Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO

Abstract Composite thin films of polyaniline (PAN)/ZnO are synthesized via electropolymerization (ECP) process in acidic medium on ITO (working electrode) with platinum mesh as a counter electrode and Ag/AgCl as a reference electrode. Acidic medium helps in polymerization and enhances the crystallin...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Srivastava, Divyanshi [verfasserIn] Shukla, R. K. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	Electropolymerization Cyclic voltammetry Chronoamperometry Photoluminescence and spectroscopy

Übergeordnetes Werk:	Enthalten in: Proceedings of the National Academy of Sciences - New York, NY : Springer, 2012, 90(2019), 2 vom: 22. Mai, Seite 309-318
Übergeordnetes Werk:	volume:90 ; year:2019 ; number:2 ; day:22 ; month:05 ; pages:309-318

Links:	Volltext

DOI / URN:	10.1007/s40010-019-00612-9

Katalog-ID:	SPR039843300

Internformat


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520			\|a Abstract Composite thin films of polyaniline (PAN)/ZnO are synthesized via electropolymerization (ECP) process in acidic medium on ITO (working electrode) with platinum mesh as a counter electrode and Ag/AgCl as a reference electrode. Acidic medium helps in polymerization and enhances the crystallinity of PAN. PAN films that are obtained in the presence of sulfuric acid give partial crystallinity in its high conducting form, i.e., emeraldine salt. Inorganic metal oxide–organic polymer thin film was used to get a new type of composite nanostructures. The cyclic voltammetry and chronoamperometric properties were investigated by potentiostat for different doping percentages of ZnO with a constant Molar concentration of PAN. Current conduction properties are found to be increased in the presence of ZnO particles. Optical properties were investigated using UV–Vis and photoluminescence spectroscopy. Photoluminescence shows emission in the blue, green and yellow regions. Band gap variation has also been calculated with the help of Tauc’s plot which found to be decreasing with the increase of doping percentage of ZnO.
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publishDate	2019
allfields	10.1007/s40010-019-00612-9 doi (DE-627)SPR039843300 (SPR)s40010-019-00612-9-e DE-627 ger DE-627 rakwb eng Srivastava, Divyanshi verfasserin aut Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Composite thin films of polyaniline (PAN)/ZnO are synthesized via electropolymerization (ECP) process in acidic medium on ITO (working electrode) with platinum mesh as a counter electrode and Ag/AgCl as a reference electrode. Acidic medium helps in polymerization and enhances the crystallinity of PAN. PAN films that are obtained in the presence of sulfuric acid give partial crystallinity in its high conducting form, i.e., emeraldine salt. Inorganic metal oxide–organic polymer thin film was used to get a new type of composite nanostructures. The cyclic voltammetry and chronoamperometric properties were investigated by potentiostat for different doping percentages of ZnO with a constant Molar concentration of PAN. Current conduction properties are found to be increased in the presence of ZnO particles. Optical properties were investigated using UV–Vis and photoluminescence spectroscopy. Photoluminescence shows emission in the blue, green and yellow regions. Band gap variation has also been calculated with the help of Tauc’s plot which found to be decreasing with the increase of doping percentage of ZnO. Electropolymerization (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Chronoamperometry (dpeaa)DE-He213 Photoluminescence and spectroscopy (dpeaa)DE-He213 Shukla, R. K. verfasserin aut Enthalten in Proceedings of the National Academy of Sciences New York, NY : Springer, 2012 90(2019), 2 vom: 22. Mai, Seite 309-318 (DE-627)73921358X (DE-600)2707742-1 2250-1762 nnns volume:90 year:2019 number:2 day:22 month:05 pages:309-318 https://dx.doi.org/10.1007/s40010-019-00612-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 90 2019 2 22 05 309-318
