Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336

Abstract A new and rapid microextraction approach termed as ultrasonic-assisted ionic liquid-based microextraction (UA-ILME) was developed using ionic liquid Aliquat-336 as extraction solvent for the extraction of chromium and cadmium in bean samples collected from different regions in Turkey. The t...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Elik, Adil [verfasserIn] Karakoy, Tolga [verfasserIn] Çilesiz, Yeter [verfasserIn] Altunay, Nail [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2020

Schlagwörter:	Flame atomic absorption spectrometry Aliquat-336 Ionic liquid Plant samples Chromium Cadmium

Übergeordnetes Werk:	Enthalten in: Journal of the Iranian Chemical Society - Tehran, 2004, 18(2020), 1 vom: 26. Juli, Seite 117-127
Übergeordnetes Werk:	volume:18 ; year:2020 ; number:1 ; day:26 ; month:07 ; pages:117-127

Links:	Volltext

DOI / URN:	10.1007/s13738-020-02009-7

Katalog-ID:	SPR042738636

Internformat


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245	1	0	\|a Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336
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520			\|a Abstract A new and rapid microextraction approach termed as ultrasonic-assisted ionic liquid-based microextraction (UA-ILME) was developed using ionic liquid Aliquat-336 as extraction solvent for the extraction of chromium and cadmium in bean samples collected from different regions in Turkey. The total amounts of analytes in the samples were measured by flame atomic absorption spectrophotometry. The basis of the extraction step is based on the complexation of Cr(III) and Cd(II) with diethyldithiocarbamate at pH 4.0. The hydrophobic ternary complexes containing analytes were then rapidly extracted from the sample solution to the ionic phase under the ultrasonic effect using tricaprylylmethylammonium chloride (Aliquat-336). Some experimental variables (pH, ligand amount, extraction solvent volume, ultrasound time, extraction temperature and sample volume) were optimized in detail. Following the optimization steps, the limits of detection (LODs, 3Sblank/m) for Cr(III) and Cd(II) were calculated as 0.45 ng $ mL^{−1} $ with linear range of 1.5–380 ng $ mL^{−1} $ and 0.25 ng $ mL^{−1} $ with linear range of 0.8–220 ng $ mL^{−1} $, respectively. Enrichment factors and average recoveries were ranged from 125.8–96.4 to 92.7–106.5%, respectively. The accuracy and precision of the method were validated by analyzing a certified reference material and spiked recovery tests. The UA-ILME method was successfully applied to the determination of Cd and Cr in the samples, highlighting that the matrix ions under consideration do not affect the extraction and determination steps.
650		4	\|a Flame atomic absorption spectrometry \|7 (dpeaa)DE-He213
650		4	\|a Aliquat-336 \|7 (dpeaa)DE-He213
650		4	\|a Ionic liquid \|7 (dpeaa)DE-He213
650		4	\|a Plant samples \|7 (dpeaa)DE-He213
650		4	\|a Chromium \|7 (dpeaa)DE-He213
650		4	\|a Cadmium \|7 (dpeaa)DE-He213
700	1		\|a Karakoy, Tolga \|e verfasserin \|4 aut
700	1		\|a Çilesiz, Yeter \|e verfasserin \|4 aut
700	1		\|a Altunay, Nail \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Journal of the Iranian Chemical Society \|d Tehran, 2004 \|g 18(2020), 1 vom: 26. Juli, Seite 117-127 \|w (DE-627)515979767 \|w (DE-600)2244820-2 \|x 1735-2428 \|7 nnns
773	1	8	\|g volume:18 \|g year:2020 \|g number:1 \|g day:26 \|g month:07 \|g pages:117-127
856	4	0	\|u https://dx.doi.org/10.1007/s13738-020-02009-7 \|z lizenzpflichtig \|3 Volltext
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912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
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912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_165
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
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912			\|a GBV_ILN_224
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Indexfelder

author_variant	a e ae t k tk y ç yç n a na
matchkey_str	article:17352428:2020----::lmaoiasrtosetoerceemntoottlhoimncdimnenapeatrlrsncsitdi
