Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers
Abstract Oxidized pitches with different oxygen content were prepared using ethylene tar as a raw material by air-blowing method, then the resultant pitch-based activated carbon fibers (ACFs) were prepared through spinning, stabilization, carbonization, and $ CO_{2} $ activation processes. The resul...
Ausführliche Beschreibung
Autor*in: |
Wang, Hanpeng [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2019 |
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Schlagwörter: |
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Anmerkung: |
© Springer Nature Switzerland AG 2019 |
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Übergeordnetes Werk: |
Enthalten in: SN applied sciences - [Cham] : Springer International Publishing, 2019, 1(2019), 3 vom: 20. Feb. |
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Übergeordnetes Werk: |
volume:1 ; year:2019 ; number:3 ; day:20 ; month:02 |
Links: |
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DOI / URN: |
10.1007/s42452-019-0282-1 |
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Katalog-ID: |
SPR038571064 |
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520 | |a Abstract Oxidized pitches with different oxygen content were prepared using ethylene tar as a raw material by air-blowing method, then the resultant pitch-based activated carbon fibers (ACFs) were prepared through spinning, stabilization, carbonization, and $ CO_{2} $ activation processes. The results showed that the oxygen content of prepared oxidized pitch was up to 4.44% when the basic pitch was air-blown at 250 °C, and the BET surface area of the corresponding ACF was up to 1047 $ m^{2} $/g with 0.536 mmol/g carboxylic group, 0.043 mmol/g lactonic group and 0.193 mmol/g phenolic hydroxyl group on the surface after 900 °C $ CO_{2} $ activation. It revealed that the spinnability of oxidized pitch became poor as increasing its oxygen content, while the obtained carbon fiber was easy to be activated and the prepared ACF was equipped with large specific surface area and rich surface functional groups. However, the pore structure was easy to collapse and the surface area was seriously decreased when the oxygen content of pitch precursor was too high. Therefore, the property regulation of pitch precursor could effectively improve the porous texture and surface chemistry of the resultant ACF. | ||
650 | 4 | |a Ethylene tar |7 (dpeaa)DE-He213 | |
650 | 4 | |a Pitch |7 (dpeaa)DE-He213 | |
650 | 4 | |a Air-blowing |7 (dpeaa)DE-He213 | |
650 | 4 | |a CO |7 (dpeaa)DE-He213 | |
650 | 4 | |a activation |7 (dpeaa)DE-He213 | |
650 | 4 | |a Activated carbon fiber |7 (dpeaa)DE-He213 | |
700 | 1 | |a Yang, Jianxiao |0 (orcid)0000-0002-5612-5035 |4 aut | |
700 | 1 | |a Li, Jun |4 aut | |
700 | 1 | |a Shi, Kui |4 aut | |
700 | 1 | |a Li, Xuanke |4 aut | |
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10.1007/s42452-019-0282-1 doi (DE-627)SPR038571064 (SPR)s42452-019-0282-1-e DE-627 ger DE-627 rakwb eng Wang, Hanpeng verfasserin aut Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2019 Abstract Oxidized pitches with different oxygen content were prepared using ethylene tar as a raw material by air-blowing method, then the resultant pitch-based activated carbon fibers (ACFs) were prepared through spinning, stabilization, carbonization, and $ CO_{2} $ activation processes. The results showed that the oxygen content of prepared oxidized pitch was up to 4.44% when the basic pitch was air-blown at 250 °C, and the BET surface area of the corresponding ACF was up to 1047 $ m^{2} $/g with 0.536 mmol/g carboxylic group, 0.043 mmol/g lactonic group and 0.193 mmol/g phenolic hydroxyl group on the surface after 900 °C $ CO_{2} $ activation. It revealed that the spinnability of oxidized pitch became poor as increasing its oxygen content, while the obtained carbon fiber was easy to be activated and the prepared ACF was equipped with large specific surface area and rich surface functional groups. However, the pore structure was easy to collapse and the surface area was seriously decreased when the oxygen content of pitch precursor was too high. Therefore, the property regulation of pitch precursor could effectively improve the porous texture and surface chemistry of the resultant ACF. Ethylene tar (dpeaa)DE-He213 Pitch (dpeaa)DE-He213 Air-blowing (dpeaa)DE-He213 CO (dpeaa)DE-He213 activation (dpeaa)DE-He213 Activated carbon fiber (dpeaa)DE-He213 Yang, Jianxiao (orcid)0000-0002-5612-5035 aut Li, Jun aut Shi, Kui aut Li, Xuanke aut Enthalten in SN applied sciences [Cham] : Springer International Publishing, 2019 1(2019), 3 vom: 20. Feb. (DE-627)103761139X (DE-600)2947292-1 2523-3971 nnns volume:1 year:2019 number:3 day:20 month:02 https://dx.doi.org/10.1007/s42452-019-0282-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_90 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2019 3 20 02 |
