Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal
Abstract The Monforte-Alter do Chão aquifer system represents one of the main water resources in Alentejo region (SW Portugal), and is located in an area of intensive agriculture and cattle breeding. The groundwater shows varied chemical composition, reflecting fast chemical changes associated with...
Ausführliche Beschreibung
Autor*in: |
Fernandes, P. [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2018 |
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Anmerkung: |
© Springer Nature Switzerland AG 2018 |
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Übergeordnetes Werk: |
Enthalten in: Sustainable Water Resources Management - Cham : Springer International Publishers, 2015, 5(2018), 1 vom: 12. Juli, Seite 249-266 |
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Übergeordnetes Werk: |
volume:5 ; year:2018 ; number:1 ; day:12 ; month:07 ; pages:249-266 |
Links: |
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DOI / URN: |
10.1007/s40899-018-0265-1 |
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Katalog-ID: |
SPR037979183 |
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520 | |a Abstract The Monforte-Alter do Chão aquifer system represents one of the main water resources in Alentejo region (SW Portugal), and is located in an area of intensive agriculture and cattle breeding. The groundwater shows varied chemical composition, reflecting fast chemical changes associated with the water–rock interaction, with waters of Ca–$ HCO_{3} $, Na/Ca–$ HCO_{3} $, and Na–$ HCO_{3} $ facies. Some of the waters have strong evidence of nitrogen contamination with nitrate concentrations above 50 mg/l. The implementation of the European Nitrates Directive and the Water Framework Directive has led to the designation of large areas as Nitrate Vulnerable Zones, for being at risk from agricultural nitrate pollution: groundwater containing or that could contain more than 50 mg/l of nitrates. Corrective measures taken to reverse the trend can only be established when the contaminant source is known. In this study, the isotopic compositions of $ NO_{3} $ ($ δ^{15} $N and $ δ^{18} $O) and B ($ δ^{11} $B) were used to identify the sources of the nitrogen contamination. Despite the occurrence of some evaporation processes, the $ δ^{15} $N and $ δ^{18} $O isotopes allowed to distinguish two groups of waters with different sources of nitrates, fertilizers, and soils or manure and domestic effluents. The analysis of the $ NO_{3} $ source based on $ δ^{11} $B isotope ratio pointed out contamination by pig farms effluents. However, considering the land occupation and the strong livestock activities in the area, it is possible that the adsorption of 11B isotopes onto clays or the high pH of the groundwater could explain the high $ δ^{11} $B values. | ||
650 | 4 | |a Nitrate source |7 (dpeaa)DE-He213 | |
650 | 4 | |a N, O, and B isotopes |7 (dpeaa)DE-He213 | |
650 | 4 | |a Monforte-Alter do Chão aquifer system |7 (dpeaa)DE-He213 | |
700 | 1 | |a Carvalho, M. R. |0 (orcid)0000-0002-5275-1311 |4 aut | |
700 | 1 | |a Silva, M. C. |4 aut | |
700 | 1 | |a Rebelo, A. |4 aut | |
700 | 1 | |a Zeferino, J. |4 aut | |
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10.1007/s40899-018-0265-1 doi (DE-627)SPR037979183 (SPR)s40899-018-0265-1-e DE-627 ger DE-627 rakwb eng Fernandes, P. verfasserin aut Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2018 Abstract The Monforte-Alter do Chão aquifer system represents one of the main water resources in Alentejo region (SW Portugal), and is located in an area of intensive agriculture and cattle breeding. The groundwater shows varied chemical composition, reflecting fast chemical changes associated with the water–rock interaction, with waters of Ca–$ HCO_{3} $, Na/Ca–$ HCO_{3} $, and Na–$ HCO_{3} $ facies. Some of the waters have strong evidence of nitrogen contamination with nitrate concentrations above 50 mg/l. The implementation of the European Nitrates Directive and the Water Framework Directive has led to the designation of large areas as Nitrate Vulnerable Zones, for being at risk from agricultural nitrate pollution: groundwater containing or that could