Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent
Abstract This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain transfer (RAFT) polymerization of wide range of monomers (acrylic and methacrylic acid, isobornyl acrylate, styrene, tert-butyl acrylate, 2,2...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Polozov, Egor [verfasserIn] Grigoreva, Alexandra [verfasserIn] Vlasov, Artem [verfasserIn] Zaitsev, Sergey [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021 |
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| Schlagwörter: |
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| Anmerkung: |
© The Polymer Society, Taipei 2021 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of polymer research - Dordrecht : Springer Science + Business Media B.V., 1994, 28(2021), 10 vom: 29. Sept. |
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| Übergeordnetes Werk: |
volume:28 ; year:2021 ; number:10 ; day:29 ; month:09 |
| Links: |
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| DOI / URN: |
10.1007/s10965-021-02758-w |
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| Katalog-ID: |
SPR04518237X |
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| 520 | |a Abstract This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain transfer (RAFT) polymerization of wide range of monomers (acrylic and methacrylic acid, isobornyl acrylate, styrene, tert-butyl acrylate, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate, vinyl acetate, N-vinylpyrrolidone, n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate). As an “pH-switchable” RAFT agent, 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate (CMPC) can be applied in polymerization both more activated monomers (MAMs), and less activated monomers (LAMs). 4-toluenesulfonic acid monohydrate (p-TSOH), trifluoromethanesulfonic acid (TFOH), and trifluoroacetic acid ($ CF_{3} $COOH) were used to moderate activity of the RAFT agent. CMPC provides good control over polymerization of LAMs (vinyl acetate, N-vinylpyrrolidone). Addition of one equivalent of a protic acid makes CMPC more effective in controlling polymerization of some MAMs. The good control was achieved also in polymerization of styrene, acrylic acid, methacrylic acid, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate monomers, and slightly worse in the case of isobornyl acrylate and tert-butyl acrylate. The poor control was shown for n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate. Besides, polyLAM-block-polyMAM (for instance, PVAc-b-PtBMA) with narrow molecular weight distributions was obtained. | ||
| 650 | 4 | |a RAFT polymerization |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Switchable RAFT agents |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Dithiocarbamates |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Block copolymers |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Grigoreva, Alexandra |e verfasserin |4 aut | |
| 700 | 1 | |a Vlasov, Artem |e verfasserin |4 aut | |
| 700 | 1 | |a Zaitsev, Sergey |e verfasserin |4 aut | |
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10.1007/s10965-021-02758-w doi (DE-627)SPR04518237X (SPR)s10965-021-02758-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Polozov, Egor verfasserin aut Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society, Taipei 2021 Abstract This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain transfer (RAFT) polymerization of wide range of monomers (acrylic and methacrylic acid, isobornyl acrylate, styrene, tert-butyl acrylate, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate, vinyl acetate, N-vinylpyrrolidone, n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate). As an “pH-switchable” RAFT agent, 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate (CMPC) can be applied in polymerization both more activated monomers (MAMs), and less activated monomers (LAMs). 4-toluenesulfonic acid monohydrate (p-TSOH), trifluoromethanesulfonic acid (TFOH), and trifluoroacetic acid ($ CF_{3} $COOH) were used to moderate activity of the RAFT agent. CMPC provides good control over polymerization of LAMs (vinyl acetate, N-vinylpyrrolidone). Addition of one equivalent of a protic acid makes CMPC more effective in controlling polymerization of some MAMs. The good control was achieved also in polymerization of styrene, acrylic acid, methacrylic acid, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate monomers, and slightly worse in the case of isobornyl acrylate and tert-butyl acrylate. The poor control was shown for n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate. Besides, polyLAM-block-polyMAM (for instance, PVAc-b-PtBMA) with narrow molecular weight distributions was obtained. RAFT polymerization (dpeaa)DE-He213 Switchable RAFT agents (dpeaa)DE-He213 Dithiocarbamates (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 Grigoreva, Alexandra verfasserin aut Vlasov, Artem verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 28(2021), 10 vom: 29. Sept. (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:28 year:2021 number:10 day:29 month:09 https://dx.doi.org/10.1007/s10965-021-02758-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 28 2021 10 29 09 |
| spelling |