spelling	10.1007/s40010-019-00612-9 doi (DE-627)SPR039843300 (SPR)s40010-019-00612-9-e DE-627 ger DE-627 rakwb eng Srivastava, Divyanshi verfasserin aut Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Composite thin films of polyaniline (PAN)/ZnO are synthesized via electropolymerization (ECP) process in acidic medium on ITO (working electrode) with platinum mesh as a counter electrode and Ag/AgCl as a reference electrode. Acidic medium helps in polymerization and enhances the crystallinity of PAN. PAN films that are obtained in the presence of sulfuric acid give partial crystallinity in its high conducting form, i.e., emeraldine salt. Inorganic metal oxide–organic polymer thin film was used to get a new type of composite nanostructures. The cyclic voltammetry and chronoamperometric properties were investigated by potentiostat for different doping percentages of ZnO with a constant Molar concentration of PAN. Current conduction properties are found to be increased in the presence of ZnO particles. Optical properties were investigated using UV–Vis and photoluminescence spectroscopy. Photoluminescence shows emission in the blue, green and yellow regions. Band gap variation has also been calculated with the help of Tauc’s plot which found to be decreasing with the increase of doping percentage of ZnO. Electropolymerization (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Chronoamperometry (dpeaa)DE-He213 Photoluminescence and spectroscopy (dpeaa)DE-He213 Shukla, R. K. verfasserin aut Enthalten in Proceedings of the National Academy of Sciences New York, NY : Springer, 2012 90(2019), 2 vom: 22. Mai, Seite 309-318 (DE-627)73921358X (DE-600)2707742-1 2250-1762 nnns volume:90 year:2019 number:2 day:22 month:05 pages:309-318 https://dx.doi.org/10.1007/s40010-019-00612-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 90 2019 2 22 05 309-318
allfields_unstemmed	10.1007/s40010-019-00612-9 doi (DE-627)SPR039843300 (SPR)s40010-019-00612-9-e DE-627 ger DE-627 rakwb eng Srivastava, Divyanshi verfasserin aut Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Composite thin films of polyaniline (PAN)/ZnO are synthesized via electropolymerization (ECP) process in acidic medium on ITO (working electrode) with platinum mesh as a counter electrode and Ag/AgCl as a reference electrode. Acidic medium helps in polymerization and enhances the crystallinity of PAN. PAN films that are obtained in the presence of sulfuric acid give partial crystallinity in its high conducting form, i.e., emeraldine salt. Inorganic metal oxide–organic polymer thin film was used to get a new type of composite nanostructures. The cyclic voltammetry and chronoamperometric properties were investigated by potentiostat for different doping percentages of ZnO with a constant Molar concentration of PAN. Current conduction properties are found to be increased in the presence of ZnO particles. Optical properties were investigated using UV–Vis and photoluminescence spectroscopy. Photoluminescence shows emission in the blue, green and yellow regions. Band gap variation has also been calculated with the help of Tauc’s plot which found to be decreasing with the increase of doping percentage of ZnO. Electropolymerization (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Chronoamperometry (dpeaa)DE-He213 Photoluminescence and spectroscopy (dpeaa)DE-He213 Shukla, R. K. verfasserin aut Enthalten in Proceedings of the National Academy of Sciences New York, NY : Springer, 2012 90(2019), 2 vom: 22. Mai, Seite 309-318 (DE-627)73921358X (DE-600)2707742-1 2250-1762 nnns volume:90 year:2019 number:2 day:22 month:05 pages:309-318 https://dx.doi.org/10.1007/s40010-019-00612-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 90 2019 2 22 05 309-318
allfieldsGer	10.1007/s40010-019-00612-9 doi (DE-627)SPR039843300 (SPR)s40010-019-00612-9-e DE-627 ger DE-627 rakwb eng Srivastava, Divyanshi verfasserin aut Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Composite thin films of polyaniline (PAN)/ZnO are synthesized via electropolymerization (ECP) process in acidic medium on ITO (working electrode) with platinum mesh as a counter electrode and Ag/AgCl as a reference electrode. Acidic medium helps in polymerization and enhances the crystallinity of PAN. PAN films that are obtained in the presence of sulfuric acid give partial crystallinity in its high conducting form, i.e., emeraldine salt. Inorganic metal oxide–organic polymer thin film was used to get a new type of composite nanostructures. The cyclic voltammetry and chronoamperometric properties were investigated by potentiostat for different doping percentages of ZnO with a constant Molar concentration of PAN. Current conduction properties are found to be increased in the presence of ZnO particles. Optical properties were investigated using UV–Vis and photoluminescence spectroscopy. Photoluminescence shows emission in the blue, green and yellow regions. Band gap variation has also been calculated with the help of Tauc’s plot which found to be decreasing with the increase of doping percentage of ZnO. Electropolymerization (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Chronoamperometry (dpeaa)DE-He213 Photoluminescence and spectroscopy (dpeaa)DE-He213 Shukla, R. K. verfasserin aut Enthalten in Proceedings of the National Academy of Sciences New York, NY : Springer, 2012 90(2019), 2 vom: 22. Mai, Seite 309-318 (DE-627)73921358X (DE-600)2707742-1 2250-1762 nnns volume:90 year:2019 number:2 day:22 month:05 pages:309-318 https://dx.doi.org/10.1007/s40010-019-00612-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 90 2019 2 22 05 309-318
