Silver Clusters Stabilized by Fe(Co)4 Ligands
Abstract The reaction of [Fe(CO)4]2- with $ Ag^{+} $ in tetrahydrofuran or acetonitrile solution affords a series of silver clusters stabilized by Fe(CO)4 pseudo-ligands, formally arising from oligomerization of [AgFe(CO)4]- and their subsequent condensation with $ Ag^{+/O/-} $. The [$ Ag_{4} %$ Fe_...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Albano, Vincenzo G. [verfasserIn] Azzaroni, Fabrizio [verfasserIn] Iapalucci, Maria Carmela [verfasserIn] Longoni, Giuliano [verfasserIn] Monari, Magda [verfasserIn] Mulley, Suzanne [verfasserIn] |
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| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
1992 |
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| Übergeordnetes Werk: |
Enthalten in: MRS online proceedings library - Warrendale, Pa. : MRS, 1998, 272(1992), 1 vom: 15. Mai, Seite 115-125 |
|---|---|
| Übergeordnetes Werk: |
volume:272 ; year:1992 ; number:1 ; day:15 ; month:05 ; pages:115-125 |
| Links: |
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| DOI / URN: |
10.1557/PROC-272-115 |
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SPR041796608 |
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| 520 | |a Abstract The reaction of [Fe(CO)4]2- with $ Ag^{+} $ in tetrahydrofuran or acetonitrile solution affords a series of silver clusters stabilized by Fe(CO)4 pseudo-ligands, formally arising from oligomerization of [AgFe(CO)4]- and their subsequent condensation with $ Ag^{+/O/-} $. The [$ Ag_{4} %$ Fe_{4} $(CO)16]4-, [$ Ag_{5} %$ Fe_{4} $(CO)16]3-, and [$ Ag_{13} %$ Fe_{8} $(CO)32]4- anions have been structurally characterized by X ray studies, while the formulation of all the remaining species is presently based on analytical and spectroscopic characterization, as well as their chemical behavior. Attempts to isolate the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- salts in a crystalline state were unsuccessful due to their ready oligomerization to completely insoluble material of [($ Ag^{+} $)n{[$ Ag_{6} %$ Fe_{4} $(CO)16]2-}n+1](n+2)- composition. This material is depolymerized by dimethylsulfoxide or by addition of stoichiometric amounts of amines and, upon dissolution, gives the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- dianion. | ||
| 700 | 1 | |a Azzaroni, Fabrizio |e verfasserin |4 aut | |
| 700 | 1 | |a Iapalucci, Maria Carmela |e verfasserin |4 aut | |
| 700 | 1 | |a Longoni, Giuliano |e verfasserin |4 aut | |
| 700 | 1 | |a Monari, Magda |e verfasserin |4 aut | |
| 700 | 1 | |a Mulley, Suzanne |e verfasserin |4 aut | |
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10.1557/PROC-272-115 doi (DE-627)SPR041796608 (SPR)PROC-272-115-e DE-627 ger DE-627 rakwb eng 670 ASE Albano, Vincenzo G. verfasserin aut Silver Clusters Stabilized by Fe(Co)4 Ligands 1992 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of [Fe(CO)4]2- with $ Ag^{+} $ in tetrahydrofuran or acetonitrile solution affords a series of silver clusters stabilized by Fe(CO)4 pseudo-ligands, formally arising from oligomerization of [AgFe(CO)4]- and their subsequent condensation with $ Ag^{+/O/-} $. The [$ Ag_{4} %$ Fe_{4} $(CO)16]4-, [$ Ag_{5} %$ Fe_{4} $(CO)16]3-, and [$ Ag_{13} %$ Fe_{8} $(CO)32]4- anions have been structurally characterized by X ray studies, while the formulation of all the remaining species is presently based on analytical and spectroscopic characterization, as well as their chemical behavior. Attempts to isolate the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- salts in a crystalline state were unsuccessful due to their ready oligomerization to completely insoluble material of [($ Ag^{+} $)n{[$ Ag_{6} %$ Fe_{4} $(CO)16]2-}n+1](n+2)- composition. This material is depolymerized by dimethylsulfoxide or by addition of stoichiometric amounts of amines and, upon dissolution, gives the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- dianion. Azzaroni, Fabrizio verfasserin aut Iapalucci, Maria Carmela verfasserin aut Longoni, Giuliano verfasserin aut Monari, Magda verfasserin aut Mulley, Suzanne verfasserin aut Enthalten in MRS online proceedings library Warrendale, Pa. : MRS, 1998 272(1992), 1 vom: 15. Mai, Seite 115-125 (DE-627)57782046X (DE-600)2451008-7 1946-4274 nnns volume:272 year:1992 number:1 day:15 month:05 pages:115-125 https://dx.doi.org/10.1557/PROC-272-115 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_2005 AR 272 1992 1 15 05 115-125 |