10.1007/s10965-021-02758-w doi (DE-627)SPR04518237X (SPR)s10965-021-02758-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Polozov, Egor verfasserin aut Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society, Taipei 2021 Abstract This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain transfer (RAFT) polymerization of wide range of monomers (acrylic and methacrylic acid, isobornyl acrylate, styrene, tert-butyl acrylate, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate, vinyl acetate, N-vinylpyrrolidone, n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate). As an “pH-switchable” RAFT agent, 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate (CMPC) can be applied in polymerization both more activated monomers (MAMs), and less activated monomers (LAMs). 4-toluenesulfonic acid monohydrate (p-TSOH), trifluoromethanesulfonic acid (TFOH), and trifluoroacetic acid ($ CF_{3} $COOH) were used to moderate activity of the RAFT agent. CMPC provides good control over polymerization of LAMs (vinyl acetate, N-vinylpyrrolidone). Addition of one equivalent of a protic acid makes CMPC more effective in controlling polymerization of some MAMs. The good control was achieved also in polymerization of styrene, acrylic acid, methacrylic acid, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate monomers, and slightly worse in the case of isobornyl acrylate and tert-butyl acrylate. The poor control was shown for n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate. Besides, polyLAM-block-polyMAM (for instance, PVAc-b-PtBMA) with narrow molecular weight distributions was obtained. RAFT polymerization (dpeaa)DE-He213 Switchable RAFT agents (dpeaa)DE-He213 Dithiocarbamates (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 Grigoreva, Alexandra verfasserin aut Vlasov, Artem verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 28(2021), 10 vom: 29. Sept. (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:28 year:2021 number:10 day:29 month:09 https://dx.doi.org/10.1007/s10965-021-02758-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 28 2021 10 29 09 |
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10.1007/s10965-021-02758-w doi (DE-627)SPR04518237X (SPR)s10965-021-02758-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Polozov, Egor verfasserin aut Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society, Taipei 2021 Abstract This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain transfer (RAFT) polymerization of wide range of monomers (acrylic and methacrylic acid, isobornyl acrylate, styrene, tert-butyl acrylate, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate, vinyl acetate, N-vinylpyrrolidone, n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate). As an “pH-switchable” RAFT agent, 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate (CMPC) can be applied in polymerization both more activated monomers (MAMs), and less activated monomers (LAMs). 4-toluenesulfonic acid monohydrate (p-TSOH), trifluoromethanesulfonic acid (TFOH), and trifluoroacetic acid ($ CF_{3} $COOH) were used to moderate activity of the RAFT agent. CMPC provides good control over polymerization of LAMs (vinyl acetate, N-vinylpyrrolidone). Addition of one equivalent of a protic acid makes CMPC more effective in controlling polymerization of some MAMs. The good control was achieved also in polymerization of styrene, acrylic acid, methacrylic acid, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate monomers, and slightly worse in the case of isobornyl acrylate and tert-butyl acrylate. The poor control was shown for n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate. Besides, polyLAM-block-polyMAM (for instance, PVAc-b-PtBMA) with narrow molecular weight distributions was obtained. RAFT polymerization (dpeaa)DE-He213 Switchable RAFT agents (dpeaa)DE-He213 Dithiocarbamates (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 Grigoreva, Alexandra verfasserin aut Vlasov, Artem verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 28(2021), 10 vom: 29. Sept. (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:28 year:2021 number:10 day:29 month:09 https://dx.doi.org/10.1007/s10965-021-02758-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 28 2021 10 29 09 |
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10.1007/s10965-021-02758-w doi (DE-627)SPR04518237X (SPR)s10965-021-02758-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Polozov, Egor verfasserin aut Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society, Taipei 2021 Abstract This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain transfer (RAFT) polymerization of wide range of monomers (acrylic and methacrylic acid, isobornyl acrylate, styrene, tert-butyl acrylate, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate, vinyl acetate, N-vinylpyrrolidone, n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate). As an “pH-switchable” RAFT agent, 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate (CMPC) can be applied in polymerization both more activated monomers (MAMs), and less activated monomers (LAMs). 