Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation
Abstract Ammonia ($ NH_{3} $) synthesis is a critical chemical process to develop nitrogen-containing commodities which remains a significant challenge in chemistry and industry. Photocatalysis reduction has been deemed as one of the most promising strategies for $ N_{2} $ fixation under mild condit...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Sun, Liguo [verfasserIn] Chu, Xini [verfasserIn] He, Chengli [verfasserIn] Zuo, Shixiang [verfasserIn] Li, Xiazhang [verfasserIn] Yao, Chao [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Applied physics - Berlin : Springer, 1973, 127(2021), 1 vom: Jan. |
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| Übergeordnetes Werk: |
volume:127 ; year:2021 ; number:1 ; month:01 |
| Links: |
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| DOI / URN: |
10.1007/s00339-020-04186-x |
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| Katalog-ID: |
SPR042540062 |
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| 245 | 1 | 0 | |a Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation |
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| 520 | |a Abstract Ammonia ($ NH_{3} $) synthesis is a critical chemical process to develop nitrogen-containing commodities which remains a significant challenge in chemistry and industry. Photocatalysis reduction has been deemed as one of the most promising strategies for $ N_{2} $ fixation under mild conditions. Herein, a series of Pr doped $ LiNbO_{3} $ ($ Pr^{3+} $:$ LiNbO_{3} $) were synthesized by a facile sol–gel method. Results showed that the $ Pr^{3+} $:$ LiNbO_{3} $ upconverted visible light into ultraviolet light and had the highest up-conversion efficiency when the molar ratio of $ Pr^{3+} $ was 2.5 mol%. In addition, the oxygen vacancies generated by the incorporation of $ Pr^{3+} $ into the $ LiNbO_{3} $ crystal lattice acted as active sites boosting the adsorption and activation of $ N_{2} $. The $ NH_{4} $+ production rate reached the highest of 30.72 μmol/L, attributed to the synergistic effects combining spontaneous polarization of the nonlinear optical (NLO) material $ LiNbO_{3} $ and up-conversion luminescence of $ Pr^{3+} $, which not only broaden the adsorption range of solar light but also enhance the charge separation. The up-conversion NLO material $ Pr^{3+} $:$ LiNbO_{3} $ in this study provides a novel alternative for guiding the design of ammonia synthesis photocatalyst. | ||
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| 650 | 4 | |a Up-conversion |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Nitrogen fixation |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Photocatalysis |7 (dpeaa)DE-He213 | |
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| 700 | 1 | |a Li, Xiazhang |e verfasserin |4 aut | |
| 700 | 1 | |a Yao, Chao |e verfasserin |4 aut | |
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10.1007/s00339-020-04186-x doi (DE-627)SPR042540062 (DE-599)SPRs00339-020-04186-x-e (SPR)s00339-020-04186-x-e DE-627 ger DE-627 rakwb eng 530 ASE 33.60 bkl 51.00 bkl 53.09 bkl Sun, Liguo verfasserin aut Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Ammonia ($ NH_{3} $) synthesis is a critical chemical process to develop nitrogen-containing commodities which remains a significant challenge in chemistry and industry. Photocatalysis reduction has been deemed as one of the most promising strategies for $ N_{2} $ fixation under mild conditions. Herein, a series of Pr doped $ LiNbO_{3} $ ($ Pr^{3+} $:$ LiNbO_{3} $) were synthesized by a facile sol–gel method. Results showed that the $ Pr^{3+} $:$ LiNbO_{3} $ upconverted visible light into ultraviolet light and had the highest up-conversion efficiency when the molar ratio of $ Pr^{3+} $ was 2.5 mol%. In addition, the oxygen vacancies generated by the incorporation of $ Pr^{3+} $ into the $ LiNbO_{3} $ crystal lattice acted as active sites boosting the adsorption and activation of $ N_{2} $. The $ NH_{4} $+ production rate reached the highest of 30.72 μmol/L, attributed to the synergistic effects combining spontaneous polarization of the nonlinear optical (NLO) material $ LiNbO_{3} $ and up-conversion luminescence of $ Pr^{3+} $, which not only broaden the adsorption range of solar light but also enhance the charge separation. The up-conversion NLO material $ Pr^{3+} $:$ LiNbO_{3} $ in this