Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber
Abstract Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [$ R_{F} $–($ CH_{2} $CHSiOMe)3)n–$ R_{F} $; n = 2, 3; $ R_{F} $ = CF($ CF_{3} $)$ OC_{3} %$ F_{7} $: $ R_{F} $–(VM)n–$ R_{F} $] undergoes the sol–gel reactions in the presence of α, ω-dihydroxy-terminated poly(dimethylsiloxane) [HO–($ S...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yamashita, Katsumi [verfasserIn] Yokouchi, Taiga [verfasserIn] Sawada, Hideo [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2020 |
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| Schlagwörter: |
-Dihydroxy-terminated poly(dimethylsiloxane) |
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| Übergeordnetes Werk: |
Enthalten in: Journal of coatings technology and research - Blue Bell, Pa., 2004, 18(2020), 1 vom: 19. Aug., Seite 63-73 |
|---|---|
| Übergeordnetes Werk: |
volume:18 ; year:2020 ; number:1 ; day:19 ; month:08 ; pages:63-73 |
| Links: |
|---|
| DOI / URN: |
10.1007/s11998-020-00382-9 |
|---|
| Katalog-ID: |
SPR042990157 |
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| 245 | 1 | 0 | |a Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber |
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| 520 | |a Abstract Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [$ R_{F} $–($ CH_{2} $CHSiOMe)3)n–$ R_{F} $; n = 2, 3; $ R_{F} $ = CF($ CF_{3} $)$ OC_{3} %$ F_{7} $: $ R_{F} $–(VM)n–$ R_{F} $] undergoes the sol–gel reactions in the presence of α, ω-dihydroxy-terminated poly(dimethylsiloxane) [HO–($ SiMe_{2} $O)nH: HPDMS] under non-catalytic conditions to provide the crosslinked $ R_{F} $–(VM)n–$ R_{F} $/HPDMS composite rubber in quantitative isolated yields. Especially, we can isolate the expected composite rubber through the sol–gel reactions, in which the contents of the $ R_{F} $–(VM)n–$ R_{F} $ oligomer based on employed oligomer and HPDMS are greater than 0.16%. In contrast, traditional silane coupling agents such as tetraethoxysilane, methyltrimethoxysilane and triethoxy-1H, 1H, 2H, 2H-tridecafluoro-n-octylsilane were unable to afford the expected composite rubber through the sol–gel reactions with HPDMS under similar conditions. The fluoroalkylated silicone composite rubber thus obtained gave no swelling behavior toward water, dimethyl sulfoxide and methanol; however, the composite rubber was found to display the higher swelling characteristic for toluene, hexane and tetrahydrofuran, especially for fluorinated aliphatic solvents. Interestingly, it was demonstrated that the fluoroalkylated silicone composite rubber swollen with hexane can adsorb a variety of aromatic compounds in aqueous methanol solutions. More interestingly, we found that the fluoroalkylated silicone composite rubber can exhibit an excellent adsorption ability toward the fluorinated aromatic compounds such as 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone, compared to that of the corresponding non-fluorinated one. Graphic abstract | ||
| 650 | 4 | |a Fluorinated oligomer |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a , |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a -Dihydroxy-terminated poly(dimethylsiloxane) |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Fluoroalkylated silicone composite rubber |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Adsorption |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Fluorinated aromatic compounds |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Yokouchi, Taiga |e verfasserin |4 aut | |
| 700 | 1 | |a Sawada, Hideo |e verfasserin |4 aut | |
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10.1007/s11998-020-00382-9 doi (DE-627)SPR042990157 (DE-599)SPRs11998-020-00382-9-e (SPR)s11998-020-00382-9-e DE-627 ger DE-627 rakwb eng 600 ASE Yamashita, Katsumi verfasserin aut Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [$ R_{F} $–($ CH_{2} $CHSiOMe)3)n–$ R_{F} $; n = 2, 3; $ R_{F} $ = CF($ CF_{3} $)$ OC_{3} %$ F_{7} $: $ R_{F} $–(VM)n–$ R_{F} $] undergoes the sol–gel reactions in the presence of α, ω-dihydroxy-terminated poly(dimethylsiloxane) [HO–($ SiMe_{2} $O)nH: HPDMS] under non-catalytic conditions to provide the crosslinked $ R_{F} $–(VM)n–$ R_{F} $/HPDMS composite rubber in quantitative isolated yields. Especially, we can isolate the expected composite rubber through the sol–gel reactions, in which the contents of the $ R_{F} $–(VM)n–$ R_{F} $ oligomer based on employed oligomer and HPDMS are greater than 0.16%. In contrast, traditional silane coupling agents such as tetraethoxysilane, methyltrimethoxysilane and triethoxy-1H, 1H, 2H, 2H-tridecafluoro-n-octylsilane were unable to afford the expected composite rubber through the sol–gel reactions with HPDMS under similar conditions. The fluoroalkylated silicone composite rubber thus obtained gave no swelling behavior toward water, dimethyl sulfoxide and methanol; however, the composite rubber was found to display the higher swelling characteristic for toluene, hexane and tetrahydrofuran, especially for fluorinated aliphatic solvents. Interestingly, it was demonstrated that the fluoroalkylated silicone composite rubber swollen with hexane can adsorb a variety of aromatic compounds in aqueous methanol solutions. More interestingly, we found that the fluoroalkylated silicone composite rubber can exhibit an excellent adsorption ability toward the fluorinated aromatic compounds such as 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone, compared to that of the corresponding non-fluorinated one. Graphic abstract Fluorinated oligomer (dpeaa)DE-He213 , (dpeaa)DE-He213 -Dihydroxy-terminated poly(dimethylsiloxane) (dpeaa)DE-He213 Fluoroalkylated silicone composite rubber (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 Fluorinated aromatic compounds (dpeaa)DE-He213 Yokouchi, Taiga verfasserin aut Sawada, Hideo verfasserin aut Enthalten in Journal of coatings technology and research Blue Bell, Pa., 2004 18(2020), 1 vom: 19. Aug., Seite 63-73 (DE-627)51834584X (DE-600)2252471-X 1935-3804 nnns volume:18 year:2020 number:1 day:19 month:08 pages:63-73 https://dx.doi.org/10.1007/s11998-020-00382-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 18 2020 1 19 08 63-73 |
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10.1007/s11998-020-00382-9 doi (DE-627)SPR042990157 (DE-599)SPRs11998-020-00382-9-e (SPR)s11998-020-00382-9-e DE-627 ger DE-627 rakwb eng 600 ASE Yamashita, Katsumi verfasserin aut Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [$ R_{F} $–($ CH_{2} $CHSiOMe)3)n–$ R_{F} $; n = 2, 3; $ R_{F} $ = CF($ CF_{3} $)$ OC_{3} %$ F_{7} $: $ R_{F} $–(VM)n–$ R_{F} $] undergoes the sol–gel reactions in the presence of α, ω-dihydroxy-terminated poly(dimethylsiloxane) [HO–($ SiMe_{2} $O)nH: HPDMS] under non-catalytic conditions to provide the crosslinked $ R_{F} $–(VM)n–$ R_{F} $/HPDMS composite rubber in quantitative isolated yields. Especially, we can isolate the expected composite rubber through the sol–gel reactions, in which the contents of the $ R_{F} $–(VM)n–$ R_{F} $ oligomer based on employed oligomer and HPDMS are greater than 0.16%. In contrast, traditional silane coupling agents such as tetraethoxysilane, methyltrimethoxysilane and triethoxy-1H, 1H, 2H, 2H-tridecafluoro-n-octylsilane were unable to afford the expected composite rubber through the sol–gel reactions with HPDMS under similar conditions. The fluoroalkylated silicone composite rubber thus obtained gave no swelling behavior toward water, dimethyl sulfoxide and methanol; however, the composite rubber was found to display the higher swelling characteristic for toluene, hexane and tetrahydrofuran, especially for fluorinated aliphatic solvents. Interestingly, it was demonstrated that the fluoroalkylated silicone composite rubber swollen with hexane can adsorb a variety of aromatic compounds in aqueous methanol solutions. More interestingly, we found that the fluoroalkylated silicone composite rubber can exhibit an excellent adsorption ability toward the fluorinated aromatic compounds such as 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone, compared to that of the corresponding non-fluorinated one. Graphic abstract Fluorinated oligomer (dpeaa)DE-He213 , (dpeaa)DE-He213 -Dihydroxy-terminated poly(dimethylsiloxane) (dpeaa)DE-He213 Fluoroalkylated silicone composite rubber (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 Fluorinated aromatic compounds (dpeaa)DE-He213 Yokouchi, Taiga verfasserin aut Sawada, Hideo verfasserin aut Enthalten in Journal of coatings technology and research Blue Bell, Pa., 2004 18(2020), 1 vom: 19. Aug., Seite 63-73 (DE-627)51834584X (DE-600)2252471-X 1935-3804 nnns volume:18 year:2020 number:1 day:19 month:08 pages:63-73 https://dx.doi.org/10.1007/s11998-020-00382-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 18 2020 1 19 08 63-73 |
