Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries

Highlights Nanocapsules made from metal–organic frameworks were designed for sustained release of additive ($ LiNO_{3} $) to passivate Li anode in commercial carbonate-based electrolyte.The nanocapsules with continuous supply of $ LiNO_{3} $ formed a nitride-rich solid electrolyte interphase layer o...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Liu, Qianqian [verfasserIn] Xu, Yifei [verfasserIn] Wang, Jianghao [verfasserIn] Zhao, Bo [verfasserIn] Li, Zijian [verfasserIn] Wu, Hao Bin [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2020

Schlagwörter:	Metal–organic frameworks LiNO Nanocapsules Lithium-metal anode Lithium-metal batteries

Übergeordnetes Werk:	Enthalten in: Nano-Micro letters - Berlin : Springer, 2009, 12(2020), 1 vom: 28. Aug.
Übergeordnetes Werk:	volume:12 ; year:2020 ; number:1 ; day:28 ; month:08

Links:	Volltext

DOI / URN:	10.1007/s40820-020-00514-1

Katalog-ID:	SPR040781992

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520			\|a Highlights Nanocapsules made from metal–organic frameworks were designed for sustained release of additive ($ LiNO_{3} $) to passivate Li anode in commercial carbonate-based electrolyte.The nanocapsules with continuous supply of $ LiNO_{3} $ formed a nitride-rich solid electrolyte interphase layer on Li anode and persistently remedied the interphase during prolonged cycling.The practical Li-metal full cell delivered a prolonged lifespan with 90% capacity retention after 240 cycles which has been hardly achieved in commercial electrolyte.
520			\|a Abstract A robust solid-electrolyte interphase (SEI) enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency. However, the self-sacrificial nature of SEI forming additives limits their capability to stabilize Li anode for long-term cycling. Herein, we demonstrate nanocapsules made from metal–organic frameworks for sustained release of $ LiNO_{3} $ as surface passivation additive in commercial carbonate-based electrolyte. The nanocapsules can offer over 10 times more $ LiNO_{3} $ than the solubility of $ LiNO_{3} $. Continuous supply of $ LiNO_{3} $ by nanocapsules forms a nitride-rich SEI layer on Li anode and persistently remedies SEI during prolonged cycling. As a result, lifespan of thin Li anode in 50 μm, which experiences drastic volume change and repeated SEI formation during cycling, has been notably improved. By pairing with an industry-level thick $ LiCoO_{2} $ cathode, practical Li-metal full cell demonstrates a remarkable capacity retention of 90% after 240 cycles, in contrast to fast capacity drop after 60 cycles in $ LiNO_{3} $ saturated electrolyte.
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allfields	10.1007/s40820-020-00514-1 doi (DE-627)SPR040781992 (DE-599)SPRs40820-020-00514-1-e (SPR)s40820-020-00514-1-e DE-627 ger DE-627 rakwb eng 050 ASE Liu, Qianqian verfasserin aut Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Highlights Nanocapsules made from metal–organic frameworks were designed for sustained release of additive ($ LiNO_{3} $) to passivate Li anode in commercial carbonate-based electrolyte.The nanocapsules with continuous supply of $ LiNO_{3} $ formed a nitride-rich solid electrolyte interphase layer on Li anode and persistently remedied the interphase during prolonged cycling.The practical Li-metal full cell delivered a prolonged lifespan with 90% capacity retention after 240 cycles which has been hardly achieved in commercial electrolyte. Abstract A robust solid-electrolyte interphase (SEI) enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency. However, the self-sacrificial nature of SEI forming additives limits their capability to stabilize Li anode for long-term cycling. Herein, we demonstrate nanocapsules made from metal–organic frameworks for sustained release of $ LiNO_{3} $ as surface passivation additive in commercial carbonate-based electrolyte. The nanocapsules