s c bsc s t n stn
matchkey_str	article:20927673:2012----::yteiadhrapoeteofroeeoiidoypclrhdi
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publishDate	2012
allfields	10.1007/s13233-013-1074-x doi (DE-627)SPR030961394 (SPR)s13233-013-1074-x-e DE-627 ger DE-627 rakwb eng Cho, Bong-Sang verfasserin aut Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2013 Abstract 2-(Methoxymethyl)oxirane (MOMO) was used as a co-monomer for ring-opening polymerization, and four different samples of poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) (poly(ECH-co-MOMO)) were synthesized by cationic ring opening copolymerization in the presence of $ BF_{3} $-etherate and 1,4-butandiol as an initiator system. Further, ferrocene modified copolymers were obtained by a substitution reaction of ferrocene methanol with the epichlorohydrin (ECH) unit in poly (ECH-co-MOMO) under mild conditions. Structural analysis of all products was performed using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly(ECH-co-MOMO) and ferrocene-modified poly(ECH-co-MOMO) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The glass transition temperatures (Tg) of PECH and PMOMO were −47 and −61 °C, respectively. As the contents of PMOMO increased, the Tg of the poly(ECH-co-MOMO)s were decreased and the onset of thermal decomposition shifted to a higher temperature. The decomposition temperature of poly(ECH-co-MOMO) was higher than that of the ferrocene-modified poly(ECH-co-MOMO). ring opening polymerization (dpeaa)DE-He213 ferrocene (dpeaa)DE-He213 thermal analysis (dpeaa)DE-He213 Noh, Si-Tae aut Enthalten in Macromolecular research Heidelberg : Springer, 2010 21(2012), 2 vom: 28. Nov., Seite 221-227 (DE-627)618327576 (DE-600)2537708-5 2092-7673 nnns volume:21 year:2012 number:2 day:28 month:11 pages:221-227 https://dx.doi.org/10.1007/s13233-013-1074-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 21 2012 2 28 11 221-227
spelling	10.1007/s13233-013-1074-x doi (DE-627)SPR030961394 (SPR)s13233-013-1074-x-e DE-627 ger DE-627 rakwb eng Cho, Bong-Sang verfasserin aut Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2013 Abstract 2-(Methoxymethyl)oxirane (MOMO) was used as a co-monomer for ring-opening polymerization, and four different samples of poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) (poly(ECH-co-MOMO)) were synthesized by cationic ring opening copolymerization in the presence of $ BF_{3} $-etherate and 1,4-butandiol as an initiator system. Further, ferrocene modified copolymers were obtained by a substitution reaction of ferrocene methanol with the epichlorohydrin (ECH) unit in poly (ECH-co-MOMO) under mild conditions. Structural analysis of all products was performed using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly(ECH-co-MOMO) and ferrocene-modified poly(ECH-co-MOMO) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The glass transition temperatures (Tg) of PECH and PMOMO were −47 and −61 °C, respectively. As the contents of PMOMO increased, the Tg of the poly(ECH-co-MOMO)s were decreased and the onset of thermal decomposition shifted to a higher temperature. The decomposition temperature of poly(ECH-co-MOMO) was higher than that of the ferrocene-modified poly(ECH-co-MOMO). ring opening polymerization (dpeaa)DE-He213 ferrocene (dpeaa)DE-He213 thermal analysis (dpeaa)DE-He213 Noh, Si-Tae aut Enthalten in Macromolecular research Heidelberg : Springer, 2010 21(2012), 2 vom: 28. Nov., Seite 221-227 (DE-627)618327576 (DE-600)2537708-5 2092-7673 nnns volume:21 year:2012 number:2 day:28 month:11 pages:221-227 https://dx.doi.org/10.1007/s13233-013-1074-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 21 2012 2 28 11 221-227
allfields_unstemmed	10.1007/s13233-013-1074-x doi (DE-627)SPR030961394 (SPR)s13233-013-1074-x-e DE-627 ger DE-627 rakwb eng Cho, Bong-Sang verfasserin aut Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2013 Abstract 2-(Methoxymethyl)oxirane (MOMO) was used as a co-monomer for ring-opening polymerization, and four different samples of poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) (poly(ECH-co-MOMO)) were synthesized by cationic ring opening copolymerization in the presence of $ BF_{3} $-etherate and 1,4-butandiol as an initiator system. Further, ferrocene modified copolymers were obtained by a substitution reaction of ferrocene methanol with the epichlorohydrin (ECH) unit in poly (ECH-co-MOMO) under mild conditions. Structural analysis of all products was performed using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly(ECH-co-MOMO) and ferrocene-modified poly(ECH-co-MOMO) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The glass transition temperatures (Tg) of PECH and PMOMO were −47 and −61 °C, respectively. As the contents of PMOMO increased, the Tg of the poly(ECH-co-MOMO)s were decreased and the onset of thermal decomposition shifted to a higher temperature. The decomposition temperature of poly(ECH-co-MOMO) was higher than that of the ferrocene-modified poly(ECH-co-MOMO). ring opening polymerization (dpeaa)DE-He213 ferrocene (dpeaa)DE-He213 thermal analysis (dpeaa)DE-He213 Noh, Si-Tae aut Enthalten in Macromolecular research Heidelberg : Springer, 2010 21(2012), 2 vom: 28. Nov., Seite 221-227 (DE-627)618327576 (DE-600)2537708-5 2092-7673 nnns volume:21 year:2012 number:2 day:28 month:11 pages:221-227 https://dx.doi.org/10.1007/s13233-013-1074-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 21 2012 2 28 11 221-227
allfieldsGer	10.1007/s13233-013-1074-x doi (DE-627)SPR030961394 (SPR)s13233-013-1074-x-e DE-627 ger DE-627 rakwb eng Cho, Bong-Sang verfasserin aut Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2013 Abstract 2-(Methoxymethyl)oxirane (MOMO) was used as a co-monomer for ring-opening polymerization, and four different samples of poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) (poly(ECH-co-MOMO)) were synthesized by cationic ring opening copolymerization in the presence of $ BF_{3} $-etherate and 1,4-butandiol as an initiator system. Further, ferrocene modified copolymers were obtained by a substitution reaction of ferrocene methanol with the epichlorohydrin (ECH) unit in poly (ECH-co-MOMO) under mild conditions. Structural analysis of all products was performed using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly(ECH-co-MOMO) and ferrocene-modified poly(ECH-co-MOMO) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The glass transition temperatures (Tg) of PECH and PMOMO were −47 and −61 °C, respectively. As the contents of PMOMO increased, the Tg of the poly(ECH-co-MOMO)s were decreased and the onset of thermal decomposition shifted to a higher temperature. The decomposition temperature of poly(ECH-co-MOMO) was higher than that of the ferrocene-modified poly(ECH-co-MOMO). ring opening polymerization (dpeaa)DE-He213 ferrocene (dpeaa)DE-He213 thermal analysis (dpeaa)DE-He213 Noh, Si-Tae aut Enthalten in Macromolecular research Heidelberg : Springer, 2010 21(2012), 2 vom: 28. Nov., Seite 221-227 (DE-627)618327576 (DE-600)2537708-5 2092-7673 nnns volume:21 year:2012 number:2 day:28 month:11 pages:221-227 https://dx.doi.org/10.1007/s13233-013-1074-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 21 2012 2 28 11 221-227
allfieldsSound	10.1007/s13233-013-1074-x doi (DE-627)SPR030961394 (SPR)s13233-013-1074-x-e DE-627 ger DE-627 rakwb eng Cho, Bong-Sang verfasserin aut Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2013 Abstract 2-(Methoxymethyl)oxirane (MOMO) was used as a co-monomer for ring-opening polymerization, and four different samples of poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) (poly(ECH-co-MOMO)) were synthesized by cationic ring opening copolymerization in the presence of $ BF_{3} $-etherate and 1,4-butandiol as an initiator system. Further, ferrocene modified copolymers were obtained by a substitution reaction of ferrocene methanol with the epichlorohydrin (ECH) unit in poly (ECH-co-MOMO) under mild conditions. Structural analysis of all products was performed using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly(ECH-co-MOMO) and ferrocene-modified poly(ECH-co-MOMO) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The glass transition temperatures (Tg) of PECH and PMOMO were −47 and −61 °C, respectively. As the contents of PMOMO increased, the Tg of the poly(ECH-co-MOMO)s were decreased and the onset of thermal decomposition shifted to a higher temperature. The decomposition temperature of poly(ECH-co-MOMO) was higher than that of the ferrocene-modified poly(ECH-co-MOMO). ring opening polymerization (dpeaa)DE-He213 ferrocene (dpeaa)DE-He213 thermal analysis (dpeaa)DE-He213 Noh, Si-Tae aut Enthalten in Macromolecular research Heidelberg : Springer, 2010 21(2012), 2 vom: 28. Nov., Seite 221-227 (DE-627)618327576 (DE-600)2537708-5 2092-7673 nnns volume:21 year:2012 number:2 day:28 month:11 pages:221-227 https://dx.doi.org/10.1007/s13233-013-1074-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 21 2012 2 28 11 221-227
