Diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery
Abstract The aluminum electrolysis spent cathode (SC) was treated by hydrothermal method and used as anode material for lithium-ion battery. The purified SC material shows excellent electrochemical performance. In order to understand the diffusion behavior of $ Li^{+} $ in the SC electrode, the diff...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Huang, Wenlong [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 |
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| Übergeordnetes Werk: |
Enthalten in: Ionics - Berlin : Springer, 1995, 28(2022), 2 vom: 07. Jan., Seite 961-971 |
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| Übergeordnetes Werk: |
volume:28 ; year:2022 ; number:2 ; day:07 ; month:01 ; pages:961-971 |
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| DOI / URN: |
10.1007/s11581-021-04398-y |
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| Katalog-ID: |
SPR046005935 |
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| 520 | |a Abstract The aluminum electrolysis spent cathode (SC) was treated by hydrothermal method and used as anode material for lithium-ion battery. The purified SC material shows excellent electrochemical performance. In order to understand the diffusion behavior of $ Li^{+} $ in the SC electrode, the diffusion coefficient of $ Li^{+} $ in the SC electrode was systematically analyzed by galvanostatic intermittent titration technique (GITT), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results show that the diffusion coefficient (%${D}_{{\text{Li}}^{+}}%$) of $ Li^{+} $ in SC electrode is calculated by CV is 2.2292 × $ 10^{−11} $ $ cm^{2} $ $ s^{−1} $, and the ranges calculated by GITT and EIS are 4.2286 × $ 10^{−13} $ − 2.9667 × $ 10^{−10} $ $ cm^{2} $ $ s^{−1} $, 4.05 × $ 10^{−13} $ − 3.87 × $ 10^{−12} $ $ cm^{2} $ $ s^{−1} $, respectively. SC electrode exhibits better $ Li^{+} $ diffusion kinetics compared to commercial graphite (CG). In addition, the full cell of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC also shows excellent cycle performance. After 80 cycles at 1 °C (1 °C = 172 mA $ g^{−1} $), the specific discharge capacity of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC full-cell can reach 94.7 mAh $ g^{−1} $, and the capacity retention can reach 98.13%. The fast lithium-ion diffusion rate and high discharge capacity provide a feasible direction for the high value utilization of aluminum electrolysis spent cathode. | ||
| 650 | 4 | |a Lithium-ion battery |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Aluminum electrolysis spent cathode |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Diffusion coefficient |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a GITT |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a EIS |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Peng, Jiaxin |4 aut | |
| 700 | 1 | |a Li, Jie |4 aut | |
| 700 | 1 | |a Hou, Xueyang |4 aut | |
| 700 | 1 | |a Zhang, Xingliang |4 aut | |
| 700 | 1 | |a Fang, Zhao |4 aut | |
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10.1007/s11581-021-04398-y doi (DE-627)SPR046005935 (SPR)s11581-021-04398-y-e DE-627 ger DE-627 rakwb eng Huang, Wenlong verfasserin aut Diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 Abstract The aluminum electrolysis spent cathode (SC) was treated by hydrothermal method and used as anode material for lithium-ion battery. The purified SC material shows excellent electrochemical performance. In order to understand the diffusion behavior of $ Li^{+} $ in the SC electrode, the diffusion coefficient of $ Li^{+} $ in the SC electrode was systematically analyzed by galvanostatic intermittent titration technique (GITT), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results show that the diffusion coefficient (%${D}_{{\text{Li}}^{+}}%$) of $ Li^{+} $ in SC electrode is calculated by CV is 2.2292 × $ 10^{−11} $ $ cm^{2} $ $ s^{−1} $, and the ranges calculated by GITT and EIS are 4.2286 × $ 10^{−13} $ − 2.9667 × $ 10^{−10} $ $ cm^{2} $ $ s^{−1} $, 4.05 × $ 10^{−13} $ − 3.87 × $ 10^{−12} $ $ cm^{2} $ $ s^{−1} $, respectively. SC electrode exhibits better $ Li^{+} $ diffusion kinetics compared to commercial graphite (CG). In addition, the full cell of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC also shows excellent cycle performance. After 80 cycles at 1 °C (1 °C = 172 mA $ g^{−1} $), the specific discharge capacity of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC full-cell can