A new empirical model for quiescent annealing of binary co-continuous polymer blends

Abstract The high sensitivity of the morphology and final properties of co-continuous polymer blends to thermal annealing has motivated many researchers to study the evolution of their morphology during thermal annealing process. In this work, phase coarsening of a low interfacial tension polylactic...
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Autor*in:	Haji Abdolrasouli, Mehdi [verfasserIn] Jalali Dil, Ebrahim [verfasserIn] Khorshidi Mal Ahmadi, Jamshid [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2021

Schlagwörter:	Co-continuous blend Morphology Annealing Phase coarsening Modeling

Übergeordnetes Werk:	Enthalten in: Iranian polymer journal - Tehran : Iran Polymer and Petrochemical Inst., 1992, 30(2021), 6 vom: 14. März, Seite 559-568
Übergeordnetes Werk:	volume:30 ; year:2021 ; number:6 ; day:14 ; month:03 ; pages:559-568

Links:	Volltext

DOI / URN:	10.1007/s13726-021-00912-1

Katalog-ID:	SPR043941583

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245	1	2	\|a A new empirical model for quiescent annealing of binary co-continuous polymer blends
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520			\|a Abstract The high sensitivity of the morphology and final properties of co-continuous polymer blends to thermal annealing has motivated many researchers to study the evolution of their morphology during thermal annealing process. In this work, phase coarsening of a low interfacial tension polylactic acid/polycaprolactone blend and a medium interfacial tension polylactic acid/polyethylene blend during quiescent annealing was studied in detail. To this aim, characteristic length scale of the microstructure of the polymer blends was determined at different annealing times. It was found that the phase size in both blends increased linearly by time at the early stage of the annealing and then the phase coarsening rate gradually decreased at longer times. Finally, the phase size of the blends approached a finite size. The mechanisms involved in the observed phase coarsening behavior were discussed in detail. Linear and exponential phase coarsening models in the literature could not explain the observed phase coarsening behavior in the studied blends. A new empirical model was presented which showed a very good agreement with both the obtained results in this work and the previous experimental data in the literature. The obtained results indicate the significant potential of the new model in analyzing phase coarsening behavior of co-continuous polymer blends.
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author_variant	a m h am amh d e j de dej m a j k maj majk
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allfields	10.1007/s13726-021-00912-1 doi (DE-627)SPR043941583 (DE-599)SPRs13726-021-00912-1-e (SPR)s13726-021-00912-1-e DE-627 ger DE-627 rakwb eng 540 660 ASE 58.22 bkl 51.70 bkl Haji Abdolrasouli, Mehdi verfasserin aut A new empirical model for quiescent annealing of binary co-continuous polymer blends 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The high sensitivity of the morphology and final properties of co-continuous polymer blends to thermal annealing has motivated many researchers to study the evolution of their morphology during thermal annealing process. In this work, phase coarsening of a low interfacial tension polylactic acid/polycaprolactone blend and a medium interfacial tension polylactic acid/polyethylene blend during quiescent annealing was studied in detail. To this aim, characteristic length scale of the microstructure of the polymer blends was determined at different annealing times. It was found that the phase size in both blends increased linearly by time at the early stage of the annealing and then the phase coarsening rate gradually decreased at longer times. Finally, the phase size of the blends approached a finite size. The mechanisms involved in the observed phase coarsening behavior were discussed in detail. Linear and exponential phase coarsening models in the literature could not explain the observed phase coarsening behavior in the studied blends. A new empirical model was presented which showed a very good agreement with both the obtained results in this work and the previous experimental data in the literature. The obtained results indicate the significant potential of the new model in analyzing phase coarsening behavior of co-continuous polymer blends. Co-continuous blend (dpeaa)DE-He213 Morphology (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Phase coarsening (dpeaa)DE-He213 Modeling (dpeaa)DE-He213 Jalali Dil, Ebrahim verfasserin aut Khorshidi Mal Ahmadi, Jamshid verfasserin aut Enthalten in Iranian polymer journal Tehran : Iran Polymer and Petrochemical Inst., 1992 30(2021), 6 vom: 14. März, Seite 559-568 (DE-627)506027341 (DE-600)2218064-3 1735-5265 nnns volume:30 year:2021 number:6 day:14 month:03 pages:559-568 https://dx.doi.org/10.1007/s13726-021-00912-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.22 ASE 51.70 ASE AR 30 2021 6 14 03 559-568
