Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route
Abstract For preparing wurtzite and cubic boron nitride (wBN, cBN) under moderate conditions, here we developed a solvothermal hot-press method, by which the phase transformation of $ sp^{3} $-bonded BN in boron nitride (BN) nanoparticles was realized at quite low temperature and pressure. The resul...
Ausführliche Beschreibung
Autor*in: |
Zhu, Lingling [verfasserIn] Zhou, Ying [verfasserIn] Ma, Juan [verfasserIn] Ye, Guotian [verfasserIn] Cui, Deliang [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2015 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: The Arabian journal for science and engineering - Berlin : Springer, 2011, 40(2015), 10 vom: Okt., Seite 2903-2911 |
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Übergeordnetes Werk: |
volume:40 ; year:2015 ; number:10 ; month:10 ; pages:2903-2911 |
Links: |
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DOI / URN: |
10.1007/s13369-015-1861-0 |
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Katalog-ID: |
SPR031845355 |
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520 | |a Abstract For preparing wurtzite and cubic boron nitride (wBN, cBN) under moderate conditions, here we developed a solvothermal hot-press method, by which the phase transformation of $ sp^{3} $-bonded BN in boron nitride (BN) nanoparticles was realized at quite low temperature and pressure. The results reveal that the transformation of aBN/rBN→cBN is highly dependent on the temperature, pressure and solvent promoting effect; and chlorobenzene seems to have a stronger effect on facilitating the phase transformation of $ sp^{3} $-bonded BN as compared to pyridine and aniline. Besides, the decrease in particle size and crystallinity as well as the existence of structural defects plays great roles on the phase transformations of $ sp^{3} $-bonded BN. On the basis of analyzing the experimental results, we proposed a simple model used for explaining the phase transformation process. | ||
650 | 4 | |a Boron nitride |7 (dpeaa)DE-He213 | |
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650 | 4 | |a Phase transformation |7 (dpeaa)DE-He213 | |
650 | 4 | |a Solvothermal hot-press |7 (dpeaa)DE-He213 | |
700 | 1 | |a Zhou, Ying |e verfasserin |4 aut | |
700 | 1 | |a Ma, Juan |e verfasserin |4 aut | |
700 | 1 | |a Ye, Guotian |e verfasserin |4 aut | |
700 | 1 | |a Cui, Deliang |e verfasserin |4 aut | |
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10.1007/s13369-015-1861-0 doi (DE-627)SPR031845355 (SPR)s13369-015-1861-0-e DE-627 ger DE-627 rakwb eng 600 500 ASE 31.00 bkl Zhu, Lingling verfasserin aut Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract For preparing wurtzite and cubic boron nitride (wBN, cBN) under moderate conditions, here we developed a solvothermal hot-press method, by which the phase transformation of $ sp^{3} $-bonded BN in boron nitride (BN) nanoparticles was realized at quite low temperature and pressure. The results reveal that the transformation of aBN/rBN→cBN is highly dependent on the temperature, pressure and solvent promoting effect; and chlorobenzene seems to have a stronger effect on facilitating the phase transformation of $ sp^{3} $-bonded BN as compared to pyridine and aniline. Besides, the decrease in particle size and crystallinity as well as the existence of structural defects plays great roles on the phase transformations of $ sp^{3} $-bonded BN. On the basis of analyzing the experimental results, we proposed a simple model used for explaining the phase transformation process. Boron nitride (dpeaa)DE-He213 Nanoparticles (dpeaa)DE-He213 Phase transformation (dpeaa)DE-He213 Solvothermal hot-press (dpeaa)DE-He213 Zhou, Ying verfasserin aut Ma, Juan verfasserin aut Ye, Guotian verfasserin aut Cui, Deliang verfasserin aut Enthalten in The Arabian journal for science and engineering Berlin : Springer, 2011 40(2015), 10 vom: Okt., Seite 2903-2911 (DE-627)588780731 (DE-600)2471504-9 2191-4281 nnns volume:40 year:2015 number:10 month:10 pages:2903-2911 https://dx.doi.org/10.1007/s13369-015-1861-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 31.00 ASE AR 40 2015 10 10 2903-2911 |
spelling |
