An eco-friendly and durable multifunctional cotton fabric incorporating ZnO and a branched polymer
Abstract In this study, we investigated a two-step method of preparing cotton fabrics with flame retardancy and UV-blocking properties. This method involved the in situ deposition of ZnO nanoparticles (NPs) and the synthesis of a phosphorus ammonium salt. The application of ZnO NPs on cotton fabrics...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ling, Chao [verfasserIn] Guo, Lamei [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Nature B.V. 2021 |
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| Übergeordnetes Werk: |
Enthalten in: Cellulose - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994, 28(2021), 9 vom: 14. Apr., Seite 5843-5854 |
|---|---|
| Übergeordnetes Werk: |
volume:28 ; year:2021 ; number:9 ; day:14 ; month:04 ; pages:5843-5854 |
| Links: |
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| DOI / URN: |
10.1007/s10570-021-03868-w |
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| Katalog-ID: |
SPR044181469 |
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| 520 | |a Abstract In this study, we investigated a two-step method of preparing cotton fabrics with flame retardancy and UV-blocking properties. This method involved the in situ deposition of ZnO nanoparticles (NPs) and the synthesis of a phosphorus ammonium salt. The application of ZnO NPs on cotton fabrics was achieved by an in situ ammonia-smoking method with zinc acetate and ammonia. A hyperbranched polyphosphate ammonium salt (FHPOPN) was synthesized for application to the cotton fabrics after the ammonia-smoked finish was applied. This research mainly focused on the fire-resistance and UV-blocking performance of cotton fabrics. The treated cotton fabrics were observed by scanning electron microscopy (SEM). The Fourier transform infrared (FTIR) spectroscopy results showed that ZnO NPs were successfully deposited in the fabric and that FHPOPN was bound to the fabric by covalent bonds. The flame retardancy and UV-protection properties of the treated cotton fabrics were studied. The effect of the zinc acetate concentration on the fire resistance and UV-blocking performance of the fabrics was investigated. The cotton fabrics treated with 70 g/L zinc acetate and 160 g/L FHPOPN obtained excellent flame retardancy with a char length of 57 mm and an limited oxygen index (LOI) value of 36.4%. The peak heat release rate and the total heat release of the ZnO/FHPOPN-treated samples were 26 kW/$ m^{2} $ and 4.4 MJ/$ m^{2} $, respectively, which were slightly lower than those of the FHPOPN-treated samples and much lower than those of the control cotton fabric sample. Furthermore, the thermogravimetric analyses of ZnO/FHPOPN-treated cotton fabric showed a char yield of 33.3% at 800 °C, whereas FHPOPN-treated cotton fabrics had a 29.7% char yield. The ZnO/FHPOPN-treated cotton fabric exhibited effective UV-protection properties with a UPF value of 224.80. These results demonstrated that the ZnO/FHPOPN-treated fabric had excellent flame retardancy, washability and UV-protection performance and revealed the importance of ZnO NPs in enhancing the flame retardancy and UV-blocking of performance cotton fabrics. Graphical abstract | ||
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10.1007/s10570-021-03868-w doi (DE-627)SPR044181469 (SPR)s10570-021-03868-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.63 bkl 35.77 bkl Ling, Chao verfasserin aut An eco-friendly and durable multifunctional cotton fabric incorporating ZnO and a branched polymer 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2021 Abstract In this study, we investigated a two-step method of preparing cotton fabrics with flame retardancy and UV-blocking properties. This method involved the in situ deposition of ZnO nanoparticles (NPs) and the synthesis of a phosphorus ammonium salt. The application of ZnO NPs on cotton fabrics was achieved by an in situ ammonia-smoking method with zinc acetate and ammonia. A hyperbranched polyphosphate ammonium salt (FHPOPN) was synthesized for application to the cotton fabrics after the ammonia-smoked finish was applied. This