Aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface
Abstract The formation of monolayers of poly(fluoro(meth)acrylate)-b-poly(acrylic acid) (PFA-b-PAA) amphiphilic diblock copolymers at the air/water interface was characterized with the Langmuir film balance technique and atomic force microscopy. Both internal and external effects on the aggregation...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Grigoreva, Alexandra [verfasserIn] Tarankova, Kseniia [verfasserIn] Zamyshlyayeva, Olga [verfasserIn] Zaitsev, Sergey [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021 |
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| Schlagwörter: |
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| Anmerkung: |
© The Polymer Society, Taipei 2021 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of polymer research - Dordrecht : Springer Science + Business Media B.V., 1994, 28(2021), 7 vom: 26. Juni |
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| Übergeordnetes Werk: |
volume:28 ; year:2021 ; number:7 ; day:26 ; month:06 |
| Links: |
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| DOI / URN: |
10.1007/s10965-021-02629-4 |
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| Katalog-ID: |
SPR044393954 |
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| 520 | |a Abstract The formation of monolayers of poly(fluoro(meth)acrylate)-b-poly(acrylic acid) (PFA-b-PAA) amphiphilic diblock copolymers at the air/water interface was characterized with the Langmuir film balance technique and atomic force microscopy. Both internal and external effects on the aggregation behaviour of the amphiphilic copolymers were considered. The structure of fluorinated hydrophobic part, as an internal factor, affects the surface behaviour of the amphiphilic copolymers through changes in the packing density of the hydrophobic core. The morphology of the LB films of all the three copolymers exhibit circular micelles with the hydrophobic core and hydrophilic coronas. The variation in pH and ionic strength leads to changes in charge distribution of PAA coronas. The surface area occupied by the PFA-b-PAA copolymers decrease with the rise of pH of subphase. The increase in salt concentration provides for the reduction of electrostatic repulsion between the hydrophilic blocks. | ||
| 650 | 4 | |a Amphiphilic copolymers |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Block copolymers |7 (dpeaa)DE-He213 | |
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| 700 | 1 | |a Tarankova, Kseniia |e verfasserin |4 aut | |
| 700 | 1 | |a Zamyshlyayeva, Olga |e verfasserin |4 aut | |
| 700 | 1 | |a Zaitsev, Sergey |e verfasserin |4 aut | |
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10.1007/s10965-021-02629-4 doi (DE-627)SPR044393954 (SPR)s10965-021-02629-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Grigoreva, Alexandra verfasserin aut Aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society, Taipei 2021 Abstract The formation of monolayers of poly(fluoro(meth)acrylate)-b-poly(acrylic acid) (PFA-b-PAA) amphiphilic diblock copolymers at the air/water interface was characterized with the Langmuir film balance technique and atomic force microscopy. Both internal and external effects on the aggregation behaviour of the amphiphilic copolymers were considered. The structure of fluorinated hydrophobic part, as an internal factor, affects the surface behaviour of the amphiphilic copolymers through changes in the packing density of the hydrophobic core. The morphology of the LB films of all the three copolymers exhibit circular micelles with the hydrophobic core and hydrophilic coronas. The variation in pH and ionic strength leads to changes in charge distribution of PAA coronas. The surface area occupied by the PFA-b-PAA copolymers decrease with the rise of pH of subphase. The increase in salt concentration provides for the reduction of electrostatic repulsion between the hydrophilic blocks. Amphiphilic copolymers (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 Langmuir monolayer (dpeaa)DE-He213 Fluoropolymers (dpeaa)DE-He213 Tarankova, Kseniia verfasserin aut Zamyshlyayeva, Olga verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 28(2021), 7 vom: 26. Juni (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:28 year:2021 number:7 day:26 month:06 https://dx.doi.org/10.1007/s10965-021-02629-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 28 2021 7 26 06 |
| spelling |
10.1007/s10965-021-02629-4 doi (DE-627)SPR044393954 (SPR)s10965-021-02629-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Grigoreva, Alexandra verfasserin aut Aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society, Taipei 2021 Abstract The formation of monolayers of poly(fluoro(meth)acrylate)-b-poly(acrylic acid) (PFA-b-PAA) amphiphilic diblock copolymers at the air/water interface was characterized with the Langmuir film balance technique and atomic force microscopy. Both internal and external effects on the aggregation behaviour of the amphiphilic copolymers were considered. The structure of fluorinated hydrophobic part, as an internal factor, affects the surface behaviour of the amphiphilic copolymers through changes in the packing density of the hydrophobic core. The morphology of the LB films of all the three copolymers exhibit circular micelles with the hydrophobic core and hydrophilic coronas. The variation in pH and ionic strength leads to changes in charge distribution of PAA coronas. The surface area occupied by the PFA-b-PAA copolymers decrease with the rise of pH of subphase. The increase in salt concentration provides for the reduction of electrostatic repulsion between the hydrophilic blocks. Amphiphilic copolymers (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 Langmuir monolayer (dpeaa)DE-He213 Fluoropolymers (dpeaa)DE-He213 Tarankova, Kseniia verfasserin aut Zamyshlyayeva, Olga verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 28(2021), 7 vom: 26. Juni (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:28 year:2021 number:7 day:26 month:06 https://dx.doi.org/10.1007/s10965-021-02629-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 28 2021 7 26 06 |
