Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain)
Abstract High sensitivity laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) has been utilized for the determination of trace elements in pyrite from the Tharsis VMS deposit, one of the most significant volcanogenic massive sulphide deposits in the southern Iberian Pyrite Belt. T...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Conde, Carmen [verfasserIn] Tornos, Fernando [verfasserIn] Danyushevsky, Leonid V. [verfasserIn] Large, Ross [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of Iberian geology - [Cham] : Springer International Publishing, 2000, 47(2021), 1-2 vom: 15. Feb., Seite 429-440 |
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| Übergeordnetes Werk: |
volume:47 ; year:2021 ; number:1-2 ; day:15 ; month:02 ; pages:429-440 |
| Links: |
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| DOI / URN: |
10.1007/s41513-020-00161-w |
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| Katalog-ID: |
SPR044001746 |
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| 520 | |a Abstract High sensitivity laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) has been utilized for the determination of trace elements in pyrite from the Tharsis VMS deposit, one of the most significant volcanogenic massive sulphide deposits in the southern Iberian Pyrite Belt. The study tracks the content and distribution of trace elements within the different facies of massive sulphides. Widespread and variable enrichment in elements such as Cu, Zn, and Pb in pyrite is interpreted to be due to the presence of nanoinclusions of chalcopyrite, sphalerite, and galena, respectively. A second group of elements, including As, Au, Tl, Mn and Mo, shows significant chemical variations according to the type of mineralization and the textural evolution of the pyrite. This behaviour is thought to be due to the fact that these metals are included in the mineral lattice and its incorporation is controlled by the degree of crystallinity, the temperature, and the redox conditions during crystallization. Early, spongiform and colloform pyrite in the stockwork is enriched in As and Au and interpreted to have formed from a high temperature and low f$ S_{2} $–f$ O_{2} $ fluid. Thallium, Mn, and Mo are enriched in pyrite precipitated at lower temperature and higher oxidation state, i.e., in the exhalative part of the system or in distal facies to the hydrothermal vents. In general, both Co and Ni show an irregular distribution and do not have the sympathetic distribution observed in equivalent studies. | ||
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10.1007/s41513-020-00161-w doi (DE-627)SPR044001746 (DE-599)SPRs41513-020-00161-w-e (SPR)s41513-020-00161-w-e DE-627 ger DE-627 rakwb eng 550 ASE 550 ASE 38.50 bkl 38.55 bkl Conde, Carmen verfasserin aut Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain) 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract High sensitivity laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) has been utilized for the determination of trace elements in pyrite from the Tharsis VMS deposit, one of the most significant volcanogenic massive sulphide deposits in the southern Iberian Pyrite Belt. The study tracks the content and distribution of trace elements within the different facies of massive sulphides. Widespread and variable enrichment in elements such as Cu, Zn, and Pb in pyrite is interpreted to be due to the presence of nanoinclusions of chalcopyrite, sphalerite, and galena, respectively. A second group of elements, including As, Au, Tl, Mn and Mo, shows significant chemical variations according to the type of mineralization and the textural evolution of the pyrite. This behaviour is thought to be due to the fact that these metals are included in the mineral lattice and its incorporation is controlled by the degree of crystallinity, the temperature, and the redox conditions during crystallization. Early, spongiform and colloform pyrite in the stockwork is enriched in As and Au and interpreted to have formed from a high temperature and low f$ S_{2} $–f$ O_{2} $ fluid. Thallium, Mn, and Mo are enriched in pyrite precipitated at lower temperature and higher oxidation state, i.e., in the exhalative part of the system or in distal facies to the hydrothermal vents. In general, both Co and Ni show an irregular distribution and do not have the sympathetic distribution observed in equivalent studies. LA-ICPMS (dpeaa)DE-He213 Pyrite (dpeaa)DE-He213 Trace elements (dpeaa)DE-He213 Tharsis (dpeaa)DE-He213 Massive sulphide (dpeaa)DE-He213 Iberian Pyrite Belt (dpeaa)DE-He213 Tornos, Fernando verfasserin aut Danyushevsky, Leonid V. verfasserin aut Large, Ross verfasserin aut Enthalten in Journal of Iberian geology [Cham] : Springer International Publishing, 2000 47(2021), 1-2 vom: 15. Feb., Seite 429-440 (DE-627)494830212 (DE-600)2196781-7 1886-7995 nnns volume:47 year:2021 number:1-2 day:15 month:02 pages:429-440 https://dx.doi.org/10.1007/s41513-020-00161-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.50 ASE 38.55 ASE AR 47 2021 1-2 15 02 429-440 |