can offer over 10 times more $ LiNO_{3} $ than the solubility of $ LiNO_{3} $. Continuous supply of $ LiNO_{3} $ by nanocapsules forms a nitride-rich SEI layer on Li anode and persistently remedies SEI during prolonged cycling. As a result, lifespan of thin Li anode in 50 μm, which experiences drastic volume change and repeated SEI formation during cycling, has been notably improved. By pairing with an industry-level thick $ LiCoO_{2} $ cathode, practical Li-metal full cell demonstrates a remarkable capacity retention of 90% after 240 cycles, in contrast to fast capacity drop after 60 cycles in $ LiNO_{3} $ saturated electrolyte. Metal–organic frameworks (dpeaa)DE-He213 LiNO (dpeaa)DE-He213 Nanocapsules (dpeaa)DE-He213 Lithium-metal anode (dpeaa)DE-He213 Lithium-metal batteries (dpeaa)DE-He213 Xu, Yifei verfasserin aut Wang, Jianghao verfasserin aut Zhao, Bo verfasserin aut Li, Zijian verfasserin aut Wu, Hao Bin verfasserin aut Enthalten in Nano-Micro letters Berlin : Springer, 2009 12(2020), 1 vom: 28. Aug. (DE-627)680319581 (DE-600)2642093-4 2150-5551 nnns volume:12 year:2020 number:1 day:28 month:08 https://dx.doi.org/10.1007/s40820-020-00514-1 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2020 1 28 08
spelling	10.1007/s40820-020-00514-1 doi (DE-627)SPR040781992 (DE-599)SPRs40820-020-00514-1-e (SPR)s40820-020-00514-1-e DE-627 ger DE-627 rakwb eng 050 ASE Liu, Qianqian verfasserin aut Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Highlights Nanocapsules made from metal–organic frameworks were designed for sustained release of additive ($ LiNO_{3} $) to passivate Li anode in commercial carbonate-based electrolyte.The nanocapsules with continuous supply of $ LiNO_{3} $ formed a nitride-rich solid electrolyte interphase layer on Li anode and persistently remedied the interphase during prolonged cycling.The practical Li-metal full cell delivered a prolonged lifespan with 90% capacity retention after 240 cycles which has been hardly achieved in commercial electrolyte. Abstract A robust solid-electrolyte interphase (SEI) enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency. However, the self-sacrificial nature of SEI forming additives limits their capability to stabilize Li anode for long-term cycling. Herein, we demonstrate nanocapsules made from metal–organic frameworks for sustained release of $ LiNO_{3} $ as surface passivation additive in commercial carbonate-based electrolyte. The nanocapsules can offer over 10 times more $ LiNO_{3} $ than the solubility of $ LiNO_{3} $. Continuous supply of $ LiNO_{3} $ by nanocapsules forms a nitride-rich SEI layer on Li anode and persistently remedies SEI during prolonged cycling. As a result, lifespan of thin Li anode in 50 μm, which experiences drastic volume change and repeated SEI formation during cycling, has been notably improved. By pairing with an industry-level thick $ LiCoO_{2} $ cathode, practical Li-metal full cell demonstrates a remarkable capacity retention of 90% after 240 cycles, in contrast to fast capacity drop after 60 cycles in $ LiNO_{3} $ saturated electrolyte. Metal–organic frameworks (dpeaa)DE-He213 LiNO (dpeaa)DE-He213 Nanocapsules (dpeaa)DE-He213 Lithium-metal anode (dpeaa)DE-He213 Lithium-metal batteries (dpeaa)DE-He213 Xu, Yifei verfasserin aut Wang, Jianghao verfasserin aut Zhao, Bo verfasserin aut Li, Zijian verfasserin aut Wu, Hao Bin verfasserin aut Enthalten in Nano-Micro letters Berlin : Springer, 2009 12(2020), 1 vom: 28. Aug. (DE-627)680319581 (DE-600)2642093-4 2150-5551 nnns volume:12 year:2020 number:1 day:28 month:08 https://dx.doi.org/10.1007/s40820-020-00514-1 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2020 1 28 08
