Synthesis and characterization of dinuclear aluminum complexes bearing N,N-Dialkylaniline-amido ligands and its catalytic properties for lactone polymerization
Abstract Two ligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $NH)]2$ CH_{2} %$ CH_{2} $(3: R=Me; 4: R=Et) were prepared by the reduction of preligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $(CH=N)]2$ CH_{2} %$ CH_{2} $(1: R=Me; 2: R=Et). These ligands reacted with $ AlMe_{3} $ to afford the corresp...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Han, Yancheng [verfasserIn] Zhu, Guangyun [verfasserIn] Zhang, Mengmeng [verfasserIn] Wang, Shuai [verfasserIn] Yao, Wei [verfasserIn] Gao, Aihong [verfasserIn] Lu, Ping [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Chemical Research in Chinese Universities - Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012, 30(2014), 5 vom: 12. Sept., Seite 874-878 |
|---|---|
| Übergeordnetes Werk: |
volume:30 ; year:2014 ; number:5 ; day:12 ; month:09 ; pages:874-878 |
| Links: |
|---|
| DOI / URN: |
10.1007/s40242-014-3507-2 |
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SPR032911831 |
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| 520 | |a Abstract Two ligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $NH)]2$ CH_{2} %$ CH_{2} $(3: R=Me; 4: R=Et) were prepared by the reduction of preligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $(CH=N)]2$ CH_{2} %$ CH_{2} $(1: R=Me; 2: R=Et). These ligands reacted with $ AlMe_{3} $ to afford the corresponding dinuclear aluminum complexes {$ AlMe_{2} $[ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $N)]}2$ CH_{2} %$ CH_{2} $(5: R=Me; 6: R=Et). All the compounds were characterized by 1H and 13C nuclear magnetic resonance(NMR) spectroscopies and elemental analyses. The catalytic properties of the aluminum complexes towards the ring-opening polymerization of lactones were investigated in the presence of benzyl alcohol. All the polymerization reactions were proceeded in a controlled manner. | ||
| 650 | 4 | |a Dinuclear aluminum |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Ring-opening polymerization |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Lactone |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Zhu, Guangyun |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Mengmeng |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Shuai |e verfasserin |4 aut | |
| 700 | 1 | |a Yao, Wei |e verfasserin |4 aut | |
| 700 | 1 | |a Gao, Aihong |e verfasserin |4 aut | |
| 700 | 1 | |a Lu, Ping |e verfasserin |4 aut | |
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10.1007/s40242-014-3507-2 doi (DE-627)SPR032911831 (SPR)s40242-014-3507-2-e DE-627 ger DE-627 rakwb eng Han, Yancheng verfasserin aut Synthesis and characterization of dinuclear aluminum complexes bearing N,N-Dialkylaniline-amido ligands and its catalytic properties for lactone polymerization 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Two ligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $NH)]2$ CH_{2} %$ CH_{2} $(3: R=Me; 4: R=Et) were prepared by the reduction of preligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $(CH=N)]2$ CH_{2} %$ CH_{2} $(1: R=Me; 2: R=Et). These ligands reacted with $ AlMe_{3} $ to afford the corresponding dinuclear aluminum complexes {$ AlMe_{2} $[ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $N)]}2$ CH_{2} %$ CH_{2} $(5: R=Me; 6: R=Et). All the compounds were characterized by 1H and 13C nuclear magnetic resonance(NMR) spectroscopies and elemental analyses. The catalytic properties of the aluminum complexes towards the ring-opening polymerization of lactones were investigated in the presence of benzyl alcohol. All the polymerization reactions were proceeded in a controlled manner. Dinuclear aluminum (dpeaa)DE-He213 Ring-opening polymerization (dpeaa)DE-He213 Lactone (dpeaa)DE-He213 Zhu, Guangyun verfasserin aut Zhang, Mengmeng verfasserin aut Wang, Shuai verfasserin aut Yao, Wei verfasserin aut Gao, Aihong verfasserin aut Lu, Ping verfasserin aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 30(2014), 5 vom: 12. Sept., Seite 874-878 (DE-627)SPR03290777X nnns volume:30 year:2014 number:5 day:12 month:09 pages:874-878 https://dx.doi.org/10.1007/s40242-014-3507-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA AR 30 2014 5 12 09 874-878 |