contain more than 50 mg/l of nitrates. Corrective measures taken to reverse the trend can only be established when the contaminant source is known. In this study, the isotopic compositions of $ NO_{3} $ ($ δ^{15} $N and $ δ^{18} $O) and B ($ δ^{11} $B) were used to identify the sources of the nitrogen contamination. Despite the occurrence of some evaporation processes, the $ δ^{15} $N and $ δ^{18} $O isotopes allowed to distinguish two groups of waters with different sources of nitrates, fertilizers, and soils or manure and domestic effluents. The analysis of the $ NO_{3} $ source based on $ δ^{11} $B isotope ratio pointed out contamination by pig farms effluents. However, considering the land occupation and the strong livestock activities in the area, it is possible that the adsorption of 11B isotopes onto clays or the high pH of the groundwater could explain the high $ δ^{11} $B values. Nitrate source (dpeaa)DE-He213 N, O, and B isotopes (dpeaa)DE-He213 Monforte-Alter do Chão aquifer system (dpeaa)DE-He213 Carvalho, M. R. (orcid)0000-0002-5275-1311 aut Silva, M. C. aut Rebelo, A. aut Zeferino, J. aut Enthalten in Sustainable Water Resources Management Cham : Springer International Publishers, 2015 5(2018), 1 vom: 12. Juli, Seite 249-266 (DE-627)827029845 (DE-600)2823488-1 2363-5045 nnns volume:5 year:2018 number:1 day:12 month:07 pages:249-266 https://dx.doi.org/10.1007/s40899-018-0265-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 5 2018 1 12 07 249-266 |
spelling |
10.1007/s40899-018-0265-1 doi (DE-627)SPR037979183 (SPR)s40899-018-0265-1-e DE-627 ger DE-627 rakwb eng Fernandes, P. verfasserin aut Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2018 Abstract The Monforte-Alter do Chão aquifer system represents one of the main water resources in Alentejo region (SW Portugal), and is located in an area of intensive agriculture and cattle breeding. The groundwater shows varied chemical composition, reflecting fast chemical changes associated with the water–rock interaction, with waters of Ca–$ HCO_{3} $, Na/Ca–$ HCO_{3} $, and Na–$ HCO_{3} $ facies. Some of the waters have strong evidence of nitrogen contamination with nitrate concentrations above 50 mg/l. The implementation of the European Nitrates Directive and the Water Framework Directive has led to the designation of large areas as Nitrate Vulnerable Zones, for being at risk from agricultural nitrate pollution: groundwater containing or that could contain more than 50 mg/l of nitrates. Corrective measures taken to reverse the trend can only be established when the contaminant source is known. In this study, the isotopic compositions of $ NO_{3} $ ($ δ^{15} $N and $ δ^{18} $O) and B ($ δ^{11} $B) were used to identify the sources of the nitrogen contamination. Despite the occurrence of some evaporation processes, the $ δ^{15} $N and $ δ^{18} $O isotopes allowed to distinguish two groups of waters with different sources of nitrates, fertilizers, and soils or manure and domestic effluents. The analysis of the $ NO_{3} $ source based on $ δ^{11} $B isotope ratio pointed out contamination by pig farms effluents. However, considering the land occupation and the strong livestock activities in the area, it is possible that the adsorption of 11B isotopes onto clays or the high pH of the groundwater could explain the high $ δ^{11} $B values. Nitrate source (dpeaa)DE-He213 N, O, and B isotopes (dpeaa)DE-He213 Monforte-Alter do Chão aquifer system (dpeaa)DE-He213 Carvalho, M. R. (orcid)0000-0002-5275-1311 aut Silva, M. C. aut Rebelo, A. aut Zeferino, J. aut Enthalten in Sustainable Water Resources Management Cham : Springer International Publishers, 2015 5(2018), 1 vom: 12. Juli, Seite 249-266 (DE-627)827029845 (DE-600)2823488-1 2363-5045 nnns volume:5 year:2018 number:1 day:12 month:07 pages:249-266 https://dx.doi.org/10.1007/s40899-018-0265-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 5 2018 1 12 07 249-266 |