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publishDate	2020
allfields	10.1007/s13738-020-02009-7 doi (DE-627)SPR042738636 (DE-599)SPRs13738-020-02009-7-e (SPR)s13738-020-02009-7-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Elik, Adil verfasserin aut Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A new and rapid microextraction approach termed as ultrasonic-assisted ionic liquid-based microextraction (UA-ILME) was developed using ionic liquid Aliquat-336 as extraction solvent for the extraction of chromium and cadmium in bean samples collected from different regions in Turkey. The total amounts of analytes in the samples were measured by flame atomic absorption spectrophotometry. The basis of the extraction step is based on the complexation of Cr(III) and Cd(II) with diethyldithiocarbamate at pH 4.0. The hydrophobic ternary complexes containing analytes were then rapidly extracted from the sample solution to the ionic phase under the ultrasonic effect using tricaprylylmethylammonium chloride (Aliquat-336). Some experimental variables (pH, ligand amount, extraction solvent volume, ultrasound time, extraction temperature and sample volume) were optimized in detail. Following the optimization steps, the limits of detection (LODs, 3Sblank/m) for Cr(III) and Cd(II) were calculated as 0.45 ng $ mL^{−1} $ with linear range of 1.5–380 ng $ mL^{−1} $ and 0.25 ng $ mL^{−1} $ with linear range of 0.8–220 ng $ mL^{−1} $, respectively. Enrichment factors and average recoveries were ranged from 125.8–96.4 to 92.7–106.5%, respectively. The accuracy and precision of the method were validated by analyzing a certified reference material and spiked recovery tests. The UA-ILME method was successfully applied to the determination of Cd and Cr in the samples, highlighting that the matrix ions under consideration do not affect the extraction and determination steps. Flame atomic absorption spectrometry (dpeaa)DE-He213 Aliquat-336 (dpeaa)DE-He213 Ionic liquid (dpeaa)DE-He213 Plant samples (dpeaa)DE-He213 Chromium (dpeaa)DE-He213 Cadmium (dpeaa)DE-He213 Karakoy, Tolga verfasserin aut Çilesiz, Yeter verfasserin aut Altunay, Nail verfasserin aut Enthalten in Journal of the Iranian Chemical Society Tehran, 2004 18(2020), 1 vom: 26. Juli, Seite 117-127 (DE-627)515979767 (DE-600)2244820-2 1735-2428 nnns volume:18 year:2020 number:1 day:26 month:07 pages:117-127 https://dx.doi.org/10.1007/s13738-020-02009-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 18 2020 1 26 07 117-127
spelling	10.1007/s13738-020-02009-7 doi (DE-627)SPR042738636 (DE-599)SPRs13738-020-02009-7-e (SPR)s13738-020-02009-7-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Elik, Adil verfasserin aut Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A new and rapid microextraction approach termed as ultrasonic-assisted ionic liquid-based microextraction (UA-ILME) was developed using ionic liquid Aliquat-336 as extraction solvent for the extraction of chromium and cadmium in bean samples collected from different regions in Turkey. The total amounts of analytes in the samples were measured by flame atomic absorption spectrophotometry. The basis of the extraction step is based on the complexation of Cr(III) and Cd(II) with diethyldithiocarbamate at pH 4.0. The hydrophobic ternary complexes containing analytes were then rapidly extracted from the sample solution to the ionic phase under the ultrasonic effect using tricaprylylmethylammonium chloride (Aliquat-336). Some experimental variables (pH, ligand amount, extraction solvent volume, ultrasound time, extraction temperature and sample volume) were optimized in detail. Following the optimization steps, the limits of detection (LODs, 3Sblank/m) for Cr(III) and Cd(II) were calculated as 0.45 ng $ mL^{−1} $ with linear range of 1.5–380 ng $ mL^{−1} $ and 0.25 ng $ mL^{−1} $ with linear range of 0.8–220 ng $ mL^{−1} $, respectively. Enrichment factors and average recoveries were ranged from 125.8–96.4 to 92.7–106.5%, respectively. The accuracy and precision of the method were validated by analyzing a certified reference material and spiked