allfields_unstemmed	10.1007/s40820-020-00514-1 doi (DE-627)SPR040781992 (DE-599)SPRs40820-020-00514-1-e (SPR)s40820-020-00514-1-e DE-627 ger DE-627 rakwb eng 050 ASE Liu, Qianqian verfasserin aut Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Highlights Nanocapsules made from metal–organic frameworks were designed for sustained release of additive ($ LiNO_{3} $) to passivate Li anode in commercial carbonate-based electrolyte.The nanocapsules with continuous supply of $ LiNO_{3} $ formed a nitride-rich solid electrolyte interphase layer on Li anode and persistently remedied the interphase during prolonged cycling.The practical Li-metal full cell delivered a prolonged lifespan with 90% capacity retention after 240 cycles which has been hardly achieved in commercial electrolyte. Abstract A robust solid-electrolyte interphase (SEI) enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency. However, the self-sacrificial nature of SEI forming additives limits their capability to stabilize Li anode for long-term cycling. Herein, we demonstrate nanocapsules made from metal–organic frameworks for sustained release of $ LiNO_{3} $ as surface passivation additive in commercial carbonate-based electrolyte. The nanocapsules can offer over 10 times more $ LiNO_{3} $ than the solubility of $ LiNO_{3} $. Continuous supply of $ LiNO_{3} $ by nanocapsules forms a nitride-rich SEI layer on Li anode and persistently remedies SEI during prolonged cycling. As a result, lifespan of thin Li anode in 50 μm, which experiences drastic volume change and repeated SEI formation during cycling, has been notably improved. By pairing with an industry-level thick $ LiCoO_{2} $ cathode, practical Li-metal full cell demonstrates a remarkable capacity retention of 90% after 240 cycles, in contrast to fast capacity drop after 60 cycles in $ LiNO_{3} $ saturated electrolyte. Metal–organic frameworks (dpeaa)DE-He213 LiNO (dpeaa)DE-He213 Nanocapsules (dpeaa)DE-He213 Lithium-metal anode (dpeaa)DE-He213 Lithium-metal batteries (dpeaa)DE-He213 Xu, Yifei verfasserin aut Wang, Jianghao verfasserin aut Zhao, Bo verfasserin aut Li, Zijian verfasserin aut Wu, Hao Bin verfasserin aut Enthalten in Nano-Micro letters Berlin : Springer, 2009 12(2020), 1 vom: 28. Aug. (DE-627)680319581 (DE-600)2642093-4 2150-5551 nnns volume:12 year:2020 number:1 day:28 month:08 https://dx.doi.org/10.1007/s40820-020-00514-1 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2020 1 28 08
allfieldsGer	10.1007/s40820-020-00514-1 doi (DE-627)SPR040781992 (DE-599)SPRs40820-020-00514-1-e (SPR)s40820-020-00514-1-e DE-627 ger DE-627 rakwb eng 050 ASE Liu, Qianqian verfasserin aut Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Highlights Nanocapsules made from metal–organic frameworks were designed for sustained release of additive ($ LiNO_{3} $) to passivate Li anode in commercial carbonate-based electrolyte.The nanocapsules with continuous supply of $ LiNO_{3} $ formed a nitride-rich solid electrolyte interphase layer on Li anode and persistently remedied the interphase during prolonged cycling.The practical Li-metal full cell delivered a prolonged lifespan with 90% capacity retention after 240 cycles which has been hardly achieved in commercial electrolyte. Abstract A robust solid-electrolyte interphase (SEI) enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency. However, the self-sacrificial nature of SEI forming additives limits their capability to stabilize Li anode for long-term cycling. Herein, we demonstrate nanocapsules made from metal–organic frameworks for sustained release of $ LiNO_{3} $ as surface passivation additive in commercial carbonate-based electrolyte. The nanocapsules can offer over 10 times more $ LiNO_{3} $ than the solubility of $ LiNO_{3} $. Continuous supply of $ LiNO_{3} $ by nanocapsules forms a nitride-rich SEI layer on Li anode and persistently remedies SEI during prolonged cycling. As a result, lifespan of thin Li anode in 50 μm, which experiences drastic volume change and repeated SEI formation during cycling, has been notably improved. By pairing with an industry-level thick $ LiCoO_{2} $ cathode, practical Li-metal full cell demonstrates a remarkable capacity