Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications

Abstract An analytical approach for halides determination in uranium-bearing phosphate rocks, based on halides extraction from natural calcium phosphate by a metathesis reaction, followed by ion chromatography with conductivity detection analysis, is presented in this work. Chloride extraction is pe...
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Autor*in:	Borojovich, Eitan J. C. [verfasserIn] Moyal, Amiram [verfasserIn] Nikolski, Andrey [verfasserIn] Assulin, Maor [verfasserIn] Shamish, Zorik [verfasserIn] Elish, Eyal [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2021

Schlagwörter:	Nuclear forensics Phosphate rocks Uranium Chloride

Anmerkung:	© Akadémiai Kiadó, Budapest, Hungary 2021

Übergeordnetes Werk:	Enthalten in: Journal of radioanalytical and nuclear chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968, 329(2021), 1 vom: 02. Juni, Seite 179-190
Übergeordnetes Werk:	volume:329 ; year:2021 ; number:1 ; day:02 ; month:06 ; pages:179-190

Links:	Volltext

DOI / URN:	10.1007/s10967-021-07788-8

Katalog-ID:	SPR044445369

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520			\|a Abstract An analytical approach for halides determination in uranium-bearing phosphate rocks, based on halides extraction from natural calcium phosphate by a metathesis reaction, followed by ion chromatography with conductivity detection analysis, is presented in this work. Chloride extraction is performed by mixing samples with sulfuric acid, causing an interchange between phosphate and sulfate ions towards calcium ions in the solid phase (metathesis). Addition of small amounts of calcium hydroxide improves the chromatographic determination by eliminating artifacts located in proximity to chloride retention time, and reducing phosphate peaks area. Limit of quantitation (LOQ) for chloride and bromide were found to be 25 mg/Kg and 50 mg/Kg, respectively. The metathesis reaction is proven by ED-XRF analysis of the precipitate produced during this reaction, showing the interchange between sulfate and phosphate ions. Chloride determination based on this approach was performed on several uranium-bearing phosphate rock samples from different sources. Since geolocation is one of the primary techniques needed for attribution, in a nuclear forensic investigation, this methodology may contribute to find new signatures, e.g. halides, in natural phosphate rocks deposits, to support that. The $ Cl^{−} $ content in 11 phosphate rock samples was determined after applying metathesis, and found to be in the range of 30–792 mg/Kg, supporting its relevance as nuclear forensic signature. The $ Br^{−} $ content was below the detection limit in all the samples.
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912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_206
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
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912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
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912			\|a GBV_ILN_602
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912			\|a GBV_ILN_2003
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912			\|a GBV_ILN_2007
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912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
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912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
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912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
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allfields	10.1007/s10967-021-07788-8 doi (DE-627)SPR044445369 (SPR)s10967-021-07788-8-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Borojovich, Eitan J. C. verfasserin aut Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2021 Abstract An analytical approach for halides determination in uranium-bearing phosphate rocks, based on halides extraction from natural calcium phosphate by a metathesis reaction, followed by ion chromatography with conductivity detection analysis, is presented in this work. Chloride extraction is performed by mixing samples with sulfuric acid, causing an interchange between phosphate and sulfate ions towards calcium ions in the solid phase (metathesis). Addition of small amounts of calcium hydroxide improves the chromatographic determination by eliminating artifacts located in proximity to chloride retention time, and reducing phosphate peaks area. Limit of quantitation (LOQ) for chloride and bromide were found to be 25 mg/Kg and 50 mg/Kg, respectively. The metathesis reaction is proven by ED-XRF analysis of the precipitate produced during this