XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii

Abstract Flavin-dependent halogenases (FHals) catalyse the halogenation of electron-rich substrates, mainly aromatics. Halogenated compounds have many applications, as pharmaceutical, agrochemicals or as starting materials for the synthesis of complex molecules. By exploring the sequenced bacterial...
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Autor*in:	Domergue, Jérémy [verfasserIn] Erdmann, Diane [verfasserIn] Fossey-Jouenne, Aurélie [verfasserIn] Petit, Jean-Louis [verfasserIn] Debard, Adrien [verfasserIn] de Berardinis, Véronique [verfasserIn] Vergne-Vaxelaire, Carine [verfasserIn] Zaparucha, Anne [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Flavin-dependent halogenases Biocatalysis Electrophilic halogenation Regioselectivity Indole derivatives

Übergeordnetes Werk:	Enthalten in: AMB express - Heidelberg : Springer, 2011, 9(2019), 1 vom: 31. Okt.
Übergeordnetes Werk:	volume:9 ; year:2019 ; number:1 ; day:31 ; month:10

Links:	Volltext

DOI / URN:	10.1186/s13568-019-0898-y

Katalog-ID:	SPR031837468

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520			\|a Abstract Flavin-dependent halogenases (FHals) catalyse the halogenation of electron-rich substrates, mainly aromatics. Halogenated compounds have many applications, as pharmaceutical, agrochemicals or as starting materials for the synthesis of complex molecules. By exploring the sequenced bacterial diversity, we discovered and characterized XszenFHal, a novel FHal from Xenorhabdus szentirmaii, a symbiotic bacterium of entomopathogenic nematode. The substrate scope of XszenFHal was examined and revealed activities towards tryptophan, indole and indole derivatives, leading to the formation of the corresponding 5-chloro products. XszenFHal makes a valuable addition to the panel of flavin-dependent halogenases already discovered and enriches the potential for biotechnology applications by allowing access to 5-halogenated indole derivatives.
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allfields	10.1186/s13568-019-0898-y doi (DE-627)SPR031837468 (SPR)s13568-019-0898-y-e DE-627 ger DE-627 rakwb eng 570 ASE 58.30 bkl Domergue, Jérémy verfasserin aut XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Flavin-dependent halogenases (FHals) catalyse the halogenation of electron-rich substrates, mainly aromatics. Halogenated compounds have many applications, as pharmaceutical, agrochemicals or as starting materials for the synthesis of complex molecules. By exploring the sequenced bacterial diversity, we discovered and characterized XszenFHal, a novel FHal from Xenorhabdus szentirmaii, a symbiotic bacterium of entomopathogenic nematode. The substrate scope of XszenFHal was examined and revealed activities towards tryptophan, indole and indole derivatives, leading to the formation of the corresponding 5-chloro products. XszenFHal makes a valuable addition to the panel of flavin-dependent halogenases already discovered and enriches the potential for biotechnology applications by allowing access to 5-halogenated indole derivatives. Flavin-dependent halogenases (dpeaa)DE-He213 Biocatalysis (dpeaa)DE-He213 Electrophilic halogenation (dpeaa)DE-He213 Regioselectivity (dpeaa)DE-He213 Indole derivatives (dpeaa)DE-He213 Erdmann, Diane verfasserin aut Fossey-Jouenne, Aurélie verfasserin aut Petit, Jean-Louis verfasserin aut Debard, Adrien verfasserin aut de Berardinis, Véronique verfasserin aut Vergne-Vaxelaire, Carine verfasserin aut Zaparucha, Anne verfasserin aut Enthalten in AMB express Heidelberg : Springer, 2011 9(2019), 1 vom: 31. Okt. (DE-627)665672926 (DE-600)2621432-5 2191-0855 nnns volume:9 year:2019 number:1 day:31 month:10 https://dx.doi.org/10.1186/s13568-019-0898-y kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 58.30 ASE AR 9 2019 1 31 10
