Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study
Abstract In the present work, $ MnO_{2} $ was electrodeposited (galvanostatic mode) on carbon cloth (CC) from manganese nitrate and sulfate precursors. Its electrochemical performance was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), which were used to study...
Ausführliche Beschreibung
Autor*in: |
Costa, J. C. M. [verfasserIn] Nascimento, M. C. [verfasserIn] Silva, E. C. [verfasserIn] Pereira, B. L. [verfasserIn] Passos, R. R. [verfasserIn] Pocrifka, L. A. [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2020 |
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Übergeordnetes Werk: |
Enthalten in: Journal of solid state electrochemistry - Berlin : Springer, 1997, 24(2020), 8 vom: 27. Apr., Seite 1727-1733 |
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Übergeordnetes Werk: |
volume:24 ; year:2020 ; number:8 ; day:27 ; month:04 ; pages:1727-1733 |
Links: |
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DOI / URN: |
10.1007/s10008-020-04532-2 |
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Katalog-ID: |
SPR040251187 |
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245 | 1 | 0 | |a Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study |
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520 | |a Abstract In the present work, $ MnO_{2} $ was electrodeposited (galvanostatic mode) on carbon cloth (CC) from manganese nitrate and sulfate precursors. Its electrochemical performance was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), which were used to study the complex behavior of the material. In CV analysis, higher cathodic and anodic loads were obtained for sulfate–$ MnO_{2} $ compared with nitrate–$ MnO_{2} $, whereas in the Nyquist graphs of the EIS technique, the nitrate–$ MnO_{2} $ material obtained larger charge transfer resistance (Rtc) than sulfate–$ MnO_{2} $. In the Bode analysis, the behavior of sulfate–$ MnO_{2} $ was better than that of nitrate–$ MnO_{2} $. because for this analysis, the phase angle is smaller, which is attributed to better pseudocapacitive behavior of sulfate than nitrate. In capacitance and complex power terms, the relaxation time constant obtained was 2.65 s. The real capacitance in C′(ω) was 107 F $ g^{−1} $ for nitrate–$ MnO_{2} $ and 197 F $ g^{−1} $ for sulfate–$ MnO_{2} $, and the intersection of the complex power curves occurred at 70%. The obtained results suggest that these materials are attractive for application in energy storage devices. | ||
650 | 4 | |a Carbon cloth (CC) |7 (dpeaa)DE-He213 | |
650 | 4 | |a Nitrate–MnO |7 (dpeaa)DE-He213 | |
650 | 4 | |a Sulfate–MnO |7 (dpeaa)DE-He213 | |
650 | 4 | |a Complex capacitance study |7 (dpeaa)DE-He213 | |
700 | 1 | |a Nascimento, M. C. |e verfasserin |4 aut | |
700 | 1 | |a Silva, E. C. |e verfasserin |4 aut | |
700 | 1 | |a Pereira, B. L. |e verfasserin |4 aut | |
700 | 1 | |a Passos, R. R. |e verfasserin |4 aut | |
700 | 1 | |a Pocrifka, L. A. |e verfasserin |4 aut | |
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10.1007/s10008-020-04532-2 doi (DE-627)SPR040251187 (SPR)s10008-020-04532-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Costa, J. C. M. verfasserin aut Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In the present work, $ MnO_{2} $ was electrodeposited (galvanostatic mode) on carbon cloth (CC) from manganese nitrate and sulfate precursors. Its electrochemical performance was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), which were used to study the complex behavior of the material. In CV analysis, higher cathodic and anodic loads were obtained for sulfate–$ MnO_{2} $ compared with nitrate–$ MnO_{2} $, whereas in the Nyquist graphs of the EIS technique, the nitrate–$ MnO_{2} $ material obtained larger charge transfer resistance (Rtc) than sulfate–$ MnO_{2} $. In the Bode analysis, the behavior of sulfate–$ MnO_{2} $ was better than that of nitrate–$ MnO_{2} $. because for this analysis, the phase angle is smaller, which is attributed to better pseudocapacitive behavior of sulfate than nitrate. In capacitance and complex power terms, the relaxation time constant obtained was 2.65 s. The real capacitance in C′(ω) was 107 F $ g^{−1} $ for nitrate–$ MnO_{2} $ and 197 F $ g^{−1} $ for sulfate–$ MnO_{2} $, and the intersection of the complex power curves occurred at 70%. The obtained results suggest that these materials are attractive for application in energy storage devices. Carbon cloth (CC) (dpeaa)DE-He213 Nitrate–MnO (dpeaa)DE-He213 Sulfate–MnO (dpeaa)DE-He213 Complex capacitance study (dpeaa)DE-He213 Nascimento, M. C. verfasserin aut Silva, E. C. verfasserin aut Pereira, B. L. verfasserin aut Passos, R. R. verfasserin aut Pocrifka, L. A. verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 24(2020), 8 vom: 27. Apr., Seite 1727-1733 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:24 year:2020 number:8 day:27 month:04 pages:1727-1733 https://dx.doi.org/10.1007/s10008-020-04532-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 24 2020 8 27 04 1727-1733 |