spelling |
10.1007/s42452-019-0282-1 doi (DE-627)SPR038571064 (SPR)s42452-019-0282-1-e DE-627 ger DE-627 rakwb eng Wang, Hanpeng verfasserin aut Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2019 Abstract Oxidized pitches with different oxygen content were prepared using ethylene tar as a raw material by air-blowing method, then the resultant pitch-based activated carbon fibers (ACFs) were prepared through spinning, stabilization, carbonization, and $ CO_{2} $ activation processes. The results showed that the oxygen content of prepared oxidized pitch was up to 4.44% when the basic pitch was air-blown at 250 °C, and the BET surface area of the corresponding ACF was up to 1047 $ m^{2} $/g with 0.536 mmol/g carboxylic group, 0.043 mmol/g lactonic group and 0.193 mmol/g phenolic hydroxyl group on the surface after 900 °C $ CO_{2} $ activation. It revealed that the spinnability of oxidized pitch became poor as increasing its oxygen content, while the obtained carbon fiber was easy to be activated and the prepared ACF was equipped with large specific surface area and rich surface functional groups. However, the pore structure was easy to collapse and the surface area was seriously decreased when the oxygen content of pitch precursor was too high. Therefore, the property regulation of pitch precursor could effectively improve the porous texture and surface chemistry of the resultant ACF. Ethylene tar (dpeaa)DE-He213 Pitch (dpeaa)DE-He213 Air-blowing (dpeaa)DE-He213 CO (dpeaa)DE-He213 activation (dpeaa)DE-He213 Activated carbon fiber (dpeaa)DE-He213 Yang, Jianxiao (orcid)0000-0002-5612-5035 aut Li, Jun aut Shi, Kui aut Li, Xuanke aut Enthalten in SN applied sciences [Cham] : Springer International Publishing, 2019 1(2019), 3 vom: 20. Feb. (DE-627)103761139X (DE-600)2947292-1 2523-3971 nnns volume:1 year:2019 number:3 day:20 month:02 https://dx.doi.org/10.1007/s42452-019-0282-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_90 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2019 3 20 02 |
allfields_unstemmed |
10.1007/s42452-019-0282-1 doi (DE-627)SPR038571064 (SPR)s42452-019-0282-1-e DE-627 ger DE-627 rakwb eng Wang, Hanpeng verfasserin aut Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2019 Abstract Oxidized pitches with different oxygen content were prepared using ethylene tar as a raw material by air-blowing method, then the resultant pitch-based activated carbon fibers (ACFs) were prepared through spinning, stabilization, carbonization, and $ CO_{2} $ activation processes. The results showed that the oxygen content of prepared oxidized pitch was up to 4.44% when the basic pitch was air-blown at 250 °C, and the BET surface area of the corresponding ACF was up to 1047 $ m^{2} $/g with 0.536 mmol/g carboxylic group, 0.043 mmol/g lactonic group and 0.193 mmol/g phenolic hydroxyl group on the surface after 900 °C $ CO_{2} $ activation. It revealed that the spinnability of oxidized pitch became poor as increasing its oxygen content, while the obtained carbon fiber was easy to be activated and the prepared ACF was equipped with large specific surface area and rich surface functional groups. However, the pore structure was easy to collapse and the surface area was seriously decreased when the oxygen content of pitch precursor was too high. Therefore, the property regulation of pitch precursor could effectively improve the porous texture and surface chemistry of the resultant ACF. Ethylene tar (dpeaa)DE-He213 Pitch (dpeaa)DE-He213 Air-blowing (dpeaa)DE-He213 CO (dpeaa)DE-He213 activation (dpeaa)DE-He213 Activated carbon fiber (dpeaa)DE-He213 Yang, Jianxiao (orcid)0000-0002-5612-5035 aut Li, Jun aut Shi, Kui aut Li, Xuanke aut Enthalten in SN applied sciences [Cham] : Springer International Publishing, 2019 1(2019), 3 vom: 20. Feb. (DE-627)103761139X (DE-600)2947292-1 2523-3971 nnns volume:1 year:2019 number:3 day:20 month:02 https://dx.doi.org/10.1007/s42452-019-0282-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_90 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2019 3 20 02 |
