Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection

Abstract The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,...
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Gespeichert in:

Autor*in:	Jiang, Shan [verfasserIn] Liu, Shengda [verfasserIn] Meng, Lingchen [verfasserIn] Qi, Qingkai [verfasserIn] Wang, Lipeng [verfasserIn] Xu, Bin [verfasserIn] Liu, Junqiu [verfasserIn] Tian, Wenjing [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2020

Schlagwörter:	aggregation-induced emission covalent organic nanospheres nitrophenol explosives detection fluorescence quenching

Übergeordnetes Werk:	Enthalten in: Science in China - Asheville, NC : Science in China Press, 1995, 63(2020), 4 vom: 11. März, Seite 497-503
Übergeordnetes Werk:	volume:63 ; year:2020 ; number:4 ; day:11 ; month:03 ; pages:497-503

Links:	Volltext

DOI / URN:	10.1007/s11426-019-9667-1

Katalog-ID:	SPR039306216

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520			\|a Abstract The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,3,5-tris(4-formyl-phenyl)benzene (TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer (PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol (TNP), 4-nitrophenol (NP) and 2,4-dinitrophenol (DNP) can reach 9.67×$ 10^{5} $, 3.14×$ 10^{5} $ and 4.8×$ 10^{4} $ $ M^{−1} $, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. The study provides a novel strategy to construct AIE-active conjugated hollow nanospheres for efficient nitrophenol explosives sensing.
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allfields	10.1007/s11426-019-9667-1 doi (DE-627)SPR039306216 (SPR)s11426-019-9667-1-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Jiang, Shan verfasserin aut Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,3,5-tris(4-formyl-phenyl)benzene (TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer (PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol (TNP), 4-nitrophenol (NP) and 2,4-dinitrophenol (DNP) can reach 9.67×$ 10^{5} $, 3.14×$ 10^{5} $ and 4.8×$ 10^{4} $ $ M^{−1} $, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. The study provides a novel strategy to construct AIE-active conjugated hollow nanospheres for efficient nitrophenol explosives sensing. aggregation-induced emission (dpeaa)DE-He213 covalent organic nanospheres (dpeaa)DE-He213 nitrophenol explosives detection (dpeaa)DE-He213 fluorescence quenching (dpeaa)DE-He213 Liu, Shengda verfasserin aut Meng, Lingchen verfasserin aut Qi, Qingkai verfasserin aut Wang, Lipeng verfasserin aut Xu, Bin verfasserin aut Liu, Junqiu verfasserin aut Tian, Wenjing verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 63(2020), 4 vom: 11. März, Seite 497-503 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:63 year:2020 number:4 day:11 month:03 pages:497-503 https://dx.doi.org/10.1007/s11426-019-9667-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.00 ASE AR 63 2020 4 11 03 497-503
spelling	10.1007/s11426-019-9667-1 doi (DE-627)SPR039306216 (SPR)s11426-019-9667-1-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Jiang, Shan verfasserin aut Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,3,5-tris(4-formyl-phenyl)benzene (TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer (PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol (TNP), 4-nitrophenol (NP) and 2,4-dinitrophenol (DNP) can reach 9.67×$ 10^{5} $, 3.14×$ 10^{5} $ and 4.8×$ 10^{4} $ $ M^{−1} $, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. The study provides a novel strategy to construct AIE-active conjugated hollow nanospheres for efficient nitrophenol explosives sensing. aggregation-induced emission (dpeaa)DE-He213 covalent organic nanospheres (dpeaa)DE-He213 nitrophenol explosives detection (dpeaa)DE-He213 fluorescence quenching (dpeaa)DE-He213 Liu, Shengda verfasserin aut Meng, Lingchen verfasserin aut Qi, Qingkai verfasserin aut Wang, Lipeng verfasserin aut Xu, Bin verfasserin aut Liu, Junqiu verfasserin aut Tian, Wenjing verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 63(2020), 4 vom: 11. März, Seite 497-503 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:63 year:2020 number:4 day:11 month:03 pages:497-503 https://dx.doi.org/10.1007/s11426-019-9667-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.00 ASE AR 63 2020 4 11 03 497-503
