Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms

Abstract The electrochemical oxidation of 4-nitrocatechol in aqueous media was studied using cyclic voltammetry. The results indicate that the stability of electrochemically generated o-nitrobenzoquinone is low and decreases with increasing pH. Also, our voltammetric data show that the species produ...
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Autor*in:	Nematollahi, D. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2011

Schlagwörter:	4-Nitrocatechol mechanism Cyclic voltammetry Digital simulation

Übergeordnetes Werk:	Enthalten in: Journal of the Iranian Chemical Society - Tehran, 2004, 8(2011), 3 vom: Sept., Seite 803-810
Übergeordnetes Werk:	volume:8 ; year:2011 ; number:3 ; month:09 ; pages:803-810

Links:	Volltext

DOI / URN:	10.1007/BF03245911

Katalog-ID:	SPR032217692

Internformat


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520			\|a Abstract The electrochemical oxidation of 4-nitrocatechol in aqueous media was studied using cyclic voltammetry. The results indicate that the stability of electrochemically generated o-nitrobenzoquinone is low and decreases with increasing pH. Also, our voltammetric data show that the species produced from the conversion of o-nitrobenzoquinone are electro-inactive in the studied potential range. In addition, the results reveal that the rate of conversion of o-nitrobenzoquinone is dependent on the nature of the solvent. According to EC mechanism, the observed homogeneous rate constant of the conversion of o-nitrobenzoquinone was estimated by comparing the experimental cyclic voltammograms with the digitally simulated results. Finally, a possible mechanism is proposed for the electrode process, on the basis of the present and previous investigations.
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650		4	\|a mechanism \|7 (dpeaa)DE-He213
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912			\|a GBV_ILN_206
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912			\|a GBV_ILN_285
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912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
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912			\|a GBV_ILN_2004
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912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
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912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
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912			\|a GBV_ILN_2044
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Indexfelder