spelling	10.1186/s13568-019-0898-y doi (DE-627)SPR031837468 (SPR)s13568-019-0898-y-e DE-627 ger DE-627 rakwb eng 570 ASE 58.30 bkl Domergue, Jérémy verfasserin aut XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Flavin-dependent halogenases (FHals) catalyse the halogenation of electron-rich substrates, mainly aromatics. Halogenated compounds have many applications, as pharmaceutical, agrochemicals or as starting materials for the synthesis of complex molecules. By exploring the sequenced bacterial diversity, we discovered and characterized XszenFHal, a novel FHal from Xenorhabdus szentirmaii, a symbiotic bacterium of entomopathogenic nematode. The substrate scope of XszenFHal was examined and revealed activities towards tryptophan, indole and indole derivatives, leading to the formation of the corresponding 5-chloro products. XszenFHal makes a valuable addition to the panel of flavin-dependent halogenases already discovered and enriches the potential for biotechnology applications by allowing access to 5-halogenated indole derivatives. Flavin-dependent halogenases (dpeaa)DE-He213 Biocatalysis (dpeaa)DE-He213 Electrophilic halogenation (dpeaa)DE-He213 Regioselectivity (dpeaa)DE-He213 Indole derivatives (dpeaa)DE-He213 Erdmann, Diane verfasserin aut Fossey-Jouenne, Aurélie verfasserin aut Petit, Jean-Louis verfasserin aut Debard, Adrien verfasserin aut de Berardinis, Véronique verfasserin aut Vergne-Vaxelaire, Carine verfasserin aut Zaparucha, Anne verfasserin aut Enthalten in AMB express Heidelberg : Springer, 2011 9(2019), 1 vom: 31. Okt. (DE-627)665672926 (DE-600)2621432-5 2191-0855 nnns volume:9 year:2019 number:1 day:31 month:10 https://dx.doi.org/10.1186/s13568-019-0898-y kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 58.30 ASE AR 9 2019 1 31 10
allfields_unstemmed	10.1186/s13568-019-0898-y doi (DE-627)SPR031837468 (SPR)s13568-019-0898-y-e DE-627 ger DE-627 rakwb eng 570 ASE 58.30 bkl Domergue, Jérémy verfasserin aut XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Flavin-dependent halogenases (FHals) catalyse the halogenation of electron-rich substrates, mainly aromatics. Halogenated compounds have many applications, as pharmaceutical, agrochemicals or as starting materials for the synthesis of complex molecules. By exploring the sequenced bacterial diversity, we discovered and characterized XszenFHal, a novel FHal from Xenorhabdus szentirmaii, a symbiotic bacterium of entomopathogenic nematode. The substrate scope of XszenFHal was examined and revealed activities towards tryptophan, indole and indole derivatives, leading to the formation of the corresponding 5-chloro products. XszenFHal makes a valuable addition to the panel of flavin-dependent halogenases already discovered and enriches the potential for biotechnology applications by allowing access to 5-halogenated indole derivatives. Flavin-dependent halogenases (dpeaa)DE-He213 Biocatalysis (dpeaa)DE-He213 Electrophilic halogenation (dpeaa)DE-He213 Regioselectivity (dpeaa)DE-He213 Indole derivatives (dpeaa)DE-He213 Erdmann, Diane verfasserin aut Fossey-Jouenne, Aurélie verfasserin aut Petit, Jean-Louis verfasserin aut Debard, Adrien verfasserin aut de Berardinis, Véronique verfasserin aut Vergne-Vaxelaire, Carine verfasserin aut Zaparucha, Anne verfasserin aut Enthalten in AMB express Heidelberg : Springer, 2011 9(2019), 1 vom: 31. Okt. (DE-627)665672926 (DE-600)2621432-5 2191-0855 nnns volume:9 year:2019 number:1 day:31 month:10 https://dx.doi.org/10.1186/s13568-019-0898-y kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 58.30 ASE AR 9 2019 1 31 10
allfieldsGer	10.1186/s13568-019-0898-y doi (DE-627)SPR031837468 (SPR)s13568-019-0898-y-e DE-627 ger DE-627 rakwb eng 570 ASE 58.30 bkl Domergue, Jérémy verfasserin aut XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Flavin-dependent halogenases (FHals) catalyse the halogenation of electron-rich substrates, mainly aromatics. Halogenated compounds have many applications, as pharmaceutical, agrochemicals or as starting materials for the synthesis of complex molecules. By exploring the sequenced bacterial diversity, we discovered and characterized XszenFHal, a novel FHal from Xenorhabdus szentirmaii, a symbiotic bacterium of entomopathogenic nematode. The substrate scope of XszenFHal was examined and revealed activities towards tryptophan, indole and indole derivatives, leading to the formation of the corresponding 5-chloro products. XszenFHal makes a valuable addition to the panel of flavin-dependent halogenases already discovered and enriches the potential for biotechnology applications by allowing access to 5-halogenated indole derivatives. Flavin-dependent halogenases (dpeaa)DE-He213 Biocatalysis (dpeaa)DE-He213 Electrophilic