High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte

Abstract Selenium attracts increasing attention as cathode material for rechargeable lithium batteries due to its high conductivity and comparable volumetric capacity with sulfur. Microporous carbon spheres (MiPCS) are synthesized via a hydrothermal-annealing route followed by activation with KOH. T...
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Autor*in:	Wu, Chao [verfasserIn] Yuan, Lixia Li, Zhen Yi, Ziqi Zeng, Rui Li, Yanrong Huang, Yunhui

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2015

Schlagwörter:	Science China Material Sulfur Cathode Ethyl Methyl Carbonate Hierarchical Porous Carbon Carbonate Electrolyte

Anmerkung:	© Science China Press and Springer-Verlag Berlin Heidelberg 2015

Übergeordnetes Werk:	Enthalten in: Science China materials - Beijing : Science China Press, 2014, 58(2015), 2 vom: Feb., Seite 91-97
Übergeordnetes Werk:	volume:58 ; year:2015 ; number:2 ; month:02 ; pages:91-97

Links:	Volltext

DOI / URN:	10.1007/s40843-015-0030-9

Katalog-ID:	SPR037909452

Internformat


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520			\|a Abstract Selenium attracts increasing attention as cathode material for rechargeable lithium batteries due to its high conductivity and comparable volumetric capacity with sulfur. Microporous carbon spheres (MiPCS) are synthesized via a hydrothermal-annealing route followed by activation with KOH. The MiPCS are used as matrix for Se loading to form Se/MiPCS composite. Such composite delivers a high specific capacity close to the theoretical value of Se. In carbonate-based electrolyte, the capacity is as high as 733 mAh $ g^{−1} $ at a current density of 50 mA $ g^{−1} $, and 353 mAh $ g^{−1} $ at 5000 mA $ g^{−1} $. At 0.5 C, the capacity retains up to 515 mAh g-1 even after 100 cycles. Such outstanding electrochemical performance of the composite cathode in the carbonate electrolyte can be ascribed to the robust structure of MiPCS and to the “ solid-solid” electrode process.
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700	1		\|a Li, Yanrong \|4 aut
700	1		\|a Huang, Yunhui \|4 aut
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912			\|a GBV_ILN_90
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912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
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912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
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912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
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912			\|a GBV_ILN_2122
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author_variant	c w cw l y ly z l zl z y zy r z rz y l yl y h yh
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publishDate	2015
allfields	10.1007/s40843-015-0030-9 doi (DE-627)SPR037909452 (SPR)s40843-015-0030-9-e DE-627 ger DE-627 rakwb eng Wu, Chao verfasserin aut High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press and Springer-Verlag Berlin Heidelberg 2015 Abstract Selenium attracts increasing attention as cathode material for rechargeable lithium batteries due to its high conductivity and comparable volumetric capacity with sulfur. Microporous carbon spheres (MiPCS) are synthesized via a hydrothermal-annealing route followed by activation with KOH. The MiPCS are used as matrix for Se loading to form Se/MiPCS composite. Such composite delivers a high specific capacity close to the theoretical value of Se. In carbonate-based electrolyte, the capacity is as high as 733 mAh $ g^{−1} $ at a current density of 50 mA $ g^{−1} $, and 353 mAh $ g^{−1} $ at 5000 mA $ g^{−1} $. At 0.5 C, the capacity retains up to 515 mAh g-1 even after 100 cycles. Such outstanding electrochemical performance of the composite cathode in the carbonate electrolyte can be ascribed to the robust structure of MiPCS and to the “ solid-solid” electrode process. Science China Material (dpeaa)DE-He213 Sulfur Cathode (dpeaa)DE-He213 Ethyl Methyl Carbonate (dpeaa)DE-He213 Hierarchical Porous Carbon (dpeaa)DE-He213 Carbonate Electrolyte (dpeaa)DE-He213 Yuan, Lixia aut Li, Zhen aut Yi, Ziqi aut Zeng, Rui aut Li, Yanrong aut Huang, Yunhui aut Enthalten in Science China materials Beijing : Science China Press, 2014 58(2015), 2 vom: Feb., Seite 91-97 (DE-627)815914733 (DE-600)2806677-7 2199-4501 nnns volume:58 year:2015 number:2 month:02 pages:91-97 https://dx.doi.org/10.1007/s40843-015-0030-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 58 2015 2 02 91-97
