Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides

Abstract We report a new fragmentation pathway for the CID of ($ b_{3} $−1+Cat)+ product ions derived from the model peptide AXAG, where X=β-alanine, γ-aminobutyric acid, ɛ-amino-n-caproic acid, or 4-aminomethylbenzoic acid. By changing the amino acid to the C-terminal side of the amino acid X, and...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Cooper, Travis J. [verfasserIn] Talaty, Erach R. Van Stipdonk, Michael J.

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2005

Schlagwörter:	Neutral Loss Fragmentation Pathway Aminobutyric Acid Oxazolin Nitrile Product

Anmerkung:	© American Society for Mass Spectrometry 2005

Übergeordnetes Werk:	Enthalten in: Journal of the American Society for Mass Spectrometry - Washington, DC : ACS Publications, 1990, 16(2005), 8 vom: 01. Aug., Seite 1305-1310
Übergeordnetes Werk:	volume:16 ; year:2005 ; number:8 ; day:01 ; month:08 ; pages:1305-1310

Links:	Volltext

DOI / URN:	10.1016/j.jasms.2005.01.028

Katalog-ID:	SPR031490026

Internformat


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024	7		\|a 10.1016/j.jasms.2005.01.028 \|2 doi
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100	1		\|a Cooper, Travis J. \|e verfasserin \|4 aut
245	1	0	\|a Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides
264		1	\|c 2005
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337			\|a Computermedien \|b c \|2 rdamedia
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520			\|a Abstract We report a new fragmentation pathway for the CID of ($ b_{3} $−1+Cat)+ product ions derived from the model peptide AXAG, where X=β-alanine, γ-aminobutyric acid, ɛ-amino-n-caproic acid, or 4-aminomethylbenzoic acid. By changing the amino acid to the C-terminal side of the amino acid X, and incorporating 15N and 13C labeled residues at the same position, we conclude that the dissociation pathway most likely leads to a metal cationized nitrile. With respect to the various amino acids at position X, the putative nitrile product becomes more prominent, relative to the conventional ($ a_{3} $−1+Cat)+ species, in the order β-alanine<γ-aminobutyric acid<ɛ-aminocaproic acid<4-aminomethylbenzoic acid. The pathway is not observed for peptides with α-amino acids at position X. The product ion is observed most prominently during the CID of $ Li^{+} $ and $ Na^{+} $ cationized peptides, only to a small extent for $ Ag^{+} $ cationized peptides, and not at all from protonated analogues.
650		4	\|a Neutral Loss \|7 (dpeaa)DE-He213
650		4	\|a Fragmentation Pathway \|7 (dpeaa)DE-He213
650		4	\|a Aminobutyric Acid \|7 (dpeaa)DE-He213
650		4	\|a Oxazolin \|7 (dpeaa)DE-He213
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700	1		\|a Talaty, Erach R. \|4 aut
700	1		\|a Van Stipdonk, Michael J. \|4 aut
773	0	8	\|i Enthalten in \|t Journal of the American Society for Mass Spectrometry \|d Washington, DC : ACS Publications, 1990 \|g 16(2005), 8 vom: 01. Aug., Seite 1305-1310 \|w (DE-627)320598799 \|w (DE-600)2019911-9 \|x 1879-1123 \|7 nnns
773	1	8	\|g volume:16 \|g year:2005 \|g number:8 \|g day:01 \|g month:08 \|g pages:1305-1310
856	4	0	\|u https://dx.doi.org/10.1016/j.jasms.2005.01.028 \|z lizenzpflichtig \|3 Volltext
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_SPRINGER
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_39
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_101
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_647
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2144
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2188
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2232
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4012
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4246
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4328
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4367
912			\|a GBV_ILN_4393
912			\|a GBV_ILN_4700
951			\|a AR
952			\|d 16 \|j 2005 \|e 8 \|b 01 \|c 08 \|h 1305-1310