author_variant	d n dn
matchkey_str	article:17352428:2011----::ieisuyfntoaehlxdtouigiiasmltoo
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bklnumber	35.00
publishDate	2011
allfields	10.1007/BF03245911 doi (DE-627)SPR032217692 (SPR)BF03245911-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Nematollahi, D. verfasserin aut Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The electrochemical oxidation of 4-nitrocatechol in aqueous media was studied using cyclic voltammetry. The results indicate that the stability of electrochemically generated o-nitrobenzoquinone is low and decreases with increasing pH. Also, our voltammetric data show that the species produced from the conversion of o-nitrobenzoquinone are electro-inactive in the studied potential range. In addition, the results reveal that the rate of conversion of o-nitrobenzoquinone is dependent on the nature of the solvent. According to EC mechanism, the observed homogeneous rate constant of the conversion of o-nitrobenzoquinone was estimated by comparing the experimental cyclic voltammograms with the digitally simulated results. Finally, a possible mechanism is proposed for the electrode process, on the basis of the present and previous investigations. 4-Nitrocatechol (dpeaa)DE-He213 mechanism (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Digital simulation (dpeaa)DE-He213 Enthalten in Journal of the Iranian Chemical Society Tehran, 2004 8(2011), 3 vom: Sept., Seite 803-810 (DE-627)515979767 (DE-600)2244820-2 1735-2428 nnns volume:8 year:2011 number:3 month:09 pages:803-810 https://dx.doi.org/10.1007/BF03245911 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 8 2011 3 09 803-810
spelling	10.1007/BF03245911 doi (DE-627)SPR032217692 (SPR)BF03245911-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Nematollahi, D. verfasserin aut Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The electrochemical oxidation of 4-nitrocatechol in aqueous media was studied using cyclic voltammetry. The results indicate that the stability of electrochemically generated o-nitrobenzoquinone is low and decreases with increasing pH. Also, our voltammetric data show that the species produced from the conversion of o-nitrobenzoquinone are electro-inactive in the studied potential range. In addition, the results reveal that the rate of conversion of o-nitrobenzoquinone is dependent on the nature of the solvent. According to EC mechanism, the observed homogeneous rate constant of the conversion of o-nitrobenzoquinone was estimated by comparing the experimental cyclic voltammograms with the digitally simulated results. Finally, a possible mechanism is proposed for the electrode process, on the basis of the present and previous investigations. 4-Nitrocatechol (dpeaa)DE-He213 mechanism (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Digital simulation (dpeaa)DE-He213 Enthalten in Journal of the Iranian Chemical Society Tehran, 2004 8(2011), 3 vom: Sept., Seite 803-810 (DE-627)515979767 (DE-600)2244820-2 1735-2428 nnns volume:8 year:2011 number:3 month:09 pages:803-810 https://dx.doi.org/10.1007/BF03245911 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 8 2011 3 09 803-810
allfields_unstemmed	10.1007/BF03245911 doi (DE-627)SPR032217692 (SPR)BF03245911-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Nematollahi, D. verfasserin aut Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The electrochemical oxidation of 4-nitrocatechol in aqueous media was studied using cyclic voltammetry. The results indicate that the stability of electrochemically generated o-nitrobenzoquinone is low and decreases with increasing pH. Also, our voltammetric data show that the species produced from the conversion of o-nitrobenzoquinone are electro-inactive in the studied potential range. In addition, the results reveal that the rate of conversion of o-nitrobenzoquinone is dependent on the nature of the solvent. According to EC mechanism, the observed homogeneous rate constant of the conversion of o-nitrobenzoquinone was estimated by comparing the experimental cyclic voltammograms with the digitally simulated results. Finally, a possible mechanism is proposed for the electrode process, on the basis of the present and previous investigations. 4-Nitrocatechol (dpeaa)DE-He213 mechanism (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Digital simulation (dpeaa)DE-He213 Enthalten in Journal of the Iranian Chemical Society Tehran, 2004 8(2011), 3 vom: Sept., Seite 803-810 (DE-627)515979767 (DE-600)2244820-2 1735-2428 nnns volume:8 year:2011 number:3 month:09 pages:803-810 https://dx.doi.org/10.1007/BF03245911 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 8 2011 3 09 803-810
allfieldsGer	10.1007/BF03245911 doi (DE-627)SPR032217692 (SPR)BF03245911-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Nematollahi, D. verfasserin aut Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The electrochemical oxidation of 4-nitrocatechol in aqueous media was studied using cyclic voltammetry. The results indicate that the stability of electrochemically generated o-nitrobenzoquinone is low and decreases with increasing pH. Also, our voltammetric data show that the species produced from the conversion of o-nitrobenzoquinone are electro-inactive in the studied potential range. In addition, the results reveal that the rate of conversion of o-nitrobenzoquinone is dependent on the nature of the solvent. According to EC mechanism, the observed homogeneous rate constant of the conversion of o-nitrobenzoquinone was estimated by comparing the experimental cyclic voltammograms with the digitally simulated results. Finally, a possible mechanism is proposed for the electrode process, on the basis of the present and previous investigations. 4-Nitrocatechol (dpeaa)DE-He213 mechanism (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Digital simulation (dpeaa)DE-He213 Enthalten in Journal of the Iranian Chemical Society Tehran, 2004 8(2011), 3 vom: Sept., Seite 803-810 (DE-627)515979767 (DE-600)2244820-2 1735-2428 nnns volume:8 year:2011 number:3 month:09 pages:803-810 https://dx.doi.org/10.1007/BF03245911 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 8 2011 3 09 803-810