spelling	10.1007/s40843-015-0030-9 doi (DE-627)SPR037909452 (SPR)s40843-015-0030-9-e DE-627 ger DE-627 rakwb eng Wu, Chao verfasserin aut High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press and Springer-Verlag Berlin Heidelberg 2015 Abstract Selenium attracts increasing attention as cathode material for rechargeable lithium batteries due to its high conductivity and comparable volumetric capacity with sulfur. Microporous carbon spheres (MiPCS) are synthesized via a hydrothermal-annealing route followed by activation with KOH. The MiPCS are used as matrix for Se loading to form Se/MiPCS composite. Such composite delivers a high specific capacity close to the theoretical value of Se. In carbonate-based electrolyte, the capacity is as high as 733 mAh $ g^{−1} $ at a current density of 50 mA $ g^{−1} $, and 353 mAh $ g^{−1} $ at 5000 mA $ g^{−1} $. At 0.5 C, the capacity retains up to 515 mAh g-1 even after 100 cycles. Such outstanding electrochemical performance of the composite cathode in the carbonate electrolyte can be ascribed to the robust structure of MiPCS and to the “ solid-solid” electrode process. Science China Material (dpeaa)DE-He213 Sulfur Cathode (dpeaa)DE-He213 Ethyl Methyl Carbonate (dpeaa)DE-He213 Hierarchical Porous Carbon (dpeaa)DE-He213 Carbonate Electrolyte (dpeaa)DE-He213 Yuan, Lixia aut Li, Zhen aut Yi, Ziqi aut Zeng, Rui aut Li, Yanrong aut Huang, Yunhui aut Enthalten in Science China materials Beijing : Science China Press, 2014 58(2015), 2 vom: Feb., Seite 91-97 (DE-627)815914733 (DE-600)2806677-7 2199-4501 nnns volume:58 year:2015 number:2 month:02 pages:91-97 https://dx.doi.org/10.1007/s40843-015-0030-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 58 2015 2 02 91-97
allfields_unstemmed	10.1007/s40843-015-0030-9 doi (DE-627)SPR037909452 (SPR)s40843-015-0030-9-e DE-627 ger DE-627 rakwb eng Wu, Chao verfasserin aut High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press and Springer-Verlag Berlin Heidelberg 2015 Abstract Selenium attracts increasing attention as cathode material for rechargeable lithium batteries due to its high conductivity and comparable volumetric capacity with sulfur. Microporous carbon spheres (MiPCS) are synthesized via a hydrothermal-annealing route followed by activation with KOH. The MiPCS are used as matrix for Se loading to form Se/MiPCS composite. Such composite delivers a high specific capacity close to the theoretical value of Se. In carbonate-based electrolyte, the capacity is as high as 733 mAh $ g^{−1} $ at a current density of 50 mA $ g^{−1} $, and 353 mAh $ g^{−1} $ at 5000 mA $ g^{−1} $. At 0.5 C, the capacity retains up to 515 mAh g-1 even after 100 cycles. Such outstanding electrochemical performance of the composite cathode in the carbonate electrolyte can be ascribed to the robust structure of MiPCS and to the “ solid-solid” electrode process. Science China Material (dpeaa)DE-He213 Sulfur Cathode (dpeaa)DE-He213 Ethyl Methyl Carbonate (dpeaa)DE-He213 Hierarchical Porous Carbon (dpeaa)DE-He213 Carbonate Electrolyte (dpeaa)DE-He213 Yuan, Lixia aut Li, Zhen aut Yi, Ziqi aut Zeng, Rui aut Li, Yanrong aut Huang, Yunhui aut Enthalten in Science China materials Beijing : Science China Press, 2014 58(2015), 2 vom: Feb., Seite 91-97 (DE-627)815914733 (DE-600)2806677-7 2199-4501 nnns volume:58 year:2015 number:2 month:02 pages:91-97 https://dx.doi.org/10.1007/s40843-015-0030-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 58 2015 2 02 91-97
allfieldsGer	10.1007/s40843-015-0030-9 doi (DE-627)SPR037909452 (SPR)s40843-015-0030-9-e DE-627 ger DE-627 rakwb eng Wu, Chao verfasserin aut High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press and Springer-Verlag Berlin Heidelberg 2015 Abstract Selenium attracts increasing attention as cathode material for rechargeable lithium batteries due to its high conductivity and comparable volumetric capacity with sulfur. Microporous carbon spheres (MiPCS) are synthesized via a hydrothermal-annealing route followed by activation with KOH. The MiPCS are used as matrix for Se loading to form Se/MiPCS composite. Such composite delivers a high specific capacity close to the theoretical value of Se. In carbonate-based electrolyte, the capacity is as high as 733 mAh $ g^{−1} $ at a current density of 50 mA $ g^{−1} $, and 353 mAh $ g^{−1} $ at 5000 