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10.1007/s42452-019-0282-1 doi (DE-627)SPR038571064 (SPR)s42452-019-0282-1-e DE-627 ger DE-627 rakwb eng Wang, Hanpeng verfasserin aut Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2019 Abstract Oxidized pitches with different oxygen content were prepared using ethylene tar as a raw material by air-blowing method, then the resultant pitch-based activated carbon fibers (ACFs) were prepared through spinning, stabilization, carbonization, and $ CO_{2} $ activation processes. The results showed that the oxygen content of prepared oxidized pitch was up to 4.44% when the basic pitch was air-blown at 250 °C, and the BET surface area of the corresponding ACF was up to 1047 $ m^{2} $/g with 0.536 mmol/g carboxylic group, 0.043 mmol/g lactonic group and 0.193 mmol/g phenolic hydroxyl group on the surface after 900 °C $ CO_{2} $ activation. It revealed that the spinnability of oxidized pitch became poor as increasing its oxygen content, while the obtained carbon fiber was easy to be activated and the prepared ACF was equipped with large specific surface area and rich surface functional groups. However, the pore structure was easy to collapse and the surface area was seriously decreased when the oxygen content of pitch precursor was too high. Therefore, the property regulation of pitch precursor could effectively improve the porous texture and surface chemistry of the resultant ACF. Ethylene tar (dpeaa)DE-He213 Pitch (dpeaa)DE-He213 Air-blowing (dpeaa)DE-He213 CO (dpeaa)DE-He213 activation (dpeaa)DE-He213 Activated carbon fiber (dpeaa)DE-He213 Yang, Jianxiao (orcid)0000-0002-5612-5035 aut Li, Jun aut Shi, Kui aut Li, Xuanke aut Enthalten in SN applied sciences [Cham] : Springer International Publishing, 2019 1(2019), 3 vom: 20. Feb. (DE-627)103761139X (DE-600)2947292-1 2523-3971 nnns volume:1 year:2019 number:3 day:20 month:02 https://dx.doi.org/10.1007/s42452-019-0282-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_90 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2019 3 20 02 |
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10.1007/s42452-019-0282-1 doi (DE-627)SPR038571064 (SPR)s42452-019-0282-1-e DE-627 ger DE-627 rakwb eng Wang, Hanpeng verfasserin aut Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2019 Abstract Oxidized pitches with different oxygen content were prepared using ethylene tar as a raw material by air-blowing method, then the resultant pitch-based activated carbon fibers (ACFs) were prepared through spinning, stabilization, carbonization, and $ CO_{2} $ activation processes. The results showed that the oxygen content of prepared oxidized pitch was up to 4.44% when the basic pitch was air-blown at 250 °C, and the BET surface area of the corresponding ACF was up to 1047 $ m^{2} $/g with 0.536 mmol/g carboxylic group, 0.043 mmol/g lactonic group and 0.193 mmol/g phenolic hydroxyl group on the surface after 900 °C $ CO_{2} $ activation. It revealed that the spinnability of oxidized pitch became poor as increasing its oxygen content, while the obtained carbon fiber was easy to be activated and the prepared ACF was equipped with large specific surface area and rich surface functional groups. However, the pore structure was easy to collapse and the surface area was seriously decreased when the oxygen content of pitch precursor was too high. Therefore, the property regulation of pitch precursor could effectively improve the porous texture and surface chemistry of the resultant ACF. Ethylene tar (dpeaa)DE-He213 Pitch (dpeaa)DE-He213 Air-blowing (dpeaa)DE-He213 CO (dpeaa)DE-He213 activation (dpeaa)DE-He213 Activated carbon fiber (dpeaa)DE-He213 Yang, Jianxiao (orcid)0000-0002-5612-5035 aut Li, Jun aut Shi, Kui aut Li, Xuanke aut Enthalten in SN applied sciences [Cham] : Springer International Publishing, 2019 1(2019), 3 vom: 20. Feb. (DE-627)103761139X (DE-600)2947292-1 2523-3971 nnns volume:1 year:2019 number:3 day:20 month:02 https://dx.doi.org/10.1007/s42452-019-0282-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_90 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2019 3 20 02 |
