Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals
Abstract— We have studied and optimized conditions for spontaneous flux growth of $ TbCr_{3} $($ BO_{3} $)4 crystals. Phase relations in the pseudoternary system $ TbCr_{3} $($ BO_{3} $)4–$ K_{2} %$ Mo_{3} %$ O_{10} $–$ B_{2} %$ O_{3} $ have been studied in the temperature range 900–1130°C and the s...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Kuzmin, N. N. [verfasserIn] Maltsev, V. V. [verfasserIn] Volkova, E. A. [verfasserIn] Leonyuk, N. I. [verfasserIn] Boldyrev, K. N. [verfasserIn] Bludov, A. N. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2020 |
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| Übergeordnetes Werk: |
Enthalten in: Inorganic materials - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996, 56(2020), 8 vom: Aug., Seite 828-835 |
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| Übergeordnetes Werk: |
volume:56 ; year:2020 ; number:8 ; month:08 ; pages:828-835 |
| Links: |
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| DOI / URN: |
10.1134/S0020168520080087 |
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| Katalog-ID: |
SPR040828204 |
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| 520 | |a Abstract— We have studied and optimized conditions for spontaneous flux growth of $ TbCr_{3} $($ BO_{3} $)4 crystals. Phase relations in the pseudoternary system $ TbCr_{3} $($ BO_{3} $)4–$ K_{2} %$ Mo_{3} %$ O_{10} $–$ B_{2} %$ O_{3} $ have been studied in the temperature range 900–1130°C and the single-phase terbium chromium borate crystallization field has been mapped out. It has been shown that increasing the $ TbCr_{3} $($ BO_{3} $)4 content of the starting high-temperature solution leads to a rhombohedral-to-monoclinic phase transition. Using $ K_{2} %$ Mo_{3} %$ O_{10} $-based high-temperature solutions, we have grown single-phase $ TbCr_{3} $($ BO_{3} $)4 single crystals or crystals in which the rhombohedral phase (sp. gr. R32) significantly prevails over the monoclinic phase (sp. gr. C2/c). The grown crystals have been characterized by X-ray diffraction techniques, IR spectroscopy, and magnetic measurements. | ||
| 700 | 1 | |a Maltsev, V. V. |e verfasserin |4 aut | |
| 700 | 1 | |a Volkova, E. A. |e verfasserin |4 aut | |
| 700 | 1 | |a Leonyuk, N. I. |e verfasserin |4 aut | |
| 700 | 1 | |a Boldyrev, K. N. |e verfasserin |4 aut | |
| 700 | 1 | |a Bludov, A. N. |e verfasserin |4 aut | |
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10.1134/S0020168520080087 doi (DE-627)SPR040828204 (SPR)S0020168520080087-e DE-627 ger DE-627 rakwb eng 540 600 670 ASE 35.40 bkl Kuzmin, N. N. verfasserin aut Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract— We have studied and optimized conditions for spontaneous flux growth of $ TbCr_{3} $($ BO_{3} $)4 crystals. Phase relations in the pseudoternary system $ TbCr_{3} $($ BO_{3} $)4–$ K_{2} %$ Mo_{3} %$ O_{10} $–$ B_{2} %$ O_{3} $ have been studied in the temperature range 900–1130°C and the single-phase terbium chromium borate crystallization field has been mapped out. It has been shown that increasing the $ TbCr_{3} $($ BO_{3} $)4 content of the starting high-temperature solution leads to a rhombohedral-to-monoclinic phase transition. Using $ K_{2} %$ Mo_{3} %$ O_{10} $-based high-temperature solutions, we have grown single-phase $ TbCr_{3} $($ BO_{3} $)4 single crystals or crystals in which the rhombohedral phase (sp. gr. R32) significantly prevails over the monoclinic phase (sp. gr. C2/c). The grown crystals have been characterized by X-ray diffraction techniques, IR spectroscopy, and magnetic measurements. Maltsev, V. V. verfasserin aut Volkova, E. A. verfasserin aut Leonyuk, N. I. verfasserin aut Boldyrev, K. N. verfasserin aut Bludov, A. N. verfasserin aut Enthalten in Inorganic materials Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996 56(2020), 8 vom: Aug., Seite 828-835 (DE-627)334292719 (DE-600)2057339-X 1608-3172 nnns volume:56 year:2020 number:8 month:08 pages:828-835 https://dx.doi.org/10.1134/S0020168520080087 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.40 ASE AR 56 2020 8 08 828-835 |