mA $ g^{−1} $. At 0.5 C, the capacity retains up to 515 mAh g-1 even after 100 cycles. Such outstanding electrochemical performance of the composite cathode in the carbonate electrolyte can be ascribed to the robust structure of MiPCS and to the “ solid-solid” electrode process. Science China Material (dpeaa)DE-He213 Sulfur Cathode (dpeaa)DE-He213 Ethyl Methyl Carbonate (dpeaa)DE-He213 Hierarchical Porous Carbon (dpeaa)DE-He213 Carbonate Electrolyte (dpeaa)DE-He213 Yuan, Lixia aut Li, Zhen aut Yi, Ziqi aut Zeng, Rui aut Li, Yanrong aut Huang, Yunhui aut Enthalten in Science China materials Beijing : Science China Press, 2014 58(2015), 2 vom: Feb., Seite 91-97 (DE-627)815914733 (DE-600)2806677-7 2199-4501 nnns volume:58 year:2015 number:2 month:02 pages:91-97 https://dx.doi.org/10.1007/s40843-015-0030-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 58 2015 2 02 91-97
allfieldsSound	10.1007/s40843-015-0030-9 doi (DE-627)SPR037909452 (SPR)s40843-015-0030-9-e DE-627 ger DE-627 rakwb eng Wu, Chao verfasserin aut High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Science China Press and Springer-Verlag Berlin Heidelberg 2015 Abstract Selenium attracts increasing attention as cathode material for rechargeable lithium batteries due to its high conductivity and comparable volumetric capacity with sulfur. Microporous carbon spheres (MiPCS) are synthesized via a hydrothermal-annealing route followed by activation with KOH. The MiPCS are used as matrix for Se loading to form Se/MiPCS composite. Such composite delivers a high specific capacity close to the theoretical value of Se. In carbonate-based electrolyte, the capacity is as high as 733 mAh $ g^{−1} $ at a current density of 50 mA $ g^{−1} $, and 353 mAh $ g^{−1} $ at 5000 mA $ g^{−1} $. At 0.5 C, the capacity retains up to 515 mAh g-1 even after 100 cycles. Such outstanding electrochemical performance of the composite cathode in the carbonate electrolyte can be ascribed to the robust structure of MiPCS and to the “ solid-solid” electrode process. Science China Material (dpeaa)DE-He213 Sulfur Cathode (dpeaa)DE-He213 Ethyl Methyl Carbonate (dpeaa)DE-He213 Hierarchical Porous Carbon (dpeaa)DE-He213 Carbonate Electrolyte (dpeaa)DE-He213 Yuan, Lixia aut Li, Zhen aut Yi, Ziqi aut Zeng, Rui aut Li, Yanrong aut Huang, Yunhui aut Enthalten in Science China materials Beijing : Science China Press, 2014 58(2015), 2 vom: Feb., Seite 91-97 (DE-627)815914733 (DE-600)2806677-7 2199-4501 nnns volume:58 year:2015 number:2 month:02 pages:91-97 https://dx.doi.org/10.1007/s40843-015-0030-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 58 2015 2 02 91-97
language	English
source	Enthalten in Science China materials 58(2015), 2 vom: Feb., Seite 91-97 volume:58 year:2015 number:2 month:02 pages:91-97
sourceStr	Enthalten in Science China materials 58(2015), 2 vom: Feb., Seite 91-97 volume:58 year:2015 number:2 month:02 pages:91-97
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Science China Material Sulfur Cathode Ethyl Methyl Carbonate Hierarchical Porous Carbon Carbonate Electrolyte
isfreeaccess_bool	false
container_title	Science China materials
authorswithroles_txt_mv	Wu, Chao @@aut@@ Yuan, Lixia @@aut@@ Li, Zhen @@aut@@ Yi, Ziqi @@aut@@ Zeng, Rui @@aut@@ Li, Yanrong @@aut@@ Huang, Yunhui @@aut@@
publishDateDaySort_date	2015-02-01T00:00:00Z
hierarchy_top_id	815914733
id	SPR037909452
language_de	englisch
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author	Wu, Chao
spellingShingle	Wu, Chao misc Science China Material misc Sulfur Cathode misc Ethyl Methyl Carbonate misc Hierarchical Porous Carbon misc Carbonate Electrolyte High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte
authorStr	Wu, Chao
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topic_title	High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte Science China Material (dpeaa)DE-He213 Sulfur Cathode (dpeaa)DE-He213 Ethyl Methyl Carbonate (dpeaa)DE-He213 Hierarchical Porous Carbon (dpeaa)DE-He213 Carbonate Electrolyte (dpeaa)DE-He213
topic	misc Science China Material misc Sulfur Cathode misc Ethyl Methyl Carbonate misc Hierarchical Porous Carbon misc Carbonate Electrolyte
topic_unstemmed	misc Science China Material misc Sulfur Cathode misc Ethyl Methyl Carbonate misc Hierarchical Porous Carbon misc Carbonate Electrolyte
topic_browse	misc Science China Material misc Sulfur Cathode misc Ethyl Methyl Carbonate misc Hierarchical Porous Carbon misc Carbonate Electrolyte
