Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method
Abstract The main objective of this study was to assess the kinetics of the deterioration of blends of babassu and castor biodiesel. The biodiesel samples were synthesized by catalytic transesterification and characterized for their main physical properties such as kinematic viscosity, density, acid...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Paula, Rubem S. F. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Nature Switzerland AG 2019 |
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| Übergeordnetes Werk: |
Enthalten in: SN applied sciences - [Cham] : Springer International Publishing, 2019, 1(2019), 8 vom: 20. Juli |
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| Übergeordnetes Werk: |
volume:1 ; year:2019 ; number:8 ; day:20 ; month:07 |
| Links: |
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| DOI / URN: |
10.1007/s42452-019-0917-2 |
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| Katalog-ID: |
SPR038577976 |
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| 520 | |a Abstract The main objective of this study was to assess the kinetics of the deterioration of blends of babassu and castor biodiesel. The biodiesel samples were synthesized by catalytic transesterification and characterized for their main physical properties such as kinematic viscosity, density, acid number, ester content, and oxidation stability. Thermal profiles were carried out using the Differential Scanning Calorimetry technique as presented in the American Society for Testing and Materials (ASTM) E537 standard. Kinetic parameters were obtained using ASTM E2041 standard (Borchardt–Daniels method), following a statistical treatment from the ASTM E1970 standard. Among all samples, the pure castor biodiesel sample showed the highest extrapolated onset temperature ($ T_{s} $), 214.92 °C, and lowest reaction rate [k(T)], 1.02 × $ 10^{−3} $ $ min^{−1} $, indicating that this sample is more resistant to oxidation. On the other hand, the blend with the babassu/castor biodiesel mass ratio of 75/25 was the most prone to oxidize. Thus, castor biodiesel may be used as an additive to improve the oxidative stability of other sources of biodiesel, including babassu biodiesel. | ||
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10.1007/s42452-019-0917-2 doi (DE-627)SPR038577976 (SPR)s42452-019-0917-2-e DE-627 ger DE-627 rakwb eng Paula, Rubem S. F. verfasserin aut Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2019 Abstract The main objective of this study was to assess the kinetics of the deterioration of blends of babassu and castor biodiesel. The biodiesel samples were synthesized by catalytic transesterification and characterized for their main physical properties such as kinematic viscosity, density, acid number, ester content, and oxidation stability. Thermal profiles were carried out using the Differential Scanning Calorimetry technique as presented in the American Society for Testing and Materials (ASTM) E537 standard. Kinetic parameters were obtained using ASTM E2041 standard (Borchardt–Daniels method), following a statistical treatment from the ASTM E1970 standard. Among all samples, the pure castor biodiesel sample showed the highest extrapolated onset temperature ($ T_{s} $), 214.92 °C, and lowest reaction rate [k(T)], 1.02 × $ 10^{−3} $ $ min^{−1} $, indicating that this sample is more resistant to oxidation. On the other hand, the blend with the babassu/castor biodiesel mass ratio of 75/25 was the most prone to oxidize. Thus, castor biodiesel may be used as an additive to improve the oxidative stability of other sources of biodiesel, including babassu biodiesel. Babassu biodiesel (dpeaa)DE-He213 Castor biodiesel (dpeaa)DE-He213 Differential Scanning Calorimetry (dpeaa)DE-He213 Kinetic parameters (dpeaa)DE-He213 Figueredo, Igor M. aut Vieira, Rodrigo S. aut Nascimento, Tassio L. aut Cavalcante, Célio L. aut Machado, Yguatyara L. aut Rios, Maria A. S. (orcid)0000-0002-3145-0456 aut Enthalten in SN applied sciences [Cham] : Springer International Publishing, 2019 1(2019), 8 vom: 20. Juli (DE-627)103761139X (DE-600)2947292-1 2523-3971 nnns volume:1 year:2019 number:8 day:20 month:07 https://dx.doi.org/10.1007/s42452-019-0917-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_90 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2019 8 20 07 |
| spelling |