study provides a novel alternative for guiding the design of ammonia synthesis photocatalyst. Nonlinear optical material (dpeaa)DE-He213 LiNbO (dpeaa)DE-He213 Up-conversion (dpeaa)DE-He213 Nitrogen fixation (dpeaa)DE-He213 Photocatalysis (dpeaa)DE-He213 Chu, Xini verfasserin aut He, Chengli verfasserin aut Zuo, Shixiang verfasserin aut Li, Xiazhang verfasserin aut Yao, Chao verfasserin aut Enthalten in Applied physics Berlin : Springer, 1973 127(2021), 1 vom: Jan. (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:127 year:2021 number:1 month:01 https://dx.doi.org/10.1007/s00339-020-04186-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.60 ASE 51.00 ASE 53.09 ASE AR 127 2021 1 01 |
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10.1007/s00339-020-04186-x doi (DE-627)SPR042540062 (DE-599)SPRs00339-020-04186-x-e (SPR)s00339-020-04186-x-e DE-627 ger DE-627 rakwb eng 530 ASE 33.60 bkl 51.00 bkl 53.09 bkl Sun, Liguo verfasserin aut Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Ammonia ($ NH_{3} $) synthesis is a critical chemical process to develop nitrogen-containing commodities which remains a significant challenge in chemistry and industry. Photocatalysis reduction has been deemed as one of the most promising strategies for $ N_{2} $ fixation under mild conditions. Herein, a series of Pr doped $ LiNbO_{3} $ ($ Pr^{3+} $:$ LiNbO_{3} $) were synthesized by a facile sol–gel method. Results showed that the $ Pr^{3+} $:$ LiNbO_{3} $ upconverted visible light into ultraviolet light and had the highest up-conversion efficiency when the molar ratio of $ Pr^{3+} $ was 2.5 mol%. In addition, the oxygen vacancies generated by the incorporation of $ Pr^{3+} $ into the $ LiNbO_{3} $ crystal lattice acted as active sites boosting the adsorption and activation of $ N_{2} $. The $ NH_{4} $+ production rate reached the highest of 30.72 μmol/L, attributed to the synergistic effects combining spontaneous polarization of the nonlinear optical (NLO) material $ LiNbO_{3} $ and up-conversion luminescence of $ Pr^{3+} $, which not only broaden the adsorption range of solar light but also enhance the charge separation. The up-conversion NLO material $ Pr^{3+} $:$ LiNbO_{3} $ in this study provides a novel alternative for guiding the design of ammonia synthesis photocatalyst. Nonlinear optical material (dpeaa)DE-He213 LiNbO (dpeaa)DE-He213 Up-conversion (dpeaa)DE-He213 Nitrogen fixation (dpeaa)DE-He213 Photocatalysis (dpeaa)DE-He213 Chu, Xini verfasserin aut He, Chengli verfasserin aut Zuo, Shixiang verfasserin aut Li, Xiazhang verfasserin aut Yao, Chao verfasserin aut Enthalten in Applied physics Berlin : Springer, 1973 127(2021), 1 vom: Jan. (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:127 year:2021 number:1 month:01 https://dx.doi.org/10.1007/s00339-020-04186-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.60 ASE 51.00 ASE 53.09 ASE AR 127 2021 1 01 |
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10.1007/s00339-020-04186-x doi (DE-627)SPR042540062 (DE-599)SPRs00339-020-04186-x-e (SPR)s00339-020-04186-x-e DE-627 ger DE-627 rakwb eng 530 ASE 33.60 bkl 51.00 bkl 53.09 bkl Sun, Liguo verfasserin aut Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Ammonia ($ NH_{3} $) synthesis is a critical chemical process to develop nitrogen-containing commodities which remains a significant challenge in chemistry and industry. Photocatalysis reduction has been deemed as one of the most promising strategies for $ N_{2} $ fixation under mild conditions. Herein, a series of Pr doped $ LiNbO_{3} $ ($ Pr^{3+} $:$ LiNbO_{3} $) were synthesized by a facile sol–gel method. Results showed that the $ Pr^{3+} $:$ LiNbO_{3} $ upconverted visible light into ultraviolet light and had the highest up-conversion efficiency when the molar ratio of $ Pr^{3+} $ was 2.5 mol%. In addition, the oxygen vacancies generated by the incorporation of $ Pr^{3+} $ into the $ LiNbO_{3} $ crystal lattice acted as active sites boosting the adsorption and activation of $ N_{2} $. The $ NH_{4} $+ production rate reached the highest of 30.72 μmol/L, attributed to the synergistic effects combining spontaneous polarization of the nonlinear optical (NLO) material $ LiNbO_{3} $ and up-conversion luminescence of $ Pr^{3+} $, which not only broaden the adsorption range of solar light but also enhance the charge separation. The up-conversion NLO material $ Pr^{3+} $:$ LiNbO_{3} $ in this study provides a novel alternative for guiding the design of ammonia synthesis photocatalyst. Nonlinear optical material (dpeaa)DE-He213 LiNbO (dpeaa)DE-He213 Up-conversion (dpeaa)DE-He213 Nitrogen fixation (dpeaa)DE-He213 Photocatalysis (dpeaa)DE-He213 Chu, Xini verfasserin aut He, Chengli verfasserin aut Zuo, Shixiang verfasserin aut Li, Xiazhang verfasserin aut Yao, Chao verfasserin aut Enthalten in Applied physics Berlin : Springer, 1973 127(2021), 1 vom: Jan. (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:127 year:2021 number:1 month:01 https://dx.doi.org/10.1007/s00339-020-04186-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.60 ASE 51.00 ASE 53.09 ASE AR 127 2021 1 01 |
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10.1007/s00339-020-04186-x doi (DE-627)SPR042540062 (DE-599)SPRs00339-020-04186-x-e (SPR)s00339-020-04186-x-e DE-627 ger DE-627 rakwb eng 530 ASE 33.60 bkl 51.00 bkl 53.09 bkl Sun, Liguo verfasserin aut Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Ammonia ($ NH_{3} $) synthesis is a critical chemical process to develop nitrogen-containing commodities which remains a significant challenge in chemistry and industry. Photocatalysis reduction has been deemed as one of the most promising strategies for $ N_{2} $ fixation under mild conditions. Herein, a series of Pr doped $ LiNbO_{3} $ ($ Pr^{3+} $:$ LiNbO_{3} $) were synthesized by a facile sol–gel method. Results showed that the $ Pr^{3+} $:$ LiNbO_{3} $ upconverted visible light into ultraviolet light and had the highest up-conversion efficiency when the molar ratio of $ Pr^{3+} $ was 2.5 mol%. In addition, the oxygen vacancies generated by the incorporation of $ Pr^{3+} $ into the $ LiNbO_{3} $ crystal lattice acted as active sites boosting the adsorption and activation of $ N_{2} $. The $ NH_{4} $+ production rate reached the highest of 30.72 μmol/L, attributed to the synergistic effects combining spontaneous polarization of the nonlinear optical (NLO) material $ LiNbO_{3} $ and up-conversion luminescence of $ Pr^{3+} $, which not only broaden the adsorption range of solar light but also enhance the charge separation. The up-conversion NLO material $ Pr^{3+} $:$ LiNbO_{3} $ in this study provides a novel alternative for guiding the design of ammonia synthesis photocatalyst. Nonlinear optical material (dpeaa)DE-He213 LiNbO (dpeaa)DE-He213 Up-conversion (dpeaa)DE-He213 Nitrogen fixation (dpeaa)DE-He213 Photocatalysis (dpeaa)DE-He213 Chu, Xini verfasserin aut He, Chengli verfasserin aut Zuo, Shixiang verfasserin aut Li, Xiazhang verfasserin aut Yao, Chao verfasserin aut Enthalten in Applied physics Berlin : Springer, 1973 127(2021), 1 vom: Jan. (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:127 year:2021 number:1 month:01 https://dx.doi.org/10.1007/s00339-020-04186-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.60 ASE 51.00 ASE 53.09 ASE AR 127 2021 1 01 |
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10.1007/s00339-020-04186-x doi (DE-627)SPR042540062 (DE-599)SPRs00339-020-04186-x-e (SPR)s00339-020-04186-x-e DE-627 ger DE-627 rakwb eng 530 ASE 33.60 bkl 51.00 bkl 53.09 bkl Sun, Liguo verfasserin aut Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Ammonia ($ NH_{3} $) synthesis is a critical chemical process to develop nitrogen-containing commodities which remains a significant challenge in chemistry and industry. Photocatalysis reduction has been deemed as one of the most promising strategies for $ N_{2} $ fixation under mild conditions. Herein, a series of Pr doped $ LiNbO_{3} $ ($ Pr^{3+} $:$ LiNbO_{3} $) were synthesized by a facile sol–gel method. Results showed that the $ Pr^{3+} $:$ LiNbO_{3} $ upconverted visible light into ultraviolet light and had the highest up-conversion efficiency when the molar ratio of $ Pr^{3+} $ was 2.5 mol%. In addition, the oxygen vacancies generated by the incorporation of $ Pr^{3+} $ into the $ LiNbO_{3} $ crystal lattice acted as active sites boosting the adsorption and activation of $ N_{2} $. The $ NH_{4} $+ production rate reached the highest of 30.72 μmol/L, attributed to the synergistic effects combining spontaneous polarization of the nonlinear optical (NLO) material $ LiNbO_{3} $ and up-conversion luminescence of $ Pr^{3+} $, which not only broaden the adsorption range of solar light but also enhance the charge separation. The up-conversion NLO material $ Pr^{3+} $:$ LiNbO_{3} $ in this study provides a novel alternative for guiding the design of ammonia synthesis photocatalyst. Nonlinear optical material (dpeaa)DE-He213 LiNbO (dpeaa)DE-He213 Up-conversion (dpeaa)DE-He213 Nitrogen fixation (dpeaa)DE-He213 Photocatalysis (dpeaa)DE-He213 Chu, Xini verfasserin aut He, Chengli verfasserin aut Zuo, Shixiang verfasserin aut Li, Xiazhang verfasserin aut Yao, Chao verfasserin aut Enthalten in Applied physics Berlin : Springer, 1973 127(2021), 1 vom: Jan. (DE-627)235503231 (DE-600)1398311-8 1432-0630 nnns volume:127 year:2021 number:1 month:01 https://dx.doi.org/10.1007/s00339-020-04186-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.60 ASE 51.00 ASE 53.09 ASE AR 127 2021 1 01 |
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English |
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Enthalten in Applied physics 127(2021), 1 vom: Jan. volume:127 year:2021 number:1 month:01 |
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Enthalten in Applied physics 127(2021), 1 vom: Jan. volume:127 year:2021 number:1 month:01 |
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Nonlinear optical material LiNbO Up-conversion Nitrogen fixation Photocatalysis |
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Sun, Liguo @@aut@@ Chu, Xini @@aut@@ He, Chengli @@aut@@ Zuo, Shixiang @@aut@@ Li, Xiazhang @@aut@@ Yao, Chao @@aut@@ |
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Photocatalysis reduction has been deemed as one of the most promising strategies for $ N_{2} $ fixation under mild conditions. Herein, a series of Pr doped $ LiNbO_{3} $ ($ Pr^{3+} $:$ LiNbO_{3} $) were synthesized by a facile sol–gel method. Results showed that the $ Pr^{3+} $:$ LiNbO_{3} $ upconverted visible light into ultraviolet light and had the highest up-conversion efficiency when the molar ratio of $ Pr^{3+} $ was 2.5 mol%. In addition, the oxygen vacancies generated by the incorporation of $ Pr^{3+} $ into the $ LiNbO_{3} $ crystal lattice acted as active sites boosting the adsorption and activation of $ N_{2} $. The $ NH_{4} $+ production rate reached the highest of 30.72 μmol/L, attributed to the synergistic effects combining spontaneous polarization of the nonlinear optical (NLO) material $ LiNbO_{3} $ and up-conversion luminescence of $ Pr^{3+} $, which not only broaden the adsorption range of solar light but also enhance the charge separation. 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Sun, Liguo |
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Sun, Liguo ddc 530 bkl 33.60 bkl 51.00 bkl 53.09 misc Nonlinear optical material misc LiNbO misc Up-conversion misc Nitrogen fixation misc Photocatalysis Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation |
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530 ASE 33.60 bkl 51.00 bkl 53.09 bkl Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation Nonlinear optical material (dpeaa)DE-He213 LiNbO (dpeaa)DE-He213 Up-conversion (dpeaa)DE-He213 Nitrogen fixation (dpeaa)DE-He213 Photocatalysis (dpeaa)DE-He213 |
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ddc 530 bkl 33.60 bkl 51.00 bkl 53.09 misc Nonlinear optical material misc LiNbO misc Up-conversion misc Nitrogen fixation misc Photocatalysis |
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ddc 530 bkl 33.60 bkl 51.00 bkl 53.09 misc Nonlinear optical material misc LiNbO misc Up-conversion misc Nitrogen fixation misc Photocatalysis |
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ddc 530 bkl 33.60 bkl 51.00 bkl 53.09 misc Nonlinear optical material misc LiNbO misc Up-conversion misc Nitrogen fixation misc Photocatalysis |
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Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation |
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Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation |
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Sun, Liguo Chu, Xini He, Chengli Zuo, Shixiang Li, Xiazhang Yao, Chao |
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Elektronische Aufsätze |
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Sun, Liguo |
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10.1007/s00339-020-04186-x |
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efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ pr^{3+} $:$ linbo_{3} $ under visible light irradiation |
| title_auth |
Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation |
| abstract |
Abstract Ammonia ($ NH_{3} $) synthesis is a critical chemical process to develop nitrogen-containing commodities which remains a significant challenge in chemistry and industry. Photocatalysis reduction has been deemed as one of the most promising strategies for $ N_{2} $ fixation under mild conditions. Herein, a series of Pr doped $ LiNbO_{3} $ ($ Pr^{3+} $:$ LiNbO_{3} $) were synthesized by a facile sol–gel method. Results showed that the $ Pr^{3+} $:$ LiNbO_{3} $ upconverted visible light into ultraviolet light and had the highest up-conversion efficiency when the molar ratio of $ Pr^{3+} $ was 2.5 mol%. In addition, the oxygen vacancies generated by the incorporation of $ Pr^{3+} $ into the $ LiNbO_{3} $ crystal lattice acted as active sites boosting the adsorption and activation of $ N_{2} $. The $ NH_{4} $+ production rate reached the highest of 30.72 μmol/L, attributed to the synergistic effects combining spontaneous polarization of the nonlinear optical (NLO) material $ LiNbO_{3} $ and up-conversion luminescence of $ Pr^{3+} $, which not only broaden the adsorption range of solar light but also enhance the charge separation. The up-conversion NLO material $ Pr^{3+} $:$ LiNbO_{3} $ in this study provides a novel alternative for guiding the design of ammonia synthesis photocatalyst. |
| abstractGer |
Abstract Ammonia ($ NH_{3} $) synthesis is a critical chemical process to develop nitrogen-containing commodities which remains a significant challenge in chemistry and industry. Photocatalysis reduction has been deemed as one of the most promising strategies for $ N_{2} $ fixation under mild conditions. Herein, a series of Pr doped $ LiNbO_{3} $ ($ Pr^{3+} $:$ LiNbO_{3} $) were synthesized by a facile sol–gel method. Results showed that the $ Pr^{3+} $:$ LiNbO_{3} $ upconverted visible light into ultraviolet light and had the highest up-conversion efficiency when the molar ratio of $ Pr^{3+} $ was 2.5 mol%. In addition, the oxygen vacancies generated by the incorporation of $ Pr^{3+} $ into the $ LiNbO_{3} $ crystal lattice acted as active sites boosting the adsorption and activation of $ N_{2} $. The $ NH_{4} $+ production rate reached the highest of 30.72 μmol/L, attributed to the synergistic effects combining spontaneous polarization of the nonlinear optical (NLO) material $ LiNbO_{3} $ and up-conversion luminescence of $ Pr^{3+} $, which not only broaden the adsorption range of solar light but also enhance the charge separation. The up-conversion NLO material $ Pr^{3+} $:$ LiNbO_{3} $ in this study provides a novel alternative for guiding the design of ammonia synthesis photocatalyst. |
| abstract_unstemmed |
Abstract Ammonia ($ NH_{3} $) synthesis is a critical chemical process to develop nitrogen-containing commodities which remains a significant challenge in chemistry and industry. Photocatalysis reduction has been deemed as one of the most promising strategies for $ N_{2} $ fixation under mild conditions. Herein, a series of Pr doped $ LiNbO_{3} $ ($ Pr^{3+} $:$ LiNbO_{3} $) were synthesized by a facile sol–gel method. Results showed that the $ Pr^{3+} $:$ LiNbO_{3} $ upconverted visible light into ultraviolet light and had the highest up-conversion efficiency when the molar ratio of $ Pr^{3+} $ was 2.5 mol%. In addition, the oxygen vacancies generated by the incorporation of $ Pr^{3+} $ into the $ LiNbO_{3} $ crystal lattice acted as active sites boosting the adsorption and activation of $ N_{2} $. The $ NH_{4} $+ production rate reached the highest of 30.72 μmol/L, attributed to the synergistic effects combining spontaneous polarization of the nonlinear optical (NLO) material $ LiNbO_{3} $ and up-conversion luminescence of $ Pr^{3+} $, which not only broaden the adsorption range of solar light but also enhance the charge separation. The up-conversion NLO material $ Pr^{3+} $:$ LiNbO_{3} $ in this study provides a novel alternative for guiding the design of ammonia synthesis photocatalyst. |
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Efficient photocatalytic nitrogen fixation over up-conversion nonlinear optical material $ Pr^{3+} $:$ LiNbO_{3} $ under visible light irradiation |
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Chu, Xini He, Chengli Zuo, Shixiang Li, Xiazhang Yao, Chao |
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| score |
7.400646 |