research mainly focused on the fire-resistance and UV-blocking performance of cotton fabrics. The treated cotton fabrics were observed by scanning electron microscopy (SEM). The Fourier transform infrared (FTIR) spectroscopy results showed that ZnO NPs were successfully deposited in the fabric and that FHPOPN was bound to the fabric by covalent bonds. The flame retardancy and UV-protection properties of the treated cotton fabrics were studied. The effect of the zinc acetate concentration on the fire resistance and UV-blocking performance of the fabrics was investigated. The cotton fabrics treated with 70 g/L zinc acetate and 160 g/L FHPOPN obtained excellent flame retardancy with a char length of 57 mm and an limited oxygen index (LOI) value of 36.4%. The peak heat release rate and the total heat release of the ZnO/FHPOPN-treated samples were 26 kW/$ m^{2} $ and 4.4 MJ/$ m^{2} $, respectively, which were slightly lower than those of the FHPOPN-treated samples and much lower than those of the control cotton fabric sample. Furthermore, the thermogravimetric analyses of ZnO/FHPOPN-treated cotton fabric showed a char yield of 33.3% at 800 °C, whereas FHPOPN-treated cotton fabrics had a 29.7% char yield. The ZnO/FHPOPN-treated cotton fabric exhibited effective UV-protection properties with a UPF value of 224.80. These results demonstrated that the ZnO/FHPOPN-treated fabric had excellent flame retardancy, washability and UV-protection performance and revealed the importance of ZnO NPs in enhancing the flame retardancy and UV-blocking of performance cotton fabrics. Graphical abstract Cotton fabric (dpeaa)DE-He213 In situ (dpeaa)DE-He213 ZnO (dpeaa)DE-He213 Flame retardant (dpeaa)DE-He213 UV protection (dpeaa)DE-He213 Guo, Lamei verfasserin aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 28(2021), 9 vom: 14. Apr., Seite 5843-5854 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:28 year:2021 number:9 day:14 month:04 pages:5843-5854 https://dx.doi.org/10.1007/s10570-021-03868-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.63 ASE 35.77 ASE AR 28 2021 9 14 04 5843-5854 |
| spelling |
10.1007/s10570-021-03868-w doi (DE-627)SPR044181469 (SPR)s10570-021-03868-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.63 bkl 35.77 bkl Ling, Chao verfasserin aut An eco-friendly and durable multifunctional cotton fabric incorporating ZnO and a branched polymer 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2021 Abstract In this study, we investigated a two-step method of preparing cotton fabrics with flame retardancy and UV-blocking properties. This method involved the in situ deposition of ZnO nanoparticles (NPs) and the synthesis of a phosphorus ammonium salt. The application of ZnO NPs on cotton fabrics was achieved by an in situ ammonia-smoking method with zinc acetate and ammonia. A hyperbranched polyphosphate ammonium salt (FHPOPN) was synthesized for application to the cotton fabrics after the ammonia-smoked finish was applied. This research mainly focused on the fire-resistance and UV-blocking performance of cotton fabrics. The treated cotton fabrics were observed by scanning electron microscopy (SEM). The Fourier transform infrared (FTIR) spectroscopy results showed that ZnO NPs were successfully deposited in the fabric and that FHPOPN was bound to the fabric by covalent bonds. The flame retardancy and UV-protection properties of the treated cotton fabrics were studied. The effect of the zinc acetate concentration on the fire resistance and UV-blocking performance of the fabrics was investigated. The cotton fabrics treated with 70 g/L zinc acetate and 160 g/L FHPOPN obtained excellent flame retardancy with a char length of 57 mm and an limited oxygen index (LOI) value of 36.4%. The peak heat release rate and the total heat release of the ZnO/FHPOPN-treated samples were 26 kW/$ m^{2} $ and 4.4 MJ/$ m^{2} $, respectively, which were slightly lower than those of the FHPOPN-treated samples and much lower than those of the control cotton fabric sample. Furthermore, the thermogravimetric analyses of ZnO/FHPOPN-treated cotton fabric showed a char yield of 33.3% at 800 °C, whereas FHPOPN-treated cotton fabrics