spelling |
10.1007/s10008-020-04532-2 doi (DE-627)SPR040251187 (SPR)s10008-020-04532-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Costa, J. C. M. verfasserin aut Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In the present work, $ MnO_{2} $ was electrodeposited (galvanostatic mode) on carbon cloth (CC) from manganese nitrate and sulfate precursors. Its electrochemical performance was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), which were used to study the complex behavior of the material. In CV analysis, higher cathodic and anodic loads were obtained for sulfate–$ MnO_{2} $ compared with nitrate–$ MnO_{2} $, whereas in the Nyquist graphs of the EIS technique, the nitrate–$ MnO_{2} $ material obtained larger charge transfer resistance (Rtc) than sulfate–$ MnO_{2} $. In the Bode analysis, the behavior of sulfate–$ MnO_{2} $ was better than that of nitrate–$ MnO_{2} $. because for this analysis, the phase angle is smaller, which is attributed to better pseudocapacitive behavior of sulfate than nitrate. In capacitance and complex power terms, the relaxation time constant obtained was 2.65 s. The real capacitance in C′(ω) was 107 F $ g^{−1} $ for nitrate–$ MnO_{2} $ and 197 F $ g^{−1} $ for sulfate–$ MnO_{2} $, and the intersection of the complex power curves occurred at 70%. The obtained results suggest that these materials are attractive for application in energy storage devices. Carbon cloth (CC) (dpeaa)DE-He213 Nitrate–MnO (dpeaa)DE-He213 Sulfate–MnO (dpeaa)DE-He213 Complex capacitance study (dpeaa)DE-He213 Nascimento, M. C. verfasserin aut Silva, E. C. verfasserin aut Pereira, B. L. verfasserin aut Passos, R. R. verfasserin aut Pocrifka, L. A. verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 24(2020), 8 vom: 27. Apr., Seite 1727-1733 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:24 year:2020 number:8 day:27 month:04 pages:1727-1733 https://dx.doi.org/10.1007/s10008-020-04532-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 24 2020 8 27 04 1727-1733 |
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10.1007/s10008-020-04532-2 doi (DE-627)SPR040251187 (SPR)s10008-020-04532-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Costa, J. C. M. verfasserin aut Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In the present work, $ MnO_{2} $ was electrodeposited (galvanostatic mode) on carbon cloth (CC) from manganese nitrate and sulfate precursors. Its electrochemical performance was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), which were used to study the complex behavior of the material. In CV analysis, higher cathodic and anodic loads were obtained for sulfate–$ MnO_{2} $ compared with nitrate–$ MnO_{2} $, whereas in the Nyquist graphs of the EIS technique, the nitrate–$ MnO_{2} $ material obtained larger charge transfer resistance (Rtc) than sulfate–$ MnO_{2} $. In the Bode analysis, the behavior of sulfate–$ MnO_{2} $ was better than that of nitrate–$ MnO_{2} $. because for this analysis, the phase angle is smaller, which is attributed to better pseudocapacitive behavior of sulfate than nitrate. In capacitance and complex power terms, the relaxation time constant obtained was 2.65 s. The real capacitance in C′(ω) was 107 F $ g^{−1} $ for nitrate–$ MnO_{2} $ and 197 F $ g^{−1} $ for sulfate–$ MnO_{2} $, and the intersection of the complex power curves occurred at 70%. The obtained results suggest that these materials are attractive for application in energy storage devices. Carbon cloth (CC) (dpeaa)DE-He213 Nitrate–MnO (dpeaa)DE-He213 Sulfate–MnO (dpeaa)DE-He213 Complex capacitance study (dpeaa)DE-He213 Nascimento, M. C. verfasserin aut Silva, E. C. verfasserin aut Pereira, B. L. verfasserin aut Passos, R. R. verfasserin aut Pocrifka, L. A. verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 24(2020), 8 vom: 27. Apr., Seite 1727-1733 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:24 year:2020 number:8 day:27 month:04 pages:1727-1733 https://dx.doi.org/10.1007/s10008-020-04532-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 24 2020 8 27 04 1727-1733 |