10.1007/s42452-019-0917-2 doi (DE-627)SPR038577976 (SPR)s42452-019-0917-2-e DE-627 ger DE-627 rakwb eng Paula, Rubem S. F. verfasserin aut Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2019 Abstract The main objective of this study was to assess the kinetics of the deterioration of blends of babassu and castor biodiesel. The biodiesel samples were synthesized by catalytic transesterification and characterized for their main physical properties such as kinematic viscosity, density, acid number, ester content, and oxidation stability. Thermal profiles were carried out using the Differential Scanning Calorimetry technique as presented in the American Society for Testing and Materials (ASTM) E537 standard. Kinetic parameters were obtained using ASTM E2041 standard (Borchardt–Daniels method), following a statistical treatment from the ASTM E1970 standard. Among all samples, the pure castor biodiesel sample showed the highest extrapolated onset temperature ($ T_{s} $), 214.92 °C, and lowest reaction rate [k(T)], 1.02 × $ 10^{−3} $ $ min^{−1} $, indicating that this sample is more resistant to oxidation. On the other hand, the blend with the babassu/castor biodiesel mass ratio of 75/25 was the most prone to oxidize. Thus, castor biodiesel may be used as an additive to improve the oxidative stability of other sources of biodiesel, including babassu biodiesel. Babassu biodiesel (dpeaa)DE-He213 Castor biodiesel (dpeaa)DE-He213 Differential Scanning Calorimetry (dpeaa)DE-He213 Kinetic parameters (dpeaa)DE-He213 Figueredo, Igor M. aut Vieira, Rodrigo S. aut Nascimento, Tassio L. aut Cavalcante, Célio L. aut Machado, Yguatyara L. aut Rios, Maria A. S. (orcid)0000-0002-3145-0456 aut Enthalten in SN applied sciences [Cham] : Springer International Publishing, 2019 1(2019), 8 vom: 20. Juli (DE-627)103761139X (DE-600)2947292-1 2523-3971 nnns volume:1 year:2019 number:8 day:20 month:07 https://dx.doi.org/10.1007/s42452-019-0917-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_90 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2019 8 20 07 |
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10.1007/s42452-019-0917-2 doi (DE-627)SPR038577976 (SPR)s42452-019-0917-2-e DE-627 ger DE-627 rakwb eng Paula, Rubem S. F. verfasserin aut Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2019 Abstract The main objective of this study was to assess the kinetics of the deterioration of blends of babassu and castor biodiesel. The biodiesel samples were synthesized by catalytic transesterification and characterized for their main physical properties such as kinematic viscosity, density, acid number, ester content, and oxidation stability. Thermal profiles were carried out using the Differential Scanning Calorimetry technique as presented in the American Society for Testing and Materials (ASTM) E537 standard. Kinetic parameters were obtained using ASTM E2041 standard (Borchardt–Daniels method), following a statistical treatment from the ASTM E1970 standard. Among all samples, the pure castor biodiesel sample showed the highest extrapolated onset temperature ($ T_{s} $), 214.92 °C, and lowest reaction rate [k(T)], 1.02 × $ 10^{−3} $ $ min^{−1} $, indicating that this sample is more resistant to oxidation. On the other hand, the blend with the babassu/castor biodiesel mass ratio of 75/25 was the most prone to oxidize. Thus, castor biodiesel may be used as an additive to improve the oxidative stability of other sources of biodiesel, including babassu biodiesel. Babassu biodiesel (dpeaa)DE-He213 Castor biodiesel (dpeaa)DE-He213 Differential Scanning Calorimetry (dpeaa)DE-He213 Kinetic parameters (dpeaa)DE-He213 Figueredo, Igor M. aut Vieira, Rodrigo S. aut Nascimento, Tassio L. aut Cavalcante, Célio L. aut Machado, Yguatyara L. aut Rios, Maria A. S. (orcid)0000-0002-3145-0456 aut Enthalten in SN applied sciences [Cham] : Springer International Publishing, 2019 1(2019), 8 vom: 20. Juli (DE-627)103761139X (DE-600)2947292-1 2523-3971 nnns volume:1 year:2019 number:8 day:20 month:07 https://dx.doi.org/10.1007/s42452-019-0917-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_90 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2019 8 20 07 |
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10.1007/s42452-019-0917-2 doi (DE-627)SPR038577976 (SPR)s42452-019-0917-2-e DE-627 ger DE-627 rakwb eng Paula, Rubem S. F. verfasserin aut Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2019 Abstract The main objective of this study was to assess the kinetics of the deterioration of blends of babassu and castor biodiesel. The biodiesel samples were synthesized by catalytic transesterification and characterized for their main physical properties such as kinematic viscosity, density, acid number, ester content, and oxidation stability. Thermal profiles were carried out using the Differential Scanning Calorimetry technique as presented in the American Society for Testing and Materials (ASTM) E537 standard. Kinetic parameters were obtained using ASTM E2041 standard (Borchardt–Daniels method), following a statistical treatment from the ASTM E1970 standard. Among all samples, the pure castor biodiesel sample showed the highest extrapolated onset temperature ($ T_{s} $), 214.92 °C, and lowest reaction rate [k(T)], 1.02 × $ 10^{−3} $ $ min^{−1} $, indicating that this sample is more resistant to oxidation. On the other hand, the blend with the babassu/castor biodiesel mass ratio of 75/25 was the most prone to oxidize. Thus, castor biodiesel may be used as an additive to improve the oxidative stability