had a 29.7% char yield. The ZnO/FHPOPN-treated cotton fabric exhibited effective UV-protection properties with a UPF value of 224.80. These results demonstrated that the ZnO/FHPOPN-treated fabric had excellent flame retardancy, washability and UV-protection performance and revealed the importance of ZnO NPs in enhancing the flame retardancy and UV-blocking of performance cotton fabrics. Graphical abstract Cotton fabric (dpeaa)DE-He213 In situ (dpeaa)DE-He213 ZnO (dpeaa)DE-He213 Flame retardant (dpeaa)DE-He213 UV protection (dpeaa)DE-He213 Guo, Lamei verfasserin aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 28(2021), 9 vom: 14. Apr., Seite 5843-5854 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:28 year:2021 number:9 day:14 month:04 pages:5843-5854 https://dx.doi.org/10.1007/s10570-021-03868-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.63 ASE 35.77 ASE AR 28 2021 9 14 04 5843-5854 |
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10.1007/s10570-021-03868-w doi (DE-627)SPR044181469 (SPR)s10570-021-03868-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.63 bkl 35.77 bkl Ling, Chao verfasserin aut An eco-friendly and durable multifunctional cotton fabric incorporating ZnO and a branched polymer 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2021 Abstract In this study, we investigated a two-step method of preparing cotton fabrics with flame retardancy and UV-blocking properties. This method involved the in situ deposition of ZnO nanoparticles (NPs) and the synthesis of a phosphorus ammonium salt. The application of ZnO NPs on cotton fabrics was achieved by an in situ ammonia-smoking method with zinc acetate and ammonia. A hyperbranched polyphosphate ammonium salt (FHPOPN) was synthesized for application to the cotton fabrics after the ammonia-smoked finish was applied. This research mainly focused on the fire-resistance and UV-blocking performance of cotton fabrics. The treated cotton fabrics were observed by scanning electron microscopy (SEM). The Fourier transform infrared (FTIR) spectroscopy results showed that ZnO NPs were successfully deposited in the fabric and that FHPOPN was bound to the fabric by covalent bonds. The flame retardancy and UV-protection properties of the treated cotton fabrics were studied. The effect of the zinc acetate concentration on the fire resistance and UV-blocking performance of the fabrics was investigated. The cotton fabrics treated with 70 g/L zinc acetate and 160 g/L FHPOPN obtained excellent flame retardancy with a char length of 57 mm and an limited oxygen index (LOI) value of 36.4%. The peak heat release rate and the total heat release of the ZnO/FHPOPN-treated samples were 26 kW/$ m^{2} $ and 4.4 MJ/$ m^{2} $, respectively, which were slightly lower than those of the FHPOPN-treated samples and much lower than those of the control cotton fabric sample. Furthermore, the thermogravimetric analyses of ZnO/FHPOPN-treated cotton fabric showed a char yield of 33.3% at 800 °C, whereas FHPOPN-treated cotton fabrics had a 29.7% char yield. The ZnO/FHPOPN-treated cotton fabric exhibited effective UV-protection properties with a UPF value of 224.80. These results demonstrated that the ZnO/FHPOPN-treated fabric had excellent flame retardancy, washability and UV-protection performance and revealed the importance of ZnO NPs in enhancing the flame retardancy and UV-blocking of performance cotton fabrics. Graphical abstract Cotton fabric (dpeaa)DE-He213 In situ (dpeaa)DE-He213 ZnO (dpeaa)DE-He213 Flame retardant (dpeaa)DE-He213 UV protection (dpeaa)DE-He213 Guo, Lamei verfasserin aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 28(2021), 9 vom: 14. Apr., Seite 5843-5854 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:28 year:2021 number:9 day:14 month:04 pages:5843-5854 https://dx.doi.org/10.1007/s10570-021-03868-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.63 ASE 35.77 ASE AR 28 2021 9 14 04 5843-5854 |
| allfieldsGer |