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10.1557/PROC-272-115 doi (DE-627)SPR041796608 (SPR)PROC-272-115-e DE-627 ger DE-627 rakwb eng 670 ASE Albano, Vincenzo G. verfasserin aut Silver Clusters Stabilized by Fe(Co)4 Ligands 1992 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of [Fe(CO)4]2- with $ Ag^{+} $ in tetrahydrofuran or acetonitrile solution affords a series of silver clusters stabilized by Fe(CO)4 pseudo-ligands, formally arising from oligomerization of [AgFe(CO)4]- and their subsequent condensation with $ Ag^{+/O/-} $. The [$ Ag_{4} %$ Fe_{4} $(CO)16]4-, [$ Ag_{5} %$ Fe_{4} $(CO)16]3-, and [$ Ag_{13} %$ Fe_{8} $(CO)32]4- anions have been structurally characterized by X ray studies, while the formulation of all the remaining species is presently based on analytical and spectroscopic characterization, as well as their chemical behavior. Attempts to isolate the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- salts in a crystalline state were unsuccessful due to their ready oligomerization to completely insoluble material of [($ Ag^{+} $)n{[$ Ag_{6} %$ Fe_{4} $(CO)16]2-}n+1](n+2)- composition. This material is depolymerized by dimethylsulfoxide or by addition of stoichiometric amounts of amines and, upon dissolution, gives the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- dianion. Azzaroni, Fabrizio verfasserin aut Iapalucci, Maria Carmela verfasserin aut Longoni, Giuliano verfasserin aut Monari, Magda verfasserin aut Mulley, Suzanne verfasserin aut Enthalten in MRS online proceedings library Warrendale, Pa. : MRS, 1998 272(1992), 1 vom: 15. Mai, Seite 115-125 (DE-627)57782046X (DE-600)2451008-7 1946-4274 nnns volume:272 year:1992 number:1 day:15 month:05 pages:115-125 https://dx.doi.org/10.1557/PROC-272-115 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_2005 AR 272 1992 1 15 05 115-125 |
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10.1557/PROC-272-115 doi (DE-627)SPR041796608 (SPR)PROC-272-115-e DE-627 ger DE-627 rakwb eng 670 ASE Albano, Vincenzo G. verfasserin aut Silver Clusters Stabilized by Fe(Co)4 Ligands 1992 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of [Fe(CO)4]2- with $ Ag^{+} $ in tetrahydrofuran or acetonitrile solution affords a series of silver clusters stabilized by Fe(CO)4 pseudo-ligands, formally arising from oligomerization of [AgFe(CO)4]- and their subsequent condensation with $ Ag^{+/O/-} $. The [$ Ag_{4} %$ Fe_{4} $(CO)16]4-, [$ Ag_{5} %$ Fe_{4} $(CO)16]3-, and [$ Ag_{13} %$ Fe_{8} $(CO)32]4- anions have been structurally characterized by X ray studies, while the formulation of all the remaining species is presently based on analytical and spectroscopic characterization, as well as their chemical behavior. Attempts to isolate the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- salts in a crystalline state were unsuccessful due to their ready oligomerization to completely insoluble material of [($ Ag^{+} $)n{[$ Ag_{6} %$ Fe_{4} $(CO)16]2-}n+1](n+2)- composition. This material is depolymerized by dimethylsulfoxide or by addition of stoichiometric amounts of amines and, upon dissolution, gives the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- dianion. Azzaroni, Fabrizio verfasserin aut Iapalucci, Maria Carmela verfasserin aut Longoni, Giuliano verfasserin aut Monari, Magda verfasserin aut Mulley, Suzanne verfasserin aut Enthalten in MRS online proceedings library Warrendale, Pa. : MRS, 1998 272(1992), 1 vom: 15. Mai, Seite 115-125 (DE-627)57782046X (DE-600)2451008-7 1946-4274 nnns volume:272 year:1992 number:1 day:15 month:05 pages:115-125 https://dx.doi.org/10.1557/PROC-272-115 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_2005 AR 272 1992 1 15 05 115-125 |
