Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers
Inverse emulsions based on acrylamide (AA), acrylonitrile (AN), and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), and their polymers have been obtained using surfactant mixture containing Span 80 and Tween 80. The stability of these monomer and polymer inverse emulsions has been studied. Ionic m...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Nechaev, Anton I. [verfasserIn] Voronina, Natalia S. [verfasserIn] Valtsifer, Viktor A. [verfasserIn] Strelnikov, Vladimir N. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 |
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| Übergeordnetes Werk: |
Enthalten in: Colloid & polymer science - Berlin : Springer, 1906, 299(2021), 7 vom: 07. Apr., Seite 1127-1138 |
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| Übergeordnetes Werk: |
volume:299 ; year:2021 ; number:7 ; day:07 ; month:04 ; pages:1127-1138 |
| Links: |
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| DOI / URN: |
10.1007/s00396-021-04832-7 |
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| Katalog-ID: |
SPR044431155 |
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| 520 | |a Inverse emulsions based on acrylamide (AA), acrylonitrile (AN), and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), and their polymers have been obtained using surfactant mixture containing Span 80 and Tween 80. The stability of these monomer and polymer inverse emulsions has been studied. Ionic monomers, AA and AMPS, have been found to give a significant contribution to the emulsion stability. The effect has been close to that of Tween 80, i.e., hydrophilic-lipophilic balance (HLB) has been improved. The spinning drop method has been used for the study of interfacial tension (IFT) kinetics. The parameters of the inverse emulsions, including ionogenic monomer concentration, have been found to change the IFT kinetics pattern. The onset of IFT equilibrium has been shown to be comparable to the duration of radical copolymerization. AA-AN-AMPSNa terpolymer was synthesized via radical copolymerization in inverse emulsion. No significant effect of radical terpolymerization on the average particle size and stability of inverse emulsions has been observed. Graphical abstract STABILITY OF THE DISPERSED SYSTEM IN INVERSE EMULSION POLYMERIZATION OF IONIC ACRYLATE MONOMERS | ||
| 650 | 4 | |a Emulsion stability |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Inverse emulsion polymerization |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Particle size distribution |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Interfacial tension |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Acrylamide copolymers |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Voronina, Natalia S. |e verfasserin |4 aut | |
| 700 | 1 | |a Valtsifer, Viktor A. |e verfasserin |4 aut | |
| 700 | 1 | |a Strelnikov, Vladimir N. |e verfasserin |4 aut | |
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10.1007/s00396-021-04832-7 doi (DE-627)SPR044431155 (SPR)s00396-021-04832-7-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Nechaev, Anton I. verfasserin aut Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 Inverse emulsions based on acrylamide (AA), acrylonitrile (AN), and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), and their polymers have been obtained using surfactant mixture containing Span 80 and Tween 80. The stability of these monomer and polymer inverse emulsions has been studied. Ionic monomers, AA and AMPS, have been found to give a significant contribution to the emulsion stability. The effect has been close to that of Tween 80, i.e., hydrophilic-lipophilic balance (HLB) has been improved. The spinning drop method has been used for the study of interfacial tension (IFT) kinetics. The parameters of the inverse emulsions, including ionogenic monomer concentration, have been found to change the IFT kinetics pattern. The onset of IFT equilibrium has been shown to be comparable to the duration of radical copolymerization. AA-AN-AMPSNa terpolymer was synthesized via radical copolymerization in inverse emulsion. No significant effect of radical terpolymerization on the average particle size and stability of inverse emulsions has been observed. Graphical abstract STABILITY OF THE DISPERSED SYSTEM IN INVERSE EMULSION POLYMERIZATION OF IONIC ACRYLATE MONOMERS Emulsion stability (dpeaa)DE-He213 Inverse emulsion polymerization (dpeaa)DE-He213 Particle size distribution (dpeaa)DE-He213 Interfacial tension (dpeaa)DE-He213 Acrylamide copolymers (dpeaa)DE-He213 Voronina, Natalia S. verfasserin aut Valtsifer, Viktor A. verfasserin aut Strelnikov, Vladimir N. verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 299(2021), 7 vom: 07. Apr., Seite 1127-1138 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:299 year:2021 number:7 day:07 month:04 pages:1127-1138 https://dx.doi.org/10.1007/s00396-021-04832-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 299 2021 7 07 04 1127-1138 |
| spelling |