| spelling |
10.1007/s41513-020-00161-w doi (DE-627)SPR044001746 (DE-599)SPRs41513-020-00161-w-e (SPR)s41513-020-00161-w-e DE-627 ger DE-627 rakwb eng 550 ASE 550 ASE 38.50 bkl 38.55 bkl Conde, Carmen verfasserin aut Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain) 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract High sensitivity laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) has been utilized for the determination of trace elements in pyrite from the Tharsis VMS deposit, one of the most significant volcanogenic massive sulphide deposits in the southern Iberian Pyrite Belt. The study tracks the content and distribution of trace elements within the different facies of massive sulphides. Widespread and variable enrichment in elements such as Cu, Zn, and Pb in pyrite is interpreted to be due to the presence of nanoinclusions of chalcopyrite, sphalerite, and galena, respectively. A second group of elements, including As, Au, Tl, Mn and Mo, shows significant chemical variations according to the type of mineralization and the textural evolution of the pyrite. This behaviour is thought to be due to the fact that these metals are included in the mineral lattice and its incorporation is controlled by the degree of crystallinity, the temperature, and the redox conditions during crystallization. Early, spongiform and colloform pyrite in the stockwork is enriched in As and Au and interpreted to have formed from a high temperature and low f$ S_{2} $–f$ O_{2} $ fluid. Thallium, Mn, and Mo are enriched in pyrite precipitated at lower temperature and higher oxidation state, i.e., in the exhalative part of the system or in distal facies to the hydrothermal vents. In general, both Co and Ni show an irregular distribution and do not have the sympathetic distribution observed in equivalent studies. LA-ICPMS (dpeaa)DE-He213 Pyrite (dpeaa)DE-He213 Trace elements (dpeaa)DE-He213 Tharsis (dpeaa)DE-He213 Massive sulphide (dpeaa)DE-He213 Iberian Pyrite Belt (dpeaa)DE-He213 Tornos, Fernando verfasserin aut Danyushevsky, Leonid V. verfasserin aut Large, Ross verfasserin aut Enthalten in Journal of Iberian geology [Cham] : Springer International Publishing, 2000 47(2021), 1-2 vom: 15. Feb., Seite 429-440 (DE-627)494830212 (DE-600)2196781-7 1886-7995 nnns volume:47 year:2021 number:1-2 day:15 month:02 pages:429-440 https://dx.doi.org/10.1007/s41513-020-00161-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.50 ASE 38.55 ASE AR 47 2021 1-2 15 02 429-440 |
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10.1007/s41513-020-00161-w doi (DE-627)SPR044001746 (DE-599)SPRs41513-020-00161-w-e (SPR)s41513-020-00161-w-e DE-627 ger DE-627 rakwb eng 550 ASE 550 ASE 38.50 bkl 38.55 bkl Conde, Carmen verfasserin aut Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain) 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract High sensitivity laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) has been utilized for the determination of trace elements in pyrite from the Tharsis VMS deposit, one of the most significant volcanogenic massive sulphide deposits in the southern Iberian Pyrite Belt. The study tracks the content and distribution of trace elements within the different facies of massive sulphides. Widespread and variable enrichment in elements such as Cu, Zn, and Pb in pyrite is interpreted to be due to the presence of nanoinclusions of chalcopyrite, sphalerite, and galena, respectively. A second group of elements, including As, Au, Tl, Mn and Mo, shows significant chemical variations according to the type of mineralization and the textural evolution of the pyrite. This behaviour is thought to be due to the fact that these metals are included in the mineral lattice and its incorporation is controlled by the degree of crystallinity, the temperature, and the redox conditions during crystallization. Early, spongiform and colloform pyrite in the stockwork is enriched in As and Au and interpreted to have formed from a high temperature and low f$ S_{2} $–f$ O_{2} $ fluid. Thallium, Mn, and Mo are enriched in pyrite precipitated at lower temperature and higher oxidation state, i.e., in the exhalative part of the system or