allfieldsGer |
10.1007/s10008-020-04532-2 doi (DE-627)SPR040251187 (SPR)s10008-020-04532-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Costa, J. C. M. verfasserin aut Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In the present work, $ MnO_{2} $ was electrodeposited (galvanostatic mode) on carbon cloth (CC) from manganese nitrate and sulfate precursors. Its electrochemical performance was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), which were used to study the complex behavior of the material. In CV analysis, higher cathodic and anodic loads were obtained for sulfate–$ MnO_{2} $ compared with nitrate–$ MnO_{2} $, whereas in the Nyquist graphs of the EIS technique, the nitrate–$ MnO_{2} $ material obtained larger charge transfer resistance (Rtc) than sulfate–$ MnO_{2} $. In the Bode analysis, the behavior of sulfate–$ MnO_{2} $ was better than that of nitrate–$ MnO_{2} $. because for this analysis, the phase angle is smaller, which is attributed to better pseudocapacitive behavior of sulfate than nitrate. In capacitance and complex power terms, the relaxation time constant obtained was 2.65 s. The real capacitance in C′(ω) was 107 F $ g^{−1} $ for nitrate–$ MnO_{2} $ and 197 F $ g^{−1} $ for sulfate–$ MnO_{2} $, and the intersection of the complex power curves occurred at 70%. The obtained results suggest that these materials are attractive for application in energy storage devices. Carbon cloth (CC) (dpeaa)DE-He213 Nitrate–MnO (dpeaa)DE-He213 Sulfate–MnO (dpeaa)DE-He213 Complex capacitance study (dpeaa)DE-He213 Nascimento, M. C. verfasserin aut Silva, E. C. verfasserin aut Pereira, B. L. verfasserin aut Passos, R. R. verfasserin aut Pocrifka, L. A. verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 24(2020), 8 vom: 27. Apr., Seite 1727-1733 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:24 year:2020 number:8 day:27 month:04 pages:1727-1733 https://dx.doi.org/10.1007/s10008-020-04532-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 24 2020 8 27 04 1727-1733 |
allfieldsSound |
10.1007/s10008-020-04532-2 doi (DE-627)SPR040251187 (SPR)s10008-020-04532-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.14 bkl 35.90 bkl Costa, J. C. M. verfasserin aut Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In the present work, $ MnO_{2} $ was electrodeposited (galvanostatic mode) on carbon cloth (CC) from manganese nitrate and sulfate precursors. Its electrochemical performance was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), which were used to study the complex behavior of the material. In CV analysis, higher cathodic and anodic loads were obtained for sulfate–$ MnO_{2} $ compared with nitrate–$ MnO_{2} $, whereas in the Nyquist graphs of the EIS technique, the nitrate–$ MnO_{2} $ material obtained larger charge transfer resistance (Rtc) than sulfate–$ MnO_{2} $. In the Bode analysis, the behavior of sulfate–$ MnO_{2} $ was better than that of nitrate–$ MnO_{2} $. because for this analysis, the phase angle is smaller, which is attributed to better pseudocapacitive behavior of sulfate than nitrate. In capacitance and complex power terms, the relaxation time constant obtained was 2.65 s. The real capacitance in C′(ω) was 107 F $ g^{−1} $ for nitrate–$ MnO_{2} $ and 197 F $ g^{−1} $ for sulfate–$ MnO_{2} $, and the intersection of the complex power curves occurred at 70%. The obtained results suggest that these materials are attractive for application in energy storage devices. Carbon cloth (CC) (dpeaa)DE-He213 Nitrate–MnO (dpeaa)DE-He213 Sulfate–MnO (dpeaa)DE-He213 Complex capacitance study (dpeaa)DE-He213 Nascimento, M. C. verfasserin aut Silva, E. C. verfasserin aut Pereira, B. L. verfasserin aut Passos, R. R. verfasserin aut Pocrifka, L. A. verfasserin aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 24(2020), 8 vom: 27. Apr., Seite 1727-1733 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:24 year:2020 number:8 day:27 month:04 pages:1727-1733 https://dx.doi.org/10.1007/s10008-020-04532-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.14 ASE 35.90 ASE AR 24 2020 8 27 04 1727-1733 |