10.1007/s00396-021-04832-7 doi (DE-627)SPR044431155 (SPR)s00396-021-04832-7-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Nechaev, Anton I. verfasserin aut Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 Inverse emulsions based on acrylamide (AA), acrylonitrile (AN), and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), and their polymers have been obtained using surfactant mixture containing Span 80 and Tween 80. The stability of these monomer and polymer inverse emulsions has been studied. Ionic monomers, AA and AMPS, have been found to give a significant contribution to the emulsion stability. The effect has been close to that of Tween 80, i.e., hydrophilic-lipophilic balance (HLB) has been improved. The spinning drop method has been used for the study of interfacial tension (IFT) kinetics. The parameters of the inverse emulsions, including ionogenic monomer concentration, have been found to change the IFT kinetics pattern. The onset of IFT equilibrium has been shown to be comparable to the duration of radical copolymerization. AA-AN-AMPSNa terpolymer was synthesized via radical copolymerization in inverse emulsion. No significant effect of radical terpolymerization on the average particle size and stability of inverse emulsions has been observed. Graphical abstract STABILITY OF THE DISPERSED SYSTEM IN INVERSE EMULSION POLYMERIZATION OF IONIC ACRYLATE MONOMERS Emulsion stability (dpeaa)DE-He213 Inverse emulsion polymerization (dpeaa)DE-He213 Particle size distribution (dpeaa)DE-He213 Interfacial tension (dpeaa)DE-He213 Acrylamide copolymers (dpeaa)DE-He213 Voronina, Natalia S. verfasserin aut Valtsifer, Viktor A. verfasserin aut Strelnikov, Vladimir N. verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 299(2021), 7 vom: 07. Apr., Seite 1127-1138 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:299 year:2021 number:7 day:07 month:04 pages:1127-1138 https://dx.doi.org/10.1007/s00396-021-04832-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 299 2021 7 07 04 1127-1138 |
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10.1007/s00396-021-04832-7 doi (DE-627)SPR044431155 (SPR)s00396-021-04832-7-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Nechaev, Anton I. verfasserin aut Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 Inverse emulsions based on acrylamide (AA), acrylonitrile (AN), and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), and their polymers have been obtained using surfactant mixture containing Span 80 and Tween 80. The stability of these monomer and polymer inverse emulsions has been studied. Ionic monomers, AA and AMPS, have been found to give a significant contribution to the emulsion stability. The effect has been close to that of Tween 80, i.e., hydrophilic-lipophilic balance (HLB) has been improved. The spinning drop method has been used for the study of interfacial tension (IFT) kinetics. The parameters of the inverse emulsions, including ionogenic monomer concentration, have been found to change the IFT kinetics pattern. The onset of IFT equilibrium has been shown to be comparable to the duration of radical copolymerization. AA-AN-AMPSNa terpolymer was synthesized via radical copolymerization in inverse emulsion. No significant effect of radical terpolymerization on the average particle size and stability of inverse emulsions has been observed. Graphical abstract STABILITY OF THE DISPERSED SYSTEM IN INVERSE EMULSION POLYMERIZATION OF IONIC ACRYLATE MONOMERS Emulsion stability (dpeaa)DE-He213 Inverse emulsion polymerization (dpeaa)DE-He213 Particle size distribution (dpeaa)DE-He213 Interfacial tension (dpeaa)DE-He213 Acrylamide copolymers (dpeaa)DE-He213 Voronina, Natalia S. verfasserin aut Valtsifer, Viktor A. verfasserin aut Strelnikov, Vladimir N. verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 299(2021), 7 vom: 07. Apr., Seite 1127-1138 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:299 year:2021 number:7 day:07 month:04 pages:1127-1138 https://dx.doi.org/10.1007/s00396-021-04832-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 299 2021 7 07 04 1127-1138 |
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10.1007/s00396-021-04832-7 doi (DE-627)SPR044431155 (SPR)s00396-021-04832-7-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Nechaev, Anton I. verfasserin aut Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 Inverse emulsions based on acrylamide (AA), acrylonitrile (AN), and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), and their polymers have been obtained using surfactant mixture containing Span 80 and Tween 80. The stability of these monomer and polymer inverse emulsions has been studied. Ionic monomers, AA and AMPS, have been found to give a significant contribution to the emulsion stability. The effect has been close to that of Tween 80, i.e., hydrophilic-lipophilic balance (HLB) has been improved. The spinning drop method has been used for the study of interfacial tension (IFT) kinetics. The parameters of the inverse emulsions, including ionogenic monomer concentration, have been found to change the IFT kinetics pattern. The onset of IFT equilibrium has been shown to be comparable to the duration of radical copolymerization. AA-AN-AMPSNa terpolymer was synthesized via radical copolymerization in inverse emulsion. No significant effect of radical terpolymerization on the average particle size and stability of inverse emulsions has been observed. Graphical abstract STABILITY OF THE DISPERSED SYSTEM IN INVERSE EMULSION POLYMERIZATION OF IONIC ACRYLATE MONOMERS Emulsion stability (dpeaa)DE-He213 Inverse emulsion polymerization (dpeaa)DE-He213 Particle size distribution (dpeaa)DE-He213 Interfacial tension (dpeaa)DE-He213 Acrylamide copolymers (dpeaa)DE-He213 Voronina, Natalia S. verfasserin aut Valtsifer, Viktor A. verfasserin aut Strelnikov, Vladimir N. verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 299(2021), 7 vom: 07. Apr., Seite 1127-1138 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:299 year:2021 number:7 day:07 month:04 pages:1127-1138 https://dx.doi.org/10.1007/s00396-021-04832-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 299 2021 7 07 04 1127-1138 |