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10.1007/s11998-020-00382-9 doi (DE-627)SPR042990157 (DE-599)SPRs11998-020-00382-9-e (SPR)s11998-020-00382-9-e DE-627 ger DE-627 rakwb eng 600 ASE Yamashita, Katsumi verfasserin aut Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [$ R_{F} $–($ CH_{2} $CHSiOMe)3)n–$ R_{F} $; n = 2, 3; $ R_{F} $ = CF($ CF_{3} $)$ OC_{3} %$ F_{7} $: $ R_{F} $–(VM)n–$ R_{F} $] undergoes the sol–gel reactions in the presence of α, ω-dihydroxy-terminated poly(dimethylsiloxane) [HO–($ SiMe_{2} $O)nH: HPDMS] under non-catalytic conditions to provide the crosslinked $ R_{F} $–(VM)n–$ R_{F} $/HPDMS composite rubber in quantitative isolated yields. Especially, we can isolate the expected composite rubber through the sol–gel reactions, in which the contents of the $ R_{F} $–(VM)n–$ R_{F} $ oligomer based on employed oligomer and HPDMS are greater than 0.16%. In contrast, traditional silane coupling agents such as tetraethoxysilane, methyltrimethoxysilane and triethoxy-1H, 1H, 2H, 2H-tridecafluoro-n-octylsilane were unable to afford the expected composite rubber through the sol–gel reactions with HPDMS under similar conditions. The fluoroalkylated silicone composite rubber thus obtained gave no swelling behavior toward water, dimethyl sulfoxide and methanol; however, the composite rubber was found to display the higher swelling characteristic for toluene, hexane and tetrahydrofuran, especially for fluorinated aliphatic solvents. Interestingly, it was demonstrated that the fluoroalkylated silicone composite rubber swollen with hexane can adsorb a variety of aromatic compounds in aqueous methanol solutions. More interestingly, we found that the fluoroalkylated silicone composite rubber can exhibit an excellent adsorption ability toward the fluorinated aromatic compounds such as 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone, compared to that of the corresponding non-fluorinated one. Graphic abstract Fluorinated oligomer (dpeaa)DE-He213 , (dpeaa)DE-He213 -Dihydroxy-terminated poly(dimethylsiloxane) (dpeaa)DE-He213 Fluoroalkylated silicone composite rubber (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 Fluorinated aromatic compounds (dpeaa)DE-He213 Yokouchi, Taiga verfasserin aut Sawada, Hideo verfasserin aut Enthalten in Journal of coatings technology and research Blue Bell, Pa., 2004 18(2020), 1 vom: 19. Aug., Seite 63-73 (DE-627)51834584X (DE-600)2252471-X 1935-3804 nnns volume:18 year:2020 number:1 day:19 month:08 pages:63-73 https://dx.doi.org/10.1007/s11998-020-00382-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 18 2020 1 19 08 63-73 |
| allfieldsGer |
10.1007/s11998-020-00382-9 doi (DE-627)SPR042990157 (DE-599)SPRs11998-020-00382-9-e (SPR)s11998-020-00382-9-e DE-627 ger DE-627 rakwb eng 600 ASE Yamashita, Katsumi verfasserin aut Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [$ R_{F} $–($ CH_{2} $CHSiOMe)3)n–$ R_{F} $; n = 2, 3; $ R_{F} $ = CF($ CF_{3} $)$ OC_{3} %$ F_{7} $: $ R_{F} $–(VM)n–$ R_{F} $] undergoes the sol–gel reactions in the presence of α, ω-dihydroxy-terminated poly(dimethylsiloxane) [HO–($ SiMe_{2} $O)nH: HPDMS] under non-catalytic conditions to provide the crosslinked $ R_{F} $–(VM)n–$ R_{F} $/HPDMS composite rubber in quantitative isolated yields. Especially, we can isolate the expected composite rubber through the sol–gel reactions, in which the contents of the $ R_{F} $–(VM)n–$ R_{F} $ oligomer based on employed oligomer and HPDMS are greater than 0.16%. In contrast, traditional silane coupling agents such as tetraethoxysilane, methyltrimethoxysilane and triethoxy-1H, 1H, 2H, 2H-tridecafluoro-n-octylsilane were unable to afford the expected composite rubber through the sol–gel reactions with HPDMS under similar conditions. The fluoroalkylated silicone composite rubber thus obtained gave no swelling behavior toward water, dimethyl sulfoxide and methanol; however, the composite rubber was found to display the higher swelling characteristic for toluene, hexane and tetrahydrofuran, especially for fluorinated aliphatic solvents. Interestingly, it was demonstrated that the fluoroalkylated silicone composite rubber swollen with hexane can adsorb a variety of aromatic compounds in aqueous methanol solutions. More interestingly, we found that the fluoroalkylated silicone composite rubber can exhibit an excellent adsorption ability toward the