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10.1007/s10965-021-02629-4 doi (DE-627)SPR044393954 (SPR)s10965-021-02629-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Grigoreva, Alexandra verfasserin aut Aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society, Taipei 2021 Abstract The formation of monolayers of poly(fluoro(meth)acrylate)-b-poly(acrylic acid) (PFA-b-PAA) amphiphilic diblock copolymers at the air/water interface was characterized with the Langmuir film balance technique and atomic force microscopy. Both internal and external effects on the aggregation behaviour of the amphiphilic copolymers were considered. The structure of fluorinated hydrophobic part, as an internal factor, affects the surface behaviour of the amphiphilic copolymers through changes in the packing density of the hydrophobic core. The morphology of the LB films of all the three copolymers exhibit circular micelles with the hydrophobic core and hydrophilic coronas. The variation in pH and ionic strength leads to changes in charge distribution of PAA coronas. The surface area occupied by the PFA-b-PAA copolymers decrease with the rise of pH of subphase. The increase in salt concentration provides for the reduction of electrostatic repulsion between the hydrophilic blocks. Amphiphilic copolymers (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 Langmuir monolayer (dpeaa)DE-He213 Fluoropolymers (dpeaa)DE-He213 Tarankova, Kseniia verfasserin aut Zamyshlyayeva, Olga verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 28(2021), 7 vom: 26. Juni (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:28 year:2021 number:7 day:26 month:06 https://dx.doi.org/10.1007/s10965-021-02629-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 28 2021 7 26 06 |
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10.1007/s10965-021-02629-4 doi (DE-627)SPR044393954 (SPR)s10965-021-02629-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Grigoreva, Alexandra verfasserin aut Aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society, Taipei 2021 Abstract The formation of monolayers of poly(fluoro(meth)acrylate)-b-poly(acrylic acid) (PFA-b-PAA) amphiphilic diblock copolymers at the air/water interface was characterized with the Langmuir film balance technique and atomic force microscopy. Both internal and external effects on the aggregation behaviour of the amphiphilic copolymers were considered. The structure of fluorinated hydrophobic part, as an internal factor, affects the surface behaviour of the amphiphilic copolymers through changes in the packing density of the hydrophobic core. The morphology of the LB films of all the three copolymers exhibit circular micelles with the hydrophobic core and hydrophilic coronas. The variation in pH and ionic strength leads to changes in charge distribution of PAA coronas. The surface area occupied by the PFA-b-PAA copolymers decrease with the rise of pH of subphase. The increase in salt concentration provides for the reduction of electrostatic repulsion between the hydrophilic blocks. Amphiphilic copolymers (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 Langmuir monolayer (dpeaa)DE-He213 Fluoropolymers (dpeaa)DE-He213 Tarankova, Kseniia verfasserin aut Zamyshlyayeva, Olga verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 28(2021), 7 vom: 26. Juni (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:28 year:2021 number:7 day:26 month:06 https://dx.doi.org/10.1007/s10965-021-02629-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 28 2021 7 26 06 |
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10.1007/s10965-021-02629-4 doi (DE-627)SPR044393954 (SPR)s10965-021-02629-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Grigoreva, Alexandra verfasserin aut Aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society, Taipei 2021 Abstract The formation of monolayers of poly(fluoro(meth)acrylate)-b-poly(acrylic acid) (PFA-b-PAA) amphiphilic diblock copolymers at the air/water interface was characterized with the Langmuir film balance technique and atomic force microscopy. Both internal and external effects on the aggregation behaviour of the amphiphilic copolymers were considered. The structure of fluorinated hydrophobic part, as an internal factor, affects the surface behaviour of the amphiphilic copolymers through changes in the packing density of the hydrophobic core. The morphology of the LB films of all the three copolymers exhibit circular micelles with the hydrophobic core and hydrophilic coronas. The variation in pH and ionic strength leads to changes in charge distribution of PAA coronas. The surface area occupied by the PFA-b-PAA copolymers decrease with the rise of pH of subphase. The increase in salt concentration provides for the reduction of electrostatic repulsion between the hydrophilic blocks. Amphiphilic copolymers (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 Langmuir monolayer (dpeaa)DE-He213 Fluoropolymers (dpeaa)DE-He213 Tarankova, Kseniia verfasserin aut Zamyshlyayeva, Olga verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 28(2021), 7 vom: 26. Juni (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:28 year:2021 number:7 day:26 month:06 https://dx.doi.org/10.1007/s10965-021-02629-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 28 2021 7 26 06 |
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Enthalten in Journal of polymer research 28(2021), 7 vom: 26. Juni volume:28 year:2021 number:7 day:26 month:06 |
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Amphiphilic copolymers Block copolymers Self-assembly Langmuir monolayer Fluoropolymers |