in distal facies to the hydrothermal vents. In general, both Co and Ni show an irregular distribution and do not have the sympathetic distribution observed in equivalent studies. LA-ICPMS (dpeaa)DE-He213 Pyrite (dpeaa)DE-He213 Trace elements (dpeaa)DE-He213 Tharsis (dpeaa)DE-He213 Massive sulphide (dpeaa)DE-He213 Iberian Pyrite Belt (dpeaa)DE-He213 Tornos, Fernando verfasserin aut Danyushevsky, Leonid V. verfasserin aut Large, Ross verfasserin aut Enthalten in Journal of Iberian geology [Cham] : Springer International Publishing, 2000 47(2021), 1-2 vom: 15. Feb., Seite 429-440 (DE-627)494830212 (DE-600)2196781-7 1886-7995 nnns volume:47 year:2021 number:1-2 day:15 month:02 pages:429-440 https://dx.doi.org/10.1007/s41513-020-00161-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.50 ASE 38.55 ASE AR 47 2021 1-2 15 02 429-440 |
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10.1007/s41513-020-00161-w doi (DE-627)SPR044001746 (DE-599)SPRs41513-020-00161-w-e (SPR)s41513-020-00161-w-e DE-627 ger DE-627 rakwb eng 550 ASE 550 ASE 38.50 bkl 38.55 bkl Conde, Carmen verfasserin aut Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain) 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract High sensitivity laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) has been utilized for the determination of trace elements in pyrite from the Tharsis VMS deposit, one of the most significant volcanogenic massive sulphide deposits in the southern Iberian Pyrite Belt. The study tracks the content and distribution of trace elements within the different facies of massive sulphides. Widespread and variable enrichment in elements such as Cu, Zn, and Pb in pyrite is interpreted to be due to the presence of nanoinclusions of chalcopyrite, sphalerite, and galena, respectively. A second group of elements, including As, Au, Tl, Mn and Mo, shows significant chemical variations according to the type of mineralization and the textural evolution of the pyrite. This behaviour is thought to be due to the fact that these metals are included in the mineral lattice and its incorporation is controlled by the degree of crystallinity, the temperature, and the redox conditions during crystallization. Early, spongiform and colloform pyrite in the stockwork is enriched in As and Au and interpreted to have formed from a high temperature and low f$ S_{2} $–f$ O_{2} $ fluid. Thallium, Mn, and Mo are enriched in pyrite precipitated at lower temperature and higher oxidation state, i.e., in the exhalative part of the system or in distal facies to the hydrothermal vents. In general, both Co and Ni show an irregular distribution and do not have the sympathetic distribution observed in equivalent studies. LA-ICPMS (dpeaa)DE-He213 Pyrite (dpeaa)DE-He213 Trace elements (dpeaa)DE-He213 Tharsis (dpeaa)DE-He213 Massive sulphide (dpeaa)DE-He213 Iberian Pyrite Belt (dpeaa)DE-He213 Tornos, Fernando verfasserin aut Danyushevsky, Leonid V. verfasserin aut Large, Ross verfasserin aut Enthalten in Journal of Iberian geology [Cham] : Springer International Publishing, 2000 47(2021), 1-2 vom: 15. Feb., Seite 429-440 (DE-627)494830212 (DE-600)2196781-7 1886-7995 nnns volume:47 year:2021 number:1-2 day:15 month:02 pages:429-440 https://dx.doi.org/10.1007/s41513-020-00161-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.50 ASE 38.55 ASE AR 47 2021 1-2 15 02 429-440 |
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10.1007/s41513-020-00161-w doi (DE-627)SPR044001746 (DE-599)SPRs41513-020-00161-w-e (SPR)s41513-020-00161-w-e DE-627 ger DE-627 rakwb eng 550 ASE 550 ASE 38.50 bkl 38.55 bkl Conde, Carmen verfasserin aut Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain) 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract High sensitivity laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) has been utilized for the determination of trace elements in pyrite from the Tharsis VMS deposit, one of the most significant volcanogenic massive sulphide deposits in the southern Iberian Pyrite Belt. The study tracks the content and distribution of trace elements within the different facies of massive sulphides. Widespread and variable enrichment in elements such as Cu, Zn, and Pb in pyrite is interpreted to be due to the presence of nanoinclusions of chalcopyrite, sphalerite, and galena, respectively. A second group of elements, including As, Au, Tl, Mn and Mo, shows significant chemical variations according to the type of mineralization and the textural evolution of the pyrite. This behaviour is thought to be due to the fact that these metals are included in the mineral lattice and its incorporation is controlled by the degree of