Zinc complexes supported by N,N-dimethylaniline-arylamido ligands: Synthesis, characterization and catalytic properties for ring-opening polymerization of L-lactide
Abstract The reaction of bidentate N,N-dimethylaniline-arylamido ligands, o-$ C_{6} %$ H_{4} %$ NMe_{2} $($ CH_{2} $NHAr)(Ar = Ph, 1a; 2,6-$ Me_{2} %$ C_{6} %$ H_{3} $, 1b; 2,6-$ Et_{2} %$ C_{6} %$ H_{3} $, 1c; 2,6-i$ Pr_{2} %$ C_{6} %$ H_{3} $, 1d) with ZnEt2 yields the complexes o-$ C_{6} %$ H_{4}...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yao, Wei [verfasserIn] Xue, Yingzhao [verfasserIn] Liu, Tiantian [verfasserIn] Gao, Aihong [verfasserIn] Wang, Yanfeng [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Chemical Research in Chinese Universities - Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012, 30(2014), 1 vom: 09. Jan., Seite 87-90 |
|---|---|
| Übergeordnetes Werk: |
volume:30 ; year:2014 ; number:1 ; day:09 ; month:01 ; pages:87-90 |
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10.1007/s40242-014-3183-2 |
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| 520 | |a Abstract The reaction of bidentate N,N-dimethylaniline-arylamido ligands, o-$ C_{6} %$ H_{4} %$ NMe_{2} $($ CH_{2} $NHAr)(Ar = Ph, 1a; 2,6-$ Me_{2} %$ C_{6} %$ H_{3} $, 1b; 2,6-$ Et_{2} %$ C_{6} %$ H_{3} $, 1c; 2,6-i$ Pr_{2} %$ C_{6} %$ H_{3} $, 1d) with ZnEt2 yields the complexes o-$ C_{6} %$ H_{4} $($ NMe_{2} $)($ CH_{2} $NAr)ZnEt (2a-2d), respectively. All the complexes were characterized by 1H and 13C NMR spectroscopy and elemental analyses. It was found that all the zinc complexes were efficient catalysts for the ring-opening polymerization of L-lactide in the presence of benzyl alcohol with good molecular weight control and narrow polydispersity. | ||
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10.1007/s40242-014-3183-2 doi (DE-627)SPR032910460 (SPR)s40242-014-3183-2-e DE-627 ger DE-627 rakwb eng Yao, Wei verfasserin aut Zinc complexes supported by N,N-dimethylaniline-arylamido ligands: Synthesis, characterization and catalytic properties for ring-opening polymerization of L-lactide 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of bidentate N,N-dimethylaniline-arylamido ligands, o-$ C_{6} %$ H_{4} %$ NMe_{2} $($ CH_{2} $NHAr)(Ar = Ph, 1a; 2,6-$ Me_{2} %$ C_{6} %$ H_{3} $, 1b; 2,6-$ Et_{2} %$ C_{6} %$ H_{3} $, 1c; 2,6-i$ Pr_{2} %$ C_{6} %$ H_{3} $, 1d) with ZnEt2 yields the complexes o-$ C_{6} %$ H_{4} $($ NMe_{2} $)($ CH_{2} $NAr)ZnEt (2a-2d), respectively. All the complexes were characterized by 1H and 13C NMR spectroscopy and elemental analyses. It was found that all the zinc complexes were efficient catalysts for the ring-opening polymerization of L-lactide in the presence of benzyl alcohol with good molecular weight control and narrow polydispersity. Zinc complex; Ring-opening polymerization; (dpeaa)DE-He213 -Lactide (dpeaa)DE-He213 Xue, Yingzhao verfasserin aut Liu, Tiantian verfasserin aut Gao, Aihong verfasserin aut Wang, Yanfeng verfasserin aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 30(2014), 1 vom: 09. Jan., Seite 87-90 (DE-627)SPR03290777X nnns volume:30 year:2014 number:1 day:09 month:01 pages:87-90 https://dx.doi.org/10.1007/s40242-014-3183-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA AR 30 2014 1 09 01 87-90 |