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10.1007/s40242-014-3507-2 doi (DE-627)SPR032911831 (SPR)s40242-014-3507-2-e DE-627 ger DE-627 rakwb eng Han, Yancheng verfasserin aut Synthesis and characterization of dinuclear aluminum complexes bearing N,N-Dialkylaniline-amido ligands and its catalytic properties for lactone polymerization 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Two ligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $NH)]2$ CH_{2} %$ CH_{2} $(3: R=Me; 4: R=Et) were prepared by the reduction of preligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $(CH=N)]2$ CH_{2} %$ CH_{2} $(1: R=Me; 2: R=Et). These ligands reacted with $ AlMe_{3} $ to afford the corresponding dinuclear aluminum complexes {$ AlMe_{2} $[ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $N)]}2$ CH_{2} %$ CH_{2} $(5: R=Me; 6: R=Et). All the compounds were characterized by 1H and 13C nuclear magnetic resonance(NMR) spectroscopies and elemental analyses. The catalytic properties of the aluminum complexes towards the ring-opening polymerization of lactones were investigated in the presence of benzyl alcohol. All the polymerization reactions were proceeded in a controlled manner. Dinuclear aluminum (dpeaa)DE-He213 Ring-opening polymerization (dpeaa)DE-He213 Lactone (dpeaa)DE-He213 Zhu, Guangyun verfasserin aut Zhang, Mengmeng verfasserin aut Wang, Shuai verfasserin aut Yao, Wei verfasserin aut Gao, Aihong verfasserin aut Lu, Ping verfasserin aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 30(2014), 5 vom: 12. Sept., Seite 874-878 (DE-627)SPR03290777X nnns volume:30 year:2014 number:5 day:12 month:09 pages:874-878 https://dx.doi.org/10.1007/s40242-014-3507-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA AR 30 2014 5 12 09 874-878 |
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10.1007/s40242-014-3507-2 doi (DE-627)SPR032911831 (SPR)s40242-014-3507-2-e DE-627 ger DE-627 rakwb eng Han, Yancheng verfasserin aut Synthesis and characterization of dinuclear aluminum complexes bearing N,N-Dialkylaniline-amido ligands and its catalytic properties for lactone polymerization 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Two ligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $NH)]2$ CH_{2} %$ CH_{2} $(3: R=Me; 4: R=Et) were prepared by the reduction of preligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $(CH=N)]2$ CH_{2} %$ CH_{2} $(1: R=Me; 2: R=Et). These ligands reacted with $ AlMe_{3} $ to afford the corresponding dinuclear aluminum complexes {$ AlMe_{2} $[ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $N)]}2$ CH_{2} %$ CH_{2} $(5: R=Me; 6: R=Et). All the compounds were characterized by 1H and 13C nuclear magnetic resonance(NMR) spectroscopies and elemental analyses. The catalytic properties of the aluminum complexes towards the ring-opening polymerization of lactones were investigated in the presence of benzyl alcohol. All the polymerization reactions were proceeded in a controlled manner. Dinuclear aluminum (dpeaa)DE-He213 Ring-opening polymerization (dpeaa)DE-He213 Lactone (dpeaa)DE-He213 Zhu, Guangyun verfasserin aut Zhang, Mengmeng verfasserin aut Wang, Shuai verfasserin aut Yao, Wei verfasserin aut Gao, Aihong verfasserin aut Lu, Ping verfasserin aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 30(2014), 5 vom: 12. Sept., Seite 874-878 (DE-627)SPR03290777X nnns volume:30 year:2014 number:5 day:12 month:09 pages:874-878 https://dx.doi.org/10.1007/s40242-014-3507-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA AR 30 2014 5 12 09 874-878 |