reaction, showing the interchange between sulfate and phosphate ions. Chloride determination based on this approach was performed on several uranium-bearing phosphate rock samples from different sources. Since geolocation is one of the primary techniques needed for attribution, in a nuclear forensic investigation, this methodology may contribute to find new signatures, e.g. halides, in natural phosphate rocks deposits, to support that. The $ Cl^{−} $ content in 11 phosphate rock samples was determined after applying metathesis, and found to be in the range of 30–792 mg/Kg, supporting its relevance as nuclear forensic signature. The $ Br^{−} $ content was below the detection limit in all the samples. Nuclear forensics (dpeaa)DE-He213 Phosphate rocks (dpeaa)DE-He213 Uranium (dpeaa)DE-He213 Chloride (dpeaa)DE-He213 Moyal, Amiram verfasserin aut Nikolski, Andrey verfasserin aut Assulin, Maor verfasserin aut Shamish, Zorik verfasserin aut Elish, Eyal verfasserin aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 329(2021), 1 vom: 02. Juni, Seite 179-190 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:329 year:2021 number:1 day:02 month:06 pages:179-190 https://dx.doi.org/10.1007/s10967-021-07788-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 329 2021 1 02 06 179-190
spelling	10.1007/s10967-021-07788-8 doi (DE-627)SPR044445369 (SPR)s10967-021-07788-8-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Borojovich, Eitan J. C. verfasserin aut Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2021 Abstract An analytical approach for halides determination in uranium-bearing phosphate rocks, based on halides extraction from natural calcium phosphate by a metathesis reaction, followed by ion chromatography with conductivity detection analysis, is presented in this work. Chloride extraction is performed by mixing samples with sulfuric acid, causing an interchange between phosphate and sulfate ions towards calcium ions in the solid phase (metathesis). Addition of small amounts of calcium hydroxide improves the chromatographic determination by eliminating artifacts located in proximity to chloride retention time, and reducing phosphate peaks area. Limit of quantitation (LOQ) for chloride and bromide were found to be 25 mg/Kg and 50 mg/Kg, respectively. The metathesis reaction is proven by ED-XRF analysis of the precipitate produced during this reaction, showing the interchange between sulfate and phosphate ions. Chloride determination based on this approach was performed on several uranium-bearing phosphate rock samples from different sources. Since geolocation is one of the primary techniques needed for attribution, in a nuclear forensic investigation, this methodology may contribute to find new signatures, e.g. halides, in natural phosphate rocks deposits, to support that. The $ Cl^{−} $ content in 11 phosphate rock samples was determined after applying metathesis, and found to be in the range of 30–792 mg/Kg, supporting its relevance as nuclear forensic signature. The $ Br^{−} $ content was below the detection limit in all the samples. Nuclear forensics (dpeaa)DE-He213 Phosphate rocks (dpeaa)DE-He213 Uranium (dpeaa)DE-He213 Chloride (dpeaa)DE-He213 Moyal, Amiram verfasserin aut Nikolski, Andrey verfasserin aut Assulin, Maor verfasserin aut Shamish, Zorik verfasserin aut Elish, Eyal verfasserin aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 329(2021), 1 vom: 02. Juni, Seite 179-190 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:329 year:2021 number:1 day:02 month:06 pages:179-190 https://dx.doi.org/10.1007/s10967-021-07788-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 329 2021 1 02 06 179-190
allfields_unstemmed	10.1007/s10967-021-07788-8 doi (DE-627)SPR044445369 (SPR)s10967-021-07788-8-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Borojovich, Eitan J. C. verfasserin aut Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2021 Abstract An analytical approach for halides determination in uranium-bearing phosphate rocks, based on halides extraction from natural calcium phosphate by a metathesis reaction, followed by ion chromatography with conductivity detection analysis, is presented in this work. Chloride extraction is performed by mixing samples with sulfuric acid, causing an interchange between phosphate and sulfate ions towards calcium ions in the solid phase (metathesis). Addition of small amounts of calcium hydroxide improves the chromatographic determination by eliminating artifacts located in proximity to chloride retention time, and reducing phosphate peaks area. Limit of quantitation (LOQ) for chloride and bromide were found to be 25 mg/Kg and 50 mg/Kg, respectively. The metathesis reaction is proven