spelling	10.1007/s13726-021-00912-1 doi (DE-627)SPR043941583 (DE-599)SPRs13726-021-00912-1-e (SPR)s13726-021-00912-1-e DE-627 ger DE-627 rakwb eng 540 660 ASE 58.22 bkl 51.70 bkl Haji Abdolrasouli, Mehdi verfasserin aut A new empirical model for quiescent annealing of binary co-continuous polymer blends 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The high sensitivity of the morphology and final properties of co-continuous polymer blends to thermal annealing has motivated many researchers to study the evolution of their morphology during thermal annealing process. In this work, phase coarsening of a low interfacial tension polylactic acid/polycaprolactone blend and a medium interfacial tension polylactic acid/polyethylene blend during quiescent annealing was studied in detail. To this aim, characteristic length scale of the microstructure of the polymer blends was determined at different annealing times. It was found that the phase size in both blends increased linearly by time at the early stage of the annealing and then the phase coarsening rate gradually decreased at longer times. Finally, the phase size of the blends approached a finite size. The mechanisms involved in the observed phase coarsening behavior were discussed in detail. Linear and exponential phase coarsening models in the literature could not explain the observed phase coarsening behavior in the studied blends. A new empirical model was presented which showed a very good agreement with both the obtained results in this work and the previous experimental data in the literature. The obtained results indicate the significant potential of the new model in analyzing phase coarsening behavior of co-continuous polymer blends. Co-continuous blend (dpeaa)DE-He213 Morphology (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Phase coarsening (dpeaa)DE-He213 Modeling (dpeaa)DE-He213 Jalali Dil, Ebrahim verfasserin aut Khorshidi Mal Ahmadi, Jamshid verfasserin aut Enthalten in Iranian polymer journal Tehran : Iran Polymer and Petrochemical Inst., 1992 30(2021), 6 vom: 14. März, Seite 559-568 (DE-627)506027341 (DE-600)2218064-3 1735-5265 nnns volume:30 year:2021 number:6 day:14 month:03 pages:559-568 https://dx.doi.org/10.1007/s13726-021-00912-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.22 ASE 51.70 ASE AR 30 2021 6 14 03 559-568
allfields_unstemmed	10.1007/s13726-021-00912-1 doi (DE-627)SPR043941583 (DE-599)SPRs13726-021-00912-1-e (SPR)s13726-021-00912-1-e DE-627 ger DE-627 rakwb eng 540 660 ASE 58.22 bkl 51.70 bkl Haji Abdolrasouli, Mehdi verfasserin aut A new empirical model for quiescent annealing of binary co-continuous polymer blends 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The high sensitivity of the morphology and final properties of co-continuous polymer blends to thermal annealing has motivated many researchers to study the evolution of their morphology during thermal annealing process. In this work, phase coarsening of a low interfacial tension polylactic acid/polycaprolactone blend and a medium interfacial tension polylactic acid/polyethylene blend during quiescent annealing was studied in detail. To this aim, characteristic length scale of the microstructure of the polymer blends was determined at different annealing times. It was found that the phase size in both blends increased linearly by time at the early stage of the annealing and then the phase coarsening rate gradually decreased at longer times. Finally, the phase size of the blends approached a finite size. The mechanisms involved in the observed phase coarsening behavior were discussed in detail. Linear and exponential phase coarsening models in the literature could not explain the observed phase coarsening behavior in the studied blends. A new empirical model was presented which showed a very good agreement with both the obtained results in this work and the previous experimental data in the literature. The obtained results indicate the significant potential of the new model in analyzing phase coarsening behavior of co-continuous polymer blends. Co-continuous blend (dpeaa)DE-He213 Morphology (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Phase coarsening (dpeaa)DE-He213 Modeling (dpeaa)DE-He213 Jalali Dil, Ebrahim verfasserin aut Khorshidi Mal Ahmadi, Jamshid verfasserin aut Enthalten in Iranian polymer journal Tehran : Iran Polymer and Petrochemical Inst., 1992 30(2021), 6 vom: 14. März, Seite 559-568 (DE-627)506027341 (DE-600)2218064-3 1735-5265 nnns volume:30 year:2021 number:6 day:14 month:03 pages:559-568 https://dx.doi.org/10.1007/s13726-021-00912-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.22 ASE 51.70 ASE AR 30 2021 6 14 03 559-568