language	English
source	Enthalten in Macromolecular research 21(2012), 2 vom: 28. Nov., Seite 221-227 volume:21 year:2012 number:2 day:28 month:11 pages:221-227
sourceStr	Enthalten in Macromolecular research 21(2012), 2 vom: 28. Nov., Seite 221-227 volume:21 year:2012 number:2 day:28 month:11 pages:221-227
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	ring opening polymerization ferrocene thermal analysis
isfreeaccess_bool	false
container_title	Macromolecular research
authorswithroles_txt_mv	Cho, Bong-Sang @@aut@@ Noh, Si-Tae @@aut@@
publishDateDaySort_date	2012-11-28T00:00:00Z
hierarchy_top_id	618327576
id	SPR030961394
language_de	englisch
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Further, ferrocene modified copolymers were obtained by a substitution reaction of ferrocene methanol with the epichlorohydrin (ECH) unit in poly (ECH-co-MOMO) under mild conditions. Structural analysis of all products was performed using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly(ECH-co-MOMO) and ferrocene-modified poly(ECH-co-MOMO) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The glass transition temperatures (Tg) of PECH and PMOMO were −47 and −61 °C, respectively. As the contents of PMOMO increased, the Tg of the poly(ECH-co-MOMO)s were decreased and the onset of thermal decomposition shifted to a higher temperature. 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author	Cho, Bong-Sang
spellingShingle	Cho, Bong-Sang misc ring opening polymerization misc ferrocene misc thermal analysis Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane)
authorStr	Cho, Bong-Sang
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topic_title	Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) ring opening polymerization (dpeaa)DE-He213 ferrocene (dpeaa)DE-He213 thermal analysis (dpeaa)DE-He213
topic	misc ring opening polymerization misc ferrocene misc thermal analysis
topic_unstemmed	misc ring opening polymerization misc ferrocene misc thermal analysis
topic_browse	misc ring opening polymerization misc ferrocene misc thermal analysis
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title	Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane)
ctrlnum	(DE-627)SPR030961394 (SPR)s13233-013-1074-x-e
title_full	Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane)
author_sort	Cho, Bong-Sang
journal	Macromolecular research
journalStr	Macromolecular research
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author_browse	Cho, Bong-Sang Noh, Si-Tae
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author-letter	Cho, Bong-Sang
doi_str_mv	10.1007/s13233-013-1074-x
title_sort	synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane)
title_auth	Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane)
abstract	Abstract 2-(Methoxymethyl)oxirane (MOMO) was used as a co-monomer for ring-opening polymerization, and four different samples of poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) (poly(ECH-co-MOMO)) were synthesized by cationic ring opening copolymerization in the presence of $ BF_{3} $-etherate and 1,4-butandiol as an initiator system. Further, ferrocene modified copolymers were obtained by a substitution reaction of ferrocene methanol with the epichlorohydrin (ECH) unit in poly (ECH-co-MOMO) under mild conditions. Structural analysis of all products was performed using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly(ECH-co-MOMO) and ferrocene-modified poly(ECH-co-MOMO) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The glass transition temperatures (Tg) of PECH and PMOMO were −47 and −61 °C, respectively. As the contents of PMOMO increased, the Tg of the poly(ECH-co-MOMO)s were decreased and the onset of thermal decomposition shifted to a higher temperature. The decomposition temperature of poly(ECH-co-MOMO) was higher than that of the ferrocene-modified poly(ECH-co-MOMO). © The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2013