language |
English |
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Enthalten in SN applied sciences 1(2019), 3 vom: 20. Feb. volume:1 year:2019 number:3 day:20 month:02 |
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Enthalten in SN applied sciences 1(2019), 3 vom: 20. Feb. volume:1 year:2019 number:3 day:20 month:02 |
format_phy_str_mv |
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institution |
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topic_facet |
Ethylene tar Pitch Air-blowing CO activation Activated carbon fiber |
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container_title |
SN applied sciences |
authorswithroles_txt_mv |
Wang, Hanpeng @@aut@@ Yang, Jianxiao @@aut@@ Li, Jun @@aut@@ Shi, Kui @@aut@@ Li, Xuanke @@aut@@ |
publishDateDaySort_date |
2019-02-20T00:00:00Z |
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SPR038571064 |
language_de |
englisch |
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Wang, Hanpeng |
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Wang, Hanpeng misc Ethylene tar misc Pitch misc Air-blowing misc CO misc activation misc Activated carbon fiber Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers |
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Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers Ethylene tar (dpeaa)DE-He213 Pitch (dpeaa)DE-He213 Air-blowing (dpeaa)DE-He213 CO (dpeaa)DE-He213 activation (dpeaa)DE-He213 Activated carbon fiber (dpeaa)DE-He213 |
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Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers |
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Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers |
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Wang, Hanpeng |
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effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers |
title_auth |
Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers |
abstract |
Abstract Oxidized pitches with different oxygen content were prepared using ethylene tar as a raw material by air-blowing method, then the resultant pitch-based activated carbon fibers (ACFs) were prepared through spinning, stabilization, carbonization, and $ CO_{2} $ activation processes. The results showed that the oxygen content of prepared oxidized pitch was up to 4.44% when the basic pitch was air-blown at 250 °C, and the BET surface area of the corresponding ACF was up to 1047 $ m^{2} $/g with 0.536 mmol/g carboxylic group, 0.043 mmol/g lactonic group and 0.193 mmol/g phenolic hydroxyl group on the surface after 900 °C $ CO_{2} $ activation. It revealed that the spinnability of oxidized pitch became poor as increasing its oxygen content, while the obtained carbon fiber was easy to be activated and the prepared ACF was equipped with large specific surface area and rich surface functional groups. However, the pore structure was easy to collapse and the surface area was seriously decreased when the oxygen content of pitch precursor was too high. Therefore, the property regulation of pitch precursor could effectively improve the porous texture and surface chemistry of the resultant ACF. © Springer Nature Switzerland AG 2019 |
abstractGer |
Abstract Oxidized pitches with different oxygen content were prepared using ethylene tar as a raw material by air-blowing method, then the resultant pitch-based activated carbon fibers (ACFs) were prepared through spinning, stabilization, carbonization, and $ CO_{2} $ activation processes. The results showed that the oxygen content of prepared oxidized pitch was up to 4.44% when the basic pitch was air-blown at 250 °C, and the BET surface area of the corresponding ACF was up to 1047 $ m^{2} $/g with 0.536 mmol/g carboxylic group, 0.043 mmol/g lactonic group and 0.193 mmol/g phenolic hydroxyl group on the surface after 900 °C $ CO_{2} $ activation. It revealed that the spinnability of oxidized pitch became poor as increasing its oxygen content, while the obtained carbon fiber was easy to be activated and the prepared ACF was equipped with large specific surface area and rich surface functional groups. However, the pore structure was easy to collapse and the surface area was seriously decreased when the oxygen content of pitch precursor was too high. Therefore, the property regulation of pitch precursor could effectively improve the porous texture and surface chemistry of the resultant ACF. © Springer Nature Switzerland AG 2019 |
