Recent progress on Kubas-type hydrogen-storage nanomaterials: from theories to experiments
Abstract Transition-metal (TM) atoms are known to form TM-$ H_{2} $ complexes, which are collectively called Kubas dihydrogen complexes. The TM-$ H_{2} $ complexes are formed through the hybridization of the TM d orbitals with the $ H_{2} $σ and σ* orbitals. The adsorption energy of $ H^{2} $ molecu...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Chung, ChiHye [verfasserIn] Ihm, Jisoon [verfasserIn] Lee, Hoonkyung [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of the Korean Physical Society - Berlin : Springer, 1968, 66(2015), 11 vom: Juni, Seite 1649-1655 |
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| Übergeordnetes Werk: |
volume:66 ; year:2015 ; number:11 ; month:06 ; pages:1649-1655 |
| Links: |
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| DOI / URN: |
10.3938/jkps.66.1649 |
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SPR03271629X |
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| 520 | |a Abstract Transition-metal (TM) atoms are known to form TM-$ H_{2} $ complexes, which are collectively called Kubas dihydrogen complexes. The TM-$ H_{2} $ complexes are formed through the hybridization of the TM d orbitals with the $ H_{2} $σ and σ* orbitals. The adsorption energy of $ H^{2} $ molecules in the TM-$ H_{2} $ complexes is usually within the range of energy required for reversible $ H_{2} $ storage at room temperature and ambient pressure (−0.4 ~ −0.2 eV/$ H_{2} $). Thus, TM-$ H_{2} $ complexes have been investigated as potential Kubas-type hydrogen-storage materials. Recently, TM-decorated nanomaterials have attracted much attention because of their promising high capacity and reversibility as Kubas-type hydrogen-storage materials. The hydrogen storage capacity of TM-decorated nanomaterials is expected to be as large as ~9 wt%, which is suitable for certain vehicular applications. However, in the TM-decorated nanostructures, the TM atoms prefer to form clusters because of the large cohesive energy (approximately 4 eV), which leads to a significant reduction in the hydrogen-storage capacity. On the other hand, Ca atoms can form complexes with $ H_{2} $ molecules via Kubas-like interactions. Ca atoms attached to nanomaterials have been reported to be able to adsorb as many $ H_{2} $ molecules as TM atoms. Ca atoms tend to cluster less because of the small cohesive energy of bulk Ca (1.83 eV), which is much smaller than those of bulk TMs. These observations suggest thatKubas interactions can occur in d orbital-free elements, thereby making Ca a more suitable element for attracting $ H^{2} $ in hydrogen-storage materials. Recently, Kubas-type TM-based, hydrogen- stor ge materials were experimentally synthesized, and the Kubas-type interactions were measured to be stronger than the van der Waals interactions. In this review, the recent progress of Kubas-type hydrogen- storage materials will be discussed from both theoretical and experimental viewpoints. | ||
| 650 | 4 | |a Hydrogen storage |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Kubas interaction |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Metal-dihydrogen complexes |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Ihm, Jisoon |e verfasserin |4 aut | |
| 700 | 1 | |a Lee, Hoonkyung |e verfasserin |4 aut | |
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10.3938/jkps.66.1649 doi (DE-627)SPR03271629X (SPR)jkps.66.1649-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Chung, ChiHye verfasserin aut Recent progress on Kubas-type hydrogen-storage nanomaterials: from theories to experiments 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Transition-metal (TM) atoms are known to form TM-$ H_{2} $ complexes, which are collectively called Kubas dihydrogen complexes. The TM-$ H_{2} $ complexes are formed through the hybridization of the TM d orbitals with the $ H_{2} $σ and σ* orbitals. The adsorption energy of $ H^{2} $ molecules in the TM-$ H_{2} $ complexes is usually within the range of energy required for reversible $ H_{2} $ storage at room temperature and ambient pressure (−0.4 ~ −0.2 eV/$ H_{2} $). Thus, TM-$ H_{2} $ complexes have been investigated as potential Kubas-type hydrogen-storage materials. Recently, TM-decorated nanomaterials have attracted much attention because of their promising high capacity and reversibility as Kubas-type hydrogen-storage materials. The hydrogen storage capacity of