by ED-XRF analysis of the precipitate produced during this reaction, showing the interchange between sulfate and phosphate ions. Chloride determination based on this approach was performed on several uranium-bearing phosphate rock samples from different sources. Since geolocation is one of the primary techniques needed for attribution, in a nuclear forensic investigation, this methodology may contribute to find new signatures, e.g. halides, in natural phosphate rocks deposits, to support that. The $ Cl^{−} $ content in 11 phosphate rock samples was determined after applying metathesis, and found to be in the range of 30–792 mg/Kg, supporting its relevance as nuclear forensic signature. The $ Br^{−} $ content was below the detection limit in all the samples. Nuclear forensics (dpeaa)DE-He213 Phosphate rocks (dpeaa)DE-He213 Uranium (dpeaa)DE-He213 Chloride (dpeaa)DE-He213 Moyal, Amiram verfasserin aut Nikolski, Andrey verfasserin aut Assulin, Maor verfasserin aut Shamish, Zorik verfasserin aut Elish, Eyal verfasserin aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 329(2021), 1 vom: 02. Juni, Seite 179-190 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:329 year:2021 number:1 day:02 month:06 pages:179-190 https://dx.doi.org/10.1007/s10967-021-07788-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 329 2021 1 02 06 179-190
allfieldsGer	10.1007/s10967-021-07788-8 doi (DE-627)SPR044445369 (SPR)s10967-021-07788-8-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Borojovich, Eitan J. C. verfasserin aut Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2021 Abstract An analytical approach for halides determination in uranium-bearing phosphate rocks, based on halides extraction from natural calcium phosphate by a metathesis reaction, followed by ion chromatography with conductivity detection analysis, is presented in this work. Chloride extraction is performed by mixing samples with sulfuric acid, causing an interchange between phosphate and sulfate ions towards calcium ions in the solid phase (metathesis). Addition of small amounts of calcium hydroxide improves the chromatographic determination by eliminating artifacts located in proximity to chloride retention time, and reducing phosphate peaks area. Limit of quantitation (LOQ) for chloride and bromide were found to be 25 mg/Kg and 50 mg/Kg, respectively. The metathesis reaction is proven by ED-XRF analysis of the precipitate produced during this reaction, showing the interchange between sulfate and phosphate ions. Chloride determination based on this approach was performed on several uranium-bearing phosphate rock samples from different sources. Since geolocation is one of the primary techniques needed for attribution, in a nuclear forensic investigation, this methodology may contribute to find new signatures, e.g. halides, in natural phosphate rocks deposits, to support that. The $ Cl^{−} $ content in 11 phosphate rock samples was determined after applying metathesis, and found to be in the range of 30–792 mg/Kg, supporting its relevance as nuclear forensic signature. The $ Br^{−} $ content was below the detection limit in all the samples. Nuclear forensics (dpeaa)DE-He213 Phosphate rocks (dpeaa)DE-He213 Uranium (dpeaa)DE-He213 Chloride (dpeaa)DE-He213 Moyal, Amiram verfasserin aut Nikolski, Andrey verfasserin aut Assulin, Maor verfasserin aut Shamish, Zorik verfasserin aut Elish, Eyal verfasserin aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 329(2021), 1 vom: 02. Juni, Seite 179-190 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:329 year:2021 number:1 day:02 month:06 pages:179-190 https://dx.doi.org/10.1007/s10967-021-07788-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 329 2021 1 02 06 179-190
allfieldsSound	10.1007/s10967-021-07788-8 doi (DE-627)SPR044445369 (SPR)s10967-021-07788-8-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Borojovich, Eitan J. C. verfasserin aut Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2021 Abstract An analytical approach for halides determination in uranium-bearing phosphate rocks, based on halides extraction from natural calcium phosphate by a metathesis reaction, followed by ion chromatography with conductivity detection analysis, is presented in this work. Chloride extraction is performed by mixing samples with sulfuric acid, causing an interchange between phosphate and sulfate ions towards calcium ions in the solid phase (metathesis). Addition of small amounts of calcium hydroxide improves the chromatographic determination by eliminating artifacts located in proximity to chloride retention time, and reducing phosphate peaks area. Limit of quantitation (LOQ) for chloride and bromide were found to be 25 mg/Kg