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10.1007/s40899-018-0265-1 doi (DE-627)SPR037979183 (SPR)s40899-018-0265-1-e DE-627 ger DE-627 rakwb eng Fernandes, P. verfasserin aut Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2018 Abstract The Monforte-Alter do Chão aquifer system represents one of the main water resources in Alentejo region (SW Portugal), and is located in an area of intensive agriculture and cattle breeding. The groundwater shows varied chemical composition, reflecting fast chemical changes associated with the water–rock interaction, with waters of Ca–$ HCO_{3} $, Na/Ca–$ HCO_{3} $, and Na–$ HCO_{3} $ facies. Some of the waters have strong evidence of nitrogen contamination with nitrate concentrations above 50 mg/l. The implementation of the European Nitrates Directive and the Water Framework Directive has led to the designation of large areas as Nitrate Vulnerable Zones, for being at risk from agricultural nitrate pollution: groundwater containing or that could contain more than 50 mg/l of nitrates. Corrective measures taken to reverse the trend can only be established when the contaminant source is known. In this study, the isotopic compositions of $ NO_{3} $ ($ δ^{15} $N and $ δ^{18} $O) and B ($ δ^{11} $B) were used to identify the sources of the nitrogen contamination. Despite the occurrence of some evaporation processes, the $ δ^{15} $N and $ δ^{18} $O isotopes allowed to distinguish two groups of waters with different sources of nitrates, fertilizers, and soils or manure and domestic effluents. The analysis of the $ NO_{3} $ source based on $ δ^{11} $B isotope ratio pointed out contamination by pig farms effluents. However, considering the land occupation and the strong livestock activities in the area, it is possible that the adsorption of 11B isotopes onto clays or the high pH of the groundwater could explain the high $ δ^{11} $B values. Nitrate source (dpeaa)DE-He213 N, O, and B isotopes (dpeaa)DE-He213 Monforte-Alter do Chão aquifer system (dpeaa)DE-He213 Carvalho, M. R. (orcid)0000-0002-5275-1311 aut Silva, M. C. aut Rebelo, A. aut Zeferino, J. aut Enthalten in Sustainable Water Resources Management Cham : Springer International Publishers, 2015 5(2018), 1 vom: 12. Juli, Seite 249-266 (DE-627)827029845 (DE-600)2823488-1 2363-5045 nnns volume:5 year:2018 number:1 day:12 month:07 pages:249-266 https://dx.doi.org/10.1007/s40899-018-0265-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 5 2018 1 12 07 249-266 |
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10.1007/s40899-018-0265-1 doi (DE-627)SPR037979183 (SPR)s40899-018-0265-1-e DE-627 ger DE-627 rakwb eng Fernandes, P. verfasserin aut Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2018 Abstract The Monforte-Alter do Chão aquifer system represents one of the main water resources in Alentejo region (SW Portugal), and is located in an area of intensive agriculture and cattle breeding. The groundwater shows varied chemical composition, reflecting fast chemical changes associated with the water–rock interaction, with waters of Ca–$ HCO_{3} $, Na/Ca–$ HCO_{3} $, and Na–$ HCO_{3} $ facies. Some of the waters have strong evidence of nitrogen contamination with nitrate concentrations above 50 mg/l. The implementation of the European Nitrates Directive and the Water Framework Directive has led to the designation of large areas as Nitrate Vulnerable Zones, for being at risk from agricultural nitrate pollution: groundwater containing or that could contain more than 50 mg/l of nitrates. Corrective measures taken to reverse the trend can only be established when the contaminant source is known. In this study, the isotopic compositions of $ NO_{3} $ ($ δ^{15} $N and $ δ^{18} $O) and B ($ δ^{11} $B) were used to identify the sources of the nitrogen contamination. Despite the occurrence of some evaporation processes, the $ δ^{15} $N and $ δ^{18} $O isotopes allowed to distinguish two groups of waters with different sources of nitrates, fertilizers, and soils or manure and domestic effluents. The analysis of the $ NO_{3} $ source based on $ δ^{11} $B isotope ratio pointed out contamination by pig farms effluents. However, considering the land occupation and the strong livestock activities in the area, it is possible that the adsorption of 11B isotopes onto clays or the high pH of the groundwater could explain the high $ δ^{11} $B values. Nitrate source (dpeaa)DE-He213 N, O, and B isotopes (dpeaa)DE-He213 Monforte-Alter do Chão aquifer system (dpeaa)DE-He213 Carvalho, M. R. (orcid)0000-0002-5275-1311 aut Silva, M. C. aut Rebelo, A. aut Zeferino, J. aut Enthalten in Sustainable Water Resources Management Cham : Springer International Publishers, 2015 5(2018), 1 vom: 12. Juli, Seite 249-266 (DE-627)827029845 (DE-600)2823488-1 2363-5045 nnns volume:5 year:2018 number:1 day:12 month:07 pages:249-266 https://dx.doi.org/10.1007/s40899-018-0265-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 5 2018 1 12 07 249-266 |