allfieldsSound	10.1007/BF03245911 doi (DE-627)SPR032217692 (SPR)BF03245911-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Nematollahi, D. verfasserin aut Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The electrochemical oxidation of 4-nitrocatechol in aqueous media was studied using cyclic voltammetry. The results indicate that the stability of electrochemically generated o-nitrobenzoquinone is low and decreases with increasing pH. Also, our voltammetric data show that the species produced from the conversion of o-nitrobenzoquinone are electro-inactive in the studied potential range. In addition, the results reveal that the rate of conversion of o-nitrobenzoquinone is dependent on the nature of the solvent. According to EC mechanism, the observed homogeneous rate constant of the conversion of o-nitrobenzoquinone was estimated by comparing the experimental cyclic voltammograms with the digitally simulated results. Finally, a possible mechanism is proposed for the electrode process, on the basis of the present and previous investigations. 4-Nitrocatechol (dpeaa)DE-He213 mechanism (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Digital simulation (dpeaa)DE-He213 Enthalten in Journal of the Iranian Chemical Society Tehran, 2004 8(2011), 3 vom: Sept., Seite 803-810 (DE-627)515979767 (DE-600)2244820-2 1735-2428 nnns volume:8 year:2011 number:3 month:09 pages:803-810 https://dx.doi.org/10.1007/BF03245911 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 8 2011 3 09 803-810
language	English
source	Enthalten in Journal of the Iranian Chemical Society 8(2011), 3 vom: Sept., Seite 803-810 volume:8 year:2011 number:3 month:09 pages:803-810
sourceStr	Enthalten in Journal of the Iranian Chemical Society 8(2011), 3 vom: Sept., Seite 803-810 volume:8 year:2011 number:3 month:09 pages:803-810
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	4-Nitrocatechol mechanism Cyclic voltammetry Digital simulation
dewey-raw	540
isfreeaccess_bool	false
container_title	Journal of the Iranian Chemical Society
authorswithroles_txt_mv	Nematollahi, D. @@aut@@
publishDateDaySort_date	2011-09-01T00:00:00Z
hierarchy_top_id	515979767
dewey-sort	3540
id	SPR032217692
language_de	englisch
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author	Nematollahi, D.
spellingShingle	Nematollahi, D. ddc 540 bkl 35.00 misc 4-Nitrocatechol misc mechanism misc Cyclic voltammetry misc Digital simulation Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms
authorStr	Nematollahi, D.
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topic_title	540 ASE 35.00 bkl Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms 4-Nitrocatechol (dpeaa)DE-He213 mechanism (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Digital simulation (dpeaa)DE-He213
topic	ddc 540 bkl 35.00 misc 4-Nitrocatechol misc mechanism misc Cyclic voltammetry misc Digital simulation
topic_unstemmed	ddc 540 bkl 35.00 misc 4-Nitrocatechol misc mechanism misc Cyclic voltammetry misc Digital simulation
topic_browse	ddc 540 bkl 35.00 misc 4-Nitrocatechol misc mechanism misc Cyclic voltammetry misc Digital simulation
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title	Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms
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title_full	Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms
author_sort	Nematollahi, D.
journal	Journal of the Iranian Chemical Society
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title_sort	kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms
title_auth	Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms
abstract	Abstract The electrochemical oxidation of 4-nitrocatechol in aqueous media was studied using cyclic voltammetry. The results indicate that the stability of electrochemically generated o-nitrobenzoquinone is low and decreases with increasing pH. Also, our voltammetric data show that the species produced from the conversion of o-nitrobenzoquinone are electro-inactive in the studied potential range. In addition, the results reveal that the rate of conversion of o-nitrobenzoquinone is dependent on the nature of the solvent. According to EC mechanism, the observed homogeneous rate constant of the conversion of o-nitrobenzoquinone was estimated by comparing the experimental cyclic voltammograms with the digitally simulated results. Finally, a possible mechanism is proposed for the electrode process, on the basis of the present and previous investigations.
abstractGer	Abstract The electrochemical oxidation of 4-nitrocatechol in aqueous media was studied using cyclic voltammetry. The results indicate that the stability of electrochemically generated o-nitrobenzoquinone is low and decreases with increasing pH. Also, our voltammetric data show that the species produced from the conversion of o-nitrobenzoquinone are electro-inactive in the studied potential range. In addition, the results reveal that the rate of conversion of o-nitrobenzoquinone is dependent on the nature of the solvent. According to EC mechanism, the observed homogeneous rate constant of the conversion of o-nitrobenzoquinone was estimated by comparing the experimental cyclic voltammograms with the digitally simulated results. Finally, a possible mechanism is proposed for the electrode process, on the basis of the present and previous investigations.
abstract_unstemmed	Abstract The electrochemical oxidation of 4-nitrocatechol in aqueous media was studied using cyclic voltammetry. The results indicate that the stability of electrochemically generated o-nitrobenzoquinone is low and decreases with increasing pH. Also, our voltammetric data show that the species produced from the conversion of o-nitrobenzoquinone are electro-inactive in the studied potential range. In addition, the results reveal that the rate of conversion of o-nitrobenzoquinone is dependent on the nature of the solvent. According to EC mechanism, the observed homogeneous rate constant of the conversion of o-nitrobenzoquinone was estimated by comparing the experimental cyclic voltammograms with the digitally simulated results. Finally, a possible mechanism is proposed for the electrode process, on the basis of the present and previous investigations.
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title_short	Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms
url	https://dx.doi.org/10.1007/BF03245911
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up_date	2024-07-04T02:46:54.936Z
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Kinetic study of 4-nitrocatechol oxidation using digital simulation of cyclic voltammograms

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