10.1007/s13369-015-1861-0 doi (DE-627)SPR031845355 (SPR)s13369-015-1861-0-e DE-627 ger DE-627 rakwb eng 600 500 ASE 31.00 bkl Zhu, Lingling verfasserin aut Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract For preparing wurtzite and cubic boron nitride (wBN, cBN) under moderate conditions, here we developed a solvothermal hot-press method, by which the phase transformation of $ sp^{3} $-bonded BN in boron nitride (BN) nanoparticles was realized at quite low temperature and pressure. The results reveal that the transformation of aBN/rBN→cBN is highly dependent on the temperature, pressure and solvent promoting effect; and chlorobenzene seems to have a stronger effect on facilitating the phase transformation of $ sp^{3} $-bonded BN as compared to pyridine and aniline. Besides, the decrease in particle size and crystallinity as well as the existence of structural defects plays great roles on the phase transformations of $ sp^{3} $-bonded BN. On the basis of analyzing the experimental results, we proposed a simple model used for explaining the phase transformation process. Boron nitride (dpeaa)DE-He213 Nanoparticles (dpeaa)DE-He213 Phase transformation (dpeaa)DE-He213 Solvothermal hot-press (dpeaa)DE-He213 Zhou, Ying verfasserin aut Ma, Juan verfasserin aut Ye, Guotian verfasserin aut Cui, Deliang verfasserin aut Enthalten in The Arabian journal for science and engineering Berlin : Springer, 2011 40(2015), 10 vom: Okt., Seite 2903-2911 (DE-627)588780731 (DE-600)2471504-9 2191-4281 nnns volume:40 year:2015 number:10 month:10 pages:2903-2911 https://dx.doi.org/10.1007/s13369-015-1861-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 31.00 ASE AR 40 2015 10 10 2903-2911 |
allfields_unstemmed |
10.1007/s13369-015-1861-0 doi (DE-627)SPR031845355 (SPR)s13369-015-1861-0-e DE-627 ger DE-627 rakwb eng 600 500 ASE 31.00 bkl Zhu, Lingling verfasserin aut Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract For preparing wurtzite and cubic boron nitride (wBN, cBN) under moderate conditions, here we developed a solvothermal hot-press method, by which the phase transformation of $ sp^{3} $-bonded BN in boron nitride (BN) nanoparticles was realized at quite low temperature and pressure. The results reveal that the transformation of aBN/rBN→cBN is highly dependent on the temperature, pressure and solvent promoting effect; and chlorobenzene seems to have a stronger effect on facilitating the phase transformation of $ sp^{3} $-bonded BN as compared to pyridine and aniline. Besides, the decrease in particle size and crystallinity as well as the existence of structural defects plays great roles on the phase transformations of $ sp^{3} $-bonded BN. On the basis of analyzing the experimental results, we proposed a simple model used for explaining the phase transformation process. Boron nitride (dpeaa)DE-He213 Nanoparticles (dpeaa)DE-He213 Phase transformation (dpeaa)DE-He213 Solvothermal hot-press (dpeaa)DE-He213 Zhou, Ying verfasserin aut Ma, Juan verfasserin aut Ye, Guotian verfasserin aut Cui, Deliang verfasserin aut Enthalten in The Arabian journal for science and engineering Berlin : Springer, 2011 40(2015), 10 vom: Okt., Seite 2903-2911 (DE-627)588780731 (DE-600)2471504-9 2191-4281 nnns volume:40 year:2015 number:10 month:10 pages:2903-2911 https://dx.doi.org/10.1007/s13369-015-1861-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 31.00 ASE AR 40 2015 10 10 2903-2911 |
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10.1007/s13369-015-1861-0 doi (DE-627)SPR031845355 (SPR)s13369-015-1861-0-e DE-627 ger DE-627 rakwb eng 600 500 ASE 31.00 bkl Zhu, Lingling verfasserin aut Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract For preparing wurtzite and cubic boron nitride (wBN, cBN) under moderate conditions, here we developed a solvothermal hot-press method, by which the phase transformation of $ sp^{3} $-bonded BN in boron nitride (BN) nanoparticles was realized at quite low temperature and pressure. The results reveal that the transformation of aBN/rBN→cBN is highly dependent on the temperature, pressure and solvent promoting effect; and chlorobenzene seems to have a stronger effect on facilitating the phase transformation of $ sp^{3} $-bonded BN as compared to pyridine and aniline. Besides, the decrease in particle size and crystallinity as well as the existence of structural defects plays great roles on the phase transformations of $ sp^{3} $-bonded BN. On the basis of analyzing the experimental results, we proposed a simple model used for explaining the phase transformation process. Boron nitride (dpeaa)DE-He213 Nanoparticles (dpeaa)DE-He213 Phase transformation (dpeaa)DE-He213 Solvothermal hot-press (dpeaa)DE-He213 Zhou, Ying verfasserin aut Ma, Juan verfasserin aut Ye, Guotian verfasserin aut Cui, Deliang verfasserin aut Enthalten in The Arabian journal for science and engineering Berlin : Springer, 2011 40(2015), 10 vom: Okt., Seite 2903-2911 (DE-627)588780731 (DE-600)2471504-9 2191-4281 nnns volume:40 year:2015 number:10 month:10 pages:2903-2911 https://dx.doi.org/10.1007/s13369-015-1861-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 31.00 ASE AR 40 2015 10 10 2903-2911 |