and 50 mg/Kg, respectively. The metathesis reaction is proven by ED-XRF analysis of the precipitate produced during this reaction, showing the interchange between sulfate and phosphate ions. Chloride determination based on this approach was performed on several uranium-bearing phosphate rock samples from different sources. Since geolocation is one of the primary techniques needed for attribution, in a nuclear forensic investigation, this methodology may contribute to find new signatures, e.g. halides, in natural phosphate rocks deposits, to support that. The $ Cl^{−} $ content in 11 phosphate rock samples was determined after applying metathesis, and found to be in the range of 30–792 mg/Kg, supporting its relevance as nuclear forensic signature. The $ Br^{−} $ content was below the detection limit in all the samples. Nuclear forensics (dpeaa)DE-He213 Phosphate rocks (dpeaa)DE-He213 Uranium (dpeaa)DE-He213 Chloride (dpeaa)DE-He213 Moyal, Amiram verfasserin aut Nikolski, Andrey verfasserin aut Assulin, Maor verfasserin aut Shamish, Zorik verfasserin aut Elish, Eyal verfasserin aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 329(2021), 1 vom: 02. Juni, Seite 179-190 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:329 year:2021 number:1 day:02 month:06 pages:179-190 https://dx.doi.org/10.1007/s10967-021-07788-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 329 2021 1 02 06 179-190
language	English
source	Enthalten in Journal of radioanalytical and nuclear chemistry 329(2021), 1 vom: 02. Juni, Seite 179-190 volume:329 year:2021 number:1 day:02 month:06 pages:179-190
sourceStr	Enthalten in Journal of radioanalytical and nuclear chemistry 329(2021), 1 vom: 02. Juni, Seite 179-190 volume:329 year:2021 number:1 day:02 month:06 pages:179-190
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Nuclear forensics Phosphate rocks Uranium Chloride
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isfreeaccess_bool	false
container_title	Journal of radioanalytical and nuclear chemistry
authorswithroles_txt_mv	Borojovich, Eitan J. C. @@aut@@ Moyal, Amiram @@aut@@ Nikolski, Andrey @@aut@@ Assulin, Maor @@aut@@ Shamish, Zorik @@aut@@ Elish, Eyal @@aut@@
publishDateDaySort_date	2021-06-02T00:00:00Z
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author	Borojovich, Eitan J. C.
spellingShingle	Borojovich, Eitan J. C. ddc 540 bkl 35.00 misc Nuclear forensics misc Phosphate rocks misc Uranium misc Chloride Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications
authorStr	Borojovich, Eitan J. C.
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topic_title	540 ASE 35.00 bkl Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications Nuclear forensics (dpeaa)DE-He213 Phosphate rocks (dpeaa)DE-He213 Uranium (dpeaa)DE-He213 Chloride (dpeaa)DE-He213
topic	ddc 540 bkl 35.00 misc Nuclear forensics misc Phosphate rocks misc Uranium misc Chloride
topic_unstemmed	ddc 540 bkl 35.00 misc Nuclear forensics misc Phosphate rocks misc Uranium misc Chloride
topic_browse	ddc 540 bkl 35.00 misc Nuclear forensics misc Phosphate rocks misc Uranium misc Chloride
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title	Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications
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title_full	Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications
author_sort	Borojovich, Eitan J. C.
journal	Journal of radioanalytical and nuclear chemistry
journalStr	Journal of radioanalytical and nuclear chemistry
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author_browse	Borojovich, Eitan J. C. Moyal, Amiram Nikolski, Andrey Assulin, Maor Shamish, Zorik Elish, Eyal
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title_sort	halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications
title_auth	Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications
abstract	Abstract An analytical approach for halides determination in uranium-bearing phosphate rocks, based on halides extraction from natural calcium phosphate by a metathesis reaction, followed by ion chromatography with conductivity detection analysis, is presented in this work. Chloride extraction is performed by mixing samples with sulfuric acid, causing an interchange between phosphate and sulfate ions towards calcium ions in the solid phase (metathesis). Addition of small amounts of calcium hydroxide improves the chromatographic determination by eliminating artifacts located in proximity to chloride retention time, and reducing phosphate peaks area. Limit of quantitation (LOQ) for chloride and bromide were found to be 25 mg/Kg and 50 mg/Kg, respectively. The metathesis reaction is proven by ED-XRF analysis of the precipitate produced during