of other sources of biodiesel, including babassu biodiesel. Babassu biodiesel (dpeaa)DE-He213 Castor biodiesel (dpeaa)DE-He213 Differential Scanning Calorimetry (dpeaa)DE-He213 Kinetic parameters (dpeaa)DE-He213 Figueredo, Igor M. aut Vieira, Rodrigo S. aut Nascimento, Tassio L. aut Cavalcante, Célio L. aut Machado, Yguatyara L. aut Rios, Maria A. S. (orcid)0000-0002-3145-0456 aut Enthalten in SN applied sciences [Cham] : Springer International Publishing, 2019 1(2019), 8 vom: 20. Juli (DE-627)103761139X (DE-600)2947292-1 2523-3971 nnns volume:1 year:2019 number:8 day:20 month:07 https://dx.doi.org/10.1007/s42452-019-0917-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_90 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2019 8 20 07 |
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10.1007/s42452-019-0917-2 doi (DE-627)SPR038577976 (SPR)s42452-019-0917-2-e DE-627 ger DE-627 rakwb eng Paula, Rubem S. F. verfasserin aut Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer Nature Switzerland AG 2019 Abstract The main objective of this study was to assess the kinetics of the deterioration of blends of babassu and castor biodiesel. The biodiesel samples were synthesized by catalytic transesterification and characterized for their main physical properties such as kinematic viscosity, density, acid number, ester content, and oxidation stability. Thermal profiles were carried out using the Differential Scanning Calorimetry technique as presented in the American Society for Testing and Materials (ASTM) E537 standard. Kinetic parameters were obtained using ASTM E2041 standard (Borchardt–Daniels method), following a statistical treatment from the ASTM E1970 standard. Among all samples, the pure castor biodiesel sample showed the highest extrapolated onset temperature ($ T_{s} $), 214.92 °C, and lowest reaction rate [k(T)], 1.02 × $ 10^{−3} $ $ min^{−1} $, indicating that this sample is more resistant to oxidation. On the other hand, the blend with the babassu/castor biodiesel mass ratio of 75/25 was the most prone to oxidize. Thus, castor biodiesel may be used as an additive to improve the oxidative stability of other sources of biodiesel, including babassu biodiesel. Babassu biodiesel (dpeaa)DE-He213 Castor biodiesel (dpeaa)DE-He213 Differential Scanning Calorimetry (dpeaa)DE-He213 Kinetic parameters (dpeaa)DE-He213 Figueredo, Igor M. aut Vieira, Rodrigo S. aut Nascimento, Tassio L. aut Cavalcante, Célio L. aut Machado, Yguatyara L. aut Rios, Maria A. S. (orcid)0000-0002-3145-0456 aut Enthalten in SN applied sciences [Cham] : Springer International Publishing, 2019 1(2019), 8 vom: 20. Juli (DE-627)103761139X (DE-600)2947292-1 2523-3971 nnns volume:1 year:2019 number:8 day:20 month:07 https://dx.doi.org/10.1007/s42452-019-0917-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_90 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2019 8 20 07 |
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Paula, Rubem S. F. @@aut@@ Figueredo, Igor M. @@aut@@ Vieira, Rodrigo S. @@aut@@ Nascimento, Tassio L. @@aut@@ Cavalcante, Célio L. @@aut@@ Machado, Yguatyara L. @@aut@@ Rios, Maria A. S. @@aut@@ |
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The biodiesel samples were synthesized by catalytic transesterification and characterized for their main physical properties such as kinematic viscosity, density, acid number, ester content, and oxidation stability. Thermal profiles were carried out using the Differential Scanning Calorimetry technique as presented in the American Society for Testing and Materials (ASTM) E537 standard. Kinetic parameters were obtained using ASTM E2041 standard (Borchardt–Daniels method), following a statistical treatment from the ASTM E1970 standard. Among all samples, the pure castor biodiesel sample showed the highest extrapolated onset temperature ($ T_{s} $), 214.92 °C, and lowest reaction rate [k(T)], 1.02 × $ 10^{−3} $ $ min^{−1} $, indicating that this sample is more resistant to oxidation. On the other hand, the blend with the babassu/castor biodiesel mass ratio of 75/25 was the most prone to oxidize. 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Paula, Rubem S. F. |
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Paula, Rubem S. F. misc Babassu biodiesel misc Castor biodiesel misc Differential Scanning Calorimetry misc Kinetic parameters Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method |
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Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method Babassu biodiesel (dpeaa)DE-He213 Castor biodiesel (dpeaa)DE-He213 Differential Scanning Calorimetry (dpeaa)DE-He213 Kinetic parameters (dpeaa)DE-He213 |
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misc Babassu biodiesel misc Castor biodiesel misc Differential Scanning Calorimetry misc Kinetic parameters |
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Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method |