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10.1134/S0020168520080087 doi (DE-627)SPR040828204 (SPR)S0020168520080087-e DE-627 ger DE-627 rakwb eng 540 600 670 ASE 35.40 bkl Kuzmin, N. N. verfasserin aut Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract— We have studied and optimized conditions for spontaneous flux growth of $ TbCr_{3} $($ BO_{3} $)4 crystals. Phase relations in the pseudoternary system $ TbCr_{3} $($ BO_{3} $)4–$ K_{2} %$ Mo_{3} %$ O_{10} $–$ B_{2} %$ O_{3} $ have been studied in the temperature range 900–1130°C and the single-phase terbium chromium borate crystallization field has been mapped out. It has been shown that increasing the $ TbCr_{3} $($ BO_{3} $)4 content of the starting high-temperature solution leads to a rhombohedral-to-monoclinic phase transition. Using $ K_{2} %$ Mo_{3} %$ O_{10} $-based high-temperature solutions, we have grown single-phase $ TbCr_{3} $($ BO_{3} $)4 single crystals or crystals in which the rhombohedral phase (sp. gr. R32) significantly prevails over the monoclinic phase (sp. gr. C2/c). The grown crystals have been characterized by X-ray diffraction techniques, IR spectroscopy, and magnetic measurements. Maltsev, V. V. verfasserin aut Volkova, E. A. verfasserin aut Leonyuk, N. I. verfasserin aut Boldyrev, K. N. verfasserin aut Bludov, A. N. verfasserin aut Enthalten in Inorganic materials Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996 56(2020), 8 vom: Aug., Seite 828-835 (DE-627)334292719 (DE-600)2057339-X 1608-3172 nnns volume:56 year:2020 number:8 month:08 pages:828-835 https://dx.doi.org/10.1134/S0020168520080087 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.40 ASE AR 56 2020 8 08 828-835 |
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10.1134/S0020168520080087 doi (DE-627)SPR040828204 (SPR)S0020168520080087-e DE-627 ger DE-627 rakwb eng 540 600 670 ASE 35.40 bkl Kuzmin, N. N. verfasserin aut Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract— We have studied and optimized conditions for spontaneous flux growth of $ TbCr_{3} $($ BO_{3} $)4 crystals. Phase relations in the pseudoternary system $ TbCr_{3} $($ BO_{3} $)4–$ K_{2} %$ Mo_{3} %$ O_{10} $–$ B_{2} %$ O_{3} $ have been studied in the temperature range 900–1130°C and the single-phase terbium chromium borate crystallization field has been mapped out. It has been shown that increasing the $ TbCr_{3} $($ BO_{3} $)4 content of the starting high-temperature solution leads to a rhombohedral-to-monoclinic phase transition. Using $ K_{2} %$ Mo_{3} %$ O_{10} $-based high-temperature solutions, we have grown single-phase $ TbCr_{3} $($ BO_{3} $)4 single crystals or crystals in which the rhombohedral phase (sp. gr. R32) significantly prevails over the monoclinic phase (sp. gr. C2/c). The grown crystals have been characterized by X-ray diffraction techniques, IR spectroscopy, and magnetic measurements. Maltsev, V. V. verfasserin aut Volkova, E. A. verfasserin aut Leonyuk, N. I. verfasserin aut Boldyrev, K. N. verfasserin aut Bludov, A. N. verfasserin aut Enthalten in Inorganic materials Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996 56(2020), 8 vom: Aug., Seite 828-835 (DE-627)334292719 (DE-600)2057339-X 1608-3172 nnns volume:56 year:2020 number:8 month:08 pages:828-835 https://dx.doi.org/10.1134/S0020168520080087 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.40 ASE AR 56 2020 8 08 828-835 |
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10.1134/S0020168520080087 doi (DE-627)SPR040828204 (SPR)S0020168520080087-e DE-627 ger DE-627 rakwb eng 540 600 670 ASE 35.40 bkl Kuzmin, N. N. verfasserin aut Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract— We have studied and optimized conditions for spontaneous flux growth of $ TbCr_{3} $($ BO_{3} $)4 crystals. Phase relations in the pseudoternary system $ TbCr_{3} $($ BO_{3} $)4–$ K_{2} %$ Mo_{3} %$ O_{10} $–$ B_{2} %$ O_{3} $ have been studied in the temperature range 900–1130°C and the single-phase terbium chromium borate crystallization field has been mapped out. It has been shown that increasing the $ TbCr_{3} $($ BO_{3} $)4 content of the starting high-temperature solution leads to a rhombohedral-to-monoclinic phase transition. Using $ K_{2} %$ Mo_{3} %$ O_{10} $-based high-temperature solutions, we have grown single-phase $ TbCr_{3} $($ BO_{3} $)4 single