Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles
Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Fiaz, Muhammad [verfasserIn] Athar, Muhammad [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2020 |
|---|
| Schlagwörter: |
|---|
| Übergeordnetes Werk: |
Enthalten in: Catalysis letters - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988, 150(2020), 11 vom: 30. Apr., Seite 3314-3326 |
|---|---|
| Übergeordnetes Werk: |
volume:150 ; year:2020 ; number:11 ; day:30 ; month:04 ; pages:3314-3326 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10562-020-03223-x |
|---|
| Katalog-ID: |
SPR040953971 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | SPR040953971 | ||
| 003 | DE-627 | ||
| 005 | 20230519065534.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 201007s2020 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1007/s10562-020-03223-x |2 doi | |
| 035 | |a (DE-627)SPR040953971 | ||
| 035 | |a (SPR)s10562-020-03223-x-e | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 540 |a 660 |q ASE |
| 084 | |a 35.17 |2 bkl | ||
| 100 | 1 | |a Fiaz, Muhammad |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles |
| 264 | 1 | |c 2020 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 520 | |a Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable amine functionalized MOF based bi-functional electrocatalyst CuO$ NH_{2} $-UiO-66 has been facilely synthesized via in-situ incorporation of pre-synthesized CuO nanoparticles into amine functionalized Zr-MOF $ NH_{2} $-UiO-66. It is observed that CuO@$ NH_{2} $-UiO-66 exhibits excellent bi-functional electrocatalytic activity towards HER as well as OER and delivers the benchmark of 10 mA $ cm^{−2} $ current density at just 166 and 283 mV overpotential, respectively, which is better than several previously, reported Cu-based, different transition metals and MOF based HER and OER catalysts. It also exhibits lower Tafel slope value 87 and 113 mV $ dec^{−1} $ towards HER and OER, respectively which indicates faster and better charge transfer during catalytic activity. CuO@$ NH_{2} $-UiO-66 exhibits significant stability and generates constant current density upto 6000 s during water electrolysis experiments. Furthermore, SEM and P-XRD techniques are used to investigate the stability of working electrode after the electrocatalytic studies and it is observed that CuO@$ NH_{2} $-UiO-66 maintains its integrity and chemical structure, after many hours of electrocatalytic activity. This study encourages the development of more earth abundant transition metals and MOFs based electrocatalysts for efficient electrochemical studies. Graphic Abstract | ||
| 650 | 4 | |a Metal–organic frameworks |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Water splitting |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Solvothermal |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Hydrogen evolution reaction |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Oxygen evolution reaction |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Athar, Muhammad |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Catalysis letters |d Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 |g 150(2020), 11 vom: 30. Apr., Seite 3314-3326 |w (DE-627)306717638 |w (DE-600)1501518-X |x 1572-879X |7 nnns |
| 773 | 1 | 8 | |g volume:150 |g year:2020 |g number:11 |g day:30 |g month:04 |g pages:3314-3326 |
| 856 | 4 | 0 | |u https://dx.doi.org/10.1007/s10562-020-03223-x |z lizenzpflichtig |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_SPRINGER | ||
| 912 | |a SSG-OLC-PHA | ||
| 912 | |a GBV_ILN_11 | ||
| 912 | |a GBV_ILN_20 | ||
| 912 | |a GBV_ILN_22 | ||
| 912 | |a GBV_ILN_23 | ||
| 912 | |a GBV_ILN_24 | ||
| 912 | |a GBV_ILN_31 | ||
| 912 | |a GBV_ILN_32 | ||
| 912 | |a GBV_ILN_39 | ||
| 912 | |a GBV_ILN_40 | ||
| 912 | |a GBV_ILN_60 | ||
| 912 | |a GBV_ILN_62 | ||
| 912 | |a GBV_ILN_63 | ||
| 912 | |a GBV_ILN_65 | ||
| 912 | |a GBV_ILN_69 | ||
| 912 | |a GBV_ILN_70 | ||
| 912 | |a GBV_ILN_73 | ||
| 912 | |a GBV_ILN_74 | ||
| 912 | |a GBV_ILN_90 | ||
| 912 | |a GBV_ILN_95 | ||
| 912 | |a GBV_ILN_100 | ||
| 912 | |a GBV_ILN_101 | ||
| 912 | |a GBV_ILN_105 | ||
| 912 | |a GBV_ILN_110 | ||
| 912 | |a GBV_ILN_120 | ||
| 912 | |a GBV_ILN_138 | ||
| 912 | |a GBV_ILN_150 | ||
| 912 | |a GBV_ILN_151 | ||