TM-decorated nanomaterials is expected to be as large as ~9 wt%, which is suitable for certain vehicular applications. However, in the TM-decorated nanostructures, the TM atoms prefer to form clusters because of the large cohesive energy (approximately 4 eV), which leads to a significant reduction in the hydrogen-storage capacity. On the other hand, Ca atoms can form complexes with $ H_{2} $ molecules via Kubas-like interactions. Ca atoms attached to nanomaterials have been reported to be able to adsorb as many $ H_{2} $ molecules as TM atoms. Ca atoms tend to cluster less because of the small cohesive energy of bulk Ca (1.83 eV), which is much smaller than those of bulk TMs. These observations suggest thatKubas interactions can occur in d orbital-free elements, thereby making Ca a more suitable element for attracting $ H^{2} $ in hydrogen-storage materials. Recently, Kubas-type TM-based, hydrogen- stor ge materials were experimentally synthesized, and the Kubas-type interactions were measured to be stronger than the van der Waals interactions. In this review, the recent progress of Kubas-type hydrogen- storage materials will be discussed from both theoretical and experimental viewpoints. Hydrogen storage (dpeaa)DE-He213 Kubas interaction (dpeaa)DE-He213 Metal-dihydrogen complexes (dpeaa)DE-He213 Ihm, Jisoon verfasserin aut Lee, Hoonkyung verfasserin aut Enthalten in Journal of the Korean Physical Society Berlin : Springer, 1968 66(2015), 11 vom: Juni, Seite 1649-1655 (DE-627)328820865 (DE-600)2046361-3 1976-8524 nnns volume:66 year:2015 number:11 month:06 pages:1649-1655 https://dx.doi.org/10.3938/jkps.66.1649 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 66 2015 11 06 1649-1655 |
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10.3938/jkps.66.1649 doi (DE-627)SPR03271629X (SPR)jkps.66.1649-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Chung, ChiHye verfasserin aut Recent progress on Kubas-type hydrogen-storage nanomaterials: from theories to experiments 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Transition-metal (TM) atoms are known to form TM-$ H_{2} $ complexes, which are collectively called Kubas dihydrogen complexes. The TM-$ H_{2} $ complexes are formed through the hybridization of the TM d orbitals with the $ H_{2} $σ and σ* orbitals. The adsorption energy of $ H^{2} $ molecules in the TM-$ H_{2} $ complexes is usually within the range of energy required for reversible $ H_{2} $ storage at room temperature and ambient pressure (−0.4 ~ −0.2 eV/$ H_{2} $). Thus, TM-$ H_{2} $ complexes have been investigated as potential Kubas-type hydrogen-storage materials. Recently, TM-decorated nanomaterials have attracted much attention because of their promising high capacity and reversibility as Kubas-type hydrogen-storage materials. The hydrogen storage capacity of TM-decorated nanomaterials is expected to be as large as ~9 wt%, which is suitable for certain vehicular applications. However, in the TM-decorated nanostructures, the TM atoms prefer to form clusters because of the large cohesive energy (approximately 4 eV), which leads to a significant reduction in the hydrogen-storage capacity. On the other hand, Ca atoms can form complexes with $ H_{2} $ molecules via Kubas-like interactions. Ca atoms attached to nanomaterials have been reported to be able to adsorb as many $ H_{2} $ molecules as TM atoms. Ca atoms tend to cluster less because of the small cohesive energy of bulk Ca (1.83 eV), which is much smaller than those of bulk TMs. These observations suggest thatKubas interactions can occur in d orbital-free elements, thereby making Ca a more suitable element for attracting $ H^{2} $ in hydrogen-storage materials. Recently, Kubas-type TM-based, hydrogen- stor ge materials were experimentally synthesized, and the Kubas-type interactions were measured to be stronger than the van der Waals interactions. In this review, the recent progress of Kubas-type hydrogen- storage materials will be discussed from both theoretical and experimental viewpoints. Hydrogen storage (dpeaa)DE-He213 Kubas interaction (dpeaa)DE-He213 Metal-dihydrogen complexes (dpeaa)DE-He213 Ihm, Jisoon verfasserin aut Lee, Hoonkyung verfasserin aut Enthalten in Journal of the Korean Physical Society Berlin : Springer, 1968 66(2015), 11 vom: Juni, Seite 1649-1655 (DE-627)328820865 (DE-600)2046361-3 1976-8524 nnns volume:66 year:2015 number:11 month:06 pages:1649-1655 https://dx.doi.org/10.3938/jkps.66.1649 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 66 2015 11 06 1649-1655 |