allfieldsGer	10.1007/s13726-021-00912-1 doi (DE-627)SPR043941583 (DE-599)SPRs13726-021-00912-1-e (SPR)s13726-021-00912-1-e DE-627 ger DE-627 rakwb eng 540 660 ASE 58.22 bkl 51.70 bkl Haji Abdolrasouli, Mehdi verfasserin aut A new empirical model for quiescent annealing of binary co-continuous polymer blends 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The high sensitivity of the morphology and final properties of co-continuous polymer blends to thermal annealing has motivated many researchers to study the evolution of their morphology during thermal annealing process. In this work, phase coarsening of a low interfacial tension polylactic acid/polycaprolactone blend and a medium interfacial tension polylactic acid/polyethylene blend during quiescent annealing was studied in detail. To this aim, characteristic length scale of the microstructure of the polymer blends was determined at different annealing times. It was found that the phase size in both blends increased linearly by time at the early stage of the annealing and then the phase coarsening rate gradually decreased at longer times. Finally, the phase size of the blends approached a finite size. The mechanisms involved in the observed phase coarsening behavior were discussed in detail. Linear and exponential phase coarsening models in the literature could not explain the observed phase coarsening behavior in the studied blends. A new empirical model was presented which showed a very good agreement with both the obtained results in this work and the previous experimental data in the literature. The obtained results indicate the significant potential of the new model in analyzing phase coarsening behavior of co-continuous polymer blends. Co-continuous blend (dpeaa)DE-He213 Morphology (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Phase coarsening (dpeaa)DE-He213 Modeling (dpeaa)DE-He213 Jalali Dil, Ebrahim verfasserin aut Khorshidi Mal Ahmadi, Jamshid verfasserin aut Enthalten in Iranian polymer journal Tehran : Iran Polymer and Petrochemical Inst., 1992 30(2021), 6 vom: 14. März, Seite 559-568 (DE-627)506027341 (DE-600)2218064-3 1735-5265 nnns volume:30 year:2021 number:6 day:14 month:03 pages:559-568 https://dx.doi.org/10.1007/s13726-021-00912-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.22 ASE 51.70 ASE AR 30 2021 6 14 03 559-568
allfieldsSound	10.1007/s13726-021-00912-1 doi (DE-627)SPR043941583 (DE-599)SPRs13726-021-00912-1-e (SPR)s13726-021-00912-1-e DE-627 ger DE-627 rakwb eng 540 660 ASE 58.22 bkl 51.70 bkl Haji Abdolrasouli, Mehdi verfasserin aut A new empirical model for quiescent annealing of binary co-continuous polymer blends 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The high sensitivity of the morphology and final properties of co-continuous polymer blends to thermal annealing has motivated many researchers to study the evolution of their morphology during thermal annealing process. In this work, phase coarsening of a low interfacial tension polylactic acid/polycaprolactone blend and a medium interfacial tension polylactic acid/polyethylene blend during quiescent annealing was studied in detail. To this aim, characteristic length scale of the microstructure of the polymer blends was determined at different annealing times. It was found that the phase size in both blends increased linearly by time at the early stage of the annealing and then the phase coarsening rate gradually decreased at longer times. Finally, the phase size of the blends approached a finite size. The mechanisms involved in the observed phase coarsening behavior were discussed in detail. Linear and exponential phase coarsening models in the literature could not explain the observed phase coarsening behavior in the studied blends. A new empirical model was presented which showed a very good agreement with both the obtained results in this work and the previous experimental data in the literature. The obtained results indicate the significant potential of the new model in analyzing phase coarsening behavior of co-continuous polymer blends. Co-continuous blend (dpeaa)DE-He213 Morphology (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Phase coarsening (dpeaa)DE-He213 Modeling (dpeaa)DE-He213 Jalali Dil, Ebrahim verfasserin aut Khorshidi Mal Ahmadi, Jamshid verfasserin aut Enthalten in Iranian polymer journal Tehran : Iran Polymer and Petrochemical Inst., 1992 30(2021), 6 vom: 14. März, Seite 559-568 (DE-627)506027341 (DE-600)2218064-3 1735-5265 nnns volume:30 year:2021 number:6 day:14 month:03 pages:559-568 https://dx.doi.org/10.1007/s13726-021-00912-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.22 ASE 51.70 ASE AR 30 2021 6 14 03 559-568
language	English
source	Enthalten in Iranian polymer journal 30(2021), 6 vom: 14. März, Seite 559-568 volume:30 year:2021 number:6 day:14 month:03 pages:559-568
sourceStr	Enthalten in Iranian polymer journal 30(2021), 6 vom: 14. März, Seite 559-568 volume:30 year:2021 number:6 day:14 month:03 pages:559-568
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Co-continuous blend Morphology Annealing Phase coarsening Modeling
dewey-raw	540
isfreeaccess_bool	false
container_title	Iranian polymer journal
authorswithroles_txt_mv	Haji Abdolrasouli, Mehdi @@aut@@ Jalali Dil, Ebrahim @@aut@@ Khorshidi Mal Ahmadi, Jamshid @@aut@@
publishDateDaySort_date	2021-03-14T00:00:00Z
hierarchy_top_id	506027341
dewey-sort	3540
id	SPR043941583
language_de	englisch
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author	Haji Abdolrasouli, Mehdi
spellingShingle	Haji Abdolrasouli, Mehdi ddc 540 bkl 58.22 bkl 51.70 misc Co-continuous blend misc Morphology misc Annealing misc Phase coarsening misc Modeling A new empirical model for quiescent annealing of binary co-continuous polymer blends
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topic_title	540 660 ASE 58.22 bkl 51.70 bkl A new empirical model for quiescent annealing of binary co-continuous polymer blends Co-continuous blend (dpeaa)DE-He213 Morphology (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Phase coarsening (dpeaa)DE-He213 Modeling (dpeaa)DE-He213