10.1007/s10570-021-03868-w doi (DE-627)SPR044181469 (SPR)s10570-021-03868-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.63 bkl 35.77 bkl Ling, Chao verfasserin aut An eco-friendly and durable multifunctional cotton fabric incorporating ZnO and a branched polymer 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2021 Abstract In this study, we investigated a two-step method of preparing cotton fabrics with flame retardancy and UV-blocking properties. This method involved the in situ deposition of ZnO nanoparticles (NPs) and the synthesis of a phosphorus ammonium salt. The application of ZnO NPs on cotton fabrics was achieved by an in situ ammonia-smoking method with zinc acetate and ammonia. A hyperbranched polyphosphate ammonium salt (FHPOPN) was synthesized for application to the cotton fabrics after the ammonia-smoked finish was applied. This research mainly focused on the fire-resistance and UV-blocking performance of cotton fabrics. The treated cotton fabrics were observed by scanning electron microscopy (SEM). The Fourier transform infrared (FTIR) spectroscopy results showed that ZnO NPs were successfully deposited in the fabric and that FHPOPN was bound to the fabric by covalent bonds. The flame retardancy and UV-protection properties of the treated cotton fabrics were studied. The effect of the zinc acetate concentration on the fire resistance and UV-blocking performance of the fabrics was investigated. The cotton fabrics treated with 70 g/L zinc acetate and 160 g/L FHPOPN obtained excellent flame retardancy with a char length of 57 mm and an limited oxygen index (LOI) value of 36.4%. The peak heat release rate and the total heat release of the ZnO/FHPOPN-treated samples were 26 kW/$ m^{2} $ and 4.4 MJ/$ m^{2} $, respectively, which were slightly lower than those of the FHPOPN-treated samples and much lower than those of the control cotton fabric sample. Furthermore, the thermogravimetric analyses of ZnO/FHPOPN-treated cotton fabric showed a char yield of 33.3% at 800 °C, whereas FHPOPN-treated cotton fabrics had a 29.7% char yield. The ZnO/FHPOPN-treated cotton fabric exhibited effective UV-protection properties with a UPF value of 224.80. These results demonstrated that the ZnO/FHPOPN-treated fabric had excellent flame retardancy, washability and UV-protection performance and revealed the importance of ZnO NPs in enhancing the flame retardancy and UV-blocking of performance cotton fabrics. Graphical abstract Cotton fabric (dpeaa)DE-He213 In situ (dpeaa)DE-He213 ZnO (dpeaa)DE-He213 Flame retardant (dpeaa)DE-He213 UV protection (dpeaa)DE-He213 Guo, Lamei verfasserin aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 28(2021), 9 vom: 14. Apr., Seite 5843-5854 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:28 year:2021 number:9 day:14 month:04 pages:5843-5854 https://dx.doi.org/10.1007/s10570-021-03868-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.63 ASE 35.77 ASE AR 28 2021 9 14 04 5843-5854 |
| allfieldsSound |
10.1007/s10570-021-03868-w doi (DE-627)SPR044181469 (SPR)s10570-021-03868-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.63 bkl 35.77 bkl Ling, Chao verfasserin aut An eco-friendly and durable multifunctional cotton fabric incorporating ZnO and a branched polymer 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature B.V. 2021 Abstract In this study, we investigated a two-step method of preparing cotton fabrics with flame retardancy and UV-blocking properties. This method involved the in situ deposition of ZnO nanoparticles (NPs) and the synthesis of a phosphorus ammonium salt. The application of ZnO NPs on cotton fabrics was achieved by an in situ ammonia-smoking method with zinc acetate and ammonia. A hyperbranched polyphosphate ammonium salt (FHPOPN) was synthesized for application to the cotton fabrics after the ammonia-smoked finish was applied. This research mainly focused on the fire-resistance and UV-blocking performance of cotton fabrics. The treated cotton fabrics were observed by scanning electron microscopy (SEM). The Fourier transform infrared (FTIR) spectroscopy results showed that ZnO NPs were successfully deposited in the fabric and that FHPOPN was bound to the fabric by covalent bonds. The flame retardancy and UV-protection properties of the treated cotton fabrics were studied. The effect of the zinc acetate concentration on the fire resistance and UV-blocking performance