abstractGer	Abstract 2-(Methoxymethyl)oxirane (MOMO) was used as a co-monomer for ring-opening polymerization, and four different samples of poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) (poly(ECH-co-MOMO)) were synthesized by cationic ring opening copolymerization in the presence of $ BF_{3} $-etherate and 1,4-butandiol as an initiator system. Further, ferrocene modified copolymers were obtained by a substitution reaction of ferrocene methanol with the epichlorohydrin (ECH) unit in poly (ECH-co-MOMO) under mild conditions. Structural analysis of all products was performed using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly(ECH-co-MOMO) and ferrocene-modified poly(ECH-co-MOMO) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The glass transition temperatures (Tg) of PECH and PMOMO were −47 and −61 °C, respectively. As the contents of PMOMO increased, the Tg of the poly(ECH-co-MOMO)s were decreased and the onset of thermal decomposition shifted to a higher temperature. The decomposition temperature of poly(ECH-co-MOMO) was higher than that of the ferrocene-modified poly(ECH-co-MOMO). © The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2013
abstract_unstemmed	Abstract 2-(Methoxymethyl)oxirane (MOMO) was used as a co-monomer for ring-opening polymerization, and four different samples of poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) (poly(ECH-co-MOMO)) were synthesized by cationic ring opening copolymerization in the presence of $ BF_{3} $-etherate and 1,4-butandiol as an initiator system. Further, ferrocene modified copolymers were obtained by a substitution reaction of ferrocene methanol with the epichlorohydrin (ECH) unit in poly (ECH-co-MOMO) under mild conditions. Structural analysis of all products was performed using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly(ECH-co-MOMO) and ferrocene-modified poly(ECH-co-MOMO) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The glass transition temperatures (Tg) of PECH and PMOMO were −47 and −61 °C, respectively. As the contents of PMOMO increased, the Tg of the poly(ECH-co-MOMO)s were decreased and the onset of thermal decomposition shifted to a higher temperature. The decomposition temperature of poly(ECH-co-MOMO) was higher than that of the ferrocene-modified poly(ECH-co-MOMO). © The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2013
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title_short	Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane)
url	https://dx.doi.org/10.1007/s13233-013-1074-x
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doi_str	10.1007/s13233-013-1074-x
up_date	2024-07-03T21:10:17.226Z
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fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR030961394</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519113150.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201007s2012 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s13233-013-1074-x</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR030961394</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s13233-013-1074-x-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Cho, Bong-Sang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane)</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2012</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2013</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract 2-(Methoxymethyl)oxirane (MOMO) was used as a co-monomer for ring-opening polymerization, and four different samples of poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) (poly(ECH-co-MOMO)) were synthesized by cationic ring opening copolymerization in the presence of $ BF_{3} $-etherate and 1,4-butandiol as an initiator system. Further, ferrocene modified copolymers were obtained by a substitution reaction of ferrocene methanol with the epichlorohydrin (ECH) unit in poly (ECH-co-MOMO) under mild conditions. Structural analysis of all products was performed using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly(ECH-co-MOMO) and ferrocene-modified poly(ECH-co-MOMO) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The glass transition temperatures (Tg) of PECH and PMOMO were −47 and −61 °C, respectively. As the contents of PMOMO increased, the Tg of the poly(ECH-co-MOMO)s were decreased and the onset of thermal decomposition shifted to a higher temperature. 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Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane)

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