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10.3938/jkps.66.1649 doi (DE-627)SPR03271629X (SPR)jkps.66.1649-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Chung, ChiHye verfasserin aut Recent progress on Kubas-type hydrogen-storage nanomaterials: from theories to experiments 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Transition-metal (TM) atoms are known to form TM-$ H_{2} $ complexes, which are collectively called Kubas dihydrogen complexes. The TM-$ H_{2} $ complexes are formed through the hybridization of the TM d orbitals with the $ H_{2} $σ and σ* orbitals. The adsorption energy of $ H^{2} $ molecules in the TM-$ H_{2} $ complexes is usually within the range of energy required for reversible $ H_{2} $ storage at room temperature and ambient pressure (−0.4 ~ −0.2 eV/$ H_{2} $). Thus, TM-$ H_{2} $ complexes have been investigated as potential Kubas-type hydrogen-storage materials. Recently, TM-decorated nanomaterials have attracted much attention because of their promising high capacity and reversibility as Kubas-type hydrogen-storage materials. The hydrogen storage capacity of TM-decorated nanomaterials is expected to be as large as ~9 wt%, which is suitable for certain vehicular applications. However, in the TM-decorated nanostructures, the TM atoms prefer to form clusters because of the large cohesive energy (approximately 4 eV), which leads to a significant reduction in the hydrogen-storage capacity. On the other hand, Ca atoms can form complexes with $ H_{2} $ molecules via Kubas-like interactions. Ca atoms attached to nanomaterials have been reported to be able to adsorb as many $ H_{2} $ molecules as TM atoms. Ca atoms tend to cluster less because of the small cohesive energy of bulk Ca (1.83 eV), which is much smaller than those of bulk TMs. These observations suggest thatKubas interactions can occur in d orbital-free elements, thereby making Ca a more suitable element for attracting $ H^{2} $ in hydrogen-storage materials. Recently, Kubas-type TM-based, hydrogen- stor ge materials were experimentally synthesized, and the Kubas-type interactions were measured to be stronger than the van der Waals interactions. In this review, the recent progress of Kubas-type hydrogen- storage materials will be discussed from both theoretical and experimental viewpoints. Hydrogen storage (dpeaa)DE-He213 Kubas interaction (dpeaa)DE-He213 Metal-dihydrogen complexes (dpeaa)DE-He213 Ihm, Jisoon verfasserin aut Lee, Hoonkyung verfasserin aut Enthalten in Journal of the Korean Physical Society Berlin : Springer, 1968 66(2015), 11 vom: Juni, Seite 1649-1655 (DE-627)328820865 (DE-600)2046361-3 1976-8524 nnns volume:66 year:2015 number:11 month:06 pages:1649-1655 https://dx.doi.org/10.3938/jkps.66.1649 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 66 2015 11 06 1649-1655 |
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10.3938/jkps.66.1649 doi (DE-627)SPR03271629X (SPR)jkps.66.1649-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Chung, ChiHye verfasserin aut Recent progress on Kubas-type hydrogen-storage nanomaterials: from theories to experiments 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Transition-metal (TM) atoms are known to form TM-$ H_{2} $ complexes, which are collectively called Kubas dihydrogen complexes. The TM-$ H_{2} $ complexes are formed through the hybridization of the TM d orbitals with the $ H_{2} $σ and σ* orbitals. The adsorption energy of $ H^{2} $ molecules in the TM-$ H_{2} $ complexes is usually within the range of energy required for reversible $ H_{2} $ storage at room temperature and ambient pressure (−0.4 ~ −0.2 eV/$ H_{2} $). Thus, TM-$ H_{2} $ complexes have been investigated as potential Kubas-type hydrogen-storage materials. Recently, TM-decorated nanomaterials have attracted much attention because of their promising high capacity and reversibility as Kubas-type hydrogen-storage materials. The hydrogen storage capacity of TM-decorated nanomaterials is expected to be as large as ~9 wt%, which is suitable for certain vehicular applications. However, in the TM-decorated nanostructures, the TM atoms prefer to form clusters because of the large cohesive energy (approximately 4 eV), which leads to a significant reduction in the hydrogen-storage capacity. On the other hand, Ca atoms can form complexes with $ H_{2} $ molecules via Kubas-like interactions. Ca atoms attached to nanomaterials have been reported to be able