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10.1007/s40242-014-3183-2 doi (DE-627)SPR032910460 (SPR)s40242-014-3183-2-e DE-627 ger DE-627 rakwb eng Yao, Wei verfasserin aut Zinc complexes supported by N,N-dimethylaniline-arylamido ligands: Synthesis, characterization and catalytic properties for ring-opening polymerization of L-lactide 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of bidentate N,N-dimethylaniline-arylamido ligands, o-$ C_{6} %$ H_{4} %$ NMe_{2} $($ CH_{2} $NHAr)(Ar = Ph, 1a; 2,6-$ Me_{2} %$ C_{6} %$ H_{3} $, 1b; 2,6-$ Et_{2} %$ C_{6} %$ H_{3} $, 1c; 2,6-i$ Pr_{2} %$ C_{6} %$ H_{3} $, 1d) with ZnEt2 yields the complexes o-$ C_{6} %$ H_{4} $($ NMe_{2} $)($ CH_{2} $NAr)ZnEt (2a-2d), respectively. All the complexes were characterized by 1H and 13C NMR spectroscopy and elemental analyses. It was found that all the zinc complexes were efficient catalysts for the ring-opening polymerization of L-lactide in the presence of benzyl alcohol with good molecular weight control and narrow polydispersity. Zinc complex; Ring-opening polymerization; (dpeaa)DE-He213 -Lactide (dpeaa)DE-He213 Xue, Yingzhao verfasserin aut Liu, Tiantian verfasserin aut Gao, Aihong verfasserin aut Wang, Yanfeng verfasserin aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 30(2014), 1 vom: 09. Jan., Seite 87-90 (DE-627)SPR03290777X nnns volume:30 year:2014 number:1 day:09 month:01 pages:87-90 https://dx.doi.org/10.1007/s40242-014-3183-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA AR 30 2014 1 09 01 87-90 |
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10.1007/s40242-014-3183-2 doi (DE-627)SPR032910460 (SPR)s40242-014-3183-2-e DE-627 ger DE-627 rakwb eng Yao, Wei verfasserin aut Zinc complexes supported by N,N-dimethylaniline-arylamido ligands: Synthesis, characterization and catalytic properties for ring-opening polymerization of L-lactide 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of bidentate N,N-dimethylaniline-arylamido ligands, o-$ C_{6} %$ H_{4} %$ NMe_{2} $($ CH_{2} $NHAr)(Ar = Ph, 1a; 2,6-$ Me_{2} %$ C_{6} %$ H_{3} $, 1b; 2,6-$ Et_{2} %$ C_{6} %$ H_{3} $, 1c; 2,6-i$ Pr_{2} %$ C_{6} %$ H_{3} $, 1d) with ZnEt2 yields the complexes o-$ C_{6} %$ H_{4} $($ NMe_{2} $)($ CH_{2} $NAr)ZnEt (2a-2d), respectively. All the complexes were characterized by 1H and 13C NMR spectroscopy and elemental analyses. It was found that all the zinc complexes were efficient catalysts for the ring-opening polymerization of L-lactide in the presence of benzyl alcohol with good molecular weight control and narrow polydispersity. Zinc complex; Ring-opening polymerization; (dpeaa)DE-He213 -Lactide (dpeaa)DE-He213 Xue, Yingzhao verfasserin aut Liu, Tiantian verfasserin aut Gao, Aihong verfasserin aut Wang, Yanfeng verfasserin aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 30(2014), 1 vom: 09. Jan., Seite 87-90 (DE-627)SPR03290777X nnns volume:30 year:2014 number:1 day:09 month:01 pages:87-90 https://dx.doi.org/10.1007/s40242-014-3183-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA AR 30 2014 1 09 01 87-90 |