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10.1007/s40242-014-3507-2 doi (DE-627)SPR032911831 (SPR)s40242-014-3507-2-e DE-627 ger DE-627 rakwb eng Han, Yancheng verfasserin aut Synthesis and characterization of dinuclear aluminum complexes bearing N,N-Dialkylaniline-amido ligands and its catalytic properties for lactone polymerization 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Two ligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $NH)]2$ CH_{2} %$ CH_{2} $(3: R=Me; 4: R=Et) were prepared by the reduction of preligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $(CH=N)]2$ CH_{2} %$ CH_{2} $(1: R=Me; 2: R=Et). These ligands reacted with $ AlMe_{3} $ to afford the corresponding dinuclear aluminum complexes {$ AlMe_{2} $[ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $N)]}2$ CH_{2} %$ CH_{2} $(5: R=Me; 6: R=Et). All the compounds were characterized by 1H and 13C nuclear magnetic resonance(NMR) spectroscopies and elemental analyses. The catalytic properties of the aluminum complexes towards the ring-opening polymerization of lactones were investigated in the presence of benzyl alcohol. All the polymerization reactions were proceeded in a controlled manner. Dinuclear aluminum (dpeaa)DE-He213 Ring-opening polymerization (dpeaa)DE-He213 Lactone (dpeaa)DE-He213 Zhu, Guangyun verfasserin aut Zhang, Mengmeng verfasserin aut Wang, Shuai verfasserin aut Yao, Wei verfasserin aut Gao, Aihong verfasserin aut Lu, Ping verfasserin aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 30(2014), 5 vom: 12. Sept., Seite 874-878 (DE-627)SPR03290777X nnns volume:30 year:2014 number:5 day:12 month:09 pages:874-878 https://dx.doi.org/10.1007/s40242-014-3507-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA AR 30 2014 5 12 09 874-878 |
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10.1007/s40242-014-3507-2 doi (DE-627)SPR032911831 (SPR)s40242-014-3507-2-e DE-627 ger DE-627 rakwb eng Han, Yancheng verfasserin aut Synthesis and characterization of dinuclear aluminum complexes bearing N,N-Dialkylaniline-amido ligands and its catalytic properties for lactone polymerization 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Two ligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $NH)]2$ CH_{2} %$ CH_{2} $(3: R=Me; 4: R=Et) were prepared by the reduction of preligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $(CH=N)]2$ CH_{2} %$ CH_{2} $(1: R=Me; 2: R=Et). These ligands reacted with $ AlMe_{3} $ to afford the corresponding dinuclear aluminum complexes {$ AlMe_{2} $[ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $N)]}2$ CH_{2} %$ CH_{2} $(5: R=Me; 6: R=Et). All the compounds were characterized by 1H and 13C nuclear magnetic resonance(NMR) spectroscopies and elemental analyses. The catalytic properties of the aluminum complexes towards the ring-opening polymerization of lactones were investigated in the presence of benzyl alcohol. All the polymerization reactions were proceeded in a controlled manner. Dinuclear aluminum (dpeaa)DE-He213 Ring-opening polymerization (dpeaa)DE-He213 Lactone (dpeaa)DE-He213 Zhu, Guangyun verfasserin aut Zhang, Mengmeng verfasserin aut Wang, Shuai verfasserin aut Yao, Wei verfasserin aut Gao, Aihong verfasserin aut Lu, Ping verfasserin aut Enthalten in Chemical Research in Chinese Universities Jilin University and The Editorial Department of Chemical Research in Chinese Universities, 2012 30(2014), 5 vom: 12. Sept., Seite 874-878 (DE-627)SPR03290777X nnns volume:30 year:2014 number:5 day:12 month:09 pages:874-878 https://dx.doi.org/10.1007/s40242-014-3507-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA AR 30 2014 5 12 09 874-878 |