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10.1007/s40899-018-0265-1 doi (DE-627)SPR037979183 (SPR)s40899-018-0265-1-e DE-627 ger DE-627 rakwb eng Fernandes, P. verfasserin aut Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2018 Abstract The Monforte-Alter do Chão aquifer system represents one of the main water resources in Alentejo region (SW Portugal), and is located in an area of intensive agriculture and cattle breeding. The groundwater shows varied chemical composition, reflecting fast chemical changes associated with the water–rock interaction, with waters of Ca–$ HCO_{3} $, Na/Ca–$ HCO_{3} $, and Na–$ HCO_{3} $ facies. Some of the waters have strong evidence of nitrogen contamination with nitrate concentrations above 50 mg/l. The implementation of the European Nitrates Directive and the Water Framework Directive has led to the designation of large areas as Nitrate Vulnerable Zones, for being at risk from agricultural nitrate pollution: groundwater containing or that could contain more than 50 mg/l of nitrates. Corrective measures taken to reverse the trend can only be established when the contaminant source is known. In this study, the isotopic compositions of $ NO_{3} $ ($ δ^{15} $N and $ δ^{18} $O) and B ($ δ^{11} $B) were used to identify the sources of the nitrogen contamination. Despite the occurrence of some evaporation processes, the $ δ^{15} $N and $ δ^{18} $O isotopes allowed to distinguish two groups of waters with different sources of nitrates, fertilizers, and soils or manure and domestic effluents. The analysis of the $ NO_{3} $ source based on $ δ^{11} $B isotope ratio pointed out contamination by pig farms effluents. However, considering the land occupation and the strong livestock activities in the area, it is possible that the adsorption of 11B isotopes onto clays or the high pH of the groundwater could explain the high $ δ^{11} $B values. Nitrate source (dpeaa)DE-He213 N, O, and B isotopes (dpeaa)DE-He213 Monforte-Alter do Chão aquifer system (dpeaa)DE-He213 Carvalho, M. R. (orcid)0000-0002-5275-1311 aut Silva, M. C. aut Rebelo, A. aut Zeferino, J. aut Enthalten in Sustainable Water Resources Management Cham : Springer International Publishers, 2015 5(2018), 1 vom: 12. Juli, Seite 249-266 (DE-627)827029845 (DE-600)2823488-1 2363-5045 nnns volume:5 year:2018 number:1 day:12 month:07 pages:249-266 https://dx.doi.org/10.1007/s40899-018-0265-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 5 2018 1 12 07 249-266 |
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The groundwater shows varied chemical composition, reflecting fast chemical changes associated with the water–rock interaction, with waters of Ca–$ HCO_{3} $, Na/Ca–$ HCO_{3} $, and Na–$ HCO_{3} $ facies. Some of the waters have strong evidence of nitrogen contamination with nitrate concentrations above 50 mg/l. The implementation of the European Nitrates Directive and the Water Framework Directive has led to the designation of large areas as Nitrate Vulnerable Zones, for being at risk from agricultural nitrate pollution: groundwater containing or that could contain more than 50 mg/l of nitrates. Corrective measures taken to reverse the trend can only be established when the contaminant source is known. In this study, the isotopic compositions of $ NO_{3} $ ($ δ^{15} $N and $ δ^{18} $O) and B ($ δ^{11} $B) were used to identify the sources of the nitrogen contamination. Despite the occurrence of some evaporation processes, the $ δ^{15} $N and $ δ^{18} $O isotopes allowed to distinguish two groups of waters with different sources of nitrates, fertilizers, and soils or manure and domestic effluents. The analysis of the $ NO_{3} $ source based on $ δ^{11} $B isotope ratio pointed out contamination by pig farms effluents. However, considering the land occupation and the strong livestock activities in the area, it is possible that the adsorption of 11B isotopes onto clays or the high pH of the groundwater could explain the high $ δ^{11} $B values.