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10.1007/s13369-015-1861-0 doi (DE-627)SPR031845355 (SPR)s13369-015-1861-0-e DE-627 ger DE-627 rakwb eng 600 500 ASE 31.00 bkl Zhu, Lingling verfasserin aut Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract For preparing wurtzite and cubic boron nitride (wBN, cBN) under moderate conditions, here we developed a solvothermal hot-press method, by which the phase transformation of $ sp^{3} $-bonded BN in boron nitride (BN) nanoparticles was realized at quite low temperature and pressure. The results reveal that the transformation of aBN/rBN→cBN is highly dependent on the temperature, pressure and solvent promoting effect; and chlorobenzene seems to have a stronger effect on facilitating the phase transformation of $ sp^{3} $-bonded BN as compared to pyridine and aniline. Besides, the decrease in particle size and crystallinity as well as the existence of structural defects plays great roles on the phase transformations of $ sp^{3} $-bonded BN. On the basis of analyzing the experimental results, we proposed a simple model used for explaining the phase transformation process. Boron nitride (dpeaa)DE-He213 Nanoparticles (dpeaa)DE-He213 Phase transformation (dpeaa)DE-He213 Solvothermal hot-press (dpeaa)DE-He213 Zhou, Ying verfasserin aut Ma, Juan verfasserin aut Ye, Guotian verfasserin aut Cui, Deliang verfasserin aut Enthalten in The Arabian journal for science and engineering Berlin : Springer, 2011 40(2015), 10 vom: Okt., Seite 2903-2911 (DE-627)588780731 (DE-600)2471504-9 2191-4281 nnns volume:40 year:2015 number:10 month:10 pages:2903-2911 https://dx.doi.org/10.1007/s13369-015-1861-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 31.00 ASE AR 40 2015 10 10 2903-2911 |
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English |
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Enthalten in The Arabian journal for science and engineering 40(2015), 10 vom: Okt., Seite 2903-2911 volume:40 year:2015 number:10 month:10 pages:2903-2911 |
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Enthalten in The Arabian journal for science and engineering 40(2015), 10 vom: Okt., Seite 2903-2911 volume:40 year:2015 number:10 month:10 pages:2903-2911 |
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topic_facet |
Boron nitride Nanoparticles Phase transformation Solvothermal hot-press |
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container_title |
The Arabian journal for science and engineering |
authorswithroles_txt_mv |
Zhu, Lingling @@aut@@ Zhou, Ying @@aut@@ Ma, Juan @@aut@@ Ye, Guotian @@aut@@ Cui, Deliang @@aut@@ |
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2015-10-01T00:00:00Z |
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Zhu, Lingling |
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Zhu, Lingling ddc 600 bkl 31.00 misc Boron nitride misc Nanoparticles misc Phase transformation misc Solvothermal hot-press Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route |
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600 500 ASE 31.00 bkl Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route Boron nitride (dpeaa)DE-He213 Nanoparticles (dpeaa)DE-He213 Phase transformation (dpeaa)DE-He213 Solvothermal hot-press (dpeaa)DE-He213 |
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ddc 600 bkl 31.00 misc Boron nitride misc Nanoparticles misc Phase transformation misc Solvothermal hot-press |
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ddc 600 bkl 31.00 misc Boron nitride misc Nanoparticles misc Phase transformation misc Solvothermal hot-press |
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Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route |
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facilitating the phase transformations of boron nitride nanoparticles at mild conditions by solvothermal hot-press route |
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Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route |
abstract |
