X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $)
Abstract A 30 year-old $ PuF_{4} $ sample consisting of brown powder ($ PuF_{4} $-b) and pink granules ($ PuF_{4} $-p) was analyzed. X-ray diffraction shows the bulk is comprised of three compounds: $ PuF_{4} $, $ PuO_{2} $, and $ PuF_{4} $·1.$ 6H_{2} $O. Broadening of $ PuF_{4} $ XRD peaks suggests...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Wayne, David M. [verfasserIn] Stritzinger, Jared T. [verfasserIn] Casella, Amanda J. [verfasserIn] Sweet, Lucas E. [verfasserIn] Corbey, Jordan F. [verfasserIn] Garcia, Daniel J. [verfasserIn] Wylie, E. Miller [verfasserIn] Tandon, Lav [verfasserIn] Olson, Angela C. [verfasserIn] Rim, Jung Ho [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021 |
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| Schlagwörter: |
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| Anmerkung: |
© This is a U.S. government work and not under copyright protection in the U.S.; foreign copyright protection may apply 2021 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of radioanalytical and nuclear chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968, 329(2021), 2 vom: 23. Juni, Seite 741-756 |
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| Übergeordnetes Werk: |
volume:329 ; year:2021 ; number:2 ; day:23 ; month:06 ; pages:741-756 |
| Links: |
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| DOI / URN: |
10.1007/s10967-021-07810-z |
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| Katalog-ID: |
SPR044694636 |
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| 520 | |a Abstract A 30 year-old $ PuF_{4} $ sample consisting of brown powder ($ PuF_{4} $-b) and pink granules ($ PuF_{4} $-p) was analyzed. X-ray diffraction shows the bulk is comprised of three compounds: $ PuF_{4} $, $ PuO_{2} $, and $ PuF_{4} $·1.$ 6H_{2} $O. Broadening of $ PuF_{4} $ XRD peaks suggests possible %$\alpha%$-damage. After annealing at 650 °C, crystalline $ PuF_{4} $ and $ PuO_{2} $ remain. Thermogravimetric analysis and differential scanning calorimetry—with simultaneous evolved gas analysis—of the separated $ PuF_{4} $-p and $ PuF_{4} $-b components reveal a distinct sequence of reactions. Dehydration occurs between ~ 90 and 300 °C. Exothermic annealing of the %$\alpha%$-damage occurs in two stages: at 350–355 °C and at 555–558 °C. Hydrofluoric acid, fluorine and helium desorb during the first exotherm. Above 700 °C, $ PuF_{4} $ reacts with $ PuO_{2} $, resulting in oxygen release and mass loss. | ||
| 650 | 4 | |a Plutonium tetrafluoride |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Differential scanning calorimetry |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Thermal analysis |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Evolved gas analysis |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Annealing |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Radiation damage |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Stritzinger, Jared T. |e verfasserin |4 aut | |
| 700 | 1 | |a Casella, Amanda J. |e verfasserin |4 aut | |
| 700 | 1 | |a Sweet, Lucas E. |e verfasserin |4 aut | |
| 700 | 1 | |a Corbey, Jordan F. |e verfasserin |4 aut | |
| 700 | 1 | |a Garcia, Daniel J. |e verfasserin |4 aut | |
| 700 | 1 | |a Wylie, E. Miller |e verfasserin |4 aut | |
| 700 | 1 | |a Tandon, Lav |e verfasserin |4 aut | |
| 700 | 1 | |a Olson, Angela C. |e verfasserin |4 aut | |
| 700 | 1 | |a Rim, Jung Ho |e verfasserin |4 aut | |
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10.1007/s10967-021-07810-z doi (DE-627)SPR044694636 (SPR)s10967-021-07810-z-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Wayne, David M. verfasserin aut X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $) 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © This is a U.S. government work and not under copyright protection in the U.S.; foreign copyright protection may apply 2021 Abstract A 30 year-old $ PuF_{4} $ sample consisting of brown powder ($ PuF_{4} $-b) and pink granules ($ PuF_{4} $-p) was analyzed. X-ray diffraction shows the bulk is comprised of three compounds: $ PuF_{4} $, $ PuO_{2} $, and $ PuF_{4} $·1.