| 912 | |a GBV_ILN_152 | ||
| 912 | |a GBV_ILN_161 | ||
| 912 | |a GBV_ILN_170 | ||
| 912 | |a GBV_ILN_171 | ||
| 912 | |a GBV_ILN_187 | ||
| 912 | |a GBV_ILN_213 | ||
| 912 | |a GBV_ILN_224 | ||
| 912 | |a GBV_ILN_230 | ||
| 912 | |a GBV_ILN_250 | ||
| 912 | |a GBV_ILN_281 | ||
| 912 | |a GBV_ILN_285 | ||
| 912 | |a GBV_ILN_293 | ||
| 912 | |a GBV_ILN_370 | ||
| 912 | |a GBV_ILN_602 | ||
| 912 | |a GBV_ILN_636 | ||
| 912 | |a GBV_ILN_702 | ||
| 912 | |a GBV_ILN_2001 | ||
| 912 | |a GBV_ILN_2003 | ||
| 912 | |a GBV_ILN_2004 | ||
| 912 | |a GBV_ILN_2005 | ||
| 912 | |a GBV_ILN_2006 | ||
| 912 | |a GBV_ILN_2007 | ||
| 912 | |a GBV_ILN_2008 | ||
| 912 | |a GBV_ILN_2009 | ||
| 912 | |a GBV_ILN_2010 | ||
| 912 | |a GBV_ILN_2011 | ||
| 912 | |a GBV_ILN_2014 | ||
| 912 | |a GBV_ILN_2015 | ||
| 912 | |a GBV_ILN_2020 | ||
| 912 | |a GBV_ILN_2021 | ||
| 912 | |a GBV_ILN_2025 | ||
| 912 | |a GBV_ILN_2026 | ||
| 912 | |a GBV_ILN_2027 | ||
| 912 | |a GBV_ILN_2031 | ||
| 912 | |a GBV_ILN_2034 | ||
| 912 | |a GBV_ILN_2037 | ||
| 912 | |a GBV_ILN_2038 | ||
| 912 | |a GBV_ILN_2039 | ||
| 912 | |a GBV_ILN_2044 | ||
| 912 | |a GBV_ILN_2048 | ||
| 912 | |a GBV_ILN_2049 | ||
| 912 | |a GBV_ILN_2050 | ||
| 912 | |a GBV_ILN_2055 | ||
| 912 | |a GBV_ILN_2056 | ||
| 912 | |a GBV_ILN_2057 | ||
| 912 | |a GBV_ILN_2059 | ||
| 912 | |a GBV_ILN_2061 | ||
| 912 | |a GBV_ILN_2064 | ||
| 912 | |a GBV_ILN_2065 | ||
| 912 | |a GBV_ILN_2068 | ||
| 912 | |a GBV_ILN_2088 | ||
| 912 | |a GBV_ILN_2093 | ||
| 912 | |a GBV_ILN_2106 | ||
| 912 | |a GBV_ILN_2107 | ||
| 912 | |a GBV_ILN_2108 | ||
| 912 | |a GBV_ILN_2110 | ||
| 912 | |a GBV_ILN_2111 | ||
| 912 | |a GBV_ILN_2112 | ||
| 912 | |a GBV_ILN_2113 | ||
| 912 | |a GBV_ILN_2118 | ||
| 912 | |a GBV_ILN_2122 | ||
| 912 | |a GBV_ILN_2129 | ||
| 912 | |a GBV_ILN_2143 | ||
| 912 | |a GBV_ILN_2144 | ||
| 912 | |a GBV_ILN_2147 | ||
| 912 | |a GBV_ILN_2148 | ||
| 912 | |a GBV_ILN_2152 | ||
| 912 | |a GBV_ILN_2153 | ||
| 912 | |a GBV_ILN_2188 | ||
| 912 | |a GBV_ILN_2190 | ||
| 912 | |a GBV_ILN_2232 | ||
| 912 | |a GBV_ILN_2336 | ||
| 912 | |a GBV_ILN_2446 | ||
| 912 | |a GBV_ILN_2470 | ||
| 912 | |a GBV_ILN_2472 | ||
| 912 | |a GBV_ILN_2507 | ||
| 912 | |a GBV_ILN_2522 | ||
| 912 | |a GBV_ILN_2548 | ||
| 912 | |a GBV_ILN_4035 | ||
| 912 | |a GBV_ILN_4037 | ||
| 912 | |a GBV_ILN_4046 | ||
| 912 | |a GBV_ILN_4112 | ||
| 912 | |a GBV_ILN_4125 | ||
| 912 | |a GBV_ILN_4126 | ||
| 912 | |a GBV_ILN_4242 | ||
| 912 | |a GBV_ILN_4246 | ||
| 912 | |a GBV_ILN_4249 | ||
| 912 | |a GBV_ILN_4251 | ||
| 912 | |a GBV_ILN_4305 | ||
| 912 | |a GBV_ILN_4306 | ||
| 912 | |a GBV_ILN_4307 | ||
| 912 | |a GBV_ILN_4313 | ||
| 912 | |a GBV_ILN_4322 | ||
| 912 | |a GBV_ILN_4323 | ||
| 912 | |a GBV_ILN_4324 | ||
| 912 | |a GBV_ILN_4325 | ||
| 912 | |a GBV_ILN_4326 | ||
| 912 | |a GBV_ILN_4328 | ||
| 912 | |a GBV_ILN_4333 | ||
| 912 | |a GBV_ILN_4334 | ||
| 912 | |a GBV_ILN_4335 | ||
| 912 | |a GBV_ILN_4336 | ||
| 912 | |a GBV_ILN_4338 | ||
| 912 | |a GBV_ILN_4393 | ||
| 912 | |a GBV_ILN_4700 | ||
| 936 | b | k | |a 35.17 |q ASE |
| 951 | |a AR | ||
| 952 | |d 150 |j 2020 |e 11 |b 30 |c 04 |h 3314-3326 | ||
| author_variant |
m f mf m a ma |
|---|---|
| matchkey_str |
article:1572879X:2020----::nacnteyrgnnoyeeouinecinfiinyfmnfntoaiemfh2i6v |
| hierarchy_sort_str |
2020 |
| bklnumber |
35.17 |
| publishDate |
2020 |
| allfields |
10.1007/s10562-020-03223-x doi (DE-627)SPR040953971 (SPR)s10562-020-03223-x-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Fiaz, Muhammad verfasserin aut Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable amine functionalized MOF based bi-functional electrocatalyst CuO$ NH_{2} $-UiO-66 has been facilely synthesized via in-situ incorporation of pre-synthesized CuO nanoparticles into amine functionalized Zr-MOF $ NH_{2} $-UiO-66. It is observed that CuO@$ NH_{2} $-UiO-66 exhibits excellent bi-functional electrocatalytic activity towards HER as well as OER and delivers the benchmark of 10 mA $ cm^{−2} $ current density at just 166 and 283 mV overpotential, respectively, which is better than several previously, reported Cu-based, different transition metals and MOF based HER and OER catalysts. It also exhibits lower Tafel slope value 87 and 113 mV $ dec^{−1} $ towards HER and OER, respectively which indicates faster and better charge transfer