fluorinated aromatic compounds such as 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone, compared to that of the corresponding non-fluorinated one. Graphic abstract Fluorinated oligomer (dpeaa)DE-He213 , (dpeaa)DE-He213 -Dihydroxy-terminated poly(dimethylsiloxane) (dpeaa)DE-He213 Fluoroalkylated silicone composite rubber (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 Fluorinated aromatic compounds (dpeaa)DE-He213 Yokouchi, Taiga verfasserin aut Sawada, Hideo verfasserin aut Enthalten in Journal of coatings technology and research Blue Bell, Pa., 2004 18(2020), 1 vom: 19. Aug., Seite 63-73 (DE-627)51834584X (DE-600)2252471-X 1935-3804 nnns volume:18 year:2020 number:1 day:19 month:08 pages:63-73 https://dx.doi.org/10.1007/s11998-020-00382-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 18 2020 1 19 08 63-73 |
| allfieldsSound |
10.1007/s11998-020-00382-9 doi (DE-627)SPR042990157 (DE-599)SPRs11998-020-00382-9-e (SPR)s11998-020-00382-9-e DE-627 ger DE-627 rakwb eng 600 ASE Yamashita, Katsumi verfasserin aut Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [$ R_{F} $–($ CH_{2} $CHSiOMe)3)n–$ R_{F} $; n = 2, 3; $ R_{F} $ = CF($ CF_{3} $)$ OC_{3} %$ F_{7} $: $ R_{F} $–(VM)n–$ R_{F} $] undergoes the sol–gel reactions in the presence of α, ω-dihydroxy-terminated poly(dimethylsiloxane) [HO–($ SiMe_{2} $O)nH: HPDMS] under non-catalytic conditions to provide the crosslinked $ R_{F} $–(VM)n–$ R_{F} $/HPDMS composite rubber in quantitative isolated yields. Especially, we can isolate the expected composite rubber through the sol–gel reactions, in which the contents of the $ R_{F} $–(VM)n–$ R_{F} $ oligomer based on employed oligomer and HPDMS are greater than 0.16%. In contrast, traditional silane coupling agents such as tetraethoxysilane, methyltrimethoxysilane and triethoxy-1H, 1H, 2H, 2H-tridecafluoro-n-octylsilane were unable to afford the expected composite rubber through the sol–gel reactions with HPDMS under similar conditions. The fluoroalkylated silicone composite rubber thus obtained gave no swelling behavior toward water, dimethyl sulfoxide and methanol; however, the composite rubber was found to display the higher swelling characteristic for toluene, hexane and tetrahydrofuran, especially for fluorinated aliphatic solvents. Interestingly, it was demonstrated that the fluoroalkylated silicone composite rubber swollen with hexane can adsorb a variety of aromatic compounds in aqueous methanol solutions. More interestingly, we found that the fluoroalkylated silicone composite rubber can exhibit an excellent adsorption ability toward the fluorinated aromatic compounds such as 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone, compared to that of the corresponding non-fluorinated one. Graphic abstract Fluorinated oligomer (dpeaa)DE-He213 , (dpeaa)DE-He213 -Dihydroxy-terminated poly(dimethylsiloxane) (dpeaa)DE-He213 Fluoroalkylated silicone composite rubber (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 Fluorinated aromatic compounds (dpeaa)DE-He213 Yokouchi, Taiga verfasserin aut Sawada, Hideo verfasserin aut Enthalten in Journal of coatings technology and research Blue Bell, Pa., 2004 18(2020), 1 vom: 19. Aug., Seite 63-73 (DE-627)51834584X (DE-600)2252471-X 1935-3804 nnns volume:18 year:2020 number:1 day:19 month:08 pages:63-73 https://dx.doi.org/10.1007/s11998-020-00382-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 18 2020 1 19 08 63-73 |
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English |
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Enthalten in Journal of coatings technology and research 18(2020), 1 vom: 19. Aug., Seite 63-73 volume:18 year:2020 number:1 day:19 month:08 pages:63-73 |
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Enthalten in Journal of coatings technology and research 18(2020), 1 vom: 19. Aug., Seite 63-73 volume:18 year:2020 number:1 day:19 month:08 pages:63-73 |
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findex.gbv.de |
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Fluorinated oligomer , -Dihydroxy-terminated poly(dimethylsiloxane) Fluoroalkylated silicone composite rubber Adsorption Fluorinated aromatic compounds |
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Journal of coatings technology and research |
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Yamashita, Katsumi @@aut@@ Yokouchi, Taiga @@aut@@ Sawada, Hideo @@aut@@ |