$ 6H_{2} $O. Broadening of $ PuF_{4} $ XRD peaks suggests possible %$\alpha%$-damage. After annealing at 650 °C, crystalline $ PuF_{4} $ and $ PuO_{2} $ remain. Thermogravimetric analysis and differential scanning calorimetry—with simultaneous evolved gas analysis—of the separated $ PuF_{4} $-p and $ PuF_{4} $-b components reveal a distinct sequence of reactions. Dehydration occurs between ~ 90 and 300 °C. Exothermic annealing of the %$\alpha%$-damage occurs in two stages: at 350–355 °C and at 555–558 °C. Hydrofluoric acid, fluorine and helium desorb during the first exotherm. Above 700 °C, $ PuF_{4} $ reacts with $ PuO_{2} $, resulting in oxygen release and mass loss. Plutonium tetrafluoride (dpeaa)DE-He213 Differential scanning calorimetry (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Radiation damage (dpeaa)DE-He213 Stritzinger, Jared T. verfasserin aut Casella, Amanda J. verfasserin aut Sweet, Lucas E. verfasserin aut Corbey, Jordan F. verfasserin aut Garcia, Daniel J. verfasserin aut Wylie, E. Miller verfasserin aut Tandon, Lav verfasserin aut Olson, Angela C. verfasserin aut Rim, Jung Ho verfasserin aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 329(2021), 2 vom: 23. Juni, Seite 741-756 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:329 year:2021 number:2 day:23 month:06 pages:741-756 https://dx.doi.org/10.1007/s10967-021-07810-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 329 2021 2 23 06 741-756 |
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10.1007/s10967-021-07810-z doi (DE-627)SPR044694636 (SPR)s10967-021-07810-z-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Wayne, David M. verfasserin aut X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $) 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © This is a U.S. government work and not under copyright protection in the U.S.; foreign copyright protection may apply 2021 Abstract A 30 year-old $ PuF_{4} $ sample consisting of brown powder ($ PuF_{4} $-b) and pink granules ($ PuF_{4} $-p) was analyzed. X-ray diffraction shows the bulk is comprised of three compounds: $ PuF_{4} $, $ PuO_{2} $, and $ PuF_{4} $·1.$ 6H_{2} $O. Broadening of $ PuF_{4} $ XRD peaks suggests possible %$\alpha%$-damage. After annealing at 650 °C, crystalline $ PuF_{4} $ and $ PuO_{2} $ remain. Thermogravimetric analysis and differential scanning calorimetry—with simultaneous evolved gas analysis—of the separated $ PuF_{4} $-p and $ PuF_{4} $-b components reveal a distinct sequence of reactions. Dehydration occurs between ~ 90 and 300 °C. Exothermic annealing of the %$\alpha%$-damage occurs in two stages: at 350–355 °C and at 555–558 °C. Hydrofluoric acid, fluorine and helium desorb during the first exotherm. Above 700 °C, $ PuF_{4} $ reacts with $ PuO_{2} $, resulting in oxygen release and mass loss. Plutonium tetrafluoride (dpeaa)DE-He213 Differential scanning calorimetry (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Radiation damage (dpeaa)DE-He213 Stritzinger, Jared T. verfasserin aut Casella, Amanda J. verfasserin aut Sweet, Lucas E. verfasserin aut Corbey, Jordan F. verfasserin aut Garcia, Daniel J. verfasserin aut Wylie, E. Miller verfasserin aut Tandon, Lav verfasserin aut Olson, Angela C. verfasserin aut Rim, Jung Ho verfasserin aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 329(2021), 2 vom: 23. Juni, Seite 741-756 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:329 year:2021 number:2 day:23 month:06 pages:741-756 https://dx.doi.org/10.1007/s10967-021-07810-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 329 2021 2 23 06 741-756 |
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10.1007/s10967-021-07810-z doi (DE-627)SPR044694636 (SPR)s10967-021-07810-z-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Wayne, David M. verfasserin aut X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $) 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © This is a U.S. government work and not under copyright protection in the U.S.; foreign copyright protection may apply 2021 Abstract A 30 year-old $ PuF_{4} $ sample consisting of brown powder ($ PuF_{4} $-b) and pink granules ($ PuF_{4} $-p) was analyzed. X-ray diffraction shows the bulk is comprised of three compounds: $ PuF_{4} $, $ PuO_{2} $, and $ PuF_{4} $·1.