during catalytic activity. CuO@$ NH_{2} $-UiO-66 exhibits significant stability and generates constant current density upto 6000 s during water electrolysis experiments. Furthermore, SEM and P-XRD techniques are used to investigate the stability of working electrode after the electrocatalytic studies and it is observed that CuO@$ NH_{2} $-UiO-66 maintains its integrity and chemical structure, after many hours of electrocatalytic activity. This study encourages the development of more earth abundant transition metals and MOFs based electrocatalysts for efficient electrochemical studies. Graphic Abstract Metal–organic frameworks (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Solvothermal (dpeaa)DE-He213 Hydrogen evolution reaction (dpeaa)DE-He213 Oxygen evolution reaction (dpeaa)DE-He213 Athar, Muhammad verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 150(2020), 11 vom: 30. Apr., Seite 3314-3326 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:150 year:2020 number:11 day:30 month:04 pages:3314-3326 https://dx.doi.org/10.1007/s10562-020-03223-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 150 2020 11 30 04 3314-3326 |
| spelling |
10.1007/s10562-020-03223-x doi (DE-627)SPR040953971 (SPR)s10562-020-03223-x-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Fiaz, Muhammad verfasserin aut Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable amine functionalized MOF based bi-functional electrocatalyst CuO$ NH_{2} $-UiO-66 has been facilely synthesized via in-situ incorporation of pre-synthesized CuO nanoparticles into amine functionalized Zr-MOF $ NH_{2} $-UiO-66. It is observed that CuO@$ NH_{2} $-UiO-66 exhibits excellent bi-functional electrocatalytic activity towards HER as well as OER and delivers the benchmark of 10 mA $ cm^{−2} $ current density at just 166 and 283 mV overpotential, respectively, which is better than several previously, reported Cu-based, different transition metals and MOF based HER and OER catalysts. It also exhibits lower Tafel slope value 87 and 113 mV $ dec^{−1} $ towards HER and OER, respectively which indicates faster and better charge transfer during catalytic activity. CuO@$ NH_{2} $-UiO-66 exhibits significant stability and generates constant current density upto 6000 s during water electrolysis experiments. Furthermore, SEM and P-XRD techniques are used to investigate the stability of working electrode after the electrocatalytic studies and it is observed that CuO@$ NH_{2} $-UiO-66 maintains its integrity and chemical structure, after many hours of electrocatalytic activity. This study encourages the development of more earth abundant transition metals and MOFs based electrocatalysts for efficient electrochemical studies. Graphic Abstract Metal–organic frameworks (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Solvothermal (dpeaa)DE-He213 Hydrogen evolution reaction (dpeaa)DE-He213 Oxygen evolution reaction (dpeaa)DE-He213 Athar, Muhammad verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 150(2020), 11 vom: 30. Apr., Seite 3314-3326 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:150 year:2020 number:11 day:30 month:04 pages:3314-3326 https://dx.doi.org/10.1007/s10562-020-03223-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 150 2020 11 30 04 3314-3326 |
| allfields_unstemmed |
10.1007/s10562-020-03223-x doi (DE-627)SPR040953971 (SPR)s10562-020-03223-x-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Fiaz, Muhammad verfasserin aut Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable amine functionalized MOF based bi-functional electrocatalyst CuO$ NH_{2} $-UiO-66 has been facilely synthesized via in-situ incorporation of pre-synthesized CuO nanoparticles into amine functionalized Zr-MOF $ NH_{2} $-UiO-66. It is observed that CuO@$ NH_{2} $-UiO-66 exhibits excellent bi-functional electrocatalytic activity towards HER as well as OER and delivers the benchmark of 10 mA $ cm^{−2} $ current density at just 166 and 283 mV overpotential, respectively, which is better than several previously, reported Cu-based, different transition metals and MOF based HER and OER catalysts. It also exhibits lower Tafel slope value 87 and 113 mV $ dec^{−1} $ towards HER and OER, respectively which indicates faster and better charge transfer during catalytic activity. CuO@$ NH_{2} $-UiO-66 