retention of 90% after 240 cycles, in contrast to fast capacity drop after 60 cycles in $ LiNO_{3} $ saturated electrolyte. Metal–organic frameworks (dpeaa)DE-He213 LiNO (dpeaa)DE-He213 Nanocapsules (dpeaa)DE-He213 Lithium-metal anode (dpeaa)DE-He213 Lithium-metal batteries (dpeaa)DE-He213 Xu, Yifei verfasserin aut Wang, Jianghao verfasserin aut Zhao, Bo verfasserin aut Li, Zijian verfasserin aut Wu, Hao Bin verfasserin aut Enthalten in Nano-Micro letters Berlin : Springer, 2009 12(2020), 1 vom: 28. Aug. (DE-627)680319581 (DE-600)2642093-4 2150-5551 nnns volume:12 year:2020 number:1 day:28 month:08 https://dx.doi.org/10.1007/s40820-020-00514-1 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2020 1 28 08
allfieldsSound	10.1007/s40820-020-00514-1 doi (DE-627)SPR040781992 (DE-599)SPRs40820-020-00514-1-e (SPR)s40820-020-00514-1-e DE-627 ger DE-627 rakwb eng 050 ASE Liu, Qianqian verfasserin aut Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Highlights Nanocapsules made from metal–organic frameworks were designed for sustained release of additive ($ LiNO_{3} $) to passivate Li anode in commercial carbonate-based electrolyte.The nanocapsules with continuous supply of $ LiNO_{3} $ formed a nitride-rich solid electrolyte interphase layer on Li anode and persistently remedied the interphase during prolonged cycling.The practical Li-metal full cell delivered a prolonged lifespan with 90% capacity retention after 240 cycles which has been hardly achieved in commercial electrolyte. Abstract A robust solid-electrolyte interphase (SEI) enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency. However, the self-sacrificial nature of SEI forming additives limits their capability to stabilize Li anode for long-term cycling. Herein, we demonstrate nanocapsules made from metal–organic frameworks for sustained release of $ LiNO_{3} $ as surface passivation additive in commercial carbonate-based electrolyte. The nanocapsules can offer over 10 times more $ LiNO_{3} $ than the solubility of $ LiNO_{3} $. Continuous supply of $ LiNO_{3} $ by nanocapsules forms a nitride-rich SEI layer on Li anode and persistently remedies SEI during prolonged cycling. As a result, lifespan of thin Li anode in 50 μm, which experiences drastic volume change and repeated SEI formation during cycling, has been notably improved. By pairing with an industry-level thick $ LiCoO_{2} $ cathode, practical Li-metal full cell demonstrates a remarkable capacity retention of 90% after 240 cycles, in contrast to fast capacity drop after 60 cycles in $ LiNO_{3} $ saturated electrolyte. Metal–organic frameworks (dpeaa)DE-He213 LiNO (dpeaa)DE-He213 Nanocapsules (dpeaa)DE-He213 Lithium-metal anode (dpeaa)DE-He213 Lithium-metal batteries (dpeaa)DE-He213 Xu, Yifei verfasserin aut Wang, Jianghao verfasserin aut Zhao, Bo verfasserin aut Li, Zijian verfasserin aut Wu, Hao Bin verfasserin aut Enthalten in Nano-Micro letters Berlin : Springer, 2009 12(2020), 1 vom: 28. Aug. (DE-627)680319581 (DE-600)2642093-4 2150-5551 nnns volume:12 year:2020 number:1 day:28 month:08 https://dx.doi.org/10.1007/s40820-020-00514-1 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2020 1 28 08
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author	Liu, Qianqian
spellingShingle	Liu, Qianqian ddc 050 misc Metal–organic frameworks misc LiNO misc Nanocapsules misc Lithium-metal anode misc Lithium-metal batteries Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries
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topic_title	050 ASE Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries Metal–organic frameworks (dpeaa)DE-He213 LiNO (dpeaa)DE-He213 Nanocapsules (dpeaa)DE-He213 Lithium-metal anode (dpeaa)DE-He213 Lithium-metal batteries (dpeaa)DE-He213
topic	ddc 050 misc Metal–organic frameworks misc LiNO misc Nanocapsules misc Lithium-metal anode misc Lithium-metal batteries
topic_unstemmed	ddc 050 misc Metal–organic frameworks misc LiNO misc Nanocapsules misc Lithium-metal anode misc Lithium-metal batteries