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10.1007/s40242-014-3183-2 doi (DE-627)SPR032910460 (SPR)s40242-014-3183-2-e DE-627 ger DE-627 rakwb eng Yao, Wei verfasserin aut Zinc complexes supported by N,N-dimethylaniline-arylamido ligands: Synthesis, characterization and catalytic properties for ring-opening polymerization of L-lactide 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of bidentate N,N-dimethylaniline-arylamido ligands, o-$ C_{6} %$ H_{4} %$ NMe_{2} $($ CH_{2} $NHAr)(Ar = Ph, 1a; 2,6-$ Me_{2} %$ C_{6} %$ H_{3} $, 1b; 2,6-$ Et_{2} %$ C_{6} %$ H_{3} $, 1c; 2,6-i$ Pr_{2} %$ C_{6} %$ H_{3} $, 1d) with ZnEt2 yields the complexes o-$ C_{6} %$ H_{4} $($ NMe_{2} $)($ CH_{2} $NAr)ZnEt (2a-2d), respectively. All the complexes were characterized by 1H and 13C NMR spectroscopy and elemental analyses. It was found that all the zinc complexes were efficient catalysts for the ring-opening polymerization of L-lactide in the presence of benzyl alcohol with good molecular weight control and narrow polydispersity. Zinc complex; Ring-opening polymerization; (dpeaa)DE-He213 -Lactide (dpeaa)DE-He213 Xue, Yingzhao verfasserin aut Liu, Tiantian verfasserin aut Gao, Aihong verfasserin aut Wang, Yanfeng verfasserin aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 30(2014), 1 vom: 09. Jan., Seite 87-90 (DE-627)SPR03290777X nnns volume:30 year:2014 number:1 day:09 month:01 pages:87-90 https://dx.doi.org/10.1007/s40242-014-3183-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA AR 30 2014 1 09 01 87-90 |
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10.1007/s40242-014-3183-2 doi (DE-627)SPR032910460 (SPR)s40242-014-3183-2-e DE-627 ger DE-627 rakwb eng Yao, Wei verfasserin aut Zinc complexes supported by N,N-dimethylaniline-arylamido ligands: Synthesis, characterization and catalytic properties for ring-opening polymerization of L-lactide 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of bidentate N,N-dimethylaniline-arylamido ligands, o-$ C_{6} %$ H_{4} %$ NMe_{2} $($ CH_{2} $NHAr)(Ar = Ph, 1a; 2,6-$ Me_{2} %$ C_{6} %$ H_{3} $, 1b; 2,6-$ Et_{2} %$ C_{6} %$ H_{3} $, 1c; 2,6-i$ Pr_{2} %$ C_{6} %$ H_{3} $, 1d) with ZnEt2 yields the complexes o-$ C_{6} %$ H_{4} $($ NMe_{2} $)($ CH_{2} $NAr)ZnEt (2a-2d), respectively. All the complexes were characterized by 1H and 13C NMR spectroscopy and elemental analyses. It was found that all the zinc complexes were efficient catalysts for the ring-opening polymerization of L-lactide in the presence of benzyl alcohol with good molecular weight control and narrow polydispersity. Zinc complex; Ring-opening polymerization; (dpeaa)DE-He213 -Lactide (dpeaa)DE-He213 Xue, Yingzhao verfasserin aut Liu, Tiantian verfasserin aut Gao, Aihong verfasserin aut Wang, Yanfeng verfasserin aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 30(2014), 1 vom: 09. Jan., Seite 87-90 (DE-627)SPR03290777X nnns volume:30 year:2014 number:1 day:09 month:01 pages:87-90 https://dx.doi.org/10.1007/s40242-014-3183-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA AR 30 2014 1 09 01 87-90 |
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Yao, Wei |
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Yao, Wei misc Zinc complex; Ring-opening polymerization; misc -Lactide Zinc complexes supported by N,N-dimethylaniline-arylamido ligands: Synthesis, characterization and catalytic properties for ring-opening polymerization of L-lactide |