allfieldsSound	10.1007/s40010-019-00612-9 doi (DE-627)SPR039843300 (SPR)s40010-019-00612-9-e DE-627 ger DE-627 rakwb eng Srivastava, Divyanshi verfasserin aut Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Composite thin films of polyaniline (PAN)/ZnO are synthesized via electropolymerization (ECP) process in acidic medium on ITO (working electrode) with platinum mesh as a counter electrode and Ag/AgCl as a reference electrode. Acidic medium helps in polymerization and enhances the crystallinity of PAN. PAN films that are obtained in the presence of sulfuric acid give partial crystallinity in its high conducting form, i.e., emeraldine salt. Inorganic metal oxide–organic polymer thin film was used to get a new type of composite nanostructures. The cyclic voltammetry and chronoamperometric properties were investigated by potentiostat for different doping percentages of ZnO with a constant Molar concentration of PAN. Current conduction properties are found to be increased in the presence of ZnO particles. Optical properties were investigated using UV–Vis and photoluminescence spectroscopy. Photoluminescence shows emission in the blue, green and yellow regions. Band gap variation has also been calculated with the help of Tauc’s plot which found to be decreasing with the increase of doping percentage of ZnO. Electropolymerization (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Chronoamperometry (dpeaa)DE-He213 Photoluminescence and spectroscopy (dpeaa)DE-He213 Shukla, R. K. verfasserin aut Enthalten in Proceedings of the National Academy of Sciences New York, NY : Springer, 2012 90(2019), 2 vom: 22. Mai, Seite 309-318 (DE-627)73921358X (DE-600)2707742-1 2250-1762 nnns volume:90 year:2019 number:2 day:22 month:05 pages:309-318 https://dx.doi.org/10.1007/s40010-019-00612-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 90 2019 2 22 05 309-318
language	English
source	Enthalten in Proceedings of the National Academy of Sciences 90(2019), 2 vom: 22. Mai, Seite 309-318 volume:90 year:2019 number:2 day:22 month:05 pages:309-318
sourceStr	Enthalten in Proceedings of the National Academy of Sciences 90(2019), 2 vom: 22. Mai, Seite 309-318 volume:90 year:2019 number:2 day:22 month:05 pages:309-318
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Electropolymerization Cyclic voltammetry Chronoamperometry Photoluminescence and spectroscopy
isfreeaccess_bool	false
container_title	Proceedings of the National Academy of Sciences
authorswithroles_txt_mv	Srivastava, Divyanshi @@aut@@ Shukla, R. K. @@aut@@
publishDateDaySort_date	2019-05-22T00:00:00Z
hierarchy_top_id	73921358X
id	SPR039843300
language_de	englisch
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author	Srivastava, Divyanshi
spellingShingle	Srivastava, Divyanshi misc Electropolymerization misc Cyclic voltammetry misc Chronoamperometry misc Photoluminescence and spectroscopy Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO
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topic_title	Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO Electropolymerization (dpeaa)DE-He213 Cyclic voltammetry (dpeaa)DE-He213 Chronoamperometry (dpeaa)DE-He213 Photoluminescence and spectroscopy (dpeaa)DE-He213
topic	misc Electropolymerization misc Cyclic voltammetry misc Chronoamperometry misc Photoluminescence and spectroscopy
topic_unstemmed	misc Electropolymerization misc Cyclic voltammetry misc Chronoamperometry misc Photoluminescence and spectroscopy
topic_browse	misc Electropolymerization misc Cyclic voltammetry misc Chronoamperometry misc Photoluminescence and spectroscopy
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title	Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO
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title_full	Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO
author_sort	Srivastava, Divyanshi
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author_browse	Srivastava, Divyanshi Shukla, R. K.
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author-letter	Srivastava, Divyanshi
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title_sort	electrochemical properties and band gap variation of polyaniline due to the presence of zno