allfields_unstemmed	10.1007/s11426-019-9667-1 doi (DE-627)SPR039306216 (SPR)s11426-019-9667-1-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Jiang, Shan verfasserin aut Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,3,5-tris(4-formyl-phenyl)benzene (TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer (PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol (TNP), 4-nitrophenol (NP) and 2,4-dinitrophenol (DNP) can reach 9.67×$ 10^{5} $, 3.14×$ 10^{5} $ and 4.8×$ 10^{4} $ $ M^{−1} $, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. The study provides a novel strategy to construct AIE-active conjugated hollow nanospheres for efficient nitrophenol explosives sensing. aggregation-induced emission (dpeaa)DE-He213 covalent organic nanospheres (dpeaa)DE-He213 nitrophenol explosives detection (dpeaa)DE-He213 fluorescence quenching (dpeaa)DE-He213 Liu, Shengda verfasserin aut Meng, Lingchen verfasserin aut Qi, Qingkai verfasserin aut Wang, Lipeng verfasserin aut Xu, Bin verfasserin aut Liu, Junqiu verfasserin aut Tian, Wenjing verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 63(2020), 4 vom: 11. März, Seite 497-503 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:63 year:2020 number:4 day:11 month:03 pages:497-503 https://dx.doi.org/10.1007/s11426-019-9667-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.00 ASE AR 63 2020 4 11 03 497-503
allfieldsGer	10.1007/s11426-019-9667-1 doi (DE-627)SPR039306216 (SPR)s11426-019-9667-1-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Jiang, Shan verfasserin aut Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,3,5-tris(4-formyl-phenyl)benzene (TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer (PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol (TNP), 4-nitrophenol (NP) and 2,4-dinitrophenol (DNP) can reach 9.67×$ 10^{5} $, 3.14×$ 10^{5} $ and 4.8×$ 10^{4} $ $ M^{−1} $, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. The study provides a novel strategy to construct AIE-active conjugated hollow nanospheres for efficient nitrophenol explosives sensing. aggregation-induced emission (dpeaa)DE-He213 covalent organic nanospheres (dpeaa)DE-He213 nitrophenol explosives detection (dpeaa)DE-He213 fluorescence quenching (dpeaa)DE-He213 Liu, Shengda verfasserin aut Meng, Lingchen verfasserin aut Qi, Qingkai verfasserin aut Wang, Lipeng verfasserin aut Xu, Bin verfasserin aut Liu, Junqiu verfasserin aut Tian, Wenjing verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 63(2020), 4 vom: 11. März, Seite 497-503 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:63 year:2020 number:4 day:11 month:03 pages:497-503 https://dx.doi.org/10.1007/s11426-019-9667-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.00 ASE AR 63 2020 4 11 03 497-503
allfieldsSound	10.1007/s11426-019-9667-1 doi (DE-627)SPR039306216 (SPR)s11426-019-9667-1-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Jiang, Shan verfasserin aut Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,3,5-tris(4-formyl-phenyl)benzene (TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer (PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol (TNP), 4-nitrophenol (NP) and 2,4-dinitrophenol (DNP) can reach 9.67×$ 10^{5} $, 3.14×$ 10^{5} $ and 4.8×$ 10^{4} $ $ M^{−1} $, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. The study provides a novel strategy to construct AIE-active conjugated hollow nanospheres for efficient nitrophenol explosives sensing. aggregation-induced emission (dpeaa)DE-He213 covalent organic nanospheres (dpeaa)DE-He213 nitrophenol explosives detection (dpeaa)DE-He213 fluorescence quenching (dpeaa)DE-He213 Liu, Shengda verfasserin aut Meng, Lingchen verfasserin aut Qi, Qingkai verfasserin aut Wang, Lipeng verfasserin aut Xu, Bin verfasserin aut Liu, Junqiu verfasserin aut Tian, Wenjing verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 63(2020), 4 vom: 11. März, Seite 497-503 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:63 year:2020 number:4 day:11 month:03 pages:497-503 https://dx.doi.org/10.1007/s11426-019-9667-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.00 ASE AR 63 2020 4 11 03 497-503
language	English
source	Enthalten in Science in China 63(2020), 4 vom: 11. März, Seite 497-503 volume:63 year:2020 number:4 day:11 month:03 pages:497-503
sourceStr	Enthalten in Science in China 63(2020), 4 vom: 11. März, Seite 497-503 volume:63 year:2020 number:4 day:11 month:03 pages:497-503
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	aggregation-induced emission covalent organic nanospheres nitrophenol explosives detection fluorescence quenching
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container_title	Science in China
authorswithroles_txt_mv	Jiang, Shan @@aut@@ Liu, Shengda @@aut@@ Meng, Lingchen @@aut@@ Qi, Qingkai @@aut@@ Wang, Lipeng @@aut@@ Xu, Bin @@aut@@ Liu, Junqiu @@aut@@ Tian, Wenjing @@aut@@
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Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,3,5-tris(4-formyl-phenyl)benzene (TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer (PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol (TNP), 4-nitrophenol (NP) and 2,4-dinitrophenol (DNP) can reach 9.67×$ 10^{5} $, 3.14×$ 10^{5} $ and 4.8×$ 10^{4} $ $ M^{−1} $, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. 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author	Jiang, Shan