this reaction, showing the interchange between sulfate and phosphate ions. Chloride determination based on this approach was performed on several uranium-bearing phosphate rock samples from different sources. Since geolocation is one of the primary techniques needed for attribution, in a nuclear forensic investigation, this methodology may contribute to find new signatures, e.g. halides, in natural phosphate rocks deposits, to support that. The $ Cl^{−} $ content in 11 phosphate rock samples was determined after applying metathesis, and found to be in the range of 30–792 mg/Kg, supporting its relevance as nuclear forensic signature. The $ Br^{−} $ content was below the detection limit in all the samples. © Akadémiai Kiadó, Budapest, Hungary 2021
abstractGer	Abstract An analytical approach for halides determination in uranium-bearing phosphate rocks, based on halides extraction from natural calcium phosphate by a metathesis reaction, followed by ion chromatography with conductivity detection analysis, is presented in this work. Chloride extraction is performed by mixing samples with sulfuric acid, causing an interchange between phosphate and sulfate ions towards calcium ions in the solid phase (metathesis). Addition of small amounts of calcium hydroxide improves the chromatographic determination by eliminating artifacts located in proximity to chloride retention time, and reducing phosphate peaks area. Limit of quantitation (LOQ) for chloride and bromide were found to be 25 mg/Kg and 50 mg/Kg, respectively. The metathesis reaction is proven by ED-XRF analysis of the precipitate produced during this reaction, showing the interchange between sulfate and phosphate ions. Chloride determination based on this approach was performed on several uranium-bearing phosphate rock samples from different sources. Since geolocation is one of the primary techniques needed for attribution, in a nuclear forensic investigation, this methodology may contribute to find new signatures, e.g. halides, in natural phosphate rocks deposits, to support that. The $ Cl^{−} $ content in 11 phosphate rock samples was determined after applying metathesis, and found to be in the range of 30–792 mg/Kg, supporting its relevance as nuclear forensic signature. The $ Br^{−} $ content was below the detection limit in all the samples. © Akadémiai Kiadó, Budapest, Hungary 2021
abstract_unstemmed	Abstract An analytical approach for halides determination in uranium-bearing phosphate rocks, based on halides extraction from natural calcium phosphate by a metathesis reaction, followed by ion chromatography with conductivity detection analysis, is presented in this work. Chloride extraction is performed by mixing samples with sulfuric acid, causing an interchange between phosphate and sulfate ions towards calcium ions in the solid phase (metathesis). Addition of small amounts of calcium hydroxide improves the chromatographic determination by eliminating artifacts located in proximity to chloride retention time, and reducing phosphate peaks area. Limit of quantitation (LOQ) for chloride and bromide were found to be 25 mg/Kg and 50 mg/Kg, respectively. The metathesis reaction is proven by ED-XRF analysis of the precipitate produced during this reaction, showing the interchange between sulfate and phosphate ions. Chloride determination based on this approach was performed on several uranium-bearing phosphate rock samples from different sources. Since geolocation is one of the primary techniques needed for attribution, in a nuclear forensic investigation, this methodology may contribute to find new signatures, e.g. halides, in natural phosphate rocks deposits, to support that. The $ Cl^{−} $ content in 11 phosphate rock samples was determined after applying metathesis, and found to be in the range of 30–792 mg/Kg, supporting its relevance as nuclear forensic signature. The $ Br^{−} $ content was below the detection limit in all the samples. © Akadémiai Kiadó, Budapest, Hungary 2021
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title_short	Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications
url	https://dx.doi.org/10.1007/s10967-021-07788-8
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author2	Moyal, Amiram Nikolski, Andrey Assulin, Maor Shamish, Zorik Elish, Eyal
author2Str	Moyal, Amiram Nikolski, Andrey Assulin, Maor Shamish, Zorik Elish, Eyal
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doi_str	10.1007/s10967-021-07788-8
up_date	2024-07-04T00:42:59.310Z
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Halides as potential signatures for geolocation of uranium phosphate rocks for nuclear forensic applications

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