$ 6H_{2} $O. Broadening of $ PuF_{4} $ XRD peaks suggests possible %$\alpha%$-damage. After annealing at 650 °C, crystalline $ PuF_{4} $ and $ PuO_{2} $ remain. Thermogravimetric analysis and differential scanning calorimetry—with simultaneous evolved gas analysis—of the separated $ PuF_{4} $-p and $ PuF_{4} $-b components reveal a distinct sequence of reactions. Dehydration occurs between ~ 90 and 300 °C. Exothermic annealing of the %$\alpha%$-damage occurs in two stages: at 350–355 °C and at 555–558 °C. Hydrofluoric acid, fluorine and helium desorb during the first exotherm. Above 700 °C, $ PuF_{4} $ reacts with $ PuO_{2} $, resulting in oxygen release and mass loss. Plutonium tetrafluoride (dpeaa)DE-He213 Differential scanning calorimetry (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Radiation damage (dpeaa)DE-He213 Stritzinger, Jared T. verfasserin aut Casella, Amanda J. verfasserin aut Sweet, Lucas E. verfasserin aut Corbey, Jordan F. verfasserin aut Garcia, Daniel J. verfasserin aut Wylie, E. Miller verfasserin aut Tandon, Lav verfasserin aut Olson, Angela C. verfasserin aut Rim, Jung Ho verfasserin aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 329(2021), 2 vom: 23. Juni, Seite 741-756 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:329 year:2021 number:2 day:23 month:06 pages:741-756 https://dx.doi.org/10.1007/s10967-021-07810-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 329 2021 2 23 06 741-756 |
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10.1007/s10967-021-07810-z doi (DE-627)SPR044694636 (SPR)s10967-021-07810-z-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Wayne, David M. verfasserin aut X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $) 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © This is a U.S. government work and not under copyright protection in the U.S.; foreign copyright protection may apply 2021 Abstract A 30 year-old $ PuF_{4} $ sample consisting of brown powder ($ PuF_{4} $-b) and pink granules ($ PuF_{4} $-p) was analyzed. X-ray diffraction shows the bulk is comprised of three compounds: $ PuF_{4} $, $ PuO_{2} $, and $ PuF_{4} $·1.$ 6H_{2} $O. Broadening of $ PuF_{4} $ XRD peaks suggests possible %$\alpha%$-damage. After annealing at 650 °C, crystalline $ PuF_{4} $ and $ PuO_{2} $ remain. Thermogravimetric analysis and differential scanning calorimetry—with simultaneous evolved gas analysis—of the separated $ PuF_{4} $-p and $ PuF_{4} $-b components reveal a distinct sequence of reactions. Dehydration occurs between ~ 90 and 300 °C. Exothermic annealing of the %$\alpha%$-damage occurs in two stages: at 350–355 °C and at 555–558 °C. Hydrofluoric acid, fluorine and helium desorb during the first exotherm. Above 700 °C, $ PuF_{4} $ reacts with $ PuO_{2} $, resulting in oxygen release and mass loss. Plutonium tetrafluoride (dpeaa)DE-He213 Differential scanning calorimetry (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Radiation damage (dpeaa)DE-He213 Stritzinger, Jared T. verfasserin aut Casella, Amanda J. verfasserin aut Sweet, Lucas E. verfasserin aut Corbey, Jordan F. verfasserin aut Garcia, Daniel J. verfasserin aut Wylie, E. Miller verfasserin aut Tandon, Lav verfasserin aut Olson, Angela C. verfasserin aut Rim, Jung Ho verfasserin aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 329(2021), 2 vom: 23. Juni, Seite 741-756 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:329 year:2021 number:2 day:23 month:06 pages:741-756 https://dx.doi.org/10.1007/s10967-021-07810-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 329 2021 2 23 06 741-756 |
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10.1007/s10967-021-07810-z doi (DE-627)SPR044694636 (SPR)s10967-021-07810-z-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Wayne, David M. verfasserin aut X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $) 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © This is a U.S. government work and not under copyright protection in the U.S.; foreign copyright protection may apply 2021 Abstract A 30 year-old $ PuF_{4} $ sample consisting of brown powder ($ PuF_{4} $-b) and pink granules ($ PuF_{4} $-p) was analyzed. X-ray diffraction shows the bulk is comprised of three compounds: $ PuF_{4} $, $ PuO_{2} $, and $ PuF_{4} $·1.$ 6H_{2} $O. Broadening of $ PuF_{4} $ XRD peaks suggests possible %$\alpha%$-damage. After annealing at 650 °C, crystalline $ PuF_{4} $ and $ PuO_{2} $ remain. Thermogravimetric analysis and differential scanning calorimetry—with simultaneous evolved gas analysis—of the separated $ PuF_{4} $-p and $ PuF_{4} $-b components reveal a distinct sequence of reactions. Dehydration occurs between ~ 90 and 300 °C. Exothermic annealing of the %$\alpha%$-damage occurs in two stages: at 350–355 °C and at 555–558 °C. Hydrofluoric acid, fluorine and helium desorb during the first exotherm. Above 700 °C, $ PuF_{4} $ reacts with $ PuO_{2} $, resulting in oxygen release and mass loss. Plutonium tetrafluoride (dpeaa)DE-He213 Differential scanning calorimetry (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Radiation damage (dpeaa)DE-He213 Stritzinger, Jared T. verfasserin aut Casella, Amanda J. verfasserin aut Sweet, Lucas E. verfasserin aut Corbey, Jordan F. verfasserin aut Garcia, Daniel J. verfasserin aut Wylie, E. Miller verfasserin aut Tandon, Lav verfasserin aut Olson, Angela C. verfasserin aut Rim, Jung Ho verfasserin aut Enthalten in Journal of radioanalytical and nuclear chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1968 329(2021), 2 vom: 23. Juni, Seite 741-756 (DE-627)320578011 (DE-600)2017242-4 1588-2780 nnns volume:329 year:2021 number:2 day:23 month:06 pages:741-756 https://dx.doi.org/10.1007/s10967-021-07810-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 329 2021 2 23 06 741-756 |