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10.1557/PROC-272-115 doi (DE-627)SPR041796608 (SPR)PROC-272-115-e DE-627 ger DE-627 rakwb eng 670 ASE Albano, Vincenzo G. verfasserin aut Silver Clusters Stabilized by Fe(Co)4 Ligands 1992 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of [Fe(CO)4]2- with $ Ag^{+} $ in tetrahydrofuran or acetonitrile solution affords a series of silver clusters stabilized by Fe(CO)4 pseudo-ligands, formally arising from oligomerization of [AgFe(CO)4]- and their subsequent condensation with $ Ag^{+/O/-} $. The [$ Ag_{4} %$ Fe_{4} $(CO)16]4-, [$ Ag_{5} %$ Fe_{4} $(CO)16]3-, and [$ Ag_{13} %$ Fe_{8} $(CO)32]4- anions have been structurally characterized by X ray studies, while the formulation of all the remaining species is presently based on analytical and spectroscopic characterization, as well as their chemical behavior. Attempts to isolate the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- salts in a crystalline state were unsuccessful due to their ready oligomerization to completely insoluble material of [($ Ag^{+} $)n{[$ Ag_{6} %$ Fe_{4} $(CO)16]2-}n+1](n+2)- composition. This material is depolymerized by dimethylsulfoxide or by addition of stoichiometric amounts of amines and, upon dissolution, gives the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- dianion. Azzaroni, Fabrizio verfasserin aut Iapalucci, Maria Carmela verfasserin aut Longoni, Giuliano verfasserin aut Monari, Magda verfasserin aut Mulley, Suzanne verfasserin aut Enthalten in MRS online proceedings library Warrendale, Pa. : MRS, 1998 272(1992), 1 vom: 15. Mai, Seite 115-125 (DE-627)57782046X (DE-600)2451008-7 1946-4274 nnns volume:272 year:1992 number:1 day:15 month:05 pages:115-125 https://dx.doi.org/10.1557/PROC-272-115 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_2005 AR 272 1992 1 15 05 115-125 |
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10.1557/PROC-272-115 doi (DE-627)SPR041796608 (SPR)PROC-272-115-e DE-627 ger DE-627 rakwb eng 670 ASE Albano, Vincenzo G. verfasserin aut Silver Clusters Stabilized by Fe(Co)4 Ligands 1992 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The reaction of [Fe(CO)4]2- with $ Ag^{+} $ in tetrahydrofuran or acetonitrile solution affords a series of silver clusters stabilized by Fe(CO)4 pseudo-ligands, formally arising from oligomerization of [AgFe(CO)4]- and their subsequent condensation with $ Ag^{+/O/-} $. The [$ Ag_{4} %$ Fe_{4} $(CO)16]4-, [$ Ag_{5} %$ Fe_{4} $(CO)16]3-, and [$ Ag_{13} %$ Fe_{8} $(CO)32]4- anions have been structurally characterized by X ray studies, while the formulation of all the remaining species is presently based on analytical and spectroscopic characterization, as well as their chemical behavior. Attempts to isolate the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- salts in a crystalline state were unsuccessful due to their ready oligomerization to completely insoluble material of [($ Ag^{+} $)n{[$ Ag_{6} %$ Fe_{4} $(CO)16]2-}n+1](n+2)- composition. This material is depolymerized by dimethylsulfoxide or by addition of stoichiometric amounts of amines and, upon dissolution, gives the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- dianion. Azzaroni, Fabrizio verfasserin aut Iapalucci, Maria Carmela verfasserin aut Longoni, Giuliano verfasserin aut Monari, Magda verfasserin aut Mulley, Suzanne verfasserin aut Enthalten in MRS online proceedings library Warrendale, Pa. : MRS, 1998 272(1992), 1 vom: 15. Mai, Seite 115-125 (DE-627)57782046X (DE-600)2451008-7 1946-4274 nnns volume:272 year:1992 number:1 day:15 month:05 pages:115-125 https://dx.doi.org/10.1557/PROC-272-115 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_2005 AR 272 1992 1 15 05 115-125 |
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Silver Clusters Stabilized by Fe(Co)4 Ligands |