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title	Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries
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title_full	Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries
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author_browse	Liu, Qianqian Xu, Yifei Wang, Jianghao Zhao, Bo Li, Zijian Wu, Hao Bin
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title_sort	sustained-release nanocapsules enable long-lasting stabilization of li anode for practical li-metal batteries
title_auth	Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries
abstract	Highlights Nanocapsules made from metal–organic frameworks were designed for sustained release of additive ($ LiNO_{3} $) to passivate Li anode in commercial carbonate-based electrolyte.The nanocapsules with continuous supply of $ LiNO_{3} $ formed a nitride-rich solid electrolyte interphase layer on Li anode and persistently remedied the interphase during prolonged cycling.The practical Li-metal full cell delivered a prolonged lifespan with 90% capacity retention after 240 cycles which has been hardly achieved in commercial electrolyte. Abstract A robust solid-electrolyte interphase (SEI) enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency. However, the self-sacrificial nature of SEI forming additives limits their capability to stabilize Li anode for long-term cycling. Herein, we demonstrate nanocapsules made from metal–organic frameworks for sustained release of $ LiNO_{3} $ as surface passivation additive in commercial carbonate-based electrolyte. The nanocapsules can offer over 10 times more $ LiNO_{3} $ than the solubility of $ LiNO_{3} $. Continuous supply of $ LiNO_{3} $ by nanocapsules forms a nitride-rich SEI layer on Li anode and persistently remedies SEI during prolonged cycling. As a result, lifespan of thin Li anode in 50 μm, which experiences drastic volume change and repeated SEI formation during cycling, has been notably improved. By pairing with an industry-level thick $ LiCoO_{2} $ cathode, practical Li-metal full cell demonstrates a remarkable capacity retention of 90% after 240 cycles, in contrast to fast capacity drop after 60 cycles in $ LiNO_{3} $ saturated electrolyte.
abstractGer	Highlights Nanocapsules made from metal–organic frameworks were designed for sustained release of additive ($ LiNO_{3} $) to passivate Li anode in commercial carbonate-based electrolyte.The nanocapsules with continuous supply of $ LiNO_{3} $ formed a nitride-rich solid electrolyte interphase layer on Li anode and persistently remedied the interphase during prolonged cycling.The practical Li-metal full cell delivered a prolonged lifespan with 90% capacity retention after 240 cycles which has been hardly achieved in commercial electrolyte. Abstract A robust solid-electrolyte interphase (SEI) enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency. However, the self-sacrificial nature of SEI forming additives limits their capability to stabilize Li anode for long-term cycling. Herein, we demonstrate nanocapsules made from metal–organic frameworks for sustained release of $ LiNO_{3} $ as surface passivation additive in commercial carbonate-based electrolyte. The nanocapsules can offer over 10 times more $ LiNO_{3} $ than the solubility of $ LiNO_{3} $. Continuous supply of $ LiNO_{3} $ by nanocapsules forms a nitride-rich SEI layer on Li anode and persistently remedies SEI during prolonged cycling. As a result, lifespan of thin Li anode in 50 μm, which experiences drastic volume change and repeated SEI formation during cycling, has been notably improved. By pairing with an industry-level thick $ LiCoO_{2} $ cathode, practical Li-metal full cell demonstrates a remarkable capacity retention of 90% after 240 cycles, in contrast to fast capacity drop after 60 cycles in $ LiNO_{3} $ saturated electrolyte.