exhibits significant stability and generates constant current density upto 6000 s during water electrolysis experiments. Furthermore, SEM and P-XRD techniques are used to investigate the stability of working electrode after the electrocatalytic studies and it is observed that CuO@$ NH_{2} $-UiO-66 maintains its integrity and chemical structure, after many hours of electrocatalytic activity. This study encourages the development of more earth abundant transition metals and MOFs based electrocatalysts for efficient electrochemical studies. Graphic Abstract Metal–organic frameworks (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Solvothermal (dpeaa)DE-He213 Hydrogen evolution reaction (dpeaa)DE-He213 Oxygen evolution reaction (dpeaa)DE-He213 Athar, Muhammad verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 150(2020), 11 vom: 30. Apr., Seite 3314-3326 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:150 year:2020 number:11 day:30 month:04 pages:3314-3326 https://dx.doi.org/10.1007/s10562-020-03223-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 150 2020 11 30 04 3314-3326 |
| allfieldsGer |
10.1007/s10562-020-03223-x doi (DE-627)SPR040953971 (SPR)s10562-020-03223-x-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Fiaz, Muhammad verfasserin aut Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable amine functionalized MOF based bi-functional electrocatalyst CuO$ NH_{2} $-UiO-66 has been facilely synthesized via in-situ incorporation of pre-synthesized CuO nanoparticles into amine functionalized Zr-MOF $ NH_{2} $-UiO-66. It is observed that CuO@$ NH_{2} $-UiO-66 exhibits excellent bi-functional electrocatalytic activity towards HER as well as OER and delivers the benchmark of 10 mA $ cm^{−2} $ current density at just 166 and 283 mV overpotential, respectively, which is better than several previously, reported Cu-based, different transition metals and MOF based HER and OER catalysts. It also exhibits lower Tafel slope value 87 and 113 mV $ dec^{−1} $ towards HER and OER, respectively which indicates faster and better charge transfer during catalytic activity. CuO@$ NH_{2} $-UiO-66 exhibits significant stability and generates constant current density upto 6000 s during water electrolysis experiments. Furthermore, SEM and P-XRD techniques are used to investigate the stability of working electrode after the electrocatalytic studies and it is observed that CuO@$ NH_{2} $-UiO-66 maintains its integrity and chemical structure, after many hours of electrocatalytic activity. This study encourages the development of more earth abundant transition metals and MOFs based electrocatalysts for efficient electrochemical studies. Graphic Abstract Metal–organic frameworks (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Solvothermal (dpeaa)DE-He213 Hydrogen evolution reaction (dpeaa)DE-He213 Oxygen evolution reaction (dpeaa)DE-He213 Athar, Muhammad verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 150(2020), 11 vom: 30. Apr., Seite 3314-3326 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:150 year:2020 number:11 day:30 month:04 pages:3314-3326 https://dx.doi.org/10.1007/s10562-020-03223-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 150 2020 11 30 04 3314-3326 |
| allfieldsSound |
10.1007/s10562-020-03223-x doi (DE-627)SPR040953971 (SPR)s10562-020-03223-x-e DE-627 ger DE-627 rakwb eng 540 660 ASE 35.17 bkl Fiaz, Muhammad verfasserin aut Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable amine functionalized MOF based bi-functional electrocatalyst CuO$ NH_{2} $-UiO-66 has been facilely synthesized via in-situ incorporation of pre-synthesized CuO nanoparticles into amine functionalized Zr-MOF $ NH_{2} $-UiO-66. It is observed that CuO@$ NH_{2} $-UiO-66 exhibits excellent bi-functional electrocatalytic activity towards HER as well as OER and delivers the benchmark of 10 mA $ cm^{−2} $ current density at just 166 and 283 mV overpotential, respectively, which is better than several previously, reported Cu-based, different transition metals and MOF based HER and OER catalysts. It also exhibits lower Tafel slope value 87 and 113 mV $ dec^{−1} $ towards HER and OER, respectively which indicates faster and better charge transfer during catalytic activity. CuO@$ NH_{2} $-UiO-66 exhibits significant stability and generates