An Effective and Stable HfP/$ SiO_{2} $ Catalyst for the Production of Furfural from Xylan
Abstract Silica-supported hafinum phosphide (HfP/$ SiO_{2} $) was prepared and applied as an effective solid acid catalyst to drive furfural production from xylan. Various characterizations were employed to analyze the intrinsic properties of the HfP/$ SiO_{2} $ catalyst, and the effects of process...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Xu, Siquan [verfasserIn] Wu, Ningxin [verfasserIn] Yuan, Hui [verfasserIn] Chen, Yuan [verfasserIn] Pan, Donghui [verfasserIn] Wu, Yuanfeng [verfasserIn] Fan, Jingdeng [verfasserIn] Gao, Lijing [verfasserIn] Xiao, Guomin [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Catalysis letters - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988, 150(2019), 4 vom: 14. Okt., Seite 1121-1127 |
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| Übergeordnetes Werk: |
volume:150 ; year:2019 ; number:4 ; day:14 ; month:10 ; pages:1121-1127 |
| Links: |
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| DOI / URN: |
10.1007/s10562-019-02994-2 |
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| Katalog-ID: |
SPR038960834 |
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| 520 | |a Abstract Silica-supported hafinum phosphide (HfP/$ SiO_{2} $) was prepared and applied as an effective solid acid catalyst to drive furfural production from xylan. Various characterizations were employed to analyze the intrinsic properties of the HfP/$ SiO_{2} $ catalyst, and the effects of process parameters on its performance were investigated in detail. The results showed that the performance of the HfP/$ SiO_{2} $ catalyst was excellent, which allowed up to 85% of the furfural yield to be achieved at 180 °C for 60 min in the $ water_{(NaCl)} $/THF biphasic system. There was no significant decrease in the performance of the HfP/$ SiO_{2} $ catalyst after seven consecutive cycles. Characterization analysis of the recovered catalyst revealed that its elemental composition and total acidity were maintained, indicating the desired hydrothermal stability of the HfP/$ SiO_{2} $ catalyst. In addition, by-products produced during xylan conversion were identified as humins and soluble molecular fragments or polymers. Graphic Abstract | ||
| 650 | 4 | |a Xylan |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Furfural |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a HfP/SiO |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Solid acid |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Recyclable |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Wu, Ningxin |e verfasserin |4 aut | |
| 700 | 1 | |a Yuan, Hui |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Yuan |e verfasserin |4 aut | |
| 700 | 1 | |a Pan, Donghui |e verfasserin |4 aut | |
| 700 | 1 | |a Wu, Yuanfeng |e verfasserin |4 aut | |
| 700 | 1 | |a Fan, Jingdeng |e verfasserin |4 aut | |
| 700 | 1 | |a Gao, Lijing |e verfasserin |4 aut | |
| 700 | 1 | |a Xiao, Guomin |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Catalysis letters |d Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 |g 150(2019), 4 vom: 14. Okt., Seite 1121-1127 |w (DE-627)306717638 |w (DE-600)1501518-X |x 1572-879X |7 nnns |
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10.1007/s10562-019-02994-2 doi (DE-627)SPR038960834 (SPR)s10562-019-02994-2-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Xu, Siquan verfasserin aut An Effective and Stable HfP/$ SiO_{2} $ Catalyst for the Production of Furfural from Xylan 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Silica-supported hafinum phosphide (HfP/$ SiO_{2} $) was prepared and applied as an effective solid acid catalyst to drive furfural production from xylan. Various characterizations were employed to analyze the intrinsic properties of the HfP/$ SiO_{2} $ catalyst, and the effects of process parameters on its performance were investigated in detail. The results showed that the performance of the HfP/$ SiO_{2} $ catalyst was excellent, which allowed up to 85% of the furfural yield to be achieved at 180 °C for 60 min in the $ water_{(NaCl)} $/THF biphasic system. There was no significant decrease in the performance of the HfP/$ SiO_{2} $ catalyst after seven consecutive cycles. Characterization analysis of the recovered catalyst revealed that its elemental composition and total acidity were maintained, indicating the desired hydrothermal stability of the HfP/$ SiO_{2} $ catalyst. In addition, by-products produced during xylan conversion were identified as humins and soluble molecular fragments or polymers. Graphic Abstract Xylan (dpeaa)DE-He213 Furfural (dpeaa)DE-He213 HfP/SiO (dpeaa)DE-He213 Solid acid (dpeaa)DE-He213 Recyclable (dpeaa)DE-He213 Wu, Ningxin verfasserin aut Yuan, Hui verfasserin aut Chen, Yuan verfasserin aut Pan, Donghui verfasserin aut Wu, Yuanfeng verfasserin aut Fan, Jingdeng verfasserin aut Gao, Lijing verfasserin aut Xiao, Guomin verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 150(2019), 4 vom: 14. Okt., Seite 1121-1127 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:150 year:2019 number:4 day:14 month:10 pages:1121-1127 https://dx.doi.org/10.1007/s10562-019-02994-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 150 2019 4 14 10 1121-1127 |