abstract_unstemmed	Highlights Nanocapsules made from metal–organic frameworks were designed for sustained release of additive ($ LiNO_{3} $) to passivate Li anode in commercial carbonate-based electrolyte.The nanocapsules with continuous supply of $ LiNO_{3} $ formed a nitride-rich solid electrolyte interphase layer on Li anode and persistently remedied the interphase during prolonged cycling.The practical Li-metal full cell delivered a prolonged lifespan with 90% capacity retention after 240 cycles which has been hardly achieved in commercial electrolyte. Abstract A robust solid-electrolyte interphase (SEI) enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency. However, the self-sacrificial nature of SEI forming additives limits their capability to stabilize Li anode for long-term cycling. Herein, we demonstrate nanocapsules made from metal–organic frameworks for sustained release of $ LiNO_{3} $ as surface passivation additive in commercial carbonate-based electrolyte. The nanocapsules can offer over 10 times more $ LiNO_{3} $ than the solubility of $ LiNO_{3} $. Continuous supply of $ LiNO_{3} $ by nanocapsules forms a nitride-rich SEI layer on Li anode and persistently remedies SEI during prolonged cycling. As a result, lifespan of thin Li anode in 50 μm, which experiences drastic volume change and repeated SEI formation during cycling, has been notably improved. By pairing with an industry-level thick $ LiCoO_{2} $ cathode, practical Li-metal full cell demonstrates a remarkable capacity retention of 90% after 240 cycles, in contrast to fast capacity drop after 60 cycles in $ LiNO_{3} $ saturated electrolyte.
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container_issue	1
title_short	Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries
url	https://dx.doi.org/10.1007/s40820-020-00514-1
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author2	Xu, Yifei Wang, Jianghao Zhao, Bo Li, Zijian Wu, Hao Bin
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up_date	2024-07-03T18:13:18.799Z
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fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR040781992</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20220112034018.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201007s2020 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s40820-020-00514-1</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR040781992</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)SPRs40820-020-00514-1-e</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s40820-020-00514-1-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">050</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Liu, Qianqian</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2020</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Highlights Nanocapsules made from metal–organic frameworks were designed for sustained release of additive ($ LiNO_{3} $) to passivate Li anode in commercial carbonate-based electrolyte.The nanocapsules with continuous supply of $ LiNO_{3} $ formed a nitride-rich solid electrolyte interphase layer on Li anode and persistently remedied the interphase during prolonged cycling.The practical Li-metal full cell delivered a prolonged lifespan with 90% capacity retention after 240 cycles which has been hardly achieved in commercial electrolyte.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract A robust solid-electrolyte interphase (SEI) enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency. However, the self-sacrificial nature of SEI forming additives limits their capability to stabilize Li anode for long-term cycling. Herein, we demonstrate nanocapsules made from metal–organic frameworks for sustained release of $ LiNO_{3} $ as surface passivation additive in commercial carbonate-based electrolyte. The nanocapsules can offer over 10 times more $ LiNO_{3} $ than the solubility of $ LiNO_{3} $. Continuous supply of $ LiNO_{3} $ by nanocapsules forms a nitride-rich SEI layer on Li anode and persistently remedies SEI during prolonged cycling. As a result, lifespan of thin Li anode in 50 μm, which experiences drastic volume change and repeated SEI formation during cycling, has been notably improved. By pairing with an industry-level thick $ LiCoO_{2} $ cathode, practical Li-metal full cell demonstrates a remarkable capacity retention of 90% after 240 cycles, in contrast to fast capacity drop after 60 cycles in $ LiNO_{3} $ saturated electrolyte.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Metal–organic frameworks</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">LiNO</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nanocapsules</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Lithium-metal anode</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Lithium-metal batteries</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xu, Yifei</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Jianghao</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhao, Bo</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Zijian</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wu, Hao Bin</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Nano-Micro letters</subfield><subfield code="d">Berlin : Springer, 2009</subfield><subfield code="g">12(2020), 1 vom: 28. 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Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal Batteries

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