Abstract For preparing wurtzite and cubic boron nitride (wBN, cBN) under moderate conditions, here we developed a solvothermal hot-press method, by which the phase transformation of $ sp^{3} $-bonded BN in boron nitride (BN) nanoparticles was realized at quite low temperature and pressure. The results reveal that the transformation of aBN/rBN→cBN is highly dependent on the temperature, pressure and solvent promoting effect; and chlorobenzene seems to have a stronger effect on facilitating the phase transformation of $ sp^{3} $-bonded BN as compared to pyridine and aniline. Besides, the decrease in particle size and crystallinity as well as the existence of structural defects plays great roles on the phase transformations of $ sp^{3} $-bonded BN. On the basis of analyzing the experimental results, we proposed a simple model used for explaining the phase transformation process. |
abstractGer |
Abstract For preparing wurtzite and cubic boron nitride (wBN, cBN) under moderate conditions, here we developed a solvothermal hot-press method, by which the phase transformation of $ sp^{3} $-bonded BN in boron nitride (BN) nanoparticles was realized at quite low temperature and pressure. The results reveal that the transformation of aBN/rBN→cBN is highly dependent on the temperature, pressure and solvent promoting effect; and chlorobenzene seems to have a stronger effect on facilitating the phase transformation of $ sp^{3} $-bonded BN as compared to pyridine and aniline. Besides, the decrease in particle size and crystallinity as well as the existence of structural defects plays great roles on the phase transformations of $ sp^{3} $-bonded BN. On the basis of analyzing the experimental results, we proposed a simple model used for explaining the phase transformation process. |
abstract_unstemmed |
Abstract For preparing wurtzite and cubic boron nitride (wBN, cBN) under moderate conditions, here we developed a solvothermal hot-press method, by which the phase transformation of $ sp^{3} $-bonded BN in boron nitride (BN) nanoparticles was realized at quite low temperature and pressure. The results reveal that the transformation of aBN/rBN→cBN is highly dependent on the temperature, pressure and solvent promoting effect; and chlorobenzene seems to have a stronger effect on facilitating the phase transformation of $ sp^{3} $-bonded BN as compared to pyridine and aniline. Besides, the decrease in particle size and crystallinity as well as the existence of structural defects plays great roles on the phase transformations of $ sp^{3} $-bonded BN. On the basis of analyzing the experimental results, we proposed a simple model used for explaining the phase transformation process. |
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Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR031845355</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20220111193056.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201007s2015 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s13369-015-1861-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR031845355</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s13369-015-1861-0-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">600</subfield><subfield code="a">500</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">31.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zhu, Lingling</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Facilitating the Phase Transformations of Boron Nitride Nanoparticles at Mild Conditions by Solvothermal Hot-Press Route</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2015</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract For preparing wurtzite and cubic boron nitride (wBN, cBN) under moderate conditions, here we developed a solvothermal hot-press method, by which the phase transformation of $ sp^{3} $-bonded BN in boron nitride (BN) nanoparticles was realized at quite low temperature and pressure. The results reveal that the transformation of aBN/rBN→cBN is highly dependent on the temperature, pressure and solvent promoting effect; and chlorobenzene seems to have a stronger effect on facilitating the phase transformation of $ sp^{3} $-bonded BN as compared to pyridine and aniline. Besides, the decrease in particle size and crystallinity as well as the existence of structural defects plays great roles on the phase transformations of $ sp^{3} $-bonded BN. On the basis of analyzing the experimental results, we proposed a simple model used for explaining the phase transformation process.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Boron nitride</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nanoparticles</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Phase transformation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Solvothermal hot-press</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhou, Ying</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Ma, Juan</subfield><subfield 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