reach 94.7 mAh $ g^{−1} $, and the capacity retention can reach 98.13%. The fast lithium-ion diffusion rate and high discharge capacity provide a feasible direction for the high value utilization of aluminum electrolysis spent cathode. Lithium-ion battery (dpeaa)DE-He213 Aluminum electrolysis spent cathode (dpeaa)DE-He213 Diffusion coefficient (dpeaa)DE-He213 GITT (dpeaa)DE-He213 EIS (dpeaa)DE-He213 Peng, Jiaxin aut Li, Jie aut Hou, Xueyang aut Zhang, Xingliang aut Fang, Zhao aut Enthalten in Ionics Berlin : Springer, 1995 28(2022), 2 vom: 07. Jan., Seite 961-971 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:28 year:2022 number:2 day:07 month:01 pages:961-971 https://dx.doi.org/10.1007/s11581-021-04398-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 28 2022 2 07 01 961-971 |
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10.1007/s11581-021-04398-y doi (DE-627)SPR046005935 (SPR)s11581-021-04398-y-e DE-627 ger DE-627 rakwb eng Huang, Wenlong verfasserin aut Diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 Abstract The aluminum electrolysis spent cathode (SC) was treated by hydrothermal method and used as anode material for lithium-ion battery. The purified SC material shows excellent electrochemical performance. In order to understand the diffusion behavior of $ Li^{+} $ in the SC electrode, the diffusion coefficient of $ Li^{+} $ in the SC electrode was systematically analyzed by galvanostatic intermittent titration technique (GITT), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results show that the diffusion coefficient (%${D}_{{\text{Li}}^{+}}%$) of $ Li^{+} $ in SC electrode is calculated by CV is 2.2292 × $ 10^{−11} $ $ cm^{2} $ $ s^{−1} $, and the ranges calculated by GITT and EIS are 4.2286 × $ 10^{−13} $ − 2.9667 × $ 10^{−10} $ $ cm^{2} $ $ s^{−1} $, 4.05 × $ 10^{−13} $ − 3.87 × $ 10^{−12} $ $ cm^{2} $ $ s^{−1} $, respectively. SC electrode exhibits better $ Li^{+} $ diffusion kinetics compared to commercial graphite (CG). In addition, the full cell of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC also shows excellent cycle performance. After 80 cycles at 1 °C (1 °C = 172 mA $ g^{−1} $), the specific discharge capacity of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC full-cell can reach 94.7 mAh $ g^{−1} $, and the capacity retention can reach 98.13%. The fast lithium-ion diffusion rate and high discharge capacity provide a feasible direction for the high value utilization of aluminum electrolysis spent cathode. Lithium-ion battery (dpeaa)DE-He213 Aluminum electrolysis spent cathode (dpeaa)DE-He213 Diffusion coefficient (dpeaa)DE-He213 GITT (dpeaa)DE-He213 EIS (dpeaa)DE-He213 Peng, Jiaxin aut Li, Jie aut Hou, Xueyang aut Zhang, Xingliang aut Fang, Zhao aut Enthalten in Ionics Berlin : Springer, 1995 28(2022), 2 vom: 07. Jan., Seite 961-971 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:28 year:2022 number:2 day:07 month:01 pages:961-971 https://dx.doi.org/10.1007/s11581-021-04398-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 28 2022 2 07 01 961-971 |
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10.1007/s11581-021-04398-y doi (DE-627)SPR046005935 (SPR)s11581-021-04398-y-e DE-627 ger DE-627 rakwb eng Huang, Wenlong verfasserin aut Diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 Abstract The aluminum electrolysis spent cathode (SC) was treated by hydrothermal method and used as anode material for lithium-ion battery. The purified SC material shows excellent electrochemical performance. In order to understand the diffusion behavior of $ Li^{+} $ in the SC electrode, the diffusion coefficient of $ Li^{+} $ in the SC electrode was systematically analyzed by galvanostatic intermittent titration technique (GITT), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results show that the diffusion coefficient (%${D}_{{\text{Li}}^{+}}%$) of $ Li^{+} $ in SC electrode is calculated by CV is 2.2292 × $ 10^{−11} $ $ cm^{2} $ $ s^{−1} $, and the ranges calculated by GITT and EIS are 4.2286 × $ 10^{−13} $ − 2.9667 × $ 10^{−10} $ $ cm^{2} $ $ s^{−1} $, 4.05 × $ 10^{−13} $ − 3.87 × $ 10^{−12} $ $ cm^{2} $ $ s^{−1} $, respectively. SC electrode exhibits better $ Li^{+} $ diffusion kinetics compared to commercial graphite (CG). In addition, the full cell of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC also shows excellent cycle performance. After 80 cycles at 1 °C (1 °C = 172 mA $ g^{−1} $), the specific discharge capacity of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC full-cell can