crystallinity, the temperature, and the redox conditions during crystallization. Early, spongiform and colloform pyrite in the stockwork is enriched in As and Au and interpreted to have formed from a high temperature and low f$ S_{2} $–f$ O_{2} $ fluid. Thallium, Mn, and Mo are enriched in pyrite precipitated at lower temperature and higher oxidation state, i.e., in the exhalative part of the system or in distal facies to the hydrothermal vents. In general, both Co and Ni show an irregular distribution and do not have the sympathetic distribution observed in equivalent studies. LA-ICPMS (dpeaa)DE-He213 Pyrite (dpeaa)DE-He213 Trace elements (dpeaa)DE-He213 Tharsis (dpeaa)DE-He213 Massive sulphide (dpeaa)DE-He213 Iberian Pyrite Belt (dpeaa)DE-He213 Tornos, Fernando verfasserin aut Danyushevsky, Leonid V. verfasserin aut Large, Ross verfasserin aut Enthalten in Journal of Iberian geology [Cham] : Springer International Publishing, 2000 47(2021), 1-2 vom: 15. Feb., Seite 429-440 (DE-627)494830212 (DE-600)2196781-7 1886-7995 nnns volume:47 year:2021 number:1-2 day:15 month:02 pages:429-440 https://dx.doi.org/10.1007/s41513-020-00161-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OPC-GGO SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.50 ASE 38.55 ASE AR 47 2021 1-2 15 02 429-440 |
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Enthalten in Journal of Iberian geology 47(2021), 1-2 vom: 15. Feb., Seite 429-440 volume:47 year:2021 number:1-2 day:15 month:02 pages:429-440 |
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LA-ICPMS Pyrite Trace elements Tharsis Massive sulphide Iberian Pyrite Belt |
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Conde, Carmen @@aut@@ Tornos, Fernando @@aut@@ Danyushevsky, Leonid V. @@aut@@ Large, Ross @@aut@@ |
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The study tracks the content and distribution of trace elements within the different facies of massive sulphides. Widespread and variable enrichment in elements such as Cu, Zn, and Pb in pyrite is interpreted to be due to the presence of nanoinclusions of chalcopyrite, sphalerite, and galena, respectively. A second group of elements, including As, Au, Tl, Mn and Mo, shows significant chemical variations according to the type of mineralization and the textural evolution of the pyrite. This behaviour is thought to be due to the fact that these metals are included in the mineral lattice and its incorporation is controlled by the degree of crystallinity, the temperature, and the redox conditions during crystallization. Early, spongiform and colloform pyrite in the stockwork is enriched in As and Au and interpreted to have formed from a high temperature and low f$ S_{2} $–f$ O_{2} $ fluid. Thallium, Mn, and Mo are enriched in pyrite precipitated at lower temperature and higher oxidation state, i.e., in the exhalative part of the system or in distal facies to the hydrothermal vents. 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Conde, Carmen |
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Conde, Carmen ddc 550 bkl 38.50 bkl 38.55 misc LA-ICPMS misc Pyrite misc Trace elements misc Tharsis misc Massive sulphide misc Iberian Pyrite Belt Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain) |
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550 ASE 38.50 bkl 38.55 bkl Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain) LA-ICPMS (dpeaa)DE-He213 Pyrite (dpeaa)DE-He213 Trace elements (dpeaa)DE-He213 Tharsis (dpeaa)DE-He213 Massive sulphide (dpeaa)DE-He213 Iberian Pyrite Belt (dpeaa)DE-He213 |
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ddc 550 bkl 38.50 bkl 38.55 misc LA-ICPMS misc Pyrite misc Trace elements misc Tharsis misc Massive sulphide misc Iberian Pyrite Belt |
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Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain) |
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Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain) |
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Conde, Carmen Tornos, Fernando Danyushevsky, Leonid V. Large, Ross |
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Conde, Carmen |
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laser ablation-icpms analysis of trace elements in pyrite from the tharsis massive sulphide deposit, iberian pyrite belt (spain) |
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Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain) |
| abstract |