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2020-08-19T00:00:00Z |
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Especially, we can isolate the expected composite rubber through the sol–gel reactions, in which the contents of the $ R_{F} $–(VM)n–$ R_{F} $ oligomer based on employed oligomer and HPDMS are greater than 0.16%. In contrast, traditional silane coupling agents such as tetraethoxysilane, methyltrimethoxysilane and triethoxy-1H, 1H, 2H, 2H-tridecafluoro-n-octylsilane were unable to afford the expected composite rubber through the sol–gel reactions with HPDMS under similar conditions. The fluoroalkylated silicone composite rubber thus obtained gave no swelling behavior toward water, dimethyl sulfoxide and methanol; however, the composite rubber was found to display the higher swelling characteristic for toluene, hexane and tetrahydrofuran, especially for fluorinated aliphatic solvents. Interestingly, it was demonstrated that the fluoroalkylated silicone composite rubber swollen with hexane can adsorb a variety of aromatic compounds in aqueous methanol solutions. More interestingly, we found that the fluoroalkylated silicone composite rubber can exhibit an excellent adsorption ability toward the fluorinated aromatic compounds such as 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone, compared to that of the corresponding non-fluorinated one. 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Yamashita, Katsumi |
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Yamashita, Katsumi ddc 600 misc Fluorinated oligomer misc , misc -Dihydroxy-terminated poly(dimethylsiloxane) misc Fluoroalkylated silicone composite rubber misc Adsorption misc Fluorinated aromatic compounds Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber |
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600 ASE Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber Fluorinated oligomer (dpeaa)DE-He213 , (dpeaa)DE-He213 -Dihydroxy-terminated poly(dimethylsiloxane) (dpeaa)DE-He213 Fluoroalkylated silicone composite rubber (dpeaa)DE-He213 Adsorption (dpeaa)DE-He213 Fluorinated aromatic compounds (dpeaa)DE-He213 |
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ddc 600 misc Fluorinated oligomer misc , misc -Dihydroxy-terminated poly(dimethylsiloxane) misc Fluoroalkylated silicone composite rubber misc Adsorption misc Fluorinated aromatic compounds |
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Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber |
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Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber |
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Yamashita, Katsumi Yokouchi, Taiga Sawada, Hideo |
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Elektronische Aufsätze |
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Yamashita, Katsumi |
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10.1007/s11998-020-00382-9 |
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| title_sort |
facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber |
| title_auth |
Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber |
| abstract |
Abstract Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [$ R_{F} $–($ CH_{2} $CHSiOMe)3)n–$ R_{F} $; n = 2, 3; $ R_{F} $ = CF($ CF_{3} $)$ OC_{3} %$ F_{7} $: $ R_{F} $–(VM)n–$ R_{F} $] undergoes the sol–gel reactions in the presence of α, ω-dihydroxy-terminated poly(dimethylsiloxane) [HO–($ SiMe_{2} $O)nH: HPDMS] under non-catalytic conditions to provide the crosslinked $ R_{F} $–(VM)n–$ R_{F} $/HPDMS composite rubber in quantitative isolated yields. Especially, we can isolate the expected composite rubber through the sol–gel reactions, in which the contents of the $ R_{F} $–(VM)n–$ R_{F} $ oligomer based on employed oligomer and HPDMS are greater than 0.16%. In contrast, traditional silane coupling agents such as tetraethoxysilane, methyltrimethoxysilane and triethoxy-1H, 1H, 2H, 2H-tridecafluoro-n-octylsilane were unable to afford the expected composite rubber through the sol–gel reactions with HPDMS under similar conditions. The fluoroalkylated silicone composite rubber thus obtained gave no swelling behavior toward water, dimethyl sulfoxide and methanol; however, the composite rubber was found to display the higher swelling characteristic for toluene, hexane and tetrahydrofuran, especially for fluorinated aliphatic solvents. Interestingly, it was demonstrated that the fluoroalkylated silicone composite rubber swollen with hexane can adsorb a variety of aromatic compounds in aqueous methanol solutions. More interestingly, we found that the fluoroalkylated silicone composite rubber can exhibit an excellent adsorption ability toward the fluorinated aromatic compounds such as 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone, compared to that of the corresponding non-fluorinated one. Graphic abstract |