constant current density upto 6000 s during water electrolysis experiments. Furthermore, SEM and P-XRD techniques are used to investigate the stability of working electrode after the electrocatalytic studies and it is observed that CuO@$ NH_{2} $-UiO-66 maintains its integrity and chemical structure, after many hours of electrocatalytic activity. This study encourages the development of more earth abundant transition metals and MOFs based electrocatalysts for efficient electrochemical studies. Graphic Abstract Metal–organic frameworks (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Solvothermal (dpeaa)DE-He213 Hydrogen evolution reaction (dpeaa)DE-He213 Oxygen evolution reaction (dpeaa)DE-He213 Athar, Muhammad verfasserin aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 150(2020), 11 vom: 30. Apr., Seite 3314-3326 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:150 year:2020 number:11 day:30 month:04 pages:3314-3326 https://dx.doi.org/10.1007/s10562-020-03223-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.17 ASE AR 150 2020 11 30 04 3314-3326 |
| language |
English |
| source |
Enthalten in Catalysis letters 150(2020), 11 vom: 30. Apr., Seite 3314-3326 volume:150 year:2020 number:11 day:30 month:04 pages:3314-3326 |
| sourceStr |
Enthalten in Catalysis letters 150(2020), 11 vom: 30. Apr., Seite 3314-3326 volume:150 year:2020 number:11 day:30 month:04 pages:3314-3326 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
Metal–organic frameworks Water splitting Solvothermal Hydrogen evolution reaction Oxygen evolution reaction |
| dewey-raw |
540 |
| isfreeaccess_bool |
false |
| container_title |
Catalysis letters |
| authorswithroles_txt_mv |
Fiaz, Muhammad @@aut@@ Athar, Muhammad @@aut@@ |
| publishDateDaySort_date |
2020-04-30T00:00:00Z |
| hierarchy_top_id |
306717638 |
| dewey-sort |
3540 |
| id |
SPR040953971 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR040953971</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519065534.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201007s2020 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10562-020-03223-x</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR040953971</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10562-020-03223-x-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="a">660</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.17</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Fiaz, Muhammad</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2020</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable amine functionalized MOF based bi-functional electrocatalyst CuO$ NH_{2} $-UiO-66 has been facilely synthesized via in-situ incorporation of pre-synthesized CuO nanoparticles into amine functionalized Zr-MOF $ NH_{2} $-UiO-66. It is observed that CuO@$ NH_{2} $-UiO-66 exhibits excellent bi-functional electrocatalytic activity towards HER as well as OER and delivers the benchmark of 10 mA $ cm^{−2} $ current density at just 166 and 283 mV overpotential, respectively, which is better than several previously, reported Cu-based, different transition metals and MOF based HER and OER catalysts. It also exhibits lower Tafel slope value 87 and 113 mV $ dec^{−1} $ towards HER and OER, respectively which indicates faster and better charge transfer during catalytic activity. CuO@$ NH_{2} $-UiO-66 exhibits significant stability and generates constant current density upto 6000 s during water electrolysis experiments. Furthermore, SEM and P-XRD techniques are used to investigate the stability of working electrode after the electrocatalytic studies and it is observed that CuO@$ NH_{2} $-UiO-66 maintains its integrity and chemical structure, after many hours of electrocatalytic activity. This study encourages the development of more earth abundant transition metals and MOFs based electrocatalysts for efficient electrochemical studies. Graphic Abstract</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Metal–organic frameworks</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Water splitting</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Solvothermal</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hydrogen evolution reaction</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxygen evolution