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10.1007/s00396-021-04832-7 doi (DE-627)SPR044431155 (SPR)s00396-021-04832-7-e DE-627 ger DE-627 rakwb eng 540 ASE 540 ASE 35.18 bkl Nechaev, Anton I. verfasserin aut Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 Inverse emulsions based on acrylamide (AA), acrylonitrile (AN), and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), and their polymers have been obtained using surfactant mixture containing Span 80 and Tween 80. The stability of these monomer and polymer inverse emulsions has been studied. Ionic monomers, AA and AMPS, have been found to give a significant contribution to the emulsion stability. The effect has been close to that of Tween 80, i.e., hydrophilic-lipophilic balance (HLB) has been improved. The spinning drop method has been used for the study of interfacial tension (IFT) kinetics. The parameters of the inverse emulsions, including ionogenic monomer concentration, have been found to change the IFT kinetics pattern. The onset of IFT equilibrium has been shown to be comparable to the duration of radical copolymerization. AA-AN-AMPSNa terpolymer was synthesized via radical copolymerization in inverse emulsion. No significant effect of radical terpolymerization on the average particle size and stability of inverse emulsions has been observed. Graphical abstract STABILITY OF THE DISPERSED SYSTEM IN INVERSE EMULSION POLYMERIZATION OF IONIC ACRYLATE MONOMERS Emulsion stability (dpeaa)DE-He213 Inverse emulsion polymerization (dpeaa)DE-He213 Particle size distribution (dpeaa)DE-He213 Interfacial tension (dpeaa)DE-He213 Acrylamide copolymers (dpeaa)DE-He213 Voronina, Natalia S. verfasserin aut Valtsifer, Viktor A. verfasserin aut Strelnikov, Vladimir N. verfasserin aut Enthalten in Colloid & polymer science Berlin : Springer, 1906 299(2021), 7 vom: 07. Apr., Seite 1127-1138 (DE-627)254629849 (DE-600)1462029-7 1435-1536 nnns volume:299 year:2021 number:7 day:07 month:04 pages:1127-1138 https://dx.doi.org/10.1007/s00396-021-04832-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 ASE AR 299 2021 7 07 04 1127-1138 |
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Enthalten in Colloid & polymer science 299(2021), 7 vom: 07. Apr., Seite 1127-1138 volume:299 year:2021 number:7 day:07 month:04 pages:1127-1138 |
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Emulsion stability Inverse emulsion polymerization Particle size distribution Interfacial tension Acrylamide copolymers |
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Nechaev, Anton I. @@aut@@ Voronina, Natalia S. @@aut@@ Valtsifer, Viktor A. @@aut@@ Strelnikov, Vladimir N. @@aut@@ |
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The stability of these monomer and polymer inverse emulsions has been studied. Ionic monomers, AA and AMPS, have been found to give a significant contribution to the emulsion stability. The effect has been close to that of Tween 80, i.e., hydrophilic-lipophilic balance (HLB) has been improved. The spinning drop method has been used for the study of interfacial tension (IFT) kinetics. The parameters of the inverse emulsions, including ionogenic monomer concentration, have been found to change the IFT kinetics pattern. The onset of IFT equilibrium has been shown to be comparable to the duration of radical copolymerization. AA-AN-AMPSNa terpolymer was synthesized via radical copolymerization in inverse emulsion. No significant effect of radical terpolymerization on the average particle size and stability of inverse emulsions has been observed. Graphical abstract STABILITY OF THE DISPERSED SYSTEM IN INVERSE EMULSION POLYMERIZATION OF IONIC ACRYLATE MONOMERS</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Emulsion stability</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Inverse emulsion polymerization</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Particle size distribution</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Interfacial tension</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Acrylamide copolymers</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Voronina, Natalia S.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Valtsifer, Viktor A.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Strelnikov, Vladimir N.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Colloid & polymer science</subfield><subfield code="d">Berlin : Springer, 1906</subfield><subfield code="g">299(2021), 7 vom: 07. 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Nechaev, Anton I. |
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Nechaev, Anton I. ddc 540 bkl 35.18 misc Emulsion stability misc Inverse emulsion polymerization misc Particle size distribution misc Interfacial tension misc Acrylamide copolymers Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers |
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540 ASE 35.18 bkl Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers Emulsion stability (dpeaa)DE-He213 Inverse emulsion polymerization (dpeaa)DE-He213 Particle size distribution (dpeaa)DE-He213 Interfacial tension (dpeaa)DE-He213 Acrylamide copolymers (dpeaa)DE-He213 |