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Abstract The reaction of [Fe(CO)4]2- with $ Ag^{+} $ in tetrahydrofuran or acetonitrile solution affords a series of silver clusters stabilized by Fe(CO)4 pseudo-ligands, formally arising from oligomerization of [AgFe(CO)4]- and their subsequent condensation with $ Ag^{+/O/-} $. The [$ Ag_{4} %$ Fe_{4} $(CO)16]4-, [$ Ag_{5} %$ Fe_{4} $(CO)16]3-, and [$ Ag_{13} %$ Fe_{8} $(CO)32]4- anions have been structurally characterized by X ray studies, while the formulation of all the remaining species is presently based on analytical and spectroscopic characterization, as well as their chemical behavior. Attempts to isolate the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- salts in a crystalline state were unsuccessful due to their ready oligomerization to completely insoluble material of [($ Ag^{+} $)n{[$ Ag_{6} %$ Fe_{4} $(CO)16]2-}n+1](n+2)- composition. This material is depolymerized by dimethylsulfoxide or by addition of stoichiometric amounts of amines and, upon dissolution, gives the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- dianion. |
| abstractGer |
Abstract The reaction of [Fe(CO)4]2- with $ Ag^{+} $ in tetrahydrofuran or acetonitrile solution affords a series of silver clusters stabilized by Fe(CO)4 pseudo-ligands, formally arising from oligomerization of [AgFe(CO)4]- and their subsequent condensation with $ Ag^{+/O/-} $. The [$ Ag_{4} %$ Fe_{4} $(CO)16]4-, [$ Ag_{5} %$ Fe_{4} $(CO)16]3-, and [$ Ag_{13} %$ Fe_{8} $(CO)32]4- anions have been structurally characterized by X ray studies, while the formulation of all the remaining species is presently based on analytical and spectroscopic characterization, as well as their chemical behavior. Attempts to isolate the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- salts in a crystalline state were unsuccessful due to their ready oligomerization to completely insoluble material of [($ Ag^{+} $)n{[$ Ag_{6} %$ Fe_{4} $(CO)16]2-}n+1](n+2)- composition. This material is depolymerized by dimethylsulfoxide or by addition of stoichiometric amounts of amines and, upon dissolution, gives the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- dianion. |
| abstract_unstemmed |
Abstract The reaction of [Fe(CO)4]2- with $ Ag^{+} $ in tetrahydrofuran or acetonitrile solution affords a series of silver clusters stabilized by Fe(CO)4 pseudo-ligands, formally arising from oligomerization of [AgFe(CO)4]- and their subsequent condensation with $ Ag^{+/O/-} $. The [$ Ag_{4} %$ Fe_{4} $(CO)16]4-, [$ Ag_{5} %$ Fe_{4} $(CO)16]3-, and [$ Ag_{13} %$ Fe_{8} $(CO)32]4- anions have been structurally characterized by X ray studies, while the formulation of all the remaining species is presently based on analytical and spectroscopic characterization, as well as their chemical behavior. Attempts to isolate the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- salts in a crystalline state were unsuccessful due to their ready oligomerization to completely insoluble material of [($ Ag^{+} $)n{[$ Ag_{6} %$ Fe_{4} $(CO)16]2-}n+1](n+2)- composition. This material is depolymerized by dimethylsulfoxide or by addition of stoichiometric amounts of amines and, upon dissolution, gives the [$ Ag_{6} %$ Fe_{4} $(CO)16]2- dianion. |
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GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_2005 |
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| title_short |
Silver Clusters Stabilized by Fe(Co)4 Ligands |
| url |
https://dx.doi.org/10.1557/PROC-272-115 |
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true |
| author2 |
Azzaroni, Fabrizio Iapalucci, Maria Carmela Longoni, Giuliano Monari, Magda Mulley, Suzanne |
| author2Str |
Azzaroni, Fabrizio Iapalucci, Maria Carmela Longoni, Giuliano Monari, Magda Mulley, Suzanne |
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57782046X |
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| doi_str |
10.1557/PROC-272-115 |
| up_date |
2024-07-03T23:41:19.391Z |
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7.4010544 |