reaction</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Athar, Muhammad</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Catalysis letters</subfield><subfield code="d">Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988</subfield><subfield code="g">150(2020), 11 vom: 30. Apr., Seite 3314-3326</subfield><subfield code="w">(DE-627)306717638</subfield><subfield code="w">(DE-600)1501518-X</subfield><subfield code="x">1572-879X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:150</subfield><subfield code="g">year:2020</subfield><subfield code="g">number:11</subfield><subfield code="g">day:30</subfield><subfield code="g">month:04</subfield><subfield code="g">pages:3314-3326</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s10562-020-03223-x</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_101</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4328</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.17</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">150</subfield><subfield code="j">2020</subfield><subfield code="e">11</subfield><subfield code="b">30</subfield><subfield code="c">04</subfield><subfield code="h">3314-3326</subfield></datafield></record></collection>
|
| author |
Fiaz, Muhammad |
| spellingShingle |
Fiaz, Muhammad ddc 540 bkl 35.17 misc Metal–organic frameworks misc Water splitting misc Solvothermal misc Hydrogen evolution reaction misc Oxygen evolution reaction Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles |
| authorStr |
Fiaz, Muhammad |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)306717638 |
| format |
electronic Article |
| dewey-ones |
540 - Chemistry & allied sciences 660 - Chemical engineering |
| delete_txt_mv |
keep |
| author_role |
aut aut |
| collection |
springer |
| remote_str |
true |
| illustrated |
Not Illustrated |
| issn |
1572-879X |
| topic_title |
540 660 ASE 35.17 bkl Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles Metal–organic frameworks (dpeaa)DE-He213 Water splitting (dpeaa)DE-He213 Solvothermal (dpeaa)DE-He213 Hydrogen evolution reaction (dpeaa)DE-He213 Oxygen evolution reaction (dpeaa)DE-He213 |
| topic |
ddc 540 bkl 35.17 misc Metal–organic frameworks misc Water splitting misc Solvothermal misc Hydrogen evolution reaction misc Oxygen evolution reaction |
| topic_unstemmed |
ddc 540 bkl 35.17 misc Metal–organic frameworks misc Water splitting misc Solvothermal misc Hydrogen evolution reaction misc Oxygen evolution reaction |
| topic_browse |
ddc 540 bkl 35.17 misc Metal–organic frameworks misc Water splitting misc Solvothermal misc Hydrogen evolution reaction misc Oxygen evolution reaction |
| format_facet |
Elektronische Aufsätze Aufsätze Elektronische Ressource |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
cr |
| hierarchy_parent_title |
Catalysis letters |
| hierarchy_parent_id |
306717638 |
| dewey-tens |
540 - Chemistry 660 - Chemical engineering |
| hierarchy_top_title |
Catalysis letters |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)306717638 (DE-600)1501518-X |
| title |
Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles |
| ctrlnum |
(DE-627)SPR040953971 (SPR)s10562-020-03223-x-e |
| title_full |
Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles |
| author_sort |
Fiaz, Muhammad |
| journal |
Catalysis letters |
| journalStr |
Catalysis letters |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
500 - Science 600 - Technology |
| recordtype |
marc |
| publishDateSort |
2020 |
| contenttype_str_mv |
txt |
| container_start_page |
3314 |
| author_browse |
Fiaz, Muhammad Athar, Muhammad |
| container_volume |
150 |
| class |
540 660 ASE 35.17 bkl |
| format_se |
Elektronische Aufsätze |
| author-letter |
Fiaz, Muhammad |
| doi_str_mv |
10.1007/s10562-020-03223-x |
| dewey-full |
540 660 |
| author2-role |
verfasserin |
| title_sort |
enhancing the hydrogen and oxygen evolution reaction efficiency of amine functionalized mof $ nh_{2} $-uio-66 via incorporation of cuo nanoparticles |
| title_auth |
Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles |
| abstract |
Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable amine functionalized MOF based bi-functional electrocatalyst CuO$ NH_{2} $-UiO-66 has been facilely synthesized via in-situ incorporation of pre-synthesized CuO nanoparticles into amine functionalized Zr-MOF $ NH_{2} $-UiO-66. It is observed that CuO@$ NH_{2} $-UiO-66 exhibits excellent bi-functional electrocatalytic activity towards HER as well as OER and delivers the benchmark of 10 mA $ cm^{−2} $ current density at just 166 and 283 mV overpotential, respectively, which is better than several previously, reported Cu-based, different transition metals and MOF based HER and OER catalysts. It also exhibits lower Tafel slope value 87 and 113 mV $ dec^{−1} $ towards HER and OER, respectively which indicates faster and better charge transfer during catalytic activity. CuO@$ NH_{2} $-UiO-66 exhibits significant stability and generates constant current density upto 6000 s during water electrolysis experiments. Furthermore, SEM and P-XRD techniques are used to investigate the stability of working electrode after the electrocatalytic studies and it is observed that CuO@$ NH_{2} $-UiO-66 maintains its integrity and chemical structure, after many hours of electrocatalytic activity. This study encourages the development of more earth abundant transition metals and MOFs based electrocatalysts for efficient electrochemical studies. Graphic Abstract |
| abstractGer |
Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable amine functionalized MOF based bi-functional electrocatalyst CuO$ NH_{2} $-UiO-66 has been facilely synthesized via in-situ incorporation of pre-synthesized CuO nanoparticles into amine functionalized Zr-MOF $ NH_{2} $-UiO-66. It is observed that CuO@$ NH_{2} $-UiO-66 exhibits excellent bi-functional electrocatalytic activity towards HER as well as OER and delivers the benchmark of 10 mA $ cm^{−2} $ current density at just 166 and 283 mV overpotential, respectively, which is better than several previously, reported Cu-based, different transition metals and MOF based HER and OER catalysts. It also exhibits lower Tafel slope value 87 and 113 mV $ dec^{−1} $ towards HER and OER, respectively which indicates faster and better charge transfer during catalytic activity. CuO@$ NH_{2} $-UiO-66 exhibits significant stability and generates constant current density upto 6000 s during water electrolysis experiments. Furthermore, SEM and P-XRD techniques are used to investigate the stability of working electrode after the electrocatalytic studies and it is observed that CuO@$ NH_{2} $-UiO-66 maintains its integrity and chemical structure, after many hours of electrocatalytic activity. This study encourages the development of more earth abundant transition metals and MOFs based electrocatalysts for efficient electrochemical studies. Graphic Abstract |
| abstract_unstemmed |
Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable amine functionalized MOF based bi-functional electrocatalyst CuO$ NH_{2} $-UiO-66 has been facilely synthesized via in-situ incorporation of pre-synthesized CuO nanoparticles into amine functionalized Zr-MOF $ NH_{2} $-UiO-66. It is observed that CuO@$ NH_{2} $-UiO-66 exhibits excellent bi-functional electrocatalytic activity towards HER as well as OER and delivers the benchmark of 10 mA $ cm^{−2} $ current density at just 166 and 283 mV overpotential, respectively, which is better than several previously, reported Cu-based, different transition metals and MOF based HER and OER catalysts. It also exhibits lower Tafel slope value 87 and 113 mV $ dec^{−1} $ towards HER and OER, respectively which indicates faster and better charge transfer during catalytic activity. CuO@$ NH_{2} $-UiO-66 exhibits significant stability and generates constant current density upto 6000 s during water electrolysis experiments. Furthermore, SEM and P-XRD techniques are used to investigate the stability of working electrode after the electrocatalytic studies and it is observed that CuO@$ NH_{2} $-UiO-66 maintains its integrity and chemical structure, after many hours of electrocatalytic activity. This study encourages the development of more earth abundant transition metals and MOFs based electrocatalysts for efficient electrochemical studies. Graphic Abstract |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 |
| container_issue |
11 |
| title_short |
Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles |
| url |
https://dx.doi.org/10.1007/s10562-020-03223-x |
| remote_bool |
true |
| author2 |
Athar, Muhammad |
| author2Str |
Athar, Muhammad |
| ppnlink |