spellingShingle	Jiang, Shan ddc 540 bkl 35.00 misc aggregation-induced emission misc covalent organic nanospheres misc nitrophenol explosives detection misc fluorescence quenching Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection
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topic_title	540 550 570 ASE 35.00 bkl Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection aggregation-induced emission (dpeaa)DE-He213 covalent organic nanospheres (dpeaa)DE-He213 nitrophenol explosives detection (dpeaa)DE-He213 fluorescence quenching (dpeaa)DE-He213
topic	ddc 540 bkl 35.00 misc aggregation-induced emission misc covalent organic nanospheres misc nitrophenol explosives detection misc fluorescence quenching
topic_unstemmed	ddc 540 bkl 35.00 misc aggregation-induced emission misc covalent organic nanospheres misc nitrophenol explosives detection misc fluorescence quenching
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title	Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection
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title_full	Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection
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journal	Science in China
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author_browse	Jiang, Shan Liu, Shengda Meng, Lingchen Qi, Qingkai Wang, Lipeng Xu, Bin Liu, Junqiu Tian, Wenjing
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title_sort	covalent organic hollow nanospheres constructed by using aie-active units for nitrophenol explosives detection
title_auth	Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection
abstract	Abstract The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,3,5-tris(4-formyl-phenyl)benzene (TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer (PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol (TNP), 4-nitrophenol (NP) and 2,4-dinitrophenol (DNP) can reach 9.67×$ 10^{5} $, 3.14×$ 10^{5} $ and 4.8×$ 10^{4} $ $ M^{−1} $, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. The study provides a novel strategy to construct AIE-active conjugated hollow nanospheres for efficient nitrophenol explosives sensing.
abstractGer	Abstract The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,3,5-tris(4-formyl-phenyl)benzene (TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer (PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol (TNP), 4-nitrophenol (NP) and 2,4-dinitrophenol (DNP) can reach 9.67×$ 10^{5} $, 3.14×$ 10^{5} $ and 4.8×$ 10^{4} $ $ M^{−1} $, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. The study provides a novel strategy to construct AIE-active conjugated hollow nanospheres for efficient nitrophenol explosives sensing.
abstract_unstemmed	Abstract The development of conjugated nanomaterials with high sensitivity and super-amplified quenching effect for the detection of nitrophenol explosives is still a great challenge. Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,3,5-tris(4-formyl-phenyl)benzene (TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer (PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol (TNP), 4-nitrophenol (NP) and 2,4-dinitrophenol (DNP) can reach 9.67×$ 10^{5} $, 3.14×$ 10^{5} $ and 4.8×$ 10^{4} $ $ M^{−1} $, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. The study provides a novel strategy to construct AIE-active conjugated hollow nanospheres for efficient nitrophenol explosives sensing.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702
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title_short	Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection
url	https://dx.doi.org/10.1007/s11426-019-9667-1
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author2	Liu, Shengda Meng, Lingchen Qi, Qingkai Wang, Lipeng Xu, Bin Liu, Junqiu Tian, Wenjing
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doi_str	10.1007/s11426-019-9667-1
up_date	2024-07-03T23:14:11.315Z
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Herein, we developed conjugated hollow nanospheres constructed by using aggregation-induced emission (AIE) active 1,3,5-tris(4-formyl-phenyl)benzene (TFPB). The high emission hollow nanospheres with uniform size and admirable dispersiveness exhibited obvious fluorescence quenching response with the addition of nitrophenol explosives owing to the photoinduced electron transfer (PET) from the hollow nanospheres to nitrophenol explosives. The Stern-Volmer constants of hollow spheres for 2,4,6-trinitrophenol (TNP), 4-nitrophenol (NP) and 2,4-dinitrophenol (DNP) can reach 9.67×$ 10^{5} $, 3.14×$ 10^{5} $ and 4.8×$ 10^{4} $ $ M^{−1} $, respectively. Furthermore, the handy test paper coated with hollow nanospheres was prepared and showed a good response toward TNP solutions and vapor. 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Covalent organic hollow nanospheres constructed by using AIE-active units for nitrophenol explosives detection

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