| spelling |
10.1007/s10562-019-02994-2 doi (DE-627)SPR038960834 (SPR)s10562-019-02994-2-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Xu, Siquan verfasserin aut An Effective and Stable HfP/$ SiO_{2} $ Catalyst for the Production of Furfural from Xylan 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Silica-supported hafinum phosphide (HfP/$ SiO_{2} $) was prepared and applied as an effective solid acid catalyst to drive furfural production from xylan. Various characterizations were employed to analyze the intrinsic properties of the HfP/$ SiO_{2} $ catalyst, and the effects of process parameters on its performance were investigated in detail. The results showed that the performance of the HfP/$ SiO_{2} $ catalyst was excellent, which allowed up to 85% of the furfural yield to be achieved at 180 °C for 60 min in the $ water_{(NaCl)} $/THF biphasic system. There was no significant decrease in the performance of the HfP/$ SiO_{2} $ catalyst after seven consecutive cycles. Characterization analysis of the recovered catalyst revealed that its elemental composition and total acidity were maintained, indicating the desired hydrothermal stability of the HfP/$ SiO_{2} $ catalyst. In addition, by-products produced during xylan conversion were identified as humins and soluble molecular fragments or polymers. Graphic Abstract Xylan (dpeaa)DE-He213 Furfural (dpeaa)DE-He213 HfP/SiO (dpeaa)DE-He213 Solid acid (dpeaa)DE-He213 Recyclable (dpeaa)DE-He213 Wu, Ningxin verfasserin aut Yuan, Hui verfasserin aut Chen, Yuan verfasserin aut Pan, Donghui verfasserin aut Wu, Yuanfeng verfasserin aut Fan, Jingdeng verfasserin aut Gao, Lijing verfasserin aut Xiao, Guomin verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 150(2019), 4 vom: 14. Okt., Seite 1121-1127 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:150 year:2019 number:4 day:14 month:10 pages:1121-1127 https://dx.doi.org/10.1007/s10562-019-02994-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 150 2019 4 14 10 1121-1127 |
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10.1007/s10562-019-02994-2 doi (DE-627)SPR038960834 (SPR)s10562-019-02994-2-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Xu, Siquan verfasserin aut An Effective and Stable HfP/$ SiO_{2} $ Catalyst for the Production of Furfural from Xylan 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Silica-supported hafinum phosphide (HfP/$ SiO_{2} $) was prepared and applied as an effective solid acid catalyst to drive furfural production from xylan. Various characterizations were employed to analyze the intrinsic properties of the HfP/$ SiO_{2} $ catalyst, and the effects of process parameters on its performance were investigated in detail. The results showed that the performance of the HfP/$ SiO_{2} $ catalyst was excellent, which allowed up to 85% of the furfural yield to be achieved at 180 °C for 60 min in the $ water_{(NaCl)} $/THF biphasic system. There was no significant decrease in the performance of the HfP/$ SiO_{2} $ catalyst after seven consecutive cycles. Characterization analysis of the recovered catalyst revealed that its elemental composition and total acidity were maintained, indicating the desired hydrothermal stability of the HfP/$ SiO_{2} $ catalyst. In addition, by-products produced during xylan conversion were identified as humins and soluble molecular fragments or polymers. Graphic Abstract Xylan (dpeaa)DE-He213 Furfural (dpeaa)DE-He213 HfP/SiO (dpeaa)DE-He213 Solid acid (dpeaa)DE-He213 Recyclable (dpeaa)DE-He213 Wu, Ningxin verfasserin aut Yuan, Hui verfasserin aut Chen, Yuan verfasserin aut Pan, Donghui verfasserin aut Wu, Yuanfeng verfasserin aut Fan, Jingdeng verfasserin aut Gao, Lijing verfasserin aut Xiao, Guomin verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 150(2019), 4 vom: 14. Okt., Seite 1121-1127 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:150 year:2019 number:4 day:14 month:10 pages:1121-1127 https://dx.doi.org/10.1007/s10562-019-02994-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 150 2019 4 14 10 1121-1127 |