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Enthalten in Journal of solid state electrochemistry 24(2020), 8 vom: 27. Apr., Seite 1727-1733 volume:24 year:2020 number:8 day:27 month:04 pages:1727-1733 |
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Carbon cloth (CC) Nitrate–MnO Sulfate–MnO Complex capacitance study |
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Costa, J. C. M. @@aut@@ Nascimento, M. C. @@aut@@ Silva, E. C. @@aut@@ Pereira, B. L. @@aut@@ Passos, R. R. @@aut@@ Pocrifka, L. A. @@aut@@ |
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C. M.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2020</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract In the present work, $ MnO_{2} $ was electrodeposited (galvanostatic mode) on carbon cloth (CC) from manganese nitrate and sulfate precursors. Its electrochemical performance was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), which were used to study the complex behavior of the material. In CV analysis, higher cathodic and anodic loads were obtained for sulfate–$ MnO_{2} $ compared with nitrate–$ MnO_{2} $, whereas in the Nyquist graphs of the EIS technique, the nitrate–$ MnO_{2} $ material obtained larger charge transfer resistance (Rtc) than sulfate–$ MnO_{2} $. In the Bode analysis, the behavior of sulfate–$ MnO_{2} $ was better than that of nitrate–$ MnO_{2} $. because for this analysis, the phase angle is smaller, which is attributed to better pseudocapacitive behavior of sulfate than nitrate. In capacitance and complex power terms, the relaxation time constant obtained was 2.65 s. The real capacitance in C′(ω) was 107 F $ g^{−1} $ for nitrate–$ MnO_{2} $ and 197 F $ g^{−1} $ for sulfate–$ MnO_{2} $, and the intersection of the complex power curves occurred at 70%. The obtained results suggest that these materials are attractive for application in energy storage devices.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Carbon cloth (CC)</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nitrate–MnO</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sulfate–MnO</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Complex capacitance study</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Nascimento, M. C.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Silva, E. 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|
author |
Costa, J. C. M. |
spellingShingle |
Costa, J. C. M. ddc 540 bkl 35.14 bkl 35.90 misc Carbon cloth (CC) misc Nitrate–MnO misc Sulfate–MnO misc Complex capacitance study Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study |
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540 ASE 35.14 bkl 35.90 bkl Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study Carbon cloth (CC) (dpeaa)DE-He213 Nitrate–MnO (dpeaa)DE-He213 Sulfate–MnO (dpeaa)DE-He213 Complex capacitance study (dpeaa)DE-He213 |
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ddc 540 bkl 35.14 bkl 35.90 misc Carbon cloth (CC) misc Nitrate–MnO misc Sulfate–MnO misc Complex capacitance study |
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ddc 540 bkl 35.14 bkl 35.90 misc Carbon cloth (CC) misc Nitrate–MnO misc Sulfate–MnO misc Complex capacitance study |
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Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study |
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Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study |
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Costa, J. C. M. |
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Journal of solid state electrochemistry |
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Costa, J. C. M. Nascimento, M. C. Silva, E. C. Pereira, B. L. Passos, R. R. Pocrifka, L. A. |
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540 ASE 35.14 bkl 35.90 bkl |
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Elektronische Aufsätze |
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Costa, J. C. M. |
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10.1007/s10008-020-04532-2 |
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540 |
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verfasserin |
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galvanostatic synthesis of $ mno_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study |
title_auth |
Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study |