recovery tests. The UA-ILME method was successfully applied to the determination of Cd and Cr in the samples, highlighting that the matrix ions under consideration do not affect the extraction and determination steps. Flame atomic absorption spectrometry (dpeaa)DE-He213 Aliquat-336 (dpeaa)DE-He213 Ionic liquid (dpeaa)DE-He213 Plant samples (dpeaa)DE-He213 Chromium (dpeaa)DE-He213 Cadmium (dpeaa)DE-He213 Karakoy, Tolga verfasserin aut Çilesiz, Yeter verfasserin aut Altunay, Nail verfasserin aut Enthalten in Journal of the Iranian Chemical Society Tehran, 2004 18(2020), 1 vom: 26. Juli, Seite 117-127 (DE-627)515979767 (DE-600)2244820-2 1735-2428 nnns volume:18 year:2020 number:1 day:26 month:07 pages:117-127 https://dx.doi.org/10.1007/s13738-020-02009-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 18 2020 1 26 07 117-127
allfields_unstemmed	10.1007/s13738-020-02009-7 doi (DE-627)SPR042738636 (DE-599)SPRs13738-020-02009-7-e (SPR)s13738-020-02009-7-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Elik, Adil verfasserin aut Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A new and rapid microextraction approach termed as ultrasonic-assisted ionic liquid-based microextraction (UA-ILME) was developed using ionic liquid Aliquat-336 as extraction solvent for the extraction of chromium and cadmium in bean samples collected from different regions in Turkey. The total amounts of analytes in the samples were measured by flame atomic absorption spectrophotometry. The basis of the extraction step is based on the complexation of Cr(III) and Cd(II) with diethyldithiocarbamate at pH 4.0. The hydrophobic ternary complexes containing analytes were then rapidly extracted from the sample solution to the ionic phase under the ultrasonic effect using tricaprylylmethylammonium chloride (Aliquat-336). Some experimental variables (pH, ligand amount, extraction solvent volume, ultrasound time, extraction temperature and sample volume) were optimized in detail. Following the optimization steps, the limits of detection (LODs, 3Sblank/m) for Cr(III) and Cd(II) were calculated as 0.45 ng $ mL^{−1} $ with linear range of 1.5–380 ng $ mL^{−1} $ and 0.25 ng $ mL^{−1} $ with linear range of 0.8–220 ng $ mL^{−1} $, respectively. Enrichment factors and average recoveries were ranged from 125.8–96.4 to 92.7–106.5%, respectively. The accuracy and precision of the method were validated by analyzing a certified reference material and spiked recovery tests. The UA-ILME method was successfully applied to the determination of Cd and Cr in the samples, highlighting that the matrix ions under consideration do not affect the extraction and determination steps. Flame atomic absorption spectrometry (dpeaa)DE-He213 Aliquat-336 (dpeaa)DE-He213 Ionic liquid (dpeaa)DE-He213 Plant samples (dpeaa)DE-He213 Chromium (dpeaa)DE-He213 Cadmium (dpeaa)DE-He213 Karakoy, Tolga verfasserin aut Çilesiz, Yeter verfasserin aut Altunay, Nail verfasserin aut Enthalten in Journal of the Iranian Chemical Society Tehran, 2004 18(2020), 1 vom: 26. Juli, Seite 117-127 (DE-627)515979767 (DE-600)2244820-2 1735-2428 nnns volume:18 year:2020 number:1 day:26 month:07 pages:117-127 https://dx.doi.org/10.1007/s13738-020-02009-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 18 2020 1 26 07 117-127
allfieldsGer	10.1007/s13738-020-02009-7 doi (DE-627)SPR042738636 (DE-599)SPRs13738-020-02009-7-e (SPR)s13738-020-02009-7-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Elik, Adil verfasserin aut Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A new and rapid microextraction approach termed as ultrasonic-assisted ionic liquid-based microextraction (UA-ILME) was developed using ionic liquid Aliquat-336 as extraction solvent for the extraction of chromium and cadmium in bean samples collected from different regions in Turkey. The total amounts of analytes in the samples were measured by flame atomic absorption spectrophotometry. The basis of the extraction step is based on the complexation of Cr(III) and Cd(II) with diethyldithiocarbamate at pH 4.0. The hydrophobic ternary complexes containing analytes were then rapidly