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10.1007/s10562-019-02994-2 doi (DE-627)SPR038960834 (SPR)s10562-019-02994-2-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Xu, Siquan verfasserin aut An Effective and Stable HfP/$ SiO_{2} $ Catalyst for the Production of Furfural from Xylan 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Silica-supported hafinum phosphide (HfP/$ SiO_{2} $) was prepared and applied as an effective solid acid catalyst to drive furfural production from xylan. Various characterizations were employed to analyze the intrinsic properties of the HfP/$ SiO_{2} $ catalyst, and the effects of process parameters on its performance were investigated in detail. The results showed that the performance of the HfP/$ SiO_{2} $ catalyst was excellent, which allowed up to 85% of the furfural yield to be achieved at 180 °C for 60 min in the $ water_{(NaCl)} $/THF biphasic system. There was no significant decrease in the performance of the HfP/$ SiO_{2} $ catalyst after seven consecutive cycles. Characterization analysis of the recovered catalyst revealed that its elemental composition and total acidity were maintained, indicating the desired hydrothermal stability of the HfP/$ SiO_{2} $ catalyst. In addition, by-products produced during xylan conversion were identified as humins and soluble molecular fragments or polymers. Graphic Abstract Xylan (dpeaa)DE-He213 Furfural (dpeaa)DE-He213 HfP/SiO (dpeaa)DE-He213 Solid acid (dpeaa)DE-He213 Recyclable (dpeaa)DE-He213 Wu, Ningxin verfasserin aut Yuan, Hui verfasserin aut Chen, Yuan verfasserin aut Pan, Donghui verfasserin aut Wu, Yuanfeng verfasserin aut Fan, Jingdeng verfasserin aut Gao, Lijing verfasserin aut Xiao, Guomin verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 150(2019), 4 vom: 14. Okt., Seite 1121-1127 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:150 year:2019 number:4 day:14 month:10 pages:1121-1127 https://dx.doi.org/10.1007/s10562-019-02994-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 150 2019 4 14 10 1121-1127 |
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10.1007/s10562-019-02994-2 doi (DE-627)SPR038960834 (SPR)s10562-019-02994-2-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Xu, Siquan verfasserin aut An Effective and Stable HfP/$ SiO_{2} $ Catalyst for the Production of Furfural from Xylan 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Silica-supported hafinum phosphide (HfP/$ SiO_{2} $) was prepared and applied as an effective solid acid catalyst to drive furfural production from xylan. Various characterizations were employed to analyze the intrinsic properties of the HfP/$ SiO_{2} $ catalyst, and the effects of process parameters on its performance were investigated in detail. The results showed that the performance of the HfP/$ SiO_{2} $ catalyst was excellent, which allowed up to 85% of the furfural yield to be achieved at 180 °C for 60 min in the $ water_{(NaCl)} $/THF biphasic system. There was no significant decrease in the performance of the HfP/$ SiO_{2} $ catalyst after seven consecutive cycles. Characterization analysis of the recovered catalyst revealed that its elemental composition and total acidity were maintained, indicating the desired hydrothermal stability of the HfP/$ SiO_{2} $ catalyst. In addition, by-products produced during xylan conversion were identified as humins and soluble molecular fragments or polymers. Graphic Abstract Xylan (dpeaa)DE-He213 Furfural (dpeaa)DE-He213 HfP/SiO (dpeaa)DE-He213 Solid acid (dpeaa)DE-He213 Recyclable (dpeaa)DE-He213 Wu, Ningxin verfasserin aut Yuan, Hui verfasserin aut Chen, Yuan verfasserin aut Pan, Donghui verfasserin aut Wu, Yuanfeng verfasserin aut Fan, Jingdeng verfasserin aut Gao, Lijing verfasserin aut Xiao, Guomin verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 150(2019), 4 vom: 14. Okt., Seite 1121-1127 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:150 year:2019 number:4 day:14 month:10 pages:1121-1127 https://dx.doi.org/10.1007/s10562-019-02994-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 150 2019 4 14 10 1121-1127 |
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Xylan Furfural HfP/SiO Solid acid Recyclable |
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Xu, Siquan @@aut@@ Wu, Ningxin @@aut@@ Yuan, Hui @@aut@@ Chen, Yuan @@aut@@ Pan, Donghui @@aut@@ Wu, Yuanfeng @@aut@@ Fan, Jingdeng @@aut@@ Gao, Lijing @@aut@@ Xiao, Guomin @@aut@@ |
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Various characterizations were employed to analyze the intrinsic properties of the HfP/$ SiO_{2} $ catalyst, and the effects of process parameters on its performance were investigated in detail. The results showed that the performance of the HfP/$ SiO_{2} $ catalyst was excellent, which allowed up to 85% of the furfural yield to be achieved at 180 °C for 60 min in the $ water_{(NaCl)} $/THF biphasic system. There was no significant decrease in the performance of the HfP/$ SiO_{2} $ catalyst after seven consecutive cycles. Characterization analysis of the recovered catalyst revealed that its elemental composition and total acidity were maintained, indicating the desired hydrothermal stability of the HfP/$ SiO_{2} $ catalyst. In addition, by-products produced during xylan conversion were identified as humins and soluble molecular fragments or polymers. 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Xu, Siquan |