topic	ddc 540 bkl 58.22 bkl 51.70 misc Co-continuous blend misc Morphology misc Annealing misc Phase coarsening misc Modeling
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title	A new empirical model for quiescent annealing of binary co-continuous polymer blends
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title_full	A new empirical model for quiescent annealing of binary co-continuous polymer blends
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title_sort	new empirical model for quiescent annealing of binary co-continuous polymer blends
title_auth	A new empirical model for quiescent annealing of binary co-continuous polymer blends
abstract	Abstract The high sensitivity of the morphology and final properties of co-continuous polymer blends to thermal annealing has motivated many researchers to study the evolution of their morphology during thermal annealing process. In this work, phase coarsening of a low interfacial tension polylactic acid/polycaprolactone blend and a medium interfacial tension polylactic acid/polyethylene blend during quiescent annealing was studied in detail. To this aim, characteristic length scale of the microstructure of the polymer blends was determined at different annealing times. It was found that the phase size in both blends increased linearly by time at the early stage of the annealing and then the phase coarsening rate gradually decreased at longer times. Finally, the phase size of the blends approached a finite size. The mechanisms involved in the observed phase coarsening behavior were discussed in detail. Linear and exponential phase coarsening models in the literature could not explain the observed phase coarsening behavior in the studied blends. A new empirical model was presented which showed a very good agreement with both the obtained results in this work and the previous experimental data in the literature. The obtained results indicate the significant potential of the new model in analyzing phase coarsening behavior of co-continuous polymer blends.
abstractGer	Abstract The high sensitivity of the morphology and final properties of co-continuous polymer blends to thermal annealing has motivated many researchers to study the evolution of their morphology during thermal annealing process. In this work, phase coarsening of a low interfacial tension polylactic acid/polycaprolactone blend and a medium interfacial tension polylactic acid/polyethylene blend during quiescent annealing was studied in detail. To this aim, characteristic length scale of the microstructure of the polymer blends was determined at different annealing times. It was found that the phase size in both blends increased linearly by time at the early stage of the annealing and then the phase coarsening rate gradually decreased at longer times. Finally, the phase size of the blends approached a finite size. The mechanisms involved in the observed phase coarsening behavior were discussed in detail. Linear and exponential phase coarsening models in the literature could not explain the observed phase coarsening behavior in the studied blends. A new empirical model was presented which showed a very good agreement with both the obtained results in this work and the previous experimental data in the literature. The obtained results indicate the significant potential of the new model in analyzing phase coarsening behavior of co-continuous polymer blends.
abstract_unstemmed	Abstract The high sensitivity of the morphology and final properties of co-continuous polymer blends to thermal annealing has motivated many researchers to study the evolution of their morphology during thermal annealing process. In this work, phase coarsening of a low interfacial tension polylactic acid/polycaprolactone blend and a medium interfacial tension polylactic acid/polyethylene blend during quiescent annealing was studied in detail. To this aim, characteristic length scale of the microstructure of the polymer blends was determined at different annealing times. It was found that the phase size in both blends increased linearly by time at the early stage of the annealing and then the phase coarsening rate gradually decreased at longer times. Finally, the phase size of the blends approached a finite size. The mechanisms involved in the observed phase coarsening behavior were discussed in detail. Linear and exponential phase coarsening models in the literature could not explain the observed phase coarsening behavior in the studied blends. A new empirical model was presented which showed a very good agreement with both the obtained results in this work and the previous experimental data in the literature. The obtained results indicate the significant potential of the new model in analyzing phase coarsening behavior of co-continuous polymer blends.
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title_short	A new empirical model for quiescent annealing of binary co-continuous polymer blends
url	https://dx.doi.org/10.1007/s13726-021-00912-1
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A new empirical model for quiescent annealing of binary co-continuous polymer blends

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