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Journal of polymer research |
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Grigoreva, Alexandra @@aut@@ Tarankova, Kseniia @@aut@@ Zamyshlyayeva, Olga @@aut@@ Zaitsev, Sergey @@aut@@ |
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Both internal and external effects on the aggregation behaviour of the amphiphilic copolymers were considered. The structure of fluorinated hydrophobic part, as an internal factor, affects the surface behaviour of the amphiphilic copolymers through changes in the packing density of the hydrophobic core. The morphology of the LB films of all the three copolymers exhibit circular micelles with the hydrophobic core and hydrophilic coronas. The variation in pH and ionic strength leads to changes in charge distribution of PAA coronas. The surface area occupied by the PFA-b-PAA copolymers decrease with the rise of pH of subphase. 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Grigoreva, Alexandra |
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Grigoreva, Alexandra ddc 540 bkl 35.00 misc Amphiphilic copolymers misc Block copolymers misc Self-assembly misc Langmuir monolayer misc Fluoropolymers Aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface |
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540 ASE 35.00 bkl Aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface Amphiphilic copolymers (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 Self-assembly (dpeaa)DE-He213 Langmuir monolayer (dpeaa)DE-He213 Fluoropolymers (dpeaa)DE-He213 |
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Aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface |
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aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface |
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Aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface |
| abstract |
Abstract The formation of monolayers of poly(fluoro(meth)acrylate)-b-poly(acrylic acid) (PFA-b-PAA) amphiphilic diblock copolymers at the air/water interface was characterized with the Langmuir film balance technique and atomic force microscopy. Both internal and external effects on the aggregation behaviour of the amphiphilic copolymers were considered. The structure of fluorinated hydrophobic part, as an internal factor, affects the surface behaviour of the amphiphilic copolymers through changes in the packing density of the hydrophobic core. The morphology of the LB films of all the three copolymers exhibit circular micelles with the hydrophobic core and hydrophilic coronas. The variation in pH and ionic strength leads to changes in charge distribution of PAA coronas. The surface area occupied by the PFA-b-PAA copolymers decrease with the rise of pH of subphase. The increase in salt concentration provides for the reduction of electrostatic repulsion between the hydrophilic blocks. © The Polymer Society, Taipei 2021 |
| abstractGer |
Abstract The formation of monolayers of poly(fluoro(meth)acrylate)-b-poly(acrylic acid) (PFA-b-PAA) amphiphilic diblock copolymers at the air/water interface was characterized with the Langmuir film balance technique and atomic force microscopy. Both internal and external effects on the aggregation behaviour of the amphiphilic copolymers were considered. The structure of fluorinated hydrophobic part, as an internal factor, affects the surface behaviour of the amphiphilic copolymers through changes in the packing density of the hydrophobic core. The morphology of the LB films of all the three copolymers exhibit circular micelles with the hydrophobic core and hydrophilic coronas. The variation in pH and ionic strength leads to changes in charge distribution of PAA coronas. The surface area occupied by the PFA-b-PAA copolymers decrease with the rise of pH of subphase. The increase in salt concentration provides for the reduction of electrostatic repulsion between the hydrophilic blocks. © The Polymer Society, Taipei 2021 |
| abstract_unstemmed |
Abstract The formation of monolayers of poly(fluoro(meth)acrylate)-b-poly(acrylic acid) (PFA-b-PAA) amphiphilic diblock copolymers at the air/water interface was characterized with the Langmuir film balance technique and atomic force microscopy. Both internal and external effects on the aggregation behaviour of the amphiphilic copolymers were considered. The structure of fluorinated hydrophobic part, as an internal factor, affects the surface behaviour of the amphiphilic copolymers through changes in the packing density of the hydrophobic core. The morphology of the LB films of all the three copolymers exhibit circular micelles with the hydrophobic core and hydrophilic coronas. The variation in pH and ionic strength leads to changes in charge distribution of PAA coronas. The surface area occupied by the PFA-b-PAA copolymers decrease with the rise of pH of subphase. The increase in salt concentration provides for the reduction of electrostatic repulsion between the hydrophilic blocks. © The Polymer Society, Taipei 2021 |
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| title_short |
Aggregation behaviour of poly(fluoro(meth)acrylate)-block-poly(acrylic acid) copolymers at the air /water interface |
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https://dx.doi.org/10.1007/s10965-021-02629-4 |
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| author2 |
Tarankova, Kseniia Zamyshlyayeva, Olga Zaitsev, Sergey |
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Tarankova, Kseniia Zamyshlyayeva, Olga Zaitsev, Sergey |
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| doi_str |
10.1007/s10965-021-02629-4 |
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2024-07-04T00:27:52.263Z |
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| score |
7.3982677 |