Indexfelder

author_variant	t j c tj tjc e r t er ert s m j v smj smjv
matchkey_str	article:18791123:2005----::oefamnainahafriobnctosrmoemt
hierarchy_sort_str	2005
publishDate	2005
allfields	10.1016/j.jasms.2005.01.028 doi (DE-627)SPR031490026 (SPR)j.jasms.2005.01.028-e DE-627 ger DE-627 rakwb eng Cooper, Travis J. verfasserin aut Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © American Society for Mass Spectrometry 2005 Abstract We report a new fragmentation pathway for the CID of ($ b_{3} $−1+Cat)+ product ions derived from the model peptide AXAG, where X=β-alanine, γ-aminobutyric acid, ɛ-amino-n-caproic acid, or 4-aminomethylbenzoic acid. By changing the amino acid to the C-terminal side of the amino acid X, and incorporating 15N and 13C labeled residues at the same position, we conclude that the dissociation pathway most likely leads to a metal cationized nitrile. With respect to the various amino acids at position X, the putative nitrile product becomes more prominent, relative to the conventional ($ a_{3} $−1+Cat)+ species, in the order β-alanine<γ-aminobutyric acid<ɛ-aminocaproic acid<4-aminomethylbenzoic acid. The pathway is not observed for peptides with α-amino acids at position X. The product ion is observed most prominently during the CID of $ Li^{+} $ and $ Na^{+} $ cationized peptides, only to a small extent for $ Ag^{+} $ cationized peptides, and not at all from protonated analogues. Neutral Loss (dpeaa)DE-He213 Fragmentation Pathway (dpeaa)DE-He213 Aminobutyric Acid (dpeaa)DE-He213 Oxazolin (dpeaa)DE-He213 Nitrile Product (dpeaa)DE-He213 Talaty, Erach R. aut Van Stipdonk, Michael J. aut Enthalten in Journal of the American Society for Mass Spectrometry Washington, DC : ACS Publications, 1990 16(2005), 8 vom: 01. Aug., Seite 1305-1310 (DE-627)320598799 (DE-600)2019911-9 1879-1123 nnns volume:16 year:2005 number:8 day:01 month:08 pages:1305-1310 https://dx.doi.org/10.1016/j.jasms.2005.01.028 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 16 2005 8 01 08 1305-1310
spelling	10.1016/j.jasms.2005.01.028 doi (DE-627)SPR031490026 (SPR)j.jasms.2005.01.028-e DE-627 ger DE-627 rakwb eng Cooper, Travis J. verfasserin aut Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © American Society for Mass Spectrometry 2005 Abstract We report a new fragmentation pathway for the CID of ($ b_{3} $−1+Cat)+ product ions derived from the model peptide AXAG, where X=β-alanine, γ-aminobutyric acid, ɛ-amino-n-caproic acid, or 4-aminomethylbenzoic acid. By changing the amino acid to the C-terminal side of the amino acid X, and incorporating 15N and 13C labeled residues at the same position, we conclude that the dissociation pathway most likely leads to a metal cationized nitrile. With respect to the various amino acids at position X, the putative nitrile product becomes more prominent, relative to the conventional ($ a_{3} $−1+Cat)+ species, in the order β-alanine<γ-aminobutyric acid<ɛ-aminocaproic acid<4-aminomethylbenzoic acid. The pathway is not observed for peptides with α-amino acids at position X. The product ion is observed most prominently during the CID of $ Li^{+} $ and $ Na^{+} $ cationized peptides, only to a small extent for $ Ag^{+} $ cationized peptides, and not at all from protonated analogues. Neutral Loss (dpeaa)DE-He213 Fragmentation Pathway (dpeaa)DE-He213 Aminobutyric Acid (dpeaa)DE-He213 Oxazolin (dpeaa)DE-He213 Nitrile Product (dpeaa)DE-He213 Talaty, Erach R. aut Van Stipdonk, Michael J. aut Enthalten in Journal of the American Society for Mass Spectrometry Washington, DC : ACS Publications, 1990 16(2005), 8 vom: 01. Aug., Seite 1305-1310 (DE-627)320598799 (DE-600)2019911-9 1879-1123 nnns volume:16 year:2005 number:8 day:01 month:08 pages:1305-1310 https://dx.doi.org/10.1016/j.jasms.2005.01.028 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 16 2005 8 01 08 1305-1310