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synthesis and characterization of dinuclear aluminum complexes bearing n,n-dialkylaniline-amido ligands and its catalytic properties for lactone polymerization |
| title_auth |
Synthesis and characterization of dinuclear aluminum complexes bearing N,N-Dialkylaniline-amido ligands and its catalytic properties for lactone polymerization |
| abstract |
Abstract Two ligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $NH)]2$ CH_{2} %$ CH_{2} $(3: R=Me; 4: R=Et) were prepared by the reduction of preligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $(CH=N)]2$ CH_{2} %$ CH_{2} $(1: R=Me; 2: R=Et). These ligands reacted with $ AlMe_{3} $ to afford the corresponding dinuclear aluminum complexes {$ AlMe_{2} $[ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $N)]}2$ CH_{2} %$ CH_{2} $(5: R=Me; 6: R=Et). All the compounds were characterized by 1H and 13C nuclear magnetic resonance(NMR) spectroscopies and elemental analyses. The catalytic properties of the aluminum complexes towards the ring-opening polymerization of lactones were investigated in the presence of benzyl alcohol. All the polymerization reactions were proceeded in a controlled manner. |
| abstractGer |
Abstract Two ligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $NH)]2$ CH_{2} %$ CH_{2} $(3: R=Me; 4: R=Et) were prepared by the reduction of preligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $(CH=N)]2$ CH_{2} %$ CH_{2} $(1: R=Me; 2: R=Et). These ligands reacted with $ AlMe_{3} $ to afford the corresponding dinuclear aluminum complexes {$ AlMe_{2} $[ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $N)]}2$ CH_{2} %$ CH_{2} $(5: R=Me; 6: R=Et). All the compounds were characterized by 1H and 13C nuclear magnetic resonance(NMR) spectroscopies and elemental analyses. The catalytic properties of the aluminum complexes towards the ring-opening polymerization of lactones were investigated in the presence of benzyl alcohol. All the polymerization reactions were proceeded in a controlled manner. |
| abstract_unstemmed |
Abstract Two ligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $NH)]2$ CH_{2} %$ CH_{2} $(3: R=Me; 4: R=Et) were prepared by the reduction of preligands [ortho-$ C_{6} %$ H_{4} %$ NR_{2} $(CH=N)]2$ CH_{2} %$ CH_{2} $(1: R=Me; 2: R=Et). These ligands reacted with $ AlMe_{3} $ to afford the corresponding dinuclear aluminum complexes {$ AlMe_{2} $[ortho-$ C_{6} %$ H_{4} %$ NR_{2} $($ CH_{2} $N)]}2$ CH_{2} %$ CH_{2} $(5: R=Me; 6: R=Et). All the compounds were characterized by 1H and 13C nuclear magnetic resonance(NMR) spectroscopies and elemental analyses. The catalytic properties of the aluminum complexes towards the ring-opening polymerization of lactones were investigated in the presence of benzyl alcohol. All the polymerization reactions were proceeded in a controlled manner. |
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GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA |
| container_issue |
5 |
| title_short |
Synthesis and characterization of dinuclear aluminum complexes bearing N,N-Dialkylaniline-amido ligands and its catalytic properties for lactone polymerization |
| url |
https://dx.doi.org/10.1007/s40242-014-3507-2 |
| remote_bool |
true |
| author2 |
Zhu, Guangyun Zhang, Mengmeng Wang, Shuai Yao, Wei Gao, Aihong Lu, Ping |
| author2Str |
Zhu, Guangyun Zhang, Mengmeng Wang, Shuai Yao, Wei Gao, Aihong Lu, Ping |
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| doi_str |
10.1007/s40242-014-3507-2 |
| up_date |
2024-07-03T15:25:11.265Z |
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1803572017905008640 |
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