extracted from the sample solution to the ionic phase under the ultrasonic effect using tricaprylylmethylammonium chloride (Aliquat-336). Some experimental variables (pH, ligand amount, extraction solvent volume, ultrasound time, extraction temperature and sample volume) were optimized in detail. Following the optimization steps, the limits of detection (LODs, 3Sblank/m) for Cr(III) and Cd(II) were calculated as 0.45 ng $ mL^{−1} $ with linear range of 1.5–380 ng $ mL^{−1} $ and 0.25 ng $ mL^{−1} $ with linear range of 0.8–220 ng $ mL^{−1} $, respectively. Enrichment factors and average recoveries were ranged from 125.8–96.4 to 92.7–106.5%, respectively. The accuracy and precision of the method were validated by analyzing a certified reference material and spiked recovery tests. The UA-ILME method was successfully applied to the determination of Cd and Cr in the samples, highlighting that the matrix ions under consideration do not affect the extraction and determination steps. Flame atomic absorption spectrometry (dpeaa)DE-He213 Aliquat-336 (dpeaa)DE-He213 Ionic liquid (dpeaa)DE-He213 Plant samples (dpeaa)DE-He213 Chromium (dpeaa)DE-He213 Cadmium (dpeaa)DE-He213 Karakoy, Tolga verfasserin aut Çilesiz, Yeter verfasserin aut Altunay, Nail verfasserin aut Enthalten in Journal of the Iranian Chemical Society Tehran, 2004 18(2020), 1 vom: 26. Juli, Seite 117-127 (DE-627)515979767 (DE-600)2244820-2 1735-2428 nnns volume:18 year:2020 number:1 day:26 month:07 pages:117-127 https://dx.doi.org/10.1007/s13738-020-02009-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 18 2020 1 26 07 117-127
allfieldsSound	10.1007/s13738-020-02009-7 doi (DE-627)SPR042738636 (DE-599)SPRs13738-020-02009-7-e (SPR)s13738-020-02009-7-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Elik, Adil verfasserin aut Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract A new and rapid microextraction approach termed as ultrasonic-assisted ionic liquid-based microextraction (UA-ILME) was developed using ionic liquid Aliquat-336 as extraction solvent for the extraction of chromium and cadmium in bean samples collected from different regions in Turkey. The total amounts of analytes in the samples were measured by flame atomic absorption spectrophotometry. The basis of the extraction step is based on the complexation of Cr(III) and Cd(II) with diethyldithiocarbamate at pH 4.0. The hydrophobic ternary complexes containing analytes were then rapidly extracted from the sample solution to the ionic phase under the ultrasonic effect using tricaprylylmethylammonium chloride (Aliquat-336). Some experimental variables (pH, ligand amount, extraction solvent volume, ultrasound time, extraction temperature and sample volume) were optimized in detail. Following the optimization steps, the limits of detection (LODs, 3Sblank/m) for Cr(III) and Cd(II) were calculated as 0.45 ng $ mL^{−1} $ with linear range of 1.5–380 ng $ mL^{−1} $ and 0.25 ng $ mL^{−1} $ with linear range of 0.8–220 ng $ mL^{−1} $, respectively. Enrichment factors and average recoveries were ranged from 125.8–96.4 to 92.7–106.5%, respectively. The accuracy and precision of the method were validated by analyzing a certified reference material and spiked recovery tests. The UA-ILME method was successfully applied to the determination of Cd and Cr in the samples, highlighting that the matrix ions under consideration do not affect the extraction and determination steps. Flame atomic absorption spectrometry (dpeaa)DE-He213 Aliquat-336 (dpeaa)DE-He213 Ionic liquid (dpeaa)DE-He213 Plant samples (dpeaa)DE-He213 Chromium (dpeaa)DE-He213 Cadmium (dpeaa)DE-He213 Karakoy, Tolga verfasserin aut Çilesiz, Yeter verfasserin aut Altunay, Nail verfasserin aut Enthalten in Journal of the Iranian Chemical Society Tehran, 2004 18(2020), 1 vom: 26. Juli, Seite 117-127 (DE-627)515979767 (DE-600)2244820-2 1735-2428 nnns volume:18 year:2020 number:1 day:26 month:07 pages:117-127 https://dx.doi.org/10.1007/s13738-020-02009-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_165 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 18 2020 1 26 07 117-127