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nitrate source</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">N, O, and B isotopes</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Monforte-Alter do Chão aquifer system</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Carvalho, M. R.</subfield><subfield code="0">(orcid)0000-0002-5275-1311</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Silva, M. 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|
author |
Fernandes, P. |
spellingShingle |
Fernandes, P. misc Nitrate source misc N, O, and B isotopes misc Monforte-Alter do Chão aquifer system Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal |
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2363-5045 |
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Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal Nitrate source (dpeaa)DE-He213 N, O, and B isotopes (dpeaa)DE-He213 Monforte-Alter do Chão aquifer system (dpeaa)DE-He213 |
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misc Nitrate source misc N, O, and B isotopes misc Monforte-Alter do Chão aquifer system |
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misc Nitrate source misc N, O, and B isotopes misc Monforte-Alter do Chão aquifer system |
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misc Nitrate source misc N, O, and B isotopes misc Monforte-Alter do Chão aquifer system |
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title |
Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal |
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(DE-627)SPR037979183 (SPR)s40899-018-0265-1-e |
title_full |
Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal |
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Fernandes, P. |
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Sustainable Water Resources Management |
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Fernandes, P. Carvalho, M. R. Silva, M. C. Rebelo, A. Zeferino, J. |
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Fernandes, P. |
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title_sort |
application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in monforte-alter do chão aquifer system, portugal |
title_auth |
Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal |
abstract |
Abstract The Monforte-Alter do Chão aquifer system represents one of the main water resources in Alentejo region (SW Portugal), and is located in an area of intensive agriculture and cattle breeding. The groundwater shows varied chemical composition, reflecting fast chemical changes associated with the water–rock interaction, with waters of Ca–$ HCO_{3} $, Na/Ca–$ HCO_{3} $, and Na–$ HCO_{3} $ facies. Some of the waters have strong evidence of nitrogen contamination with nitrate concentrations above 50 mg/l. The implementation of the European Nitrates Directive and the Water Framework Directive has led to the designation of large areas as Nitrate Vulnerable Zones, for being at risk from agricultural nitrate pollution: groundwater containing or that could contain more than 50 mg/l of nitrates. Corrective measures taken to reverse the trend can only be established when the contaminant source is known. In this study, the isotopic compositions of $ NO_{3} $ ($ δ^{15} $N and $ δ^{18} $O) and B ($ δ^{11} $B) were used to identify the sources of the nitrogen contamination. Despite the occurrence of some evaporation processes, the $ δ^{15} $N and $ δ^{18} $O isotopes allowed to distinguish two groups of waters with different sources of nitrates, fertilizers, and soils or manure and domestic effluents. The analysis of the $ NO_{3} $ source based on $ δ^{11} $B isotope ratio pointed out contamination by pig farms effluents. However, considering the land occupation and the strong livestock activities in the area, it is possible that the adsorption of 11B isotopes onto clays or the high pH of the groundwater could explain the high $ δ^{11} $B values. © Springer Nature Switzerland AG 2018 |