abstract |
Abstract In the present work, $ MnO_{2} $ was electrodeposited (galvanostatic mode) on carbon cloth (CC) from manganese nitrate and sulfate precursors. Its electrochemical performance was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), which were used to study the complex behavior of the material. In CV analysis, higher cathodic and anodic loads were obtained for sulfate–$ MnO_{2} $ compared with nitrate–$ MnO_{2} $, whereas in the Nyquist graphs of the EIS technique, the nitrate–$ MnO_{2} $ material obtained larger charge transfer resistance (Rtc) than sulfate–$ MnO_{2} $. In the Bode analysis, the behavior of sulfate–$ MnO_{2} $ was better than that of nitrate–$ MnO_{2} $. because for this analysis, the phase angle is smaller, which is attributed to better pseudocapacitive behavior of sulfate than nitrate. In capacitance and complex power terms, the relaxation time constant obtained was 2.65 s. The real capacitance in C′(ω) was 107 F $ g^{−1} $ for nitrate–$ MnO_{2} $ and 197 F $ g^{−1} $ for sulfate–$ MnO_{2} $, and the intersection of the complex power curves occurred at 70%. The obtained results suggest that these materials are attractive for application in energy storage devices. |
abstractGer |
Abstract In the present work, $ MnO_{2} $ was electrodeposited (galvanostatic mode) on carbon cloth (CC) from manganese nitrate and sulfate precursors. Its electrochemical performance was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), which were used to study the complex behavior of the material. In CV analysis, higher cathodic and anodic loads were obtained for sulfate–$ MnO_{2} $ compared with nitrate–$ MnO_{2} $, whereas in the Nyquist graphs of the EIS technique, the nitrate–$ MnO_{2} $ material obtained larger charge transfer resistance (Rtc) than sulfate–$ MnO_{2} $. In the Bode analysis, the behavior of sulfate–$ MnO_{2} $ was better than that of nitrate–$ MnO_{2} $. because for this analysis, the phase angle is smaller, which is attributed to better pseudocapacitive behavior of sulfate than nitrate. In capacitance and complex power terms, the relaxation time constant obtained was 2.65 s. The real capacitance in C′(ω) was 107 F $ g^{−1} $ for nitrate–$ MnO_{2} $ and 197 F $ g^{−1} $ for sulfate–$ MnO_{2} $, and the intersection of the complex power curves occurred at 70%. The obtained results suggest that these materials are attractive for application in energy storage devices. |
abstract_unstemmed |
Abstract In the present work, $ MnO_{2} $ was electrodeposited (galvanostatic mode) on carbon cloth (CC) from manganese nitrate and sulfate precursors. Its electrochemical performance was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), which were used to study the complex behavior of the material. In CV analysis, higher cathodic and anodic loads were obtained for sulfate–$ MnO_{2} $ compared with nitrate–$ MnO_{2} $, whereas in the Nyquist graphs of the EIS technique, the nitrate–$ MnO_{2} $ material obtained larger charge transfer resistance (Rtc) than sulfate–$ MnO_{2} $. In the Bode analysis, the behavior of sulfate–$ MnO_{2} $ was better than that of nitrate–$ MnO_{2} $. because for this analysis, the phase angle is smaller, which is attributed to better pseudocapacitive behavior of sulfate than nitrate. In capacitance and complex power terms, the relaxation time constant obtained was 2.65 s. The real capacitance in C′(ω) was 107 F $ g^{−1} $ for nitrate–$ MnO_{2} $ and 197 F $ g^{−1} $ for sulfate–$ MnO_{2} $, and the intersection of the complex power curves occurred at 70%. The obtained results suggest that these materials are attractive for application in energy storage devices. |
collection_details |
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container_issue |
8 |
title_short |
Galvanostatic synthesis of $ MnO_{2} $ in carbon cloth: an electrochemical impedance spectroscopy study |
url |
https://dx.doi.org/10.1007/s10008-020-04532-2 |
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author2 |
Nascimento, M. C. Silva, E. C. Pereira, B. L. Passos, R. R. Pocrifka, L. A. |
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Nascimento, M. C. Silva, E. C. Pereira, B. L. Passos, R. R. Pocrifka, L. A. |
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doi_str |
10.1007/s10008-020-04532-2 |
up_date |
2024-07-03T14:46:28.952Z |
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|
score |
7.399727 |