allfields_unstemmed	10.1016/j.jasms.2005.01.028 doi (DE-627)SPR031490026 (SPR)j.jasms.2005.01.028-e DE-627 ger DE-627 rakwb eng Cooper, Travis J. verfasserin aut Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © American Society for Mass Spectrometry 2005 Abstract We report a new fragmentation pathway for the CID of ($ b_{3} $−1+Cat)+ product ions derived from the model peptide AXAG, where X=β-alanine, γ-aminobutyric acid, ɛ-amino-n-caproic acid, or 4-aminomethylbenzoic acid. By changing the amino acid to the C-terminal side of the amino acid X, and incorporating 15N and 13C labeled residues at the same position, we conclude that the dissociation pathway most likely leads to a metal cationized nitrile. With respect to the various amino acids at position X, the putative nitrile product becomes more prominent, relative to the conventional ($ a_{3} $−1+Cat)+ species, in the order β-alanine<γ-aminobutyric acid<ɛ-aminocaproic acid<4-aminomethylbenzoic acid. The pathway is not observed for peptides with α-amino acids at position X. The product ion is observed most prominently during the CID of $ Li^{+} $ and $ Na^{+} $ cationized peptides, only to a small extent for $ Ag^{+} $ cationized peptides, and not at all from protonated analogues. Neutral Loss (dpeaa)DE-He213 Fragmentation Pathway (dpeaa)DE-He213 Aminobutyric Acid (dpeaa)DE-He213 Oxazolin (dpeaa)DE-He213 Nitrile Product (dpeaa)DE-He213 Talaty, Erach R. aut Van Stipdonk, Michael J. aut Enthalten in Journal of the American Society for Mass Spectrometry Washington, DC : ACS Publications, 1990 16(2005), 8 vom: 01. Aug., Seite 1305-1310 (DE-627)320598799 (DE-600)2019911-9 1879-1123 nnns volume:16 year:2005 number:8 day:01 month:08 pages:1305-1310 https://dx.doi.org/10.1016/j.jasms.2005.01.028 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 16 2005 8 01 08 1305-1310
allfieldsGer	10.1016/j.jasms.2005.01.028 doi (DE-627)SPR031490026 (SPR)j.jasms.2005.01.028-e DE-627 ger DE-627 rakwb eng Cooper, Travis J. verfasserin aut Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © American Society for Mass Spectrometry 2005 Abstract We report a new fragmentation pathway for the CID of ($ b_{3} $−1+Cat)+ product ions derived from the model peptide AXAG, where X=β-alanine, γ-aminobutyric acid, ɛ-amino-n-caproic acid, or 4-aminomethylbenzoic acid. By changing the amino acid to the C-terminal side of the amino acid X, and incorporating 15N and 13C labeled residues at the same position, we conclude that the dissociation pathway most likely leads to a metal cationized nitrile. With respect to the various amino acids at position X, the putative nitrile product becomes more prominent, relative to the conventional ($ a_{3} $−1+Cat)+ species, in the order β-alanine<γ-aminobutyric acid<ɛ-aminocaproic acid<4-aminomethylbenzoic acid. The pathway is not observed for peptides with α-amino acids at position X. The product ion is observed most prominently during the CID of $ Li^{+} $ and $ Na^{+} $ cationized peptides, only to a small extent for $ Ag^{+} $ cationized peptides, and not at all from protonated analogues. Neutral Loss (dpeaa)DE-He213 Fragmentation Pathway (dpeaa)DE-He213 Aminobutyric Acid (dpeaa)DE-He213 Oxazolin (dpeaa)DE-He213 Nitrile Product (dpeaa)DE-He213 Talaty, Erach R. aut Van Stipdonk, Michael J. aut Enthalten in Journal of the American Society for Mass Spectrometry Washington, DC : ACS Publications, 1990 16(2005), 8 vom: 01. Aug., Seite 1305-1310 (DE-627)320598799 (DE-600)2019911-9 1879-1123 nnns volume:16 year:2005 number:8 day:01 month:08 pages:1305-1310 https://dx.doi.org/10.1016/j.jasms.2005.01.028 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 16 2005 8 01 08 1305-1310
allfieldsSound	10.1016/j.jasms.2005.01.028 doi (DE-627)SPR031490026 (SPR)j.jasms.2005.01.028-e DE-627 ger DE-627 rakwb eng Cooper, Travis J. verfasserin aut Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © American Society for Mass Spectrometry 2005 Abstract We report a new fragmentation pathway for the CID of ($ b_{3} $−1+Cat)+ product ions derived from the model peptide AXAG, where X=β-alanine, γ-aminobutyric acid, ɛ-amino-n-caproic acid, or 4-aminomethylbenzoic acid. By changing the amino acid to the C-terminal side of the amino acid X, and incorporating 15N and 13C labeled residues at the same position, we conclude that the dissociation pathway most likely leads to a metal cationized nitrile. With respect to