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ddc 540 bkl 35.18 misc Emulsion stability misc Inverse emulsion polymerization misc Particle size distribution misc Interfacial tension misc Acrylamide copolymers |
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ddc 540 bkl 35.18 misc Emulsion stability misc Inverse emulsion polymerization misc Particle size distribution misc Interfacial tension misc Acrylamide copolymers |
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ddc 540 bkl 35.18 misc Emulsion stability misc Inverse emulsion polymerization misc Particle size distribution misc Interfacial tension misc Acrylamide copolymers |
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Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers |
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Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers |
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Nechaev, Anton I. |
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stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers |
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Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers |
| abstract |
Inverse emulsions based on acrylamide (AA), acrylonitrile (AN), and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), and their polymers have been obtained using surfactant mixture containing Span 80 and Tween 80. The stability of these monomer and polymer inverse emulsions has been studied. Ionic monomers, AA and AMPS, have been found to give a significant contribution to the emulsion stability. The effect has been close to that of Tween 80, i.e., hydrophilic-lipophilic balance (HLB) has been improved. The spinning drop method has been used for the study of interfacial tension (IFT) kinetics. The parameters of the inverse emulsions, including ionogenic monomer concentration, have been found to change the IFT kinetics pattern. The onset of IFT equilibrium has been shown to be comparable to the duration of radical copolymerization. AA-AN-AMPSNa terpolymer was synthesized via radical copolymerization in inverse emulsion. No significant effect of radical terpolymerization on the average particle size and stability of inverse emulsions has been observed. Graphical abstract STABILITY OF THE DISPERSED SYSTEM IN INVERSE EMULSION POLYMERIZATION OF IONIC ACRYLATE MONOMERS © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 |
| abstractGer |
Inverse emulsions based on acrylamide (AA), acrylonitrile (AN), and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), and their polymers have been obtained using surfactant mixture containing Span 80 and Tween 80. The stability of these monomer and polymer inverse emulsions has been studied. Ionic monomers, AA and AMPS, have been found to give a significant contribution to the emulsion stability. The effect has been close to that of Tween 80, i.e., hydrophilic-lipophilic balance (HLB) has been improved. The spinning drop method has been used for the study of interfacial tension (IFT) kinetics. The parameters of the inverse emulsions, including ionogenic monomer concentration, have been found to change the IFT kinetics pattern. The onset of IFT equilibrium has been shown to be comparable to the duration of radical copolymerization. AA-AN-AMPSNa terpolymer was synthesized via radical copolymerization in inverse emulsion. No significant effect of radical terpolymerization on the average particle size and stability of inverse emulsions has been observed. Graphical abstract STABILITY OF THE DISPERSED SYSTEM IN INVERSE EMULSION POLYMERIZATION OF IONIC ACRYLATE MONOMERS © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 |
| abstract_unstemmed |
Inverse emulsions based on acrylamide (AA), acrylonitrile (AN), and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), and their polymers have been obtained using surfactant mixture containing Span 80 and Tween 80. The stability of these monomer and polymer inverse emulsions has been studied. Ionic monomers, AA and AMPS, have been found to give a significant contribution to the emulsion stability. The effect has been close to that of Tween 80, i.e., hydrophilic-lipophilic balance (HLB) has been improved. The spinning drop method has been used for the study of interfacial tension (IFT) kinetics. The parameters of the inverse emulsions, including ionogenic monomer concentration, have been found to change the IFT kinetics pattern. The onset of IFT equilibrium has been shown to be comparable to the duration of radical copolymerization. AA-AN-AMPSNa terpolymer was synthesized via radical copolymerization in inverse emulsion. No significant effect of radical terpolymerization on the average particle size and stability of inverse emulsions has been observed. Graphical abstract STABILITY OF THE DISPERSED SYSTEM IN INVERSE EMULSION POLYMERIZATION OF IONIC ACRYLATE MONOMERS © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 |
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| title_short |
Stability of the dispersed system in inverse emulsion polymerization of ionic acrylate monomers |
| url |
https://dx.doi.org/10.1007/s00396-021-04832-7 |
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| author2 |
Voronina, Natalia S. Valtsifer, Viktor A. Strelnikov, Vladimir N. |
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Voronina, Natalia S. Valtsifer, Viktor A. Strelnikov, Vladimir N. |
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| score |
7.3993406 |