abstractGer |
Abstract The Monforte-Alter do Chão aquifer system represents one of the main water resources in Alentejo region (SW Portugal), and is located in an area of intensive agriculture and cattle breeding. The groundwater shows varied chemical composition, reflecting fast chemical changes associated with the water–rock interaction, with waters of Ca–$ HCO_{3} $, Na/Ca–$ HCO_{3} $, and Na–$ HCO_{3} $ facies. Some of the waters have strong evidence of nitrogen contamination with nitrate concentrations above 50 mg/l. The implementation of the European Nitrates Directive and the Water Framework Directive has led to the designation of large areas as Nitrate Vulnerable Zones, for being at risk from agricultural nitrate pollution: groundwater containing or that could contain more than 50 mg/l of nitrates. Corrective measures taken to reverse the trend can only be established when the contaminant source is known. In this study, the isotopic compositions of $ NO_{3} $ ($ δ^{15} $N and $ δ^{18} $O) and B ($ δ^{11} $B) were used to identify the sources of the nitrogen contamination. Despite the occurrence of some evaporation processes, the $ δ^{15} $N and $ δ^{18} $O isotopes allowed to distinguish two groups of waters with different sources of nitrates, fertilizers, and soils or manure and domestic effluents. The analysis of the $ NO_{3} $ source based on $ δ^{11} $B isotope ratio pointed out contamination by pig farms effluents. However, considering the land occupation and the strong livestock activities in the area, it is possible that the adsorption of 11B isotopes onto clays or the high pH of the groundwater could explain the high $ δ^{11} $B values. © Springer Nature Switzerland AG 2018 |
abstract_unstemmed |
Abstract The Monforte-Alter do Chão aquifer system represents one of the main water resources in Alentejo region (SW Portugal), and is located in an area of intensive agriculture and cattle breeding. The groundwater shows varied chemical composition, reflecting fast chemical changes associated with the water–rock interaction, with waters of Ca–$ HCO_{3} $, Na/Ca–$ HCO_{3} $, and Na–$ HCO_{3} $ facies. Some of the waters have strong evidence of nitrogen contamination with nitrate concentrations above 50 mg/l. The implementation of the European Nitrates Directive and the Water Framework Directive has led to the designation of large areas as Nitrate Vulnerable Zones, for being at risk from agricultural nitrate pollution: groundwater containing or that could contain more than 50 mg/l of nitrates. Corrective measures taken to reverse the trend can only be established when the contaminant source is known. In this study, the isotopic compositions of $ NO_{3} $ ($ δ^{15} $N and $ δ^{18} $O) and B ($ δ^{11} $B) were used to identify the sources of the nitrogen contamination. Despite the occurrence of some evaporation processes, the $ δ^{15} $N and $ δ^{18} $O isotopes allowed to distinguish two groups of waters with different sources of nitrates, fertilizers, and soils or manure and domestic effluents. The analysis of the $ NO_{3} $ source based on $ δ^{11} $B isotope ratio pointed out contamination by pig farms effluents. However, considering the land occupation and the strong livestock activities in the area, it is possible that the adsorption of 11B isotopes onto clays or the high pH of the groundwater could explain the high $ δ^{11} $B values. © Springer Nature Switzerland AG 2018 |
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container_issue |
1 |
title_short |
Application of nitrogen and boron isotopes for tracing sources of anthropogenic contamination in Monforte-Alter do Chão aquifer system, Portugal |
url |
https://dx.doi.org/10.1007/s40899-018-0265-1 |
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author2 |
Carvalho, M. R. Silva, M. C. Rebelo, A. Zeferino, J. |
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Carvalho, M. R. Silva, M. C. Rebelo, A. Zeferino, J. |
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doi_str |
10.1007/s40899-018-0265-1 |
up_date |
2024-07-03T15:31:33.084Z |
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score |
7.3982754 |