of the fabrics was investigated. The cotton fabrics treated with 70 g/L zinc acetate and 160 g/L FHPOPN obtained excellent flame retardancy with a char length of 57 mm and an limited oxygen index (LOI) value of 36.4%. The peak heat release rate and the total heat release of the ZnO/FHPOPN-treated samples were 26 kW/$ m^{2} $ and 4.4 MJ/$ m^{2} $, respectively, which were slightly lower than those of the FHPOPN-treated samples and much lower than those of the control cotton fabric sample. Furthermore, the thermogravimetric analyses of ZnO/FHPOPN-treated cotton fabric showed a char yield of 33.3% at 800 °C, whereas FHPOPN-treated cotton fabrics had a 29.7% char yield. The ZnO/FHPOPN-treated cotton fabric exhibited effective UV-protection properties with a UPF value of 224.80. These results demonstrated that the ZnO/FHPOPN-treated fabric had excellent flame retardancy, washability and UV-protection performance and revealed the importance of ZnO NPs in enhancing the flame retardancy and UV-blocking of performance cotton fabrics. Graphical abstract Cotton fabric (dpeaa)DE-He213 In situ (dpeaa)DE-He213 ZnO (dpeaa)DE-He213 Flame retardant (dpeaa)DE-He213 UV protection (dpeaa)DE-He213 Guo, Lamei verfasserin aut Enthalten in Cellulose Dordrecht [u.a.] : Springer Science + Business Media B.V, 1994 28(2021), 9 vom: 14. Apr., Seite 5843-5854 (DE-627)306353857 (DE-600)1496831-9 1572-882X nnns volume:28 year:2021 number:9 day:14 month:04 pages:5843-5854 https://dx.doi.org/10.1007/s10570-021-03868-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.63 ASE 35.77 ASE AR 28 2021 9 14 04 5843-5854 |
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Enthalten in Cellulose 28(2021), 9 vom: 14. Apr., Seite 5843-5854 volume:28 year:2021 number:9 day:14 month:04 pages:5843-5854 |
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Enthalten in Cellulose 28(2021), 9 vom: 14. Apr., Seite 5843-5854 volume:28 year:2021 number:9 day:14 month:04 pages:5843-5854 |
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Ling, Chao @@aut@@ Guo, Lamei @@aut@@ |
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This method involved the in situ deposition of ZnO nanoparticles (NPs) and the synthesis of a phosphorus ammonium salt. The application of ZnO NPs on cotton fabrics was achieved by an in situ ammonia-smoking method with zinc acetate and ammonia. A hyperbranched polyphosphate ammonium salt (FHPOPN) was synthesized for application to the cotton fabrics after the ammonia-smoked finish was applied. This research mainly focused on the fire-resistance and UV-blocking performance of cotton fabrics. The treated cotton fabrics were observed by scanning electron microscopy (SEM). The Fourier transform infrared (FTIR) spectroscopy results showed that ZnO NPs were successfully deposited in the fabric and that FHPOPN was bound to the fabric by covalent bonds. The flame retardancy and UV-protection properties of the treated cotton fabrics were studied. The effect of the zinc acetate concentration on the fire resistance and UV-blocking performance of the fabrics was investigated. The cotton fabrics treated with 70 g/L zinc acetate and 160 g/L FHPOPN obtained excellent flame retardancy with a char length of 57 mm and an limited oxygen index (LOI) value of 36.4%. The peak heat release rate and the total heat release of the ZnO/FHPOPN-treated samples were 26 kW/$ m^{2} $ and 4.4 MJ/$ m^{2} $, respectively, which were slightly lower than those of the FHPOPN-treated samples and much lower than those of the control cotton fabric sample. Furthermore, the thermogravimetric analyses of ZnO/FHPOPN-treated cotton fabric showed a char yield of 33.3% at 800 °C, whereas FHPOPN-treated cotton fabrics had a 29.7% char yield. The ZnO/FHPOPN-treated cotton fabric exhibited effective UV-protection properties with a UPF value of 224.80. These results demonstrated that the ZnO/FHPOPN-treated fabric had excellent flame retardancy, washability and UV-protection performance and revealed the importance of ZnO NPs in enhancing the flame retardancy and UV-blocking of performance cotton fabrics. 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Ling, Chao |