the various amino acids at position X, the putative nitrile product becomes more prominent, relative to the conventional ($ a_{3} $−1+Cat)+ species, in the order β-alanine<γ-aminobutyric acid<ɛ-aminocaproic acid<4-aminomethylbenzoic acid. The pathway is not observed for peptides with α-amino acids at position X. The product ion is observed most prominently during the CID of $ Li^{+} $ and $ Na^{+} $ cationized peptides, only to a small extent for $ Ag^{+} $ cationized peptides, and not at all from protonated analogues. Neutral Loss (dpeaa)DE-He213 Fragmentation Pathway (dpeaa)DE-He213 Aminobutyric Acid (dpeaa)DE-He213 Oxazolin (dpeaa)DE-He213 Nitrile Product (dpeaa)DE-He213 Talaty, Erach R. aut Van Stipdonk, Michael J. aut Enthalten in Journal of the American Society for Mass Spectrometry Washington, DC : ACS Publications, 1990 16(2005), 8 vom: 01. Aug., Seite 1305-1310 (DE-627)320598799 (DE-600)2019911-9 1879-1123 nnns volume:16 year:2005 number:8 day:01 month:08 pages:1305-1310 https://dx.doi.org/10.1016/j.jasms.2005.01.028 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 16 2005 8 01 08 1305-1310
language	English
source	Enthalten in Journal of the American Society for Mass Spectrometry 16(2005), 8 vom: 01. Aug., Seite 1305-1310 volume:16 year:2005 number:8 day:01 month:08 pages:1305-1310
sourceStr	Enthalten in Journal of the American Society for Mass Spectrometry 16(2005), 8 vom: 01. Aug., Seite 1305-1310 volume:16 year:2005 number:8 day:01 month:08 pages:1305-1310
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Neutral Loss Fragmentation Pathway Aminobutyric Acid Oxazolin Nitrile Product
isfreeaccess_bool	false
container_title	Journal of the American Society for Mass Spectrometry
authorswithroles_txt_mv	Cooper, Travis J. @@aut@@ Talaty, Erach R. @@aut@@ Van Stipdonk, Michael J. @@aut@@
publishDateDaySort_date	2005-08-01T00:00:00Z
hierarchy_top_id	320598799
id	SPR031490026
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR031490026</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230331083340.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201007s2005 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.jasms.2005.01.028</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR031490026</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)j.jasms.2005.01.028-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Cooper, Travis J.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2005</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© American Society for Mass Spectrometry 2005</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract We report a new fragmentation pathway for the CID of ($ b_{3} $−1+Cat)+ product ions derived from the model peptide AXAG, where X=β-alanine, γ-aminobutyric acid, ɛ-amino-n-caproic acid, or 4-aminomethylbenzoic acid. 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author	Cooper, Travis J.
spellingShingle	Cooper, Travis J. misc Neutral Loss misc Fragmentation Pathway misc Aminobutyric Acid misc Oxazolin misc Nitrile Product Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides
authorStr	Cooper, Travis J.
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topic_title	Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides Neutral Loss (dpeaa)DE-He213 Fragmentation Pathway (dpeaa)DE-He213 Aminobutyric Acid (dpeaa)DE-He213 Oxazolin (dpeaa)DE-He213 Nitrile Product (dpeaa)DE-He213
topic	misc Neutral Loss misc Fragmentation Pathway misc Aminobutyric Acid misc Oxazolin misc Nitrile Product
topic_unstemmed	misc Neutral Loss misc Fragmentation Pathway misc Aminobutyric Acid misc Oxazolin misc Nitrile Product
topic_browse	misc Neutral Loss misc Fragmentation Pathway misc Aminobutyric Acid misc Oxazolin misc Nitrile Product
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title	Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides
ctrlnum	(DE-627)SPR031490026 (SPR)j.jasms.2005.01.028-e
title_full	Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides
author_sort	Cooper, Travis J.
journal	Journal of the American Society for Mass Spectrometry