306717638 |
| mediatype_str_mv |
c |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1007/s10562-020-03223-x |
| up_date |
2024-07-03T19:19:41.199Z |
| _version_ |
1803586771309559809 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR040953971</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519065534.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201007s2020 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10562-020-03223-x</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR040953971</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10562-020-03223-x-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="a">660</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.17</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Fiaz, Muhammad</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Enhancing the Hydrogen and Oxygen Evolution Reaction Efficiency of Amine Functionalized MOF $ NH_{2} $-UiO-66 via Incorporation of CuO Nanoparticles</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2020</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Development of highly efficient and stable bi-functional electrocatalyst towards both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by engaging the earth abundant precursors has attracted much research attention. In this study, a highly efficient, durable and stable amine functionalized MOF based bi-functional electrocatalyst CuO$ NH_{2} $-UiO-66 has been facilely synthesized via in-situ incorporation of pre-synthesized CuO nanoparticles into amine functionalized Zr-MOF $ NH_{2} $-UiO-66. It is observed that CuO@$ NH_{2} $-UiO-66 exhibits excellent bi-functional electrocatalytic activity towards HER as well as OER and delivers the benchmark of 10 mA $ cm^{−2} $ current density at just 166 and 283 mV overpotential, respectively, which is better than several previously, reported Cu-based, different transition metals and MOF based HER and OER catalysts. It also exhibits lower Tafel slope value 87 and 113 mV $ dec^{−1} $ towards HER and OER, respectively which indicates faster and better charge transfer during catalytic activity. CuO@$ NH_{2} $-UiO-66 exhibits significant stability and generates constant current density upto 6000 s during water electrolysis experiments. Furthermore, SEM and P-XRD techniques are used to investigate the stability of working electrode after the electrocatalytic studies and it is observed that CuO@$ NH_{2} $-UiO-66 maintains its integrity and chemical structure, after many hours of electrocatalytic activity. This study encourages the development of more earth abundant transition metals and MOFs based electrocatalysts for efficient electrochemical studies. Graphic Abstract</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Metal–organic frameworks</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Water splitting</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Solvothermal</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hydrogen evolution reaction</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxygen evolution reaction</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Athar, Muhammad</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Catalysis letters</subfield><subfield code="d">Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988</subfield><subfield code="g">150(2020), 11 vom: 30. Apr., Seite 3314-3326</subfield><subfield code="w">(DE-627)306717638</subfield><subfield code="w">(DE-600)1501518-X</subfield><subfield code="x">1572-879X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:150</subfield><subfield code="g">year:2020</subfield><subfield code="g">number:11</subfield><subfield code="g">day:30</subfield><subfield code="g">month:04</subfield><subfield code="g">pages:3314-3326</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s10562-020-03223-x</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_101</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4328</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.17</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">150</subfield><subfield code="j">2020</subfield><subfield code="e">11</subfield><subfield code="b">30</subfield><subfield code="c">04</subfield><subfield code="h">3314-3326</subfield></datafield></record></collection>
|
| score |
7.3989124 |