Application of the buffer theory for evaluating attenuation and natural remediation of ionic pollutants in aquatic ecosystems

Abstract The main focus in this review is showing how to use the developed buffer theory for assessing and predicting the long-term phenomena of attenuation and natural remediation of ionic pollutants in contaminated aquatic ecosystems, as well as for analyzing the way by which metals move and trans...
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Gespeichert in:

Autor*in:	Povar, Igor [verfasserIn] Spinu, Oxana [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2015

Schlagwörter:	Buffer capacity Ecosystem Heterogeneous multicomponent system Proportionality relation between buffer capacities

Übergeordnetes Werk:	Enthalten in: Ecological Processes - Heidelberg : SpringerOpen, 2012, 4(2015), 1 vom: 30. Dez.
Übergeordnetes Werk:	volume:4 ; year:2015 ; number:1 ; day:30 ; month:12

Links:	Volltext

DOI / URN:	10.1186/s13717-015-0043-z

Katalog-ID:	SPR032184549

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spelling	10.1186/s13717-015-0043-z doi (DE-627)SPR032184549 (SPR)s13717-015-0043-z-e DE-627 ger DE-627 rakwb eng 333.7 ASE Povar, Igor verfasserin aut Application of the buffer theory for evaluating attenuation and natural remediation of ionic pollutants in aquatic ecosystems 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The main focus in this review is showing how to use the developed buffer theory for assessing and predicting the long-term phenomena of attenuation and natural remediation of ionic pollutants in contaminated aquatic ecosystems, as well as for analyzing the way by which metals move and transform within the environment, the distribution of metals in ecosystems, their deposition and cycling in the terrestrial environment. The buffer theory is based on the rigorous thermodynamic analysis of complex chemical equilibria under environmental conditions in aquatic ecosystems, as natural waters and soils. It has been established that both homogeneous and heterogeneous systems manifest a buffer action towards all their components. The buffer properties in relation to the solid phase components are amplified with an increase of solubility due to protolytic or complex formation equilibria in saturated solutions. It has been established that the buffer capacities of components are mutually proportional, whereas for heterogeneous systems these relationships depend on the stoichiometric composition of solid phases. The use of the developed buffer approach may yield extended knowledge and a deeper understanding of the processes that control the concentrations of components. A number of the important conclusions concerning the investigated buffer systems have been made. The obtained results are indented to provide researchers with a tool needed to help them to set reliable limits of ion (metal) levels in the environment. Buffer capacity (dpeaa)DE-He213 Ecosystem (dpeaa)DE-He213 Heterogeneous multicomponent system (dpeaa)DE-He213 Proportionality relation between buffer capacities (dpeaa)DE-He213 Spinu, Oxana verfasserin aut Enthalten in Ecological Processes Heidelberg : SpringerOpen, 2012 4(2015), 1 vom: 30. Dez. (DE-627)732623693 (DE-600)2694945-3 2192-1709 nnns volume:4 year:2015 number:1 day:30 month:12 https://dx.doi.org/10.1186/s13717-015-0043-z kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4367 GBV_ILN_4700 AR 4 2015 1 30 12
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allfieldsSound	10.1186/s13717-015-0043-z doi (DE-627)SPR032184549 (SPR)s13717-015-0043-z-e DE-627 ger DE-627 rakwb eng 333.7 ASE Povar, Igor verfasserin aut Application of the buffer theory for evaluating attenuation and natural remediation of ionic pollutants in aquatic ecosystems 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The main focus in this review is showing how to use the developed buffer theory for assessing and predicting the long-term phenomena of attenuation and natural remediation of ionic pollutants in contaminated aquatic ecosystems, as well as for analyzing the way by which metals move and transform within the environment, the distribution of metals in ecosystems, their deposition and cycling in the terrestrial environment. The buffer theory is based on the rigorous thermodynamic analysis of complex chemical equilibria under environmental conditions in aquatic ecosystems, as natural waters and soils. It has been established that both homogeneous and heterogeneous systems manifest a buffer action towards all their components. The buffer properties in relation to the solid phase components are amplified with an increase of solubility due to protolytic or complex formation equilibria in saturated solutions. It has been established that the buffer capacities of components are mutually proportional, whereas for heterogeneous systems these relationships depend on the stoichiometric composition of solid phases. The use of the developed buffer approach may yield extended knowledge and a deeper understanding of the processes that control the concentrations of components. A number of the important conclusions concerning the investigated buffer systems have been made. The obtained results are indented to provide researchers with a tool needed to help them to set reliable limits of ion (metal) levels in the environment. Buffer capacity (dpeaa)DE-He213 Ecosystem (dpeaa)DE-He213 Heterogeneous multicomponent system (dpeaa)DE-He213 Proportionality relation between buffer capacities (dpeaa)DE-He213 Spinu, Oxana verfasserin aut Enthalten in Ecological Processes Heidelberg : SpringerOpen, 2012 4(2015), 1 vom: 30. Dez. (DE-627)732623693 (DE-600)2694945-3 2192-1709 nnns volume:4 year:2015 number:1 day:30 month:12 https://dx.doi.org/10.1186/s13717-015-0043-z kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4367 GBV_ILN_4700 AR 4 2015 1 30 12
language	English
source	Enthalten in Ecological Processes 4(2015), 1 vom: 30. Dez. volume:4 year:2015 number:1 day:30 month:12
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author	Povar, Igor