reach 94.7 mAh $ g^{−1} $, and the capacity retention can reach 98.13%. The fast lithium-ion diffusion rate and high discharge capacity provide a feasible direction for the high value utilization of aluminum electrolysis spent cathode. Lithium-ion battery (dpeaa)DE-He213 Aluminum electrolysis spent cathode (dpeaa)DE-He213 Diffusion coefficient (dpeaa)DE-He213 GITT (dpeaa)DE-He213 EIS (dpeaa)DE-He213 Peng, Jiaxin aut Li, Jie aut Hou, Xueyang aut Zhang, Xingliang aut Fang, Zhao aut Enthalten in Ionics Berlin : Springer, 1995 28(2022), 2 vom: 07. Jan., Seite 961-971 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:28 year:2022 number:2 day:07 month:01 pages:961-971 https://dx.doi.org/10.1007/s11581-021-04398-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 28 2022 2 07 01 961-971 |
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10.1007/s11581-021-04398-y doi (DE-627)SPR046005935 (SPR)s11581-021-04398-y-e DE-627 ger DE-627 rakwb eng Huang, Wenlong verfasserin aut Diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 Abstract The aluminum electrolysis spent cathode (SC) was treated by hydrothermal method and used as anode material for lithium-ion battery. The purified SC material shows excellent electrochemical performance. In order to understand the diffusion behavior of $ Li^{+} $ in the SC electrode, the diffusion coefficient of $ Li^{+} $ in the SC electrode was systematically analyzed by galvanostatic intermittent titration technique (GITT), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results show that the diffusion coefficient (%${D}_{{\text{Li}}^{+}}%$) of $ Li^{+} $ in SC electrode is calculated by CV is 2.2292 × $ 10^{−11} $ $ cm^{2} $ $ s^{−1} $, and the ranges calculated by GITT and EIS are 4.2286 × $ 10^{−13} $ − 2.9667 × $ 10^{−10} $ $ cm^{2} $ $ s^{−1} $, 4.05 × $ 10^{−13} $ − 3.87 × $ 10^{−12} $ $ cm^{2} $ $ s^{−1} $, respectively. SC electrode exhibits better $ Li^{+} $ diffusion kinetics compared to commercial graphite (CG). In addition, the full cell of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC also shows excellent cycle performance. After 80 cycles at 1 °C (1 °C = 172 mA $ g^{−1} $), the specific discharge capacity of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC full-cell can reach 94.7 mAh $ g^{−1} $, and the capacity retention can reach 98.13%. The fast lithium-ion diffusion rate and high discharge capacity provide a feasible direction for the high value utilization of aluminum electrolysis spent cathode. Lithium-ion battery (dpeaa)DE-He213 Aluminum electrolysis spent cathode (dpeaa)DE-He213 Diffusion coefficient (dpeaa)DE-He213 GITT (dpeaa)DE-He213 EIS (dpeaa)DE-He213 Peng, Jiaxin aut Li, Jie aut Hou, Xueyang aut Zhang, Xingliang aut Fang, Zhao aut Enthalten in Ionics Berlin : Springer, 1995 28(2022), 2 vom: 07. Jan., Seite 961-971 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:28 year:2022 number:2 day:07 month:01 pages:961-971 https://dx.doi.org/10.1007/s11581-021-04398-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 28 2022 2 07 01 961-971 |
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10.1007/s11581-021-04398-y doi (DE-627)SPR046005935 (SPR)s11581-021-04398-y-e DE-627 ger DE-627 rakwb eng Huang, Wenlong verfasserin aut Diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 Abstract The aluminum electrolysis spent cathode (SC) was treated by hydrothermal method and used as anode material for lithium-ion battery. The purified SC material shows excellent electrochemical performance. In order to understand the diffusion behavior of $ Li^{+} $ in the SC electrode, the diffusion coefficient of $ Li^{+} $ in the SC electrode was systematically analyzed by galvanostatic intermittent titration technique (GITT), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results show that the diffusion coefficient (%${D}_{{\text{Li}}^{+}}%$) of $ Li^{+} $ in SC electrode is calculated by CV is 2.2292 × $ 10^{−11} $ $ cm^{2} $ $ s^{−1} $, and the ranges calculated by GITT and EIS are 4.2286 × $ 10^{−13} $ − 2.9667 × $ 10^{−10} $ $ cm^{2} $ $ s^{−1} $, 4.05 × $ 10^{−13} $ − 3.87 × $ 10^{−12} $ $ cm^{2} $ $ s^{−1} $, respectively. SC electrode exhibits better $ Li^{+} $ diffusion kinetics compared to commercial graphite (CG). In addition, the full cell of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC also shows excellent cycle performance. After 80 cycles at 1 °C (1 °C = 172 mA $ g^{−1} $), the specific discharge capacity of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC full-cell can