Abstract High sensitivity laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) has been utilized for the determination of trace elements in pyrite from the Tharsis VMS deposit, one of the most significant volcanogenic massive sulphide deposits in the southern Iberian Pyrite Belt. The study tracks the content and distribution of trace elements within the different facies of massive sulphides. Widespread and variable enrichment in elements such as Cu, Zn, and Pb in pyrite is interpreted to be due to the presence of nanoinclusions of chalcopyrite, sphalerite, and galena, respectively. A second group of elements, including As, Au, Tl, Mn and Mo, shows significant chemical variations according to the type of mineralization and the textural evolution of the pyrite. This behaviour is thought to be due to the fact that these metals are included in the mineral lattice and its incorporation is controlled by the degree of crystallinity, the temperature, and the redox conditions during crystallization. Early, spongiform and colloform pyrite in the stockwork is enriched in As and Au and interpreted to have formed from a high temperature and low f$ S_{2} $–f$ O_{2} $ fluid. Thallium, Mn, and Mo are enriched in pyrite precipitated at lower temperature and higher oxidation state, i.e., in the exhalative part of the system or in distal facies to the hydrothermal vents. In general, both Co and Ni show an irregular distribution and do not have the sympathetic distribution observed in equivalent studies. |
| abstractGer |
Abstract High sensitivity laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) has been utilized for the determination of trace elements in pyrite from the Tharsis VMS deposit, one of the most significant volcanogenic massive sulphide deposits in the southern Iberian Pyrite Belt. The study tracks the content and distribution of trace elements within the different facies of massive sulphides. Widespread and variable enrichment in elements such as Cu, Zn, and Pb in pyrite is interpreted to be due to the presence of nanoinclusions of chalcopyrite, sphalerite, and galena, respectively. A second group of elements, including As, Au, Tl, Mn and Mo, shows significant chemical variations according to the type of mineralization and the textural evolution of the pyrite. This behaviour is thought to be due to the fact that these metals are included in the mineral lattice and its incorporation is controlled by the degree of crystallinity, the temperature, and the redox conditions during crystallization. Early, spongiform and colloform pyrite in the stockwork is enriched in As and Au and interpreted to have formed from a high temperature and low f$ S_{2} $–f$ O_{2} $ fluid. Thallium, Mn, and Mo are enriched in pyrite precipitated at lower temperature and higher oxidation state, i.e., in the exhalative part of the system or in distal facies to the hydrothermal vents. In general, both Co and Ni show an irregular distribution and do not have the sympathetic distribution observed in equivalent studies. |
| abstract_unstemmed |
Abstract High sensitivity laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) has been utilized for the determination of trace elements in pyrite from the Tharsis VMS deposit, one of the most significant volcanogenic massive sulphide deposits in the southern Iberian Pyrite Belt. The study tracks the content and distribution of trace elements within the different facies of massive sulphides. Widespread and variable enrichment in elements such as Cu, Zn, and Pb in pyrite is interpreted to be due to the presence of nanoinclusions of chalcopyrite, sphalerite, and galena, respectively. A second group of elements, including As, Au, Tl, Mn and Mo, shows significant chemical variations according to the type of mineralization and the textural evolution of the pyrite. This behaviour is thought to be due to the fact that these metals are included in the mineral lattice and its incorporation is controlled by the degree of crystallinity, the temperature, and the redox conditions during crystallization. Early, spongiform and colloform pyrite in the stockwork is enriched in As and Au and interpreted to have formed from a high temperature and low f$ S_{2} $–f$ O_{2} $ fluid. Thallium, Mn, and Mo are enriched in pyrite precipitated at lower temperature and higher oxidation state, i.e., in the exhalative part of the system or in distal facies to the hydrothermal vents. In general, both Co and Ni show an irregular distribution and do not have the sympathetic distribution observed in equivalent studies. |
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Laser ablation-ICPMS analysis of trace elements in pyrite from the Tharsis massive sulphide deposit, Iberian Pyrite Belt (Spain) |
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| score |
7.3978424 |