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Wayne, David M. @@aut@@ Stritzinger, Jared T. @@aut@@ Casella, Amanda J. @@aut@@ Sweet, Lucas E. @@aut@@ Corbey, Jordan F. @@aut@@ Garcia, Daniel J. @@aut@@ Wylie, E. Miller @@aut@@ Tandon, Lav @@aut@@ Olson, Angela C. @@aut@@ Rim, Jung Ho @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR044694636</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519231555.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">210730s2021 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10967-021-07810-z</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR044694636</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10967-021-07810-z-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Wayne, David M.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $)</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2021</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© This is a U.S. government work and not under copyright protection in the U.S.; foreign copyright protection may apply 2021</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract A 30 year-old $ PuF_{4} $ sample consisting of brown powder ($ PuF_{4} $-b) and pink granules ($ PuF_{4} $-p) was analyzed. X-ray diffraction shows the bulk is comprised of three compounds: $ PuF_{4} $, $ PuO_{2} $, and $ PuF_{4} $·1.$ 6H_{2} $O. Broadening of $ PuF_{4} $ XRD peaks suggests possible %$\alpha%$-damage. After annealing at 650 °C, crystalline $ PuF_{4} $ and $ PuO_{2} $ remain. Thermogravimetric analysis and differential scanning calorimetry—with simultaneous evolved gas analysis—of the separated $ PuF_{4} $-p and $ PuF_{4} $-b components reveal a distinct sequence of reactions. Dehydration occurs between ~ 90 and 300 °C. Exothermic annealing of the %$\alpha%$-damage occurs in two stages: at 350–355 °C and at 555–558 °C. Hydrofluoric acid, fluorine and helium desorb during the first exotherm. 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Wayne, David M. |
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Wayne, David M. ddc 540 bkl 35.00 misc Plutonium tetrafluoride misc Differential scanning calorimetry misc Thermal analysis misc Evolved gas analysis misc Annealing misc Radiation damage X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $) |
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540 ASE 35.00 bkl X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $) Plutonium tetrafluoride (dpeaa)DE-He213 Differential scanning calorimetry (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213 Annealing (dpeaa)DE-He213 Radiation damage (dpeaa)DE-He213 |
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ddc 540 bkl 35.00 misc Plutonium tetrafluoride misc Differential scanning calorimetry misc Thermal analysis misc Evolved gas analysis misc Annealing misc Radiation damage |
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ddc 540 bkl 35.00 misc Plutonium tetrafluoride misc Differential scanning calorimetry misc Thermal analysis misc Evolved gas analysis misc Annealing misc Radiation damage |
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ddc 540 bkl 35.00 misc Plutonium tetrafluoride misc Differential scanning calorimetry misc Thermal analysis misc Evolved gas analysis misc Annealing misc Radiation damage |
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X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $) |
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X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $) |
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Wayne, David M. |
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Journal of radioanalytical and nuclear chemistry |
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Journal of radioanalytical and nuclear chemistry |