to adsorb as many $ H_{2} $ molecules as TM atoms. Ca atoms tend to cluster less because of the small cohesive energy of bulk Ca (1.83 eV), which is much smaller than those of bulk TMs. These observations suggest thatKubas interactions can occur in d orbital-free elements, thereby making Ca a more suitable element for attracting $ H^{2} $ in hydrogen-storage materials. Recently, Kubas-type TM-based, hydrogen- stor ge materials were experimentally synthesized, and the Kubas-type interactions were measured to be stronger than the van der Waals interactions. In this review, the recent progress of Kubas-type hydrogen- storage materials will be discussed from both theoretical and experimental viewpoints. Hydrogen storage (dpeaa)DE-He213 Kubas interaction (dpeaa)DE-He213 Metal-dihydrogen complexes (dpeaa)DE-He213 Ihm, Jisoon verfasserin aut Lee, Hoonkyung verfasserin aut Enthalten in Journal of the Korean Physical Society Berlin : Springer, 1968 66(2015), 11 vom: Juni, Seite 1649-1655 (DE-627)328820865 (DE-600)2046361-3 1976-8524 nnns volume:66 year:2015 number:11 month:06 pages:1649-1655 https://dx.doi.org/10.3938/jkps.66.1649 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 66 2015 11 06 1649-1655 |
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10.3938/jkps.66.1649 doi (DE-627)SPR03271629X (SPR)jkps.66.1649-e DE-627 ger DE-627 rakwb eng 530 ASE 33.00 bkl Chung, ChiHye verfasserin aut Recent progress on Kubas-type hydrogen-storage nanomaterials: from theories to experiments 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Transition-metal (TM) atoms are known to form TM-$ H_{2} $ complexes, which are collectively called Kubas dihydrogen complexes. The TM-$ H_{2} $ complexes are formed through the hybridization of the TM d orbitals with the $ H_{2} $σ and σ* orbitals. The adsorption energy of $ H^{2} $ molecules in the TM-$ H_{2} $ complexes is usually within the range of energy required for reversible $ H_{2} $ storage at room temperature and ambient pressure (−0.4 ~ −0.2 eV/$ H_{2} $). Thus, TM-$ H_{2} $ complexes have been investigated as potential Kubas-type hydrogen-storage materials. Recently, TM-decorated nanomaterials have attracted much attention because of their promising high capacity and reversibility as Kubas-type hydrogen-storage materials. The hydrogen storage capacity of TM-decorated nanomaterials is expected to be as large as ~9 wt%, which is suitable for certain vehicular applications. However, in the TM-decorated nanostructures, the TM atoms prefer to form clusters because of the large cohesive energy (approximately 4 eV), which leads to a significant reduction in the hydrogen-storage capacity. On the other hand, Ca atoms can form complexes with $ H_{2} $ molecules via Kubas-like interactions. Ca atoms attached to nanomaterials have been reported to be able to adsorb as many $ H_{2} $ molecules as TM atoms. Ca atoms tend to cluster less because of the small cohesive energy of bulk Ca (1.83 eV), which is much smaller than those of bulk TMs. These observations suggest thatKubas interactions can occur in d orbital-free elements, thereby making Ca a more suitable element for attracting $ H^{2} $ in hydrogen-storage materials. Recently, Kubas-type TM-based, hydrogen- stor ge materials were experimentally synthesized, and the Kubas-type interactions were measured to be stronger than the van der Waals interactions. In this review, the recent progress of Kubas-type hydrogen- storage materials will be discussed from both theoretical and experimental viewpoints. Hydrogen storage (dpeaa)DE-He213 Kubas interaction (dpeaa)DE-He213 Metal-dihydrogen complexes (dpeaa)DE-He213 Ihm, Jisoon verfasserin aut Lee, Hoonkyung verfasserin aut Enthalten in Journal of the Korean Physical Society Berlin : Springer, 1968 66(2015), 11 vom: Juni, Seite 1649-1655 (DE-627)328820865 (DE-600)2046361-3 1976-8524 nnns volume:66 year:2015 number:11 month:06 pages:1649-1655 https://dx.doi.org/10.3938/jkps.66.1649 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 66 2015 11 06 1649-1655 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR03271629X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20220111204715.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201007s2015 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.3938/jkps.66.1649</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR03271629X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)jkps.66.1649-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">530</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">33.