crystals or crystals in which the rhombohedral phase (sp. gr. R32) significantly prevails over the monoclinic phase (sp. gr. C2/c). The grown crystals have been characterized by X-ray diffraction techniques, IR spectroscopy, and magnetic measurements. Maltsev, V. V. verfasserin aut Volkova, E. A. verfasserin aut Leonyuk, N. I. verfasserin aut Boldyrev, K. N. verfasserin aut Bludov, A. N. verfasserin aut Enthalten in Inorganic materials Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996 56(2020), 8 vom: Aug., Seite 828-835 (DE-627)334292719 (DE-600)2057339-X 1608-3172 nnns volume:56 year:2020 number:8 month:08 pages:828-835 https://dx.doi.org/10.1134/S0020168520080087 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.40 ASE AR 56 2020 8 08 828-835 |
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10.1134/S0020168520080087 doi (DE-627)SPR040828204 (SPR)S0020168520080087-e DE-627 ger DE-627 rakwb eng 540 600 670 ASE 35.40 bkl Kuzmin, N. N. verfasserin aut Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract— We have studied and optimized conditions for spontaneous flux growth of $ TbCr_{3} $($ BO_{3} $)4 crystals. Phase relations in the pseudoternary system $ TbCr_{3} $($ BO_{3} $)4–$ K_{2} %$ Mo_{3} %$ O_{10} $–$ B_{2} %$ O_{3} $ have been studied in the temperature range 900–1130°C and the single-phase terbium chromium borate crystallization field has been mapped out. It has been shown that increasing the $ TbCr_{3} $($ BO_{3} $)4 content of the starting high-temperature solution leads to a rhombohedral-to-monoclinic phase transition. Using $ K_{2} %$ Mo_{3} %$ O_{10} $-based high-temperature solutions, we have grown single-phase $ TbCr_{3} $($ BO_{3} $)4 single crystals or crystals in which the rhombohedral phase (sp. gr. R32) significantly prevails over the monoclinic phase (sp. gr. C2/c). The grown crystals have been characterized by X-ray diffraction techniques, IR spectroscopy, and magnetic measurements. Maltsev, V. V. verfasserin aut Volkova, E. A. verfasserin aut Leonyuk, N. I. verfasserin aut Boldyrev, K. N. verfasserin aut Bludov, A. N. verfasserin aut Enthalten in Inorganic materials Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996 56(2020), 8 vom: Aug., Seite 828-835 (DE-627)334292719 (DE-600)2057339-X 1608-3172 nnns volume:56 year:2020 number:8 month:08 pages:828-835 https://dx.doi.org/10.1134/S0020168520080087 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.40 ASE AR 56 2020 8 08 828-835 |
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Kuzmin, N. N. @@aut@@ Maltsev, V. V. @@aut@@ Volkova, E. A. @@aut@@ Leonyuk, N. I. @@aut@@ Boldyrev, K. N. @@aut@@ Bludov, A. N. @@aut@@ |
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N.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2020</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract— We have studied and optimized conditions for spontaneous flux growth of $ TbCr_{3} $($ BO_{3} $)4 crystals. Phase relations in the pseudoternary system $ TbCr_{3} $($ BO_{3} $)4–$ K_{2} %$ Mo_{3} %$ O_{10} $–$ B_{2} %$ O_{3} $ have been studied in the temperature range 900–1130°C and the single-phase terbium chromium borate crystallization field has been mapped out. It has been shown that increasing the $ TbCr_{3} $($ BO_{3} $)4 content of the starting high-temperature solution leads to a rhombohedral-to-monoclinic phase transition. Using $ K_{2} %$ Mo_{3} %$ O_{10} $-based high-temperature solutions, we have grown single-phase $ TbCr_{3} $($ BO_{3} $)4 single crystals or crystals in which the rhombohedral phase (sp. gr. R32) significantly prevails over the monoclinic phase (sp. gr. C2/c). The grown crystals have been characterized by X-ray diffraction techniques, IR spectroscopy, and magnetic measurements.</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Maltsev, V. 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Kuzmin, N. N. |
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Kuzmin, N. N. ddc 540 bkl 35.40 Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals |
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540 600 670 ASE 35.40 bkl Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals |
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Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals |
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Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals |
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Kuzmin, N. N. |
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Kuzmin, N. N. Maltsev, V. V. Volkova, E. A. Leonyuk, N. I. Boldyrev, K. N. Bludov, A. N. |
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Kuzmin, N. N. |
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growth and spectroscopic and magnetic properties of $ tbcr_{3} $($ bo_{3} $)4 crystals |
| title_auth |
Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals |
| abstract |
Abstract— We have studied and optimized conditions for spontaneous flux growth of $ TbCr_{3} $($ BO_{3} $)4 crystals. Phase relations in the pseudoternary system $ TbCr_{3} $($ BO_{3} $)4–$ K_{2} %$ Mo_{3} %$ O_{10} $–$ B_{2} %$ O_{3} $ have been studied in the temperature range 900–1130°C and the single-phase terbium chromium borate crystallization field has been mapped out. It has been shown that increasing the $ TbCr_{3} $($ BO_{3} $)4 content of the starting high-temperature solution leads to a rhombohedral-to-monoclinic phase transition. Using $ K_{2} %$ Mo_{3} %$ O_{10} $-based high-temperature solutions, we have grown single-phase $ TbCr_{3} $($ BO_{3} $)4 single crystals or crystals in which the rhombohedral phase (sp. gr. R32) significantly prevails over the monoclinic phase (sp. gr. C2/c). The grown crystals have been characterized by X-ray diffraction techniques, IR spectroscopy, and magnetic measurements. |
| abstractGer |
Abstract— We have studied and optimized conditions for spontaneous flux growth of $ TbCr_{3} $($ BO_{3} $)4 crystals. Phase relations in the pseudoternary system $ TbCr_{3} $($ BO_{3} $)4–$ K_{2} %$ Mo_{3} %$ O_{10} $–$ B_{2} %$ O_{3} $ have been studied in the temperature range 900–1130°C and the single-phase terbium chromium borate crystallization field has been mapped out. It has been shown that increasing the $ TbCr_{3} $($ BO_{3} $)4 content of the starting high-temperature solution leads to a rhombohedral-to-monoclinic phase transition. Using $ K_{2} %$ Mo_{3} %$ O_{10} $-based high-temperature solutions, we have grown single-phase $ TbCr_{3} $($ BO_{3} $)4 single crystals or crystals in which the rhombohedral phase (sp. gr. R32) significantly prevails over the monoclinic phase (sp. gr. C2/c). The grown crystals have been characterized by X-ray diffraction techniques, IR spectroscopy, and magnetic measurements. |
| abstract_unstemmed |
Abstract— We have studied and optimized conditions for spontaneous flux growth of $ TbCr_{3} $($ BO_{3} $)4 crystals. Phase relations in the pseudoternary system $ TbCr_{3} $($ BO_{3} $)4–$ K_{2} %$ Mo_{3} %$ O_{10} $–$ B_{2} %$ O_{3} $ have been studied in the temperature range 900–1130°C and the single-phase terbium chromium borate crystallization field has been mapped out. It has been shown that increasing the $ TbCr_{3} $($ BO_{3} $)4 content of the starting high-temperature solution leads to a rhombohedral-to-monoclinic phase transition. Using $ K_{2} %$ Mo_{3} %$ O_{10} $-based high-temperature solutions, we have grown single-phase $ TbCr_{3} $($ BO_{3} $)4 single crystals or crystals in which the rhombohedral phase (sp. gr. R32) significantly prevails over the monoclinic phase (sp. gr. C2/c). The grown crystals have been characterized by X-ray diffraction techniques, IR spectroscopy, and magnetic measurements. |
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| title_short |
Growth and Spectroscopic and Magnetic Properties of $ TbCr_{3} $($ BO_{3} $)4 Crystals |
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https://dx.doi.org/10.1134/S0020168520080087 |
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Maltsev, V. V. Volkova, E. A. Leonyuk, N. I. Boldyrev, K. N. Bludov, A. N. |
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Maltsev, V. V. Volkova, E. A. Leonyuk, N. I. Boldyrev, K. N. Bludov, A. N. |
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| doi_str |
10.1134/S0020168520080087 |
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2024-07-03T18:31:25.986Z |
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|
| score |
7.3996 |