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
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title	High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte
ctrlnum	(DE-627)SPR037909452 (SPR)s40843-015-0030-9-e
title_full	High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte
author_sort	Wu, Chao
journal	Science China materials
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author_browse	Wu, Chao Yuan, Lixia Li, Zhen Yi, Ziqi Zeng, Rui Li, Yanrong Huang, Yunhui
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author-letter	Wu, Chao
doi_str_mv	10.1007/s40843-015-0030-9
title_sort	high-performance lithium-selenium battery with se/microporous carbon composite cathode and carbonate-based electrolyte
title_auth	High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte
abstract	Abstract Selenium attracts increasing attention as cathode material for rechargeable lithium batteries due to its high conductivity and comparable volumetric capacity with sulfur. Microporous carbon spheres (MiPCS) are synthesized via a hydrothermal-annealing route followed by activation with KOH. The MiPCS are used as matrix for Se loading to form Se/MiPCS composite. Such composite delivers a high specific capacity close to the theoretical value of Se. In carbonate-based electrolyte, the capacity is as high as 733 mAh $ g^{−1} $ at a current density of 50 mA $ g^{−1} $, and 353 mAh $ g^{−1} $ at 5000 mA $ g^{−1} $. At 0.5 C, the capacity retains up to 515 mAh g-1 even after 100 cycles. Such outstanding electrochemical performance of the composite cathode in the carbonate electrolyte can be ascribed to the robust structure of MiPCS and to the “ solid-solid” electrode process. © Science China Press and Springer-Verlag Berlin Heidelberg 2015
abstractGer	Abstract Selenium attracts increasing attention as cathode material for rechargeable lithium batteries due to its high conductivity and comparable volumetric capacity with sulfur. Microporous carbon spheres (MiPCS) are synthesized via a hydrothermal-annealing route followed by activation with KOH. The MiPCS are used as matrix for Se loading to form Se/MiPCS composite. Such composite delivers a high specific capacity close to the theoretical value of Se. In carbonate-based electrolyte, the capacity is as high as 733 mAh $ g^{−1} $ at a current density of 50 mA $ g^{−1} $, and 353 mAh $ g^{−1} $ at 5000 mA $ g^{−1} $. At 0.5 C, the capacity retains up to 515 mAh g-1 even after 100 cycles. Such outstanding electrochemical performance of the composite cathode in the carbonate electrolyte can be ascribed to the robust structure of MiPCS and to the “ solid-solid” electrode process. © Science China Press and Springer-Verlag Berlin Heidelberg 2015
abstract_unstemmed	Abstract Selenium attracts increasing attention as cathode material for rechargeable lithium batteries due to its high conductivity and comparable volumetric capacity with sulfur. Microporous carbon spheres (MiPCS) are synthesized via a hydrothermal-annealing route followed by activation with KOH. The MiPCS are used as matrix for Se loading to form Se/MiPCS composite. Such composite delivers a high specific capacity close to the theoretical value of Se. In carbonate-based electrolyte, the capacity is as high as 733 mAh $ g^{−1} $ at a current density of 50 mA $ g^{−1} $, and 353 mAh $ g^{−1} $ at 5000 mA $ g^{−1} $. At 0.5 C, the capacity retains up to 515 mAh g-1 even after 100 cycles. Such outstanding electrochemical performance of the composite cathode in the carbonate electrolyte can be ascribed to the robust structure of MiPCS and to the “ solid-solid” electrode process. © Science China Press and Springer-Verlag Berlin Heidelberg 2015
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container_issue	2
title_short	High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte
url	https://dx.doi.org/10.1007/s40843-015-0030-9
remote_bool	true
author2	Yuan, Lixia Li, Zhen Yi, Ziqi Zeng, Rui Li, Yanrong Huang, Yunhui
author2Str	Yuan, Lixia Li, Zhen Yi, Ziqi Zeng, Rui Li, Yanrong Huang, Yunhui
ppnlink	815914733
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doi_str	10.1007/s40843-015-0030-9
up_date	2024-07-03T15:05:12.654Z
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High-performance lithium-selenium battery with Se/microporous carbon composite cathode and carbonate-based electrolyte

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