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Chung, ChiHye</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Recent progress on Kubas-type hydrogen-storage nanomaterials: from theories to experiments</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2015</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Transition-metal (TM) atoms are known to form TM-$ H_{2} $ complexes, which are collectively called Kubas dihydrogen complexes. The TM-$ H_{2} $ complexes are formed through the hybridization of the TM d orbitals with the $ H_{2} $σ and σ* orbitals. The adsorption energy of $ H^{2} $ molecules in the TM-$ H_{2} $ complexes is usually within the range of energy required for reversible $ H_{2} $ storage at room temperature and ambient pressure (−0.4 ~ −0.2 eV/$ H_{2} $). Thus, TM-$ H_{2} $ complexes have been investigated as potential Kubas-type hydrogen-storage materials. Recently, TM-decorated nanomaterials have attracted much attention because of their promising high capacity and reversibility as Kubas-type hydrogen-storage materials. The hydrogen storage capacity of TM-decorated nanomaterials is expected to be as large as ~9 wt%, which is suitable for certain vehicular applications. However, in the TM-decorated nanostructures, the TM atoms prefer to form clusters because of the large cohesive energy (approximately 4 eV), which leads to a significant reduction in the hydrogen-storage capacity. On the other hand, Ca atoms can form complexes with $ H_{2} $ molecules via Kubas-like interactions. Ca atoms attached to nanomaterials have been reported to be able to adsorb as many $ H_{2} $ molecules as TM atoms. Ca atoms tend to cluster less because of the small cohesive energy of bulk Ca (1.83 eV), which is much smaller than those of bulk TMs. These observations suggest thatKubas interactions can occur in d orbital-free elements, thereby making Ca a more suitable element for attracting $ H^{2} $ in hydrogen-storage materials. Recently, Kubas-type TM-based, hydrogen- stor ge materials were experimentally synthesized, and the Kubas-type interactions were measured to be stronger than the van der Waals interactions. 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Chung, ChiHye |
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Recent progress on Kubas-type hydrogen-storage nanomaterials: from theories to experiments |
| abstract |
Abstract Transition-metal (TM) atoms are known to form TM-$ H_{2} $ complexes, which are collectively called Kubas dihydrogen complexes. The TM-$ H_{2} $ complexes are formed through the hybridization of the TM d orbitals with the $ H_{2} $σ and σ* orbitals. The adsorption energy of $ H^{2} $ molecules in the TM-$ H_{2} $ complexes is usually within the range of energy required for reversible $ H_{2} $ storage at room temperature and ambient pressure (−0.4 ~ −0.2 eV/$ H_{2} $). Thus, TM-$ H_{2} $ complexes have been investigated as potential Kubas-type hydrogen-storage materials. Recently, TM-decorated nanomaterials have attracted much attention because of their promising high capacity and reversibility as Kubas-type hydrogen-storage materials. The hydrogen storage capacity of TM-decorated nanomaterials is expected to be as large as ~9 wt%, which is suitable for certain vehicular applications. However, in the TM-decorated nanostructures, the TM atoms prefer to form clusters because of the large cohesive energy (approximately 4 eV), which leads to a significant reduction in the hydrogen-storage capacity. On the other hand, Ca atoms can form complexes with $ H_{2} $ molecules via Kubas-like interactions. Ca atoms attached to nanomaterials have been reported to be able to adsorb as many $ H_{2} $ molecules as TM atoms. Ca atoms tend to cluster less because of the small cohesive energy of bulk Ca (1.83 eV), which is much smaller than those of bulk TMs. These observations suggest thatKubas interactions can occur in d orbital-free elements, thereby making Ca a more suitable element for attracting $ H^{2} $ in hydrogen-storage materials. Recently, Kubas-type TM-based, hydrogen- stor ge materials were experimentally synthesized, and the Kubas-type interactions were measured to be stronger than the van der Waals interactions. In this review, the recent progress of Kubas-type hydrogen- storage materials will be discussed from both theoretical and experimental viewpoints. |
| abstractGer |