reach 94.7 mAh $ g^{−1} $, and the capacity retention can reach 98.13%. The fast lithium-ion diffusion rate and high discharge capacity provide a feasible direction for the high value utilization of aluminum electrolysis spent cathode. Lithium-ion battery (dpeaa)DE-He213 Aluminum electrolysis spent cathode (dpeaa)DE-He213 Diffusion coefficient (dpeaa)DE-He213 GITT (dpeaa)DE-He213 EIS (dpeaa)DE-He213 Peng, Jiaxin aut Li, Jie aut Hou, Xueyang aut Zhang, Xingliang aut Fang, Zhao aut Enthalten in Ionics Berlin : Springer, 1995 28(2022), 2 vom: 07. Jan., Seite 961-971 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:28 year:2022 number:2 day:07 month:01 pages:961-971 https://dx.doi.org/10.1007/s11581-021-04398-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 28 2022 2 07 01 961-971 |
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Enthalten in Ionics 28(2022), 2 vom: 07. Jan., Seite 961-971 volume:28 year:2022 number:2 day:07 month:01 pages:961-971 |
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Huang, Wenlong @@aut@@ Peng, Jiaxin @@aut@@ Li, Jie @@aut@@ Hou, Xueyang @@aut@@ Zhang, Xingliang @@aut@@ Fang, Zhao @@aut@@ |
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The purified SC material shows excellent electrochemical performance. In order to understand the diffusion behavior of $ Li^{+} $ in the SC electrode, the diffusion coefficient of $ Li^{+} $ in the SC electrode was systematically analyzed by galvanostatic intermittent titration technique (GITT), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results show that the diffusion coefficient (%${D}_{{\text{Li}}^{+}}%$) of $ Li^{+} $ in SC electrode is calculated by CV is 2.2292 × $ 10^{−11} $ $ cm^{2} $ $ s^{−1} $, and the ranges calculated by GITT and EIS are 4.2286 × $ 10^{−13} $ − 2.9667 × $ 10^{−10} $ $ cm^{2} $ $ s^{−1} $, 4.05 × $ 10^{−13} $ − 3.87 × $ 10^{−12} $ $ cm^{2} $ $ s^{−1} $, respectively. SC electrode exhibits better $ Li^{+} $ diffusion kinetics compared to commercial graphite (CG). In addition, the full cell of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC also shows excellent cycle performance. After 80 cycles at 1 °C (1 °C = 172 mA $ g^{−1} $), the specific discharge capacity of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC full-cell can reach 94.7 mAh $ g^{−1} $, and the capacity retention can reach 98.13%. 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Huang, Wenlong |
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Huang, Wenlong misc Lithium-ion battery misc Aluminum electrolysis spent cathode misc Diffusion coefficient misc GITT misc EIS Diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery |
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Diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery Lithium-ion battery (dpeaa)DE-He213 Aluminum electrolysis spent cathode (dpeaa)DE-He213 Diffusion coefficient (dpeaa)DE-He213 GITT (dpeaa)DE-He213 EIS (dpeaa)DE-He213 |
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misc Lithium-ion battery misc Aluminum electrolysis spent cathode misc Diffusion coefficient misc GITT misc EIS |
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misc Lithium-ion battery misc Aluminum electrolysis spent cathode misc Diffusion coefficient misc GITT misc EIS |
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Diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery |
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Huang, Wenlong |
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Huang, Wenlong Peng, Jiaxin Li, Jie Hou, Xueyang Zhang, Xingliang Fang, Zhao |
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diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery |
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Diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery |
| abstract |
Abstract The aluminum electrolysis spent cathode (SC) was treated by hydrothermal method and used as anode material for lithium-ion battery. The purified SC material shows excellent electrochemical performance. In order to understand the diffusion behavior of $ Li^{+} $ in the SC electrode, the diffusion coefficient of $ Li^{+} $ in the SC electrode was systematically analyzed by galvanostatic intermittent titration technique (GITT), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results show that the diffusion coefficient (%${D}_{{\text{Li}}^{+}}%$) of $ Li^{+} $ in SC electrode is calculated by CV is 2.2292 × $ 10^{−11} $ $ cm^{2} $ $ s^{−1} $, and the ranges calculated by GITT and EIS