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Ling, Chao ddc 540 bkl 35.63 bkl 35.77 misc Cotton fabric misc In situ misc ZnO misc Flame retardant misc UV protection An eco-friendly and durable multifunctional cotton fabric incorporating ZnO and a branched polymer |
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540 ASE 35.63 bkl 35.77 bkl An eco-friendly and durable multifunctional cotton fabric incorporating ZnO and a branched polymer Cotton fabric (dpeaa)DE-He213 In situ (dpeaa)DE-He213 ZnO (dpeaa)DE-He213 Flame retardant (dpeaa)DE-He213 UV protection (dpeaa)DE-He213 |
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ddc 540 bkl 35.63 bkl 35.77 misc Cotton fabric misc In situ misc ZnO misc Flame retardant misc UV protection |
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ddc 540 bkl 35.63 bkl 35.77 misc Cotton fabric misc In situ misc ZnO misc Flame retardant misc UV protection |
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An eco-friendly and durable multifunctional cotton fabric incorporating ZnO and a branched polymer |
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eco-friendly and durable multifunctional cotton fabric incorporating zno and a branched polymer |
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An eco-friendly and durable multifunctional cotton fabric incorporating ZnO and a branched polymer |
| abstract |
Abstract In this study, we investigated a two-step method of preparing cotton fabrics with flame retardancy and UV-blocking properties. This method involved the in situ deposition of ZnO nanoparticles (NPs) and the synthesis of a phosphorus ammonium salt. The application of ZnO NPs on cotton fabrics was achieved by an in situ ammonia-smoking method with zinc acetate and ammonia. A hyperbranched polyphosphate ammonium salt (FHPOPN) was synthesized for application to the cotton fabrics after the ammonia-smoked finish was applied. This research mainly focused on the fire-resistance and UV-blocking performance of cotton fabrics. The treated cotton fabrics were observed by scanning electron microscopy (SEM). The Fourier transform infrared (FTIR) spectroscopy results showed that ZnO NPs were successfully deposited in the fabric and that FHPOPN was bound to the fabric by covalent bonds. The flame retardancy and UV-protection properties of the treated cotton fabrics were studied. The effect of the zinc acetate concentration on the fire resistance and UV-blocking performance of the fabrics was investigated. The cotton fabrics treated with 70 g/L zinc acetate and 160 g/L FHPOPN obtained excellent flame retardancy with a char length of 57 mm and an limited oxygen index (LOI) value of 36.4%. The peak heat release rate and the total heat release of the ZnO/FHPOPN-treated samples were 26 kW/$ m^{2} $ and 4.4 MJ/$ m^{2} $, respectively, which were slightly lower than those of the FHPOPN-treated samples and much lower than those of the control cotton fabric sample. Furthermore, the thermogravimetric analyses of ZnO/FHPOPN-treated cotton fabric showed a char yield of 33.3% at 800 °C, whereas FHPOPN-treated cotton fabrics had a 29.7% char yield. The ZnO/FHPOPN-treated cotton fabric exhibited effective UV-protection properties with a UPF value of 224.80. These results demonstrated that the ZnO/FHPOPN-treated fabric had excellent flame retardancy, washability and UV-protection performance and revealed the importance of ZnO NPs in enhancing the flame retardancy and UV-blocking of performance cotton fabrics. Graphical abstract © The Author(s), under exclusive licence to Springer Nature B.V. 2021 |
| abstractGer |