language	English
source	Enthalten in Journal of the Iranian Chemical Society 18(2020), 1 vom: 26. Juli, Seite 117-127 volume:18 year:2020 number:1 day:26 month:07 pages:117-127
sourceStr	Enthalten in Journal of the Iranian Chemical Society 18(2020), 1 vom: 26. Juli, Seite 117-127 volume:18 year:2020 number:1 day:26 month:07 pages:117-127
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Flame atomic absorption spectrometry Aliquat-336 Ionic liquid Plant samples Chromium Cadmium
dewey-raw	540
isfreeaccess_bool	false
container_title	Journal of the Iranian Chemical Society
authorswithroles_txt_mv	Elik, Adil @@aut@@ Karakoy, Tolga @@aut@@ Çilesiz, Yeter @@aut@@ Altunay, Nail @@aut@@
publishDateDaySort_date	2020-07-26T00:00:00Z
hierarchy_top_id	515979767
dewey-sort	3540
id	SPR042738636
language_de	englisch
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author	Elik, Adil
spellingShingle	Elik, Adil ddc 540 bkl 35.00 misc Flame atomic absorption spectrometry misc Aliquat-336 misc Ionic liquid misc Plant samples misc Chromium misc Cadmium Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336
authorStr	Elik, Adil
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topic_title	540 ASE 35.00 bkl Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336 Flame atomic absorption spectrometry (dpeaa)DE-He213 Aliquat-336 (dpeaa)DE-He213 Ionic liquid (dpeaa)DE-He213 Plant samples (dpeaa)DE-He213 Chromium (dpeaa)DE-He213 Cadmium (dpeaa)DE-He213
topic	ddc 540 bkl 35.00 misc Flame atomic absorption spectrometry misc Aliquat-336 misc Ionic liquid misc Plant samples misc Chromium misc Cadmium
topic_unstemmed	ddc 540 bkl 35.00 misc Flame atomic absorption spectrometry misc Aliquat-336 misc Ionic liquid misc Plant samples misc Chromium misc Cadmium
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title	Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336
ctrlnum	(DE-627)SPR042738636 (DE-599)SPRs13738-020-02009-7-e (SPR)s13738-020-02009-7-e
title_full	Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336
author_sort	Elik, Adil
journal	Journal of the Iranian Chemical Society
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author_browse	Elik, Adil Karakoy, Tolga Çilesiz, Yeter Altunay, Nail
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author-letter	Elik, Adil
doi_str_mv	10.1007/s13738-020-02009-7
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title_sort	flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid aliquat-336
title_auth	Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336
abstract	Abstract A new and rapid microextraction approach termed as ultrasonic-assisted ionic liquid-based microextraction (UA-ILME) was developed using ionic liquid Aliquat-336 as extraction solvent for the extraction of chromium and cadmium in bean samples collected from different regions in Turkey. The total amounts of analytes in the samples were measured by flame atomic absorption spectrophotometry. The basis of the extraction step is based on the complexation of Cr(III) and Cd(II) with diethyldithiocarbamate at pH 4.0. The hydrophobic ternary complexes containing analytes were then rapidly extracted from the sample solution to the ionic phase under the ultrasonic effect using tricaprylylmethylammonium chloride (Aliquat-336). Some experimental variables (pH, ligand amount, extraction solvent volume, ultrasound time, extraction temperature and sample volume) were optimized in detail. Following the optimization steps, the limits of detection (LODs, 3Sblank/m) for Cr(III) and Cd(II) were calculated as 0.45 ng $ mL^{−1} $ with linear range of 1.5–380 ng $ mL^{−1} $ and 0.25 ng $ mL^{−1} $ with linear range of 0.8–220 ng $ mL^{−1} $, respectively. Enrichment factors and average recoveries were ranged from 125.8–96.4 to 92.7–106.5%, respectively. The accuracy and precision of the method were validated by analyzing a certified reference material and spiked recovery tests. The UA-ILME method was successfully applied to the determination of Cd and Cr in the samples, highlighting that the matrix ions under consideration do not affect the extraction and determination steps.