| abstractGer |
Abstract Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [$ R_{F} $–($ CH_{2} $CHSiOMe)3)n–$ R_{F} $; n = 2, 3; $ R_{F} $ = CF($ CF_{3} $)$ OC_{3} %$ F_{7} $: $ R_{F} $–(VM)n–$ R_{F} $] undergoes the sol–gel reactions in the presence of α, ω-dihydroxy-terminated poly(dimethylsiloxane) [HO–($ SiMe_{2} $O)nH: HPDMS] under non-catalytic conditions to provide the crosslinked $ R_{F} $–(VM)n–$ R_{F} $/HPDMS composite rubber in quantitative isolated yields. Especially, we can isolate the expected composite rubber through the sol–gel reactions, in which the contents of the $ R_{F} $–(VM)n–$ R_{F} $ oligomer based on employed oligomer and HPDMS are greater than 0.16%. In contrast, traditional silane coupling agents such as tetraethoxysilane, methyltrimethoxysilane and triethoxy-1H, 1H, 2H, 2H-tridecafluoro-n-octylsilane were unable to afford the expected composite rubber through the sol–gel reactions with HPDMS under similar conditions. The fluoroalkylated silicone composite rubber thus obtained gave no swelling behavior toward water, dimethyl sulfoxide and methanol; however, the composite rubber was found to display the higher swelling characteristic for toluene, hexane and tetrahydrofuran, especially for fluorinated aliphatic solvents. Interestingly, it was demonstrated that the fluoroalkylated silicone composite rubber swollen with hexane can adsorb a variety of aromatic compounds in aqueous methanol solutions. More interestingly, we found that the fluoroalkylated silicone composite rubber can exhibit an excellent adsorption ability toward the fluorinated aromatic compounds such as 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone, compared to that of the corresponding non-fluorinated one. Graphic abstract |
| abstract_unstemmed |
Abstract Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [$ R_{F} $–($ CH_{2} $CHSiOMe)3)n–$ R_{F} $; n = 2, 3; $ R_{F} $ = CF($ CF_{3} $)$ OC_{3} %$ F_{7} $: $ R_{F} $–(VM)n–$ R_{F} $] undergoes the sol–gel reactions in the presence of α, ω-dihydroxy-terminated poly(dimethylsiloxane) [HO–($ SiMe_{2} $O)nH: HPDMS] under non-catalytic conditions to provide the crosslinked $ R_{F} $–(VM)n–$ R_{F} $/HPDMS composite rubber in quantitative isolated yields. Especially, we can isolate the expected composite rubber through the sol–gel reactions, in which the contents of the $ R_{F} $–(VM)n–$ R_{F} $ oligomer based on employed oligomer and HPDMS are greater than 0.16%. In contrast, traditional silane coupling agents such as tetraethoxysilane, methyltrimethoxysilane and triethoxy-1H, 1H, 2H, 2H-tridecafluoro-n-octylsilane were unable to afford the expected composite rubber through the sol–gel reactions with HPDMS under similar conditions. The fluoroalkylated silicone composite rubber thus obtained gave no swelling behavior toward water, dimethyl sulfoxide and methanol; however, the composite rubber was found to display the higher swelling characteristic for toluene, hexane and tetrahydrofuran, especially for fluorinated aliphatic solvents. Interestingly, it was demonstrated that the fluoroalkylated silicone composite rubber swollen with hexane can adsorb a variety of aromatic compounds in aqueous methanol solutions. More interestingly, we found that the fluoroalkylated silicone composite rubber can exhibit an excellent adsorption ability toward the fluorinated aromatic compounds such as 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone, compared to that of the corresponding non-fluorinated one. Graphic abstract |
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Facile preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α, ω-dihydroxy-terminated poly(dimethylsiloxane) composite rubber: application to effective removal of fluorinated aromatic compound from aqueous methanol solution by fluoroalkylated silicone composite rubber |
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| score |
7.4014225 |