Abstract In this study, we investigated a two-step method of preparing cotton fabrics with flame retardancy and UV-blocking properties. This method involved the in situ deposition of ZnO nanoparticles (NPs) and the synthesis of a phosphorus ammonium salt. The application of ZnO NPs on cotton fabrics was achieved by an in situ ammonia-smoking method with zinc acetate and ammonia. A hyperbranched polyphosphate ammonium salt (FHPOPN) was synthesized for application to the cotton fabrics after the ammonia-smoked finish was applied. This research mainly focused on the fire-resistance and UV-blocking performance of cotton fabrics. The treated cotton fabrics were observed by scanning electron microscopy (SEM). The Fourier transform infrared (FTIR) spectroscopy results showed that ZnO NPs were successfully deposited in the fabric and that FHPOPN was bound to the fabric by covalent bonds. The flame retardancy and UV-protection properties of the treated cotton fabrics were studied. The effect of the zinc acetate concentration on the fire resistance and UV-blocking performance of the fabrics was investigated. The cotton fabrics treated with 70 g/L zinc acetate and 160 g/L FHPOPN obtained excellent flame retardancy with a char length of 57 mm and an limited oxygen index (LOI) value of 36.4%. The peak heat release rate and the total heat release of the ZnO/FHPOPN-treated samples were 26 kW/$ m^{2} $ and 4.4 MJ/$ m^{2} $, respectively, which were slightly lower than those of the FHPOPN-treated samples and much lower than those of the control cotton fabric sample. Furthermore, the thermogravimetric analyses of ZnO/FHPOPN-treated cotton fabric showed a char yield of 33.3% at 800 °C, whereas FHPOPN-treated cotton fabrics had a 29.7% char yield. The ZnO/FHPOPN-treated cotton fabric exhibited effective UV-protection properties with a UPF value of 224.80. These results demonstrated that the ZnO/FHPOPN-treated fabric had excellent flame retardancy, washability and UV-protection performance and revealed the importance of ZnO NPs in enhancing the flame retardancy and UV-blocking of performance cotton fabrics. Graphical abstract © The Author(s), under exclusive licence to Springer Nature B.V. 2021 |
| abstract_unstemmed |
Abstract In this study, we investigated a two-step method of preparing cotton fabrics with flame retardancy and UV-blocking properties. This method involved the in situ deposition of ZnO nanoparticles (NPs) and the synthesis of a phosphorus ammonium salt. The application of ZnO NPs on cotton fabrics was achieved by an in situ ammonia-smoking method with zinc acetate and ammonia. A hyperbranched polyphosphate ammonium salt (FHPOPN) was synthesized for application to the cotton fabrics after the ammonia-smoked finish was applied. This research mainly focused on the fire-resistance and UV-blocking performance of cotton fabrics. The treated cotton fabrics were observed by scanning electron microscopy (SEM). The Fourier transform infrared (FTIR) spectroscopy results showed that ZnO NPs were successfully deposited in the fabric and that FHPOPN was bound to the fabric by covalent bonds. The flame retardancy and UV-protection properties of the treated cotton fabrics were studied. The effect of the zinc acetate concentration on the fire resistance and UV-blocking performance of the fabrics was investigated. The cotton fabrics treated with 70 g/L zinc acetate and 160 g/L FHPOPN obtained excellent flame retardancy with a char length of 57 mm and an limited oxygen index (LOI) value of 36.4%. The peak heat release rate and the total heat release of the ZnO/FHPOPN-treated samples were 26 kW/$ m^{2} $ and 4.4 MJ/$ m^{2} $, respectively, which were slightly lower than those of the FHPOPN-treated samples and much lower than those of the control cotton fabric sample. Furthermore, the thermogravimetric analyses of ZnO/FHPOPN-treated cotton fabric showed a char yield of 33.3% at 800 °C, whereas FHPOPN-treated cotton fabrics had a 29.7% char yield. The ZnO/FHPOPN-treated cotton fabric exhibited effective UV-protection properties with a UPF value of 224.80. These results demonstrated that the ZnO/FHPOPN-treated fabric had excellent flame retardancy, washability and UV-protection performance and revealed the importance of ZnO NPs in enhancing the flame retardancy and UV-blocking of performance cotton fabrics. Graphical abstract © The Author(s), under exclusive licence to Springer Nature B.V. 2021 |
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| title_short |
An eco-friendly and durable multifunctional cotton fabric incorporating ZnO and a branched polymer |
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https://dx.doi.org/10.1007/s10570-021-03868-w |
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| score |
7.401636 |