Abstract Transition-metal (TM) atoms are known to form TM-$ H_{2} $ complexes, which are collectively called Kubas dihydrogen complexes. The TM-$ H_{2} $ complexes are formed through the hybridization of the TM d orbitals with the $ H_{2} $σ and σ* orbitals. The adsorption energy of $ H^{2} $ molecules in the TM-$ H_{2} $ complexes is usually within the range of energy required for reversible $ H_{2} $ storage at room temperature and ambient pressure (−0.4 ~ −0.2 eV/$ H_{2} $). Thus, TM-$ H_{2} $ complexes have been investigated as potential Kubas-type hydrogen-storage materials. Recently, TM-decorated nanomaterials have attracted much attention because of their promising high capacity and reversibility as Kubas-type hydrogen-storage materials. The hydrogen storage capacity of TM-decorated nanomaterials is expected to be as large as ~9 wt%, which is suitable for certain vehicular applications. However, in the TM-decorated nanostructures, the TM atoms prefer to form clusters because of the large cohesive energy (approximately 4 eV), which leads to a significant reduction in the hydrogen-storage capacity. On the other hand, Ca atoms can form complexes with $ H_{2} $ molecules via Kubas-like interactions. Ca atoms attached to nanomaterials have been reported to be able to adsorb as many $ H_{2} $ molecules as TM atoms. Ca atoms tend to cluster less because of the small cohesive energy of bulk Ca (1.83 eV), which is much smaller than those of bulk TMs. These observations suggest thatKubas interactions can occur in d orbital-free elements, thereby making Ca a more suitable element for attracting $ H^{2} $ in hydrogen-storage materials. Recently, Kubas-type TM-based, hydrogen- stor ge materials were experimentally synthesized, and the Kubas-type interactions were measured to be stronger than the van der Waals interactions. In this review, the recent progress of Kubas-type hydrogen- storage materials will be discussed from both theoretical and experimental viewpoints. |
| abstract_unstemmed |
Abstract Transition-metal (TM) atoms are known to form TM-$ H_{2} $ complexes, which are collectively called Kubas dihydrogen complexes. The TM-$ H_{2} $ complexes are formed through the hybridization of the TM d orbitals with the $ H_{2} $σ and σ* orbitals. The adsorption energy of $ H^{2} $ molecules in the TM-$ H_{2} $ complexes is usually within the range of energy required for reversible $ H_{2} $ storage at room temperature and ambient pressure (−0.4 ~ −0.2 eV/$ H_{2} $). Thus, TM-$ H_{2} $ complexes have been investigated as potential Kubas-type hydrogen-storage materials. Recently, TM-decorated nanomaterials have attracted much attention because of their promising high capacity and reversibility as Kubas-type hydrogen-storage materials. The hydrogen storage capacity of TM-decorated nanomaterials is expected to be as large as ~9 wt%, which is suitable for certain vehicular applications. However, in the TM-decorated nanostructures, the TM atoms prefer to form clusters because of the large cohesive energy (approximately 4 eV), which leads to a significant reduction in the hydrogen-storage capacity. On the other hand, Ca atoms can form complexes with $ H_{2} $ molecules via Kubas-like interactions. Ca atoms attached to nanomaterials have been reported to be able to adsorb as many $ H_{2} $ molecules as TM atoms. Ca atoms tend to cluster less because of the small cohesive energy of bulk Ca (1.83 eV), which is much smaller than those of bulk TMs. These observations suggest thatKubas interactions can occur in d orbital-free elements, thereby making Ca a more suitable element for attracting $ H^{2} $ in hydrogen-storage materials. Recently, Kubas-type TM-based, hydrogen- stor ge materials were experimentally synthesized, and the Kubas-type interactions were measured to be stronger than the van der Waals interactions. In this review, the recent progress of Kubas-type hydrogen- storage materials will be discussed from both theoretical and experimental viewpoints. |
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11 |
| title_short |
Recent progress on Kubas-type hydrogen-storage nanomaterials: from theories to experiments |
| url |
https://dx.doi.org/10.3938/jkps.66.1649 |
| remote_bool |
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| author2 |
Ihm, Jisoon Lee, Hoonkyung |
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| doi_str |
10.3938/jkps.66.1649 |
| up_date |
2024-07-03T14:22:20.754Z |
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| score |
7.4008236 |