abstractGer	Abstract A new and rapid microextraction approach termed as ultrasonic-assisted ionic liquid-based microextraction (UA-ILME) was developed using ionic liquid Aliquat-336 as extraction solvent for the extraction of chromium and cadmium in bean samples collected from different regions in Turkey. The total amounts of analytes in the samples were measured by flame atomic absorption spectrophotometry. The basis of the extraction step is based on the complexation of Cr(III) and Cd(II) with diethyldithiocarbamate at pH 4.0. The hydrophobic ternary complexes containing analytes were then rapidly extracted from the sample solution to the ionic phase under the ultrasonic effect using tricaprylylmethylammonium chloride (Aliquat-336). Some experimental variables (pH, ligand amount, extraction solvent volume, ultrasound time, extraction temperature and sample volume) were optimized in detail. Following the optimization steps, the limits of detection (LODs, 3Sblank/m) for Cr(III) and Cd(II) were calculated as 0.45 ng $ mL^{−1} $ with linear range of 1.5–380 ng $ mL^{−1} $ and 0.25 ng $ mL^{−1} $ with linear range of 0.8–220 ng $ mL^{−1} $, respectively. Enrichment factors and average recoveries were ranged from 125.8–96.4 to 92.7–106.5%, respectively. The accuracy and precision of the method were validated by analyzing a certified reference material and spiked recovery tests. The UA-ILME method was successfully applied to the determination of Cd and Cr in the samples, highlighting that the matrix ions under consideration do not affect the extraction and determination steps.
abstract_unstemmed	Abstract A new and rapid microextraction approach termed as ultrasonic-assisted ionic liquid-based microextraction (UA-ILME) was developed using ionic liquid Aliquat-336 as extraction solvent for the extraction of chromium and cadmium in bean samples collected from different regions in Turkey. The total amounts of analytes in the samples were measured by flame atomic absorption spectrophotometry. The basis of the extraction step is based on the complexation of Cr(III) and Cd(II) with diethyldithiocarbamate at pH 4.0. The hydrophobic ternary complexes containing analytes were then rapidly extracted from the sample solution to the ionic phase under the ultrasonic effect using tricaprylylmethylammonium chloride (Aliquat-336). Some experimental variables (pH, ligand amount, extraction solvent volume, ultrasound time, extraction temperature and sample volume) were optimized in detail. Following the optimization steps, the limits of detection (LODs, 3Sblank/m) for Cr(III) and Cd(II) were calculated as 0.45 ng $ mL^{−1} $ with linear range of 1.5–380 ng $ mL^{−1} $ and 0.25 ng $ mL^{−1} $ with linear range of 0.8–220 ng $ mL^{−1} $, respectively. Enrichment factors and average recoveries were ranged from 125.8–96.4 to 92.7–106.5%, respectively. The accuracy and precision of the method were validated by analyzing a certified reference material and spiked recovery tests. The UA-ILME method was successfully applied to the determination of Cd and Cr in the samples, highlighting that the matrix ions under consideration do not affect the extraction and determination steps.
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container_issue	1
title_short	Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336
url	https://dx.doi.org/10.1007/s13738-020-02009-7
remote_bool	true
author2	Karakoy, Tolga Çilesiz, Yeter Altunay, Nail
author2Str	Karakoy, Tolga Çilesiz, Yeter Altunay, Nail
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doi_str	10.1007/s13738-020-02009-7
up_date	2024-07-03T14:34:29.046Z
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Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336

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