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author_browse	Cooper, Travis J. Talaty, Erach R. Van Stipdonk, Michael J.
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author-letter	Cooper, Travis J.
doi_str_mv	10.1016/j.jasms.2005.01.028
title_sort	novel fragmentation pathway for cid of ($ b_{n} $−1+cat)+ ions from model, metal cationized peptides
title_auth	Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides
abstract	Abstract We report a new fragmentation pathway for the CID of ($ b_{3} $−1+Cat)+ product ions derived from the model peptide AXAG, where X=β-alanine, γ-aminobutyric acid, ɛ-amino-n-caproic acid, or 4-aminomethylbenzoic acid. By changing the amino acid to the C-terminal side of the amino acid X, and incorporating 15N and 13C labeled residues at the same position, we conclude that the dissociation pathway most likely leads to a metal cationized nitrile. With respect to the various amino acids at position X, the putative nitrile product becomes more prominent, relative to the conventional ($ a_{3} $−1+Cat)+ species, in the order β-alanine<γ-aminobutyric acid<ɛ-aminocaproic acid<4-aminomethylbenzoic acid. The pathway is not observed for peptides with α-amino acids at position X. The product ion is observed most prominently during the CID of $ Li^{+} $ and $ Na^{+} $ cationized peptides, only to a small extent for $ Ag^{+} $ cationized peptides, and not at all from protonated analogues. © American Society for Mass Spectrometry 2005
abstractGer	Abstract We report a new fragmentation pathway for the CID of ($ b_{3} $−1+Cat)+ product ions derived from the model peptide AXAG, where X=β-alanine, γ-aminobutyric acid, ɛ-amino-n-caproic acid, or 4-aminomethylbenzoic acid. By changing the amino acid to the C-terminal side of the amino acid X, and incorporating 15N and 13C labeled residues at the same position, we conclude that the dissociation pathway most likely leads to a metal cationized nitrile. With respect to the various amino acids at position X, the putative nitrile product becomes more prominent, relative to the conventional ($ a_{3} $−1+Cat)+ species, in the order β-alanine<γ-aminobutyric acid<ɛ-aminocaproic acid<4-aminomethylbenzoic acid. The pathway is not observed for peptides with α-amino acids at position X. The product ion is observed most prominently during the CID of $ Li^{+} $ and $ Na^{+} $ cationized peptides, only to a small extent for $ Ag^{+} $ cationized peptides, and not at all from protonated analogues. © American Society for Mass Spectrometry 2005
abstract_unstemmed	Abstract We report a new fragmentation pathway for the CID of ($ b_{3} $−1+Cat)+ product ions derived from the model peptide AXAG, where X=β-alanine, γ-aminobutyric acid, ɛ-amino-n-caproic acid, or 4-aminomethylbenzoic acid. By changing the amino acid to the C-terminal side of the amino acid X, and incorporating 15N and 13C labeled residues at the same position, we conclude that the dissociation pathway most likely leads to a metal cationized nitrile. With respect to the various amino acids at position X, the putative nitrile product becomes more prominent, relative to the conventional ($ a_{3} $−1+Cat)+ species, in the order β-alanine<γ-aminobutyric acid<ɛ-aminocaproic acid<4-aminomethylbenzoic acid. The pathway is not observed for peptides with α-amino acids at position X. The product ion is observed most prominently during the CID of $ Li^{+} $ and $ Na^{+} $ cationized peptides, only to a small extent for $ Ag^{+} $ cationized peptides, and not at all from protonated analogues. © American Society for Mass Spectrometry 2005
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title_short	Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides
url	https://dx.doi.org/10.1016/j.jasms.2005.01.028
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author2	Talaty, Erach R. Van Stipdonk, Michael J.
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doi_str	10.1016/j.jasms.2005.01.028
up_date	2024-07-03T23:58:04.831Z
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Novel fragmentation pathway for CID of ($ b_{n} $−1+Cat)+ ions from model, metal cationized peptides

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