4-toluenesulfonic acid monohydrate (p-TSOH), trifluoromethanesulfonic acid (TFOH), and trifluoroacetic acid ($ CF_{3} $COOH) were used to moderate activity of the RAFT agent. CMPC provides good control over polymerization of LAMs (vinyl acetate, N-vinylpyrrolidone). Addition of one equivalent of a protic acid makes CMPC more effective in controlling polymerization of some MAMs. The good control was achieved also in polymerization of styrene, acrylic acid, methacrylic acid, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate monomers, and slightly worse in the case of isobornyl acrylate and tert-butyl acrylate. The poor control was shown for n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate. Besides, polyLAM-block-polyMAM (for instance, PVAc-b-PtBMA) with narrow molecular weight distributions was obtained. RAFT polymerization (dpeaa)DE-He213 Switchable RAFT agents (dpeaa)DE-He213 Dithiocarbamates (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 Grigoreva, Alexandra verfasserin aut Vlasov, Artem verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 28(2021), 10 vom: 29. Sept. (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:28 year:2021 number:10 day:29 month:09 https://dx.doi.org/10.1007/s10965-021-02758-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 28 2021 10 29 09 |
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10.1007/s10965-021-02758-w doi (DE-627)SPR04518237X (SPR)s10965-021-02758-w-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Polozov, Egor verfasserin aut Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Polymer Society, Taipei 2021 Abstract This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain transfer (RAFT) polymerization of wide range of monomers (acrylic and methacrylic acid, isobornyl acrylate, styrene, tert-butyl acrylate, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate, vinyl acetate, N-vinylpyrrolidone, n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate). As an “pH-switchable” RAFT agent, 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate (CMPC) can be applied in polymerization both more activated monomers (MAMs), and less activated monomers (LAMs). 4-toluenesulfonic acid monohydrate (p-TSOH), trifluoromethanesulfonic acid (TFOH), and trifluoroacetic acid ($ CF_{3} $COOH) were used to moderate activity of the RAFT agent. CMPC provides good control over polymerization of LAMs (vinyl acetate, N-vinylpyrrolidone). Addition of one equivalent of a protic acid makes CMPC more effective in controlling polymerization of some MAMs. The good control was achieved also in polymerization of styrene, acrylic acid, methacrylic acid, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate monomers, and slightly worse in the case of isobornyl acrylate and tert-butyl acrylate. The poor control was shown for n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate. Besides, polyLAM-block-polyMAM (for instance, PVAc-b-PtBMA) with narrow molecular weight distributions was obtained. RAFT polymerization (dpeaa)DE-He213 Switchable RAFT agents (dpeaa)DE-He213 Dithiocarbamates (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 Grigoreva, Alexandra verfasserin aut Vlasov, Artem verfasserin aut Zaitsev, Sergey verfasserin aut Enthalten in Journal of polymer research Dordrecht : Springer Science + Business Media B.V., 1994 28(2021), 10 vom: 29. Sept. (DE-627)340872098 (DE-600)2065616-6 1572-8935 nnns volume:28 year:2021 number:10 day:29 month:09 https://dx.doi.org/10.1007/s10965-021-02758-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 28 2021 10 29 09 |
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Enthalten in Journal of polymer research 28(2021), 10 vom: 29. Sept. volume:28 year:2021 number:10 day:29 month:09 |
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RAFT polymerization Switchable RAFT agents Dithiocarbamates Block copolymers |
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Polozov, Egor @@aut@@ Grigoreva, Alexandra @@aut@@ Vlasov, Artem @@aut@@ Zaitsev, Sergey @@aut@@ |
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As an “pH-switchable” RAFT agent, 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate (CMPC) can be applied in polymerization both more activated monomers (MAMs), and less activated monomers (LAMs). 4-toluenesulfonic acid monohydrate (p-TSOH), trifluoromethanesulfonic acid (TFOH), and trifluoroacetic acid ($ CF_{3} $COOH) were used to moderate activity of the RAFT agent. CMPC provides good control over polymerization of LAMs (vinyl acetate, N-vinylpyrrolidone). Addition of one equivalent of a protic acid makes CMPC more effective in controlling polymerization of some MAMs. The good control was achieved also in polymerization of styrene, acrylic acid, methacrylic acid, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate monomers, and slightly worse in the case of isobornyl acrylate and tert-butyl acrylate. The poor control was shown for n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate. 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Polozov, Egor |
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Polozov, Egor ddc 540 bkl 35.00 misc RAFT polymerization misc Switchable RAFT agents misc Dithiocarbamates misc Block copolymers Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent |
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540 ASE 35.00 bkl Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent RAFT polymerization (dpeaa)DE-He213 Switchable RAFT agents (dpeaa)DE-He213 Dithiocarbamates (dpeaa)DE-He213 Block copolymers (dpeaa)DE-He213 |
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ddc 540 bkl 35.00 misc RAFT polymerization misc Switchable RAFT agents misc Dithiocarbamates misc Block copolymers |
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Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent |
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Polozov, Egor Grigoreva, Alexandra Vlasov, Artem Zaitsev, Sergey |
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peculiarities of reversible addition-fragmentation chain transfer (raft) polymerization in the presence of switchable raft agent |
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Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent |
| abstract |
Abstract This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain transfer (RAFT) polymerization of wide range of monomers (acrylic and methacrylic acid, isobornyl acrylate, styrene, tert-butyl acrylate, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate, vinyl acetate, N-vinylpyrrolidone, n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate). As an “pH-switchable” RAFT agent, 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate (CMPC) can be applied in polymerization both more activated monomers (MAMs), and less activated monomers (LAMs). 4-toluenesulfonic acid monohydrate (p-TSOH), trifluoromethanesulfonic acid (TFOH), and trifluoroacetic acid ($ CF_{3} $COOH) were used to moderate activity of the RAFT agent. CMPC provides good control over polymerization of LAMs (vinyl acetate, N-vinylpyrrolidone). Addition of one equivalent of a protic acid makes CMPC more effective in controlling polymerization of some MAMs. The good control was achieved also in polymerization of styrene, acrylic acid, methacrylic acid, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate monomers, and slightly worse in the case of isobornyl acrylate and tert-butyl acrylate. The poor control was shown for n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate. Besides, polyLAM-block-polyMAM (for instance, PVAc-b-PtBMA) with narrow molecular weight distributions was obtained. © The Polymer Society, Taipei 2021 |
| abstractGer |
Abstract This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain transfer (RAFT) polymerization of wide range of monomers (acrylic and methacrylic acid, isobornyl acrylate, styrene, tert-butyl acrylate, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate, vinyl acetate, N-vinylpyrrolidone, n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate). As an “pH-switchable” RAFT agent, 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate (CMPC) can be applied in polymerization both more activated monomers (MAMs), and less activated monomers (LAMs). 4-toluenesulfonic acid monohydrate (p-TSOH), trifluoromethanesulfonic acid (TFOH), and trifluoroacetic acid ($ CF_{3} $COOH) were used to moderate activity of the RAFT agent. CMPC provides good control over polymerization of LAMs (vinyl acetate, N-vinylpyrrolidone). Addition of one equivalent of a protic acid makes CMPC more effective in controlling polymerization of some MAMs. The good control was achieved also in polymerization of styrene, acrylic acid, methacrylic acid, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate monomers, and slightly worse in the case of isobornyl acrylate and tert-butyl acrylate. The poor control was shown for n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate. Besides, polyLAM-block-polyMAM (for instance, PVAc-b-PtBMA) with narrow molecular weight distributions was obtained. © The Polymer Society, Taipei 2021 |
| abstract_unstemmed |
Abstract This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain transfer (RAFT) polymerization of wide range of monomers (acrylic and methacrylic acid, isobornyl acrylate, styrene, tert-butyl acrylate, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate, vinyl acetate, N-vinylpyrrolidone, n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate). As an “pH-switchable” RAFT agent, 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate (CMPC) can be applied in polymerization both more activated monomers (MAMs), and less activated monomers (LAMs). 4-toluenesulfonic acid monohydrate (p-TSOH), trifluoromethanesulfonic acid (TFOH), and trifluoroacetic acid ($ CF_{3} $COOH) were used to moderate activity of the RAFT agent. CMPC provides good control over polymerization of LAMs (vinyl acetate, N-vinylpyrrolidone). Addition of one equivalent of a protic acid makes CMPC more effective in controlling polymerization of some MAMs. The good control was achieved also in polymerization of styrene, acrylic acid, methacrylic acid, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate monomers, and slightly worse in the case of isobornyl acrylate and tert-butyl acrylate. The poor control was shown for n-butyl methacrylate, tert-butyl methacrylate, methyl methacrylate. Besides, polyLAM-block-polyMAM (for instance, PVAc-b-PtBMA) with narrow molecular weight distributions was obtained. © The Polymer Society, Taipei 2021 |
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| title_short |
Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent |
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https://dx.doi.org/10.1007/s10965-021-02758-w |
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| author2 |
Grigoreva, Alexandra Vlasov, Artem Zaitsev, Sergey |
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Grigoreva, Alexandra Vlasov, Artem Zaitsev, Sergey |
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| doi_str |
10.1007/s10965-021-02758-w |
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2024-07-03T14:18:17.143Z |
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|
| score |
7.400714 |