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Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method |
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Paula, Rubem S. F. |
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Paula, Rubem S. F. Figueredo, Igor M. Vieira, Rodrigo S. Nascimento, Tassio L. Cavalcante, Célio L. Machado, Yguatyara L. Rios, Maria A. S. |
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castor–babassu biodiesel blends: estimating kinetic parameters by differential scanning calorimetry using the borchardt and daniels method |
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Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method |
| abstract |
Abstract The main objective of this study was to assess the kinetics of the deterioration of blends of babassu and castor biodiesel. The biodiesel samples were synthesized by catalytic transesterification and characterized for their main physical properties such as kinematic viscosity, density, acid number, ester content, and oxidation stability. Thermal profiles were carried out using the Differential Scanning Calorimetry technique as presented in the American Society for Testing and Materials (ASTM) E537 standard. Kinetic parameters were obtained using ASTM E2041 standard (Borchardt–Daniels method), following a statistical treatment from the ASTM E1970 standard. Among all samples, the pure castor biodiesel sample showed the highest extrapolated onset temperature ($ T_{s} $), 214.92 °C, and lowest reaction rate [k(T)], 1.02 × $ 10^{−3} $ $ min^{−1} $, indicating that this sample is more resistant to oxidation. On the other hand, the blend with the babassu/castor biodiesel mass ratio of 75/25 was the most prone to oxidize. Thus, castor biodiesel may be used as an additive to improve the oxidative stability of other sources of biodiesel, including babassu biodiesel. © Springer Nature Switzerland AG 2019 |
| abstractGer |
Abstract The main objective of this study was to assess the kinetics of the deterioration of blends of babassu and castor biodiesel. The biodiesel samples were synthesized by catalytic transesterification and characterized for their main physical properties such as kinematic viscosity, density, acid number, ester content, and oxidation stability. Thermal profiles were carried out using the Differential Scanning Calorimetry technique as presented in the American Society for Testing and Materials (ASTM) E537 standard. Kinetic parameters were obtained using ASTM E2041 standard (Borchardt–Daniels method), following a statistical treatment from the ASTM E1970 standard. Among all samples, the pure castor biodiesel sample showed the highest extrapolated onset temperature ($ T_{s} $), 214.92 °C, and lowest reaction rate [k(T)], 1.02 × $ 10^{−3} $ $ min^{−1} $, indicating that this sample is more resistant to oxidation. On the other hand, the blend with the babassu/castor biodiesel mass ratio of 75/25 was the most prone to oxidize. Thus, castor biodiesel may be used as an additive to improve the oxidative stability of other sources of biodiesel, including babassu biodiesel. © Springer Nature Switzerland AG 2019 |
| abstract_unstemmed |
Abstract The main objective of this study was to assess the kinetics of the deterioration of blends of babassu and castor biodiesel. The biodiesel samples were synthesized by catalytic transesterification and characterized for their main physical properties such as kinematic viscosity, density, acid number, ester content, and oxidation stability. Thermal profiles were carried out using the Differential Scanning Calorimetry technique as presented in the American Society for Testing and Materials (ASTM) E537 standard. Kinetic parameters were obtained using ASTM E2041 standard (Borchardt–Daniels method), following a statistical treatment from the ASTM E1970 standard. Among all samples, the pure castor biodiesel sample showed the highest extrapolated onset temperature ($ T_{s} $), 214.92 °C, and lowest reaction rate [k(T)], 1.02 × $ 10^{−3} $ $ min^{−1} $, indicating that this sample is more resistant to oxidation. On the other hand, the blend with the babassu/castor biodiesel mass ratio of 75/25 was the most prone to oxidize. Thus, castor biodiesel may be used as an additive to improve the oxidative stability of other sources of biodiesel, including babassu biodiesel. © Springer Nature Switzerland AG 2019 |
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Castor–babassu biodiesel blends: estimating kinetic parameters by Differential Scanning Calorimetry using the Borchardt and Daniels method |
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Figueredo, Igor M. Vieira, Rodrigo S. Nascimento, Tassio L. Cavalcante, Célio L. Machado, Yguatyara L. Rios, Maria A. S. |
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Figueredo, Igor M. Vieira, Rodrigo S. Nascimento, Tassio L. Cavalcante, Célio L. Machado, Yguatyara L. Rios, Maria A. S. |
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