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Zinc complexes supported by N,N-dimethylaniline-arylamido ligands: Synthesis, characterization and catalytic properties for ring-opening polymerization of L-lactide Zinc complex; Ring-opening polymerization; (dpeaa)DE-He213 -Lactide (dpeaa)DE-He213 |
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zinc complexes supported by n,n-dimethylaniline-arylamido ligands: synthesis, characterization and catalytic properties for ring-opening polymerization of l-lactide |
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Zinc complexes supported by N,N-dimethylaniline-arylamido ligands: Synthesis, characterization and catalytic properties for ring-opening polymerization of L-lactide |
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Abstract The reaction of bidentate N,N-dimethylaniline-arylamido ligands, o-$ C_{6} %$ H_{4} %$ NMe_{2} $($ CH_{2} $NHAr)(Ar = Ph, 1a; 2,6-$ Me_{2} %$ C_{6} %$ H_{3} $, 1b; 2,6-$ Et_{2} %$ C_{6} %$ H_{3} $, 1c; 2,6-i$ Pr_{2} %$ C_{6} %$ H_{3} $, 1d) with ZnEt2 yields the complexes o-$ C_{6} %$ H_{4} $($ NMe_{2} $)($ CH_{2} $NAr)ZnEt (2a-2d), respectively. All the complexes were characterized by 1H and 13C NMR spectroscopy and elemental analyses. It was found that all the zinc complexes were efficient catalysts for the ring-opening polymerization of L-lactide in the presence of benzyl alcohol with good molecular weight control and narrow polydispersity. |
| abstractGer |
Abstract The reaction of bidentate N,N-dimethylaniline-arylamido ligands, o-$ C_{6} %$ H_{4} %$ NMe_{2} $($ CH_{2} $NHAr)(Ar = Ph, 1a; 2,6-$ Me_{2} %$ C_{6} %$ H_{3} $, 1b; 2,6-$ Et_{2} %$ C_{6} %$ H_{3} $, 1c; 2,6-i$ Pr_{2} %$ C_{6} %$ H_{3} $, 1d) with ZnEt2 yields the complexes o-$ C_{6} %$ H_{4} $($ NMe_{2} $)($ CH_{2} $NAr)ZnEt (2a-2d), respectively. All the complexes were characterized by 1H and 13C NMR spectroscopy and elemental analyses. It was found that all the zinc complexes were efficient catalysts for the ring-opening polymerization of L-lactide in the presence of benzyl alcohol with good molecular weight control and narrow polydispersity. |
| abstract_unstemmed |
Abstract The reaction of bidentate N,N-dimethylaniline-arylamido ligands, o-$ C_{6} %$ H_{4} %$ NMe_{2} $($ CH_{2} $NHAr)(Ar = Ph, 1a; 2,6-$ Me_{2} %$ C_{6} %$ H_{3} $, 1b; 2,6-$ Et_{2} %$ C_{6} %$ H_{3} $, 1c; 2,6-i$ Pr_{2} %$ C_{6} %$ H_{3} $, 1d) with ZnEt2 yields the complexes o-$ C_{6} %$ H_{4} $($ NMe_{2} $)($ CH_{2} $NAr)ZnEt (2a-2d), respectively. All the complexes were characterized by 1H and 13C NMR spectroscopy and elemental analyses. It was found that all the zinc complexes were efficient catalysts for the ring-opening polymerization of L-lactide in the presence of benzyl alcohol with good molecular weight control and narrow polydispersity. |
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Zinc complexes supported by N,N-dimethylaniline-arylamido ligands: Synthesis, characterization and catalytic properties for ring-opening polymerization of L-lactide |
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https://dx.doi.org/10.1007/s40242-014-3183-2 |
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Xue, Yingzhao Liu, Tiantian Gao, Aihong Wang, Yanfeng |
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2024-07-03T15:24:47.933Z |
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