title_auth	Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO
abstract	Abstract Composite thin films of polyaniline (PAN)/ZnO are synthesized via electropolymerization (ECP) process in acidic medium on ITO (working electrode) with platinum mesh as a counter electrode and Ag/AgCl as a reference electrode. Acidic medium helps in polymerization and enhances the crystallinity of PAN. PAN films that are obtained in the presence of sulfuric acid give partial crystallinity in its high conducting form, i.e., emeraldine salt. Inorganic metal oxide–organic polymer thin film was used to get a new type of composite nanostructures. The cyclic voltammetry and chronoamperometric properties were investigated by potentiostat for different doping percentages of ZnO with a constant Molar concentration of PAN. Current conduction properties are found to be increased in the presence of ZnO particles. Optical properties were investigated using UV–Vis and photoluminescence spectroscopy. Photoluminescence shows emission in the blue, green and yellow regions. Band gap variation has also been calculated with the help of Tauc’s plot which found to be decreasing with the increase of doping percentage of ZnO.
abstractGer	Abstract Composite thin films of polyaniline (PAN)/ZnO are synthesized via electropolymerization (ECP) process in acidic medium on ITO (working electrode) with platinum mesh as a counter electrode and Ag/AgCl as a reference electrode. Acidic medium helps in polymerization and enhances the crystallinity of PAN. PAN films that are obtained in the presence of sulfuric acid give partial crystallinity in its high conducting form, i.e., emeraldine salt. Inorganic metal oxide–organic polymer thin film was used to get a new type of composite nanostructures. The cyclic voltammetry and chronoamperometric properties were investigated by potentiostat for different doping percentages of ZnO with a constant Molar concentration of PAN. Current conduction properties are found to be increased in the presence of ZnO particles. Optical properties were investigated using UV–Vis and photoluminescence spectroscopy. Photoluminescence shows emission in the blue, green and yellow regions. Band gap variation has also been calculated with the help of Tauc’s plot which found to be decreasing with the increase of doping percentage of ZnO.
abstract_unstemmed	Abstract Composite thin films of polyaniline (PAN)/ZnO are synthesized via electropolymerization (ECP) process in acidic medium on ITO (working electrode) with platinum mesh as a counter electrode and Ag/AgCl as a reference electrode. Acidic medium helps in polymerization and enhances the crystallinity of PAN. PAN films that are obtained in the presence of sulfuric acid give partial crystallinity in its high conducting form, i.e., emeraldine salt. Inorganic metal oxide–organic polymer thin film was used to get a new type of composite nanostructures. The cyclic voltammetry and chronoamperometric properties were investigated by potentiostat for different doping percentages of ZnO with a constant Molar concentration of PAN. Current conduction properties are found to be increased in the presence of ZnO particles. Optical properties were investigated using UV–Vis and photoluminescence spectroscopy. Photoluminescence shows emission in the blue, green and yellow regions. Band gap variation has also been calculated with the help of Tauc’s plot which found to be decreasing with the increase of doping percentage of ZnO.
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title_short	Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO
url	https://dx.doi.org/10.1007/s40010-019-00612-9
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Acidic medium helps in polymerization and enhances the crystallinity of PAN. PAN films that are obtained in the presence of sulfuric acid give partial crystallinity in its high conducting form, i.e., emeraldine salt. Inorganic metal oxide–organic polymer thin film was used to get a new type of composite nanostructures. The cyclic voltammetry and chronoamperometric properties were investigated by potentiostat for different doping percentages of ZnO with a constant Molar concentration of PAN. Current conduction properties are found to be increased in the presence of ZnO particles. Optical properties were investigated using UV–Vis and photoluminescence spectroscopy. Photoluminescence shows emission in the blue, green and yellow regions. 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Electrochemical Properties and Band Gap Variation of Polyaniline Due to the Presence of ZnO

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