halogenation (dpeaa)DE-He213 Regioselectivity (dpeaa)DE-He213 Indole derivatives (dpeaa)DE-He213 Erdmann, Diane verfasserin aut Fossey-Jouenne, Aurélie verfasserin aut Petit, Jean-Louis verfasserin aut Debard, Adrien verfasserin aut de Berardinis, Véronique verfasserin aut Vergne-Vaxelaire, Carine verfasserin aut Zaparucha, Anne verfasserin aut Enthalten in AMB express Heidelberg : Springer, 2011 9(2019), 1 vom: 31. Okt. (DE-627)665672926 (DE-600)2621432-5 2191-0855 nnns volume:9 year:2019 number:1 day:31 month:10 https://dx.doi.org/10.1186/s13568-019-0898-y kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 58.30 ASE AR 9 2019 1 31 10
allfieldsSound	10.1186/s13568-019-0898-y doi (DE-627)SPR031837468 (SPR)s13568-019-0898-y-e DE-627 ger DE-627 rakwb eng 570 ASE 58.30 bkl Domergue, Jérémy verfasserin aut XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Flavin-dependent halogenases (FHals) catalyse the halogenation of electron-rich substrates, mainly aromatics. Halogenated compounds have many applications, as pharmaceutical, agrochemicals or as starting materials for the synthesis of complex molecules. By exploring the sequenced bacterial diversity, we discovered and characterized XszenFHal, a novel FHal from Xenorhabdus szentirmaii, a symbiotic bacterium of entomopathogenic nematode. The substrate scope of XszenFHal was examined and revealed activities towards tryptophan, indole and indole derivatives, leading to the formation of the corresponding 5-chloro products. XszenFHal makes a valuable addition to the panel of flavin-dependent halogenases already discovered and enriches the potential for biotechnology applications by allowing access to 5-halogenated indole derivatives. Flavin-dependent halogenases (dpeaa)DE-He213 Biocatalysis (dpeaa)DE-He213 Electrophilic halogenation (dpeaa)DE-He213 Regioselectivity (dpeaa)DE-He213 Indole derivatives (dpeaa)DE-He213 Erdmann, Diane verfasserin aut Fossey-Jouenne, Aurélie verfasserin aut Petit, Jean-Louis verfasserin aut Debard, Adrien verfasserin aut de Berardinis, Véronique verfasserin aut Vergne-Vaxelaire, Carine verfasserin aut Zaparucha, Anne verfasserin aut Enthalten in AMB express Heidelberg : Springer, 2011 9(2019), 1 vom: 31. Okt. (DE-627)665672926 (DE-600)2621432-5 2191-0855 nnns volume:9 year:2019 number:1 day:31 month:10 https://dx.doi.org/10.1186/s13568-019-0898-y kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 58.30 ASE AR 9 2019 1 31 10
language	English
source	Enthalten in AMB express 9(2019), 1 vom: 31. Okt. volume:9 year:2019 number:1 day:31 month:10
sourceStr	Enthalten in AMB express 9(2019), 1 vom: 31. Okt. volume:9 year:2019 number:1 day:31 month:10
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Flavin-dependent halogenases Biocatalysis Electrophilic halogenation Regioselectivity Indole derivatives
dewey-raw	570
isfreeaccess_bool	true
container_title	AMB express
authorswithroles_txt_mv	Domergue, Jérémy @@aut@@ Erdmann, Diane @@aut@@ Fossey-Jouenne, Aurélie @@aut@@ Petit, Jean-Louis @@aut@@ Debard, Adrien @@aut@@ de Berardinis, Véronique @@aut@@ Vergne-Vaxelaire, Carine @@aut@@ Zaparucha, Anne @@aut@@
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author	Domergue, Jérémy
spellingShingle	Domergue, Jérémy ddc 570 bkl 58.30 misc Flavin-dependent halogenases misc Biocatalysis misc Electrophilic halogenation misc Regioselectivity misc Indole derivatives XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii
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topic_title	570 ASE 58.30 bkl XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii Flavin-dependent halogenases (dpeaa)DE-He213 Biocatalysis (dpeaa)DE-He213 Electrophilic halogenation (dpeaa)DE-He213 Regioselectivity (dpeaa)DE-He213 Indole derivatives (dpeaa)DE-He213
topic	ddc 570 bkl 58.30 misc Flavin-dependent halogenases misc Biocatalysis misc Electrophilic halogenation misc Regioselectivity misc Indole derivatives
topic_unstemmed	ddc 570 bkl 58.30 misc Flavin-dependent halogenases misc Biocatalysis misc Electrophilic halogenation misc Regioselectivity misc Indole derivatives
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title	XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii
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title_full	XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii
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author_browse	Domergue, Jérémy Erdmann, Diane Fossey-Jouenne, Aurélie Petit, Jean-Louis Debard, Adrien de Berardinis, Véronique Vergne-Vaxelaire, Carine Zaparucha, Anne
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title_sort	xszenfhal, a novel tryptophan 5-halogenase from xenorhabdus szentirmaii
title_auth	XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii
abstract	Abstract Flavin-dependent halogenases (FHals) catalyse the halogenation of electron-rich substrates, mainly aromatics. Halogenated compounds have many applications, as pharmaceutical, agrochemicals or as starting materials for the synthesis of complex molecules. By exploring the sequenced bacterial diversity, we discovered and characterized XszenFHal, a novel FHal from Xenorhabdus szentirmaii, a symbiotic bacterium of entomopathogenic nematode. The substrate scope of XszenFHal was examined and revealed activities towards tryptophan, indole and indole derivatives, leading to the formation of the corresponding 5-chloro products. XszenFHal makes a valuable addition to the panel of flavin-dependent halogenases already discovered and enriches the potential for biotechnology applications by allowing access to 5-halogenated indole derivatives.
abstractGer	Abstract Flavin-dependent halogenases (FHals) catalyse the halogenation of electron-rich substrates, mainly aromatics. Halogenated compounds have many applications, as pharmaceutical, agrochemicals or as starting materials for the synthesis of complex molecules. By exploring the sequenced bacterial diversity, we discovered and characterized XszenFHal, a novel FHal from Xenorhabdus szentirmaii, a symbiotic bacterium of entomopathogenic nematode. The substrate scope of XszenFHal was examined and revealed activities towards tryptophan, indole and indole derivatives, leading to the formation of the corresponding 5-chloro products. XszenFHal makes a valuable addition to the panel of flavin-dependent halogenases already discovered and enriches the potential for biotechnology applications by allowing access to 5-halogenated indole derivatives.
abstract_unstemmed	Abstract Flavin-dependent halogenases (FHals) catalyse the halogenation of electron-rich substrates, mainly aromatics. Halogenated compounds have many applications, as pharmaceutical, agrochemicals or as starting materials for the synthesis of complex molecules. By exploring the sequenced bacterial diversity, we discovered and characterized XszenFHal, a novel FHal from Xenorhabdus szentirmaii, a symbiotic bacterium of entomopathogenic nematode. The substrate scope of XszenFHal was examined and revealed activities towards tryptophan, indole and indole derivatives, leading to the formation of the corresponding 5-chloro products. XszenFHal makes a valuable addition to the panel of flavin-dependent halogenases already discovered and enriches the potential for biotechnology applications by allowing access to 5-halogenated indole derivatives.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700
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title_short	XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii
url	https://dx.doi.org/10.1186/s13568-019-0898-y
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author2	Erdmann, Diane Fossey-Jouenne, Aurélie Petit, Jean-Louis Debard, Adrien de Berardinis, Véronique Vergne-Vaxelaire, Carine Zaparucha, Anne
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up_date	2024-07-04T01:27:41.535Z
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Halogenated compounds have many applications, as pharmaceutical, agrochemicals or as starting materials for the synthesis of complex molecules. By exploring the sequenced bacterial diversity, we discovered and characterized XszenFHal, a novel FHal from Xenorhabdus szentirmaii, a symbiotic bacterium of entomopathogenic nematode. The substrate scope of XszenFHal was examined and revealed activities towards tryptophan, indole and indole derivatives, leading to the formation of the corresponding 5-chloro products. 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XszenFHal, a novel tryptophan 5-halogenase from Xenorhabdus szentirmaii

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