are 4.2286 × $ 10^{−13} $ − 2.9667 × $ 10^{−10} $ $ cm^{2} $ $ s^{−1} $, 4.05 × $ 10^{−13} $ − 3.87 × $ 10^{−12} $ $ cm^{2} $ $ s^{−1} $, respectively. SC electrode exhibits better $ Li^{+} $ diffusion kinetics compared to commercial graphite (CG). In addition, the full cell of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC also shows excellent cycle performance. After 80 cycles at 1 °C (1 °C = 172 mA $ g^{−1} $), the specific discharge capacity of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC full-cell can reach 94.7 mAh $ g^{−1} $, and the capacity retention can reach 98.13%. The fast lithium-ion diffusion rate and high discharge capacity provide a feasible direction for the high value utilization of aluminum electrolysis spent cathode. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 |
| abstractGer |
Abstract The aluminum electrolysis spent cathode (SC) was treated by hydrothermal method and used as anode material for lithium-ion battery. The purified SC material shows excellent electrochemical performance. In order to understand the diffusion behavior of $ Li^{+} $ in the SC electrode, the diffusion coefficient of $ Li^{+} $ in the SC electrode was systematically analyzed by galvanostatic intermittent titration technique (GITT), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results show that the diffusion coefficient (%${D}_{{\text{Li}}^{+}}%$) of $ Li^{+} $ in SC electrode is calculated by CV is 2.2292 × $ 10^{−11} $ $ cm^{2} $ $ s^{−1} $, and the ranges calculated by GITT and EIS are 4.2286 × $ 10^{−13} $ − 2.9667 × $ 10^{−10} $ $ cm^{2} $ $ s^{−1} $, 4.05 × $ 10^{−13} $ − 3.87 × $ 10^{−12} $ $ cm^{2} $ $ s^{−1} $, respectively. SC electrode exhibits better $ Li^{+} $ diffusion kinetics compared to commercial graphite (CG). In addition, the full cell of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC also shows excellent cycle performance. After 80 cycles at 1 °C (1 °C = 172 mA $ g^{−1} $), the specific discharge capacity of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC full-cell can reach 94.7 mAh $ g^{−1} $, and the capacity retention can reach 98.13%. The fast lithium-ion diffusion rate and high discharge capacity provide a feasible direction for the high value utilization of aluminum electrolysis spent cathode. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 |
| abstract_unstemmed |
Abstract The aluminum electrolysis spent cathode (SC) was treated by hydrothermal method and used as anode material for lithium-ion battery. The purified SC material shows excellent electrochemical performance. In order to understand the diffusion behavior of $ Li^{+} $ in the SC electrode, the diffusion coefficient of $ Li^{+} $ in the SC electrode was systematically analyzed by galvanostatic intermittent titration technique (GITT), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results show that the diffusion coefficient (%${D}_{{\text{Li}}^{+}}%$) of $ Li^{+} $ in SC electrode is calculated by CV is 2.2292 × $ 10^{−11} $ $ cm^{2} $ $ s^{−1} $, and the ranges calculated by GITT and EIS are 4.2286 × $ 10^{−13} $ − 2.9667 × $ 10^{−10} $ $ cm^{2} $ $ s^{−1} $, 4.05 × $ 10^{−13} $ − 3.87 × $ 10^{−12} $ $ cm^{2} $ $ s^{−1} $, respectively. SC electrode exhibits better $ Li^{+} $ diffusion kinetics compared to commercial graphite (CG). In addition, the full cell of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC also shows excellent cycle performance. After 80 cycles at 1 °C (1 °C = 172 mA $ g^{−1} $), the specific discharge capacity of $ LiNi_{0.5} %$ Co_{0.2} %$ Mn_{0.3} %$ O_{2} $/SC full-cell can reach 94.7 mAh $ g^{−1} $, and the capacity retention can reach 98.13%. The fast lithium-ion diffusion rate and high discharge capacity provide a feasible direction for the high value utilization of aluminum electrolysis spent cathode. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 |
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Diffusion coefficient analysis of aluminum electrolysis spent cathode as anode material for lithium-ion battery |
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https://dx.doi.org/10.1007/s11581-021-04398-y |
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Peng, Jiaxin Li, Jie Hou, Xueyang Zhang, Xingliang Fang, Zhao |
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Peng, Jiaxin Li, Jie Hou, Xueyang Zhang, Xingliang Fang, Zhao |
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2024-07-03T19:43:25.778Z |
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| score |
7.402214 |