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Xu, Siquan ddc 540 bkl 35.17 misc Xylan misc Furfural misc HfP/SiO misc Solid acid misc Recyclable An Effective and Stable HfP/$ SiO_{2} $ Catalyst for the Production of Furfural from Xylan |
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540 660 ASE 35.17 bkl An Effective and Stable HfP/$ SiO_{2} $ Catalyst for the Production of Furfural from Xylan Xylan (dpeaa)DE-He213 Furfural (dpeaa)DE-He213 HfP/SiO (dpeaa)DE-He213 Solid acid (dpeaa)DE-He213 Recyclable (dpeaa)DE-He213 |
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An Effective and Stable HfP/$ SiO_{2} $ Catalyst for the Production of Furfural from Xylan |
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Xu, Siquan Wu, Ningxin Yuan, Hui Chen, Yuan Pan, Donghui Wu, Yuanfeng Fan, Jingdeng Gao, Lijing Xiao, Guomin |
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effective and stable hfp/$ sio_{2} $ catalyst for the production of furfural from xylan |
| title_auth |
An Effective and Stable HfP/$ SiO_{2} $ Catalyst for the Production of Furfural from Xylan |
| abstract |
Abstract Silica-supported hafinum phosphide (HfP/$ SiO_{2} $) was prepared and applied as an effective solid acid catalyst to drive furfural production from xylan. Various characterizations were employed to analyze the intrinsic properties of the HfP/$ SiO_{2} $ catalyst, and the effects of process parameters on its performance were investigated in detail. The results showed that the performance of the HfP/$ SiO_{2} $ catalyst was excellent, which allowed up to 85% of the furfural yield to be achieved at 180 °C for 60 min in the $ water_{(NaCl)} $/THF biphasic system. There was no significant decrease in the performance of the HfP/$ SiO_{2} $ catalyst after seven consecutive cycles. Characterization analysis of the recovered catalyst revealed that its elemental composition and total acidity were maintained, indicating the desired hydrothermal stability of the HfP/$ SiO_{2} $ catalyst. In addition, by-products produced during xylan conversion were identified as humins and soluble molecular fragments or polymers. Graphic Abstract |
| abstractGer |
Abstract Silica-supported hafinum phosphide (HfP/$ SiO_{2} $) was prepared and applied as an effective solid acid catalyst to drive furfural production from xylan. Various characterizations were employed to analyze the intrinsic properties of the HfP/$ SiO_{2} $ catalyst, and the effects of process parameters on its performance were investigated in detail. The results showed that the performance of the HfP/$ SiO_{2} $ catalyst was excellent, which allowed up to 85% of the furfural yield to be achieved at 180 °C for 60 min in the $ water_{(NaCl)} $/THF biphasic system. There was no significant decrease in the performance of the HfP/$ SiO_{2} $ catalyst after seven consecutive cycles. Characterization analysis of the recovered catalyst revealed that its elemental composition and total acidity were maintained, indicating the desired hydrothermal stability of the HfP/$ SiO_{2} $ catalyst. In addition, by-products produced during xylan conversion were identified as humins and soluble molecular fragments or polymers. Graphic Abstract |
| abstract_unstemmed |
Abstract Silica-supported hafinum phosphide (HfP/$ SiO_{2} $) was prepared and applied as an effective solid acid catalyst to drive furfural production from xylan. Various characterizations were employed to analyze the intrinsic properties of the HfP/$ SiO_{2} $ catalyst, and the effects of process parameters on its performance were investigated in detail. The results showed that the performance of the HfP/$ SiO_{2} $ catalyst was excellent, which allowed up to 85% of the furfural yield to be achieved at 180 °C for 60 min in the $ water_{(NaCl)} $/THF biphasic system. There was no significant decrease in the performance of the HfP/$ SiO_{2} $ catalyst after seven consecutive cycles. Characterization analysis of the recovered catalyst revealed that its elemental composition and total acidity were maintained, indicating the desired hydrothermal stability of the HfP/$ SiO_{2} $ catalyst. In addition, by-products produced during xylan conversion were identified as humins and soluble molecular fragments or polymers. Graphic Abstract |
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4 |
| title_short |
An Effective and Stable HfP/$ SiO_{2} $ Catalyst for the Production of Furfural from Xylan |
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https://dx.doi.org/10.1007/s10562-019-02994-2 |
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Wu, Ningxin Yuan, Hui Chen, Yuan Pan, Donghui Wu, Yuanfeng Fan, Jingdeng Gao, Lijing Xiao, Guomin |
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Wu, Ningxin Yuan, Hui Chen, Yuan Pan, Donghui Wu, Yuanfeng Fan, Jingdeng Gao, Lijing Xiao, Guomin |
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2024-07-03T20:59:50.043Z |
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| score |
7.399131 |