abstract_unstemmed |
Abstract Oxidized pitches with different oxygen content were prepared using ethylene tar as a raw material by air-blowing method, then the resultant pitch-based activated carbon fibers (ACFs) were prepared through spinning, stabilization, carbonization, and $ CO_{2} $ activation processes. The results showed that the oxygen content of prepared oxidized pitch was up to 4.44% when the basic pitch was air-blown at 250 °C, and the BET surface area of the corresponding ACF was up to 1047 $ m^{2} $/g with 0.536 mmol/g carboxylic group, 0.043 mmol/g lactonic group and 0.193 mmol/g phenolic hydroxyl group on the surface after 900 °C $ CO_{2} $ activation. It revealed that the spinnability of oxidized pitch became poor as increasing its oxygen content, while the obtained carbon fiber was easy to be activated and the prepared ACF was equipped with large specific surface area and rich surface functional groups. However, the pore structure was easy to collapse and the surface area was seriously decreased when the oxygen content of pitch precursor was too high. Therefore, the property regulation of pitch precursor could effectively improve the porous texture and surface chemistry of the resultant ACF. © Springer Nature Switzerland AG 2019 |
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Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR038571064</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230328214951.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201007s2019 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s42452-019-0282-1</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR038571064</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s42452-019-0282-1-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Wang, Hanpeng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Effects of oxygen content of pitch precursors on the porous texture and surface chemistry of pitch-based activated carbon fibers</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Nature Switzerland AG 2019</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Oxidized pitches with different oxygen content were prepared using ethylene tar as a raw material by air-blowing method, then the resultant pitch-based activated carbon fibers (ACFs) were prepared through spinning, stabilization, carbonization, and $ CO_{2} $ activation processes. The results showed that the oxygen content of prepared oxidized pitch was up to 4.44% when the basic pitch was air-blown at 250 °C, and the BET surface area of the corresponding ACF was up to 1047 $ m^{2} $/g with 0.536 mmol/g carboxylic group, 0.043 mmol/g lactonic group and 0.193 mmol/g phenolic hydroxyl group on the surface after 900 °C $ CO_{2} $ activation. It revealed that the spinnability of oxidized pitch became poor as increasing its oxygen content, while the obtained carbon fiber was easy to be activated and the prepared ACF was equipped with large specific surface area and rich surface functional groups. However, the pore structure was easy to collapse and the surface area was seriously decreased when the oxygen content of pitch precursor was too high. Therefore, the property regulation of pitch precursor could effectively improve the porous texture and surface chemistry of the resultant ACF.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ethylene tar</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Pitch</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Air-blowing</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">CO</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">activation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Activated carbon fiber</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yang, Jianxiao</subfield><subfield code="0">(orcid)0000-0002-5612-5035</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Jun</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Shi, Kui</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Xuanke</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">SN applied sciences</subfield><subfield code="d">[Cham] : Springer International Publishing, 2019</subfield><subfield code="g">1(2019), 3 vom: 20. 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