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Wayne, David M. Stritzinger, Jared T. Casella, Amanda J. Sweet, Lucas E. Corbey, Jordan F. Garcia, Daniel J. Wylie, E. Miller Tandon, Lav Olson, Angela C. Rim, Jung Ho |
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Elektronische Aufsätze |
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Wayne, David M. |
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10.1007/s10967-021-07810-z |
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540 |
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x‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ puf_{4} $) |
| title_auth |
X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $) |
| abstract |
Abstract A 30 year-old $ PuF_{4} $ sample consisting of brown powder ($ PuF_{4} $-b) and pink granules ($ PuF_{4} $-p) was analyzed. X-ray diffraction shows the bulk is comprised of three compounds: $ PuF_{4} $, $ PuO_{2} $, and $ PuF_{4} $·1.$ 6H_{2} $O. Broadening of $ PuF_{4} $ XRD peaks suggests possible %$\alpha%$-damage. After annealing at 650 °C, crystalline $ PuF_{4} $ and $ PuO_{2} $ remain. Thermogravimetric analysis and differential scanning calorimetry—with simultaneous evolved gas analysis—of the separated $ PuF_{4} $-p and $ PuF_{4} $-b components reveal a distinct sequence of reactions. Dehydration occurs between ~ 90 and 300 °C. Exothermic annealing of the %$\alpha%$-damage occurs in two stages: at 350–355 °C and at 555–558 °C. Hydrofluoric acid, fluorine and helium desorb during the first exotherm. Above 700 °C, $ PuF_{4} $ reacts with $ PuO_{2} $, resulting in oxygen release and mass loss. © This is a U.S. government work and not under copyright protection in the U.S.; foreign copyright protection may apply 2021 |
| abstractGer |
Abstract A 30 year-old $ PuF_{4} $ sample consisting of brown powder ($ PuF_{4} $-b) and pink granules ($ PuF_{4} $-p) was analyzed. X-ray diffraction shows the bulk is comprised of three compounds: $ PuF_{4} $, $ PuO_{2} $, and $ PuF_{4} $·1.$ 6H_{2} $O. Broadening of $ PuF_{4} $ XRD peaks suggests possible %$\alpha%$-damage. After annealing at 650 °C, crystalline $ PuF_{4} $ and $ PuO_{2} $ remain. Thermogravimetric analysis and differential scanning calorimetry—with simultaneous evolved gas analysis—of the separated $ PuF_{4} $-p and $ PuF_{4} $-b components reveal a distinct sequence of reactions. Dehydration occurs between ~ 90 and 300 °C. Exothermic annealing of the %$\alpha%$-damage occurs in two stages: at 350–355 °C and at 555–558 °C. Hydrofluoric acid, fluorine and helium desorb during the first exotherm. Above 700 °C, $ PuF_{4} $ reacts with $ PuO_{2} $, resulting in oxygen release and mass loss. © This is a U.S. government work and not under copyright protection in the U.S.; foreign copyright protection may apply 2021 |
| abstract_unstemmed |
Abstract A 30 year-old $ PuF_{4} $ sample consisting of brown powder ($ PuF_{4} $-b) and pink granules ($ PuF_{4} $-p) was analyzed. X-ray diffraction shows the bulk is comprised of three compounds: $ PuF_{4} $, $ PuO_{2} $, and $ PuF_{4} $·1.$ 6H_{2} $O. Broadening of $ PuF_{4} $ XRD peaks suggests possible %$\alpha%$-damage. After annealing at 650 °C, crystalline $ PuF_{4} $ and $ PuO_{2} $ remain. Thermogravimetric analysis and differential scanning calorimetry—with simultaneous evolved gas analysis—of the separated $ PuF_{4} $-p and $ PuF_{4} $-b components reveal a distinct sequence of reactions. Dehydration occurs between ~ 90 and 300 °C. Exothermic annealing of the %$\alpha%$-damage occurs in two stages: at 350–355 °C and at 555–558 °C. Hydrofluoric acid, fluorine and helium desorb during the first exotherm. Above 700 °C, $ PuF_{4} $ reacts with $ PuO_{2} $, resulting in oxygen release and mass loss. © This is a U.S. government work and not under copyright protection in the U.S.; foreign copyright protection may apply 2021 |
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X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride ($ PuF_{4} $) |
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https://dx.doi.org/10.1007/s10967-021-07810-z |
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Stritzinger, Jared T. Casella, Amanda J. Sweet, Lucas E. Corbey, Jordan F. Garcia, Daniel J. Wylie, E. Miller Tandon, Lav Olson, Angela C. Rim, Jung Ho |
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Stritzinger, Jared T. Casella, Amanda J. Sweet, Lucas E. Corbey, Jordan F. Garcia, Daniel J. Wylie, E. Miller Tandon, Lav Olson, Angela C. Rim, Jung Ho |
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| score |
7.3987494 |