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topic_title	333.7 ASE Application of the buffer theory for evaluating attenuation and natural remediation of ionic pollutants in aquatic ecosystems Buffer capacity (dpeaa)DE-He213 Ecosystem (dpeaa)DE-He213 Heterogeneous multicomponent system (dpeaa)DE-He213 Proportionality relation between buffer capacities (dpeaa)DE-He213
topic	ddc 333.7 misc Buffer capacity misc Ecosystem misc Heterogeneous multicomponent system misc Proportionality relation between buffer capacities
topic_unstemmed	ddc 333.7 misc Buffer capacity misc Ecosystem misc Heterogeneous multicomponent system misc Proportionality relation between buffer capacities
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title	Application of the buffer theory for evaluating attenuation and natural remediation of ionic pollutants in aquatic ecosystems
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title_full	Application of the buffer theory for evaluating attenuation and natural remediation of ionic pollutants in aquatic ecosystems
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title_sort	application of the buffer theory for evaluating attenuation and natural remediation of ionic pollutants in aquatic ecosystems
title_auth	Application of the buffer theory for evaluating attenuation and natural remediation of ionic pollutants in aquatic ecosystems
abstract	Abstract The main focus in this review is showing how to use the developed buffer theory for assessing and predicting the long-term phenomena of attenuation and natural remediation of ionic pollutants in contaminated aquatic ecosystems, as well as for analyzing the way by which metals move and transform within the environment, the distribution of metals in ecosystems, their deposition and cycling in the terrestrial environment. The buffer theory is based on the rigorous thermodynamic analysis of complex chemical equilibria under environmental conditions in aquatic ecosystems, as natural waters and soils. It has been established that both homogeneous and heterogeneous systems manifest a buffer action towards all their components. The buffer properties in relation to the solid phase components are amplified with an increase of solubility due to protolytic or complex formation equilibria in saturated solutions. It has been established that the buffer capacities of components are mutually proportional, whereas for heterogeneous systems these relationships depend on the stoichiometric composition of solid phases. The use of the developed buffer approach may yield extended knowledge and a deeper understanding of the processes that control the concentrations of components. A number of the important conclusions concerning the investigated buffer systems have been made. The obtained results are indented to provide researchers with a tool needed to help them to set reliable limits of ion (metal) levels in the environment.
abstractGer	Abstract The main focus in this review is showing how to use the developed buffer theory for assessing and predicting the long-term phenomena of attenuation and natural remediation of ionic pollutants in contaminated aquatic ecosystems, as well as for analyzing the way by which metals move and transform within the environment, the distribution of metals in ecosystems, their deposition and cycling in the terrestrial environment. The buffer theory is based on the rigorous thermodynamic analysis of complex chemical equilibria under environmental conditions in aquatic ecosystems, as natural waters and soils. It has been established that both homogeneous and heterogeneous systems manifest a buffer action towards all their components. The buffer properties in relation to the solid phase components are amplified with an increase of solubility due to protolytic or complex formation equilibria in saturated solutions. It has been established that the buffer capacities of components are mutually proportional, whereas for heterogeneous systems these relationships depend on the stoichiometric composition of solid phases. The use of the developed buffer approach may yield extended knowledge and a deeper understanding of the processes that control the concentrations of components. A number of the important conclusions concerning the investigated buffer systems have been made. The obtained results are indented to provide researchers with a tool needed to help them to set reliable limits of ion (metal) levels in the environment.
abstract_unstemmed	Abstract The main focus in this review is showing how to use the developed buffer theory for assessing and predicting the long-term phenomena of attenuation and natural remediation of ionic pollutants in contaminated aquatic ecosystems, as well as for analyzing the way by which metals move and transform within the environment, the distribution of metals in ecosystems, their deposition and cycling in the terrestrial environment. The buffer theory is based on the rigorous thermodynamic analysis of complex chemical equilibria under environmental conditions in aquatic ecosystems, as natural waters and soils. It has been established that both homogeneous and heterogeneous systems manifest a buffer action towards all their components. The buffer properties in relation to the solid phase components are amplified with an increase of solubility due to protolytic or complex formation equilibria in saturated solutions. It has been established that the buffer capacities of components are mutually proportional, whereas for heterogeneous systems these relationships depend on the stoichiometric composition of solid phases. The use of the developed buffer approach may yield extended knowledge and a deeper understanding of the processes that control the concentrations of components. A number of the important conclusions concerning the investigated buffer systems have been made. The obtained results are indented to provide researchers with a tool needed to help them to set reliable limits of ion (metal) levels in the environment.
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title_short	Application of the buffer theory for evaluating attenuation and natural remediation of ionic pollutants in aquatic ecosystems
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