Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range
X-ray diffraction measurements are performed on a 1 m (= mol $ kg^{−1} $) $ CeCl_{3} $ aqueous solution over a temperature range of 300–600 K and a pressure range of 0.1 MPa to 4 GPa. The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling....
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yamaguchi, Toshio [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry 2022 |
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| Übergeordnetes Werk: |
Enthalten in: Analytical sciences - [Cham] : Springer International Publishing, 1985, 38(2022), 2 vom: Feb., Seite 409-417 |
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| Übergeordnetes Werk: |
volume:38 ; year:2022 ; number:2 ; month:02 ; pages:409-417 |
| Links: |
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| DOI / URN: |
10.2116/analsci.21P297 |
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| Katalog-ID: |
SPR046555234 |
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| 100 | 1 | |a Yamaguchi, Toshio |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range |
| 264 | 1 | |c 2022 | |
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| 520 | |a X-ray diffraction measurements are performed on a 1 m (= mol $ kg^{−1} $) $ CeCl_{3} $ aqueous solution over a temperature range of 300–600 K and a pressure range of 0.1 MPa to 4 GPa. The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling. The $ Ce^{3+} $ coordinates water molecules in a tricapped trigonal prism configuration under the ambient condition. The number of water molecules around $ Ce^{3+} $ changes from 8.8 at 0.1 MPa/300 K to 11.5 at 4 GPa/600 K. The number of water molecules around $ Cl^{−} $ changes drastically from 10 under the ambient condition to 17 at 4 GPa/600 K. The tetrahedral-like network structure of water under the ambient condition is transformed toward a simple liquid-like packing in the GPa pressure range. The corresponding coordination number is increased from 4.3 in the ambient condition to 9.7 at 4 GPa/600 K. The $ Ce^{3+} $–$ Cl^{−} $ association decreases with increasing pressure. Graphical abstract | ||
| 650 | 4 | |a Cerium chloride |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Ion solvation |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Water structure |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a X-ray scattering |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a High pressure |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a EPSR |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Fukuyama, Nami |4 aut | |
| 700 | 1 | |a Yoshida, Koji |4 aut | |
| 700 | 1 | |a Katayama, Yoshinori |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Analytical sciences |d [Cham] : Springer International Publishing, 1985 |g 38(2022), 2 vom: Feb., Seite 409-417 |w (DE-627)300895925 |w (DE-600)1483376-1 |x 1348-2246 |7 nnns |
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10.2116/analsci.21P297 doi (DE-627)SPR046555234 (SPR)analsci.21P297-e DE-627 ger DE-627 rakwb eng Yamaguchi, Toshio verfasserin aut Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry 2022 X-ray diffraction measurements are performed on a 1 m (= mol $ kg^{−1} $) $ CeCl_{3} $ aqueous solution over a temperature range of 300–600 K and a pressure range of 0.1 MPa to 4 GPa. The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling. The $ Ce^{3+} $ coordinates water molecules in a tricapped trigonal prism configuration under the ambient condition. The number of water molecules around $ Ce^{3+} $ changes from 8.8 at 0.1 MPa/300 K to 11.5 at 4 GPa/600 K. The number of water molecules around $ Cl^{−} $ changes drastically from 10 under the ambient condition to 17 at 4 GPa/600 K. The tetrahedral-like network structure of water under the ambient condition is transformed toward a simple liquid-like packing in the GPa pressure range. The corresponding coordination number is increased from 4.3 in the ambient condition to 9.7 at 4 GPa/600 K. The $ Ce^{3+} $–$ Cl^{−} $ association decreases with increasing pressure. Graphical abstract Cerium chloride (dpeaa)DE-He213 Ion solvation (dpeaa)DE-He213 Water structure (dpeaa)DE-He213 X-ray scattering (dpeaa)DE-He213 High pressure (dpeaa)DE-He213 EPSR (dpeaa)DE-He213 Fukuyama, Nami aut Yoshida, Koji aut Katayama, Yoshinori aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 38(2022), 2 vom: Feb., Seite 409-417 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:38 year:2022 number:2 month:02 pages:409-417 https://dx.doi.org/10.2116/analsci.21P297 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 38 2022 2 02 409-417 |
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10.2116/analsci.21P297 doi (DE-627)SPR046555234 (SPR)analsci.21P297-e DE-627 ger DE-627 rakwb eng Yamaguchi, Toshio verfasserin aut Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry 2022 X-ray diffraction measurements are performed on a 1 m (= mol $ kg^{−1} $) $ CeCl_{3} $ aqueous solution over a temperature range of 300–600 K and a pressure range of 0.1 MPa to 4 GPa. The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling. The $ Ce^{3+} $ coordinates water molecules in a tricapped trigonal prism configuration under the ambient condition. The number of water molecules around $ Ce^{3+} $ changes from 8.8 at 0.1 MPa/300 K to 11.5 at 4 GPa/600 K. The number of water molecules around $ Cl^{−} $ changes drastically from 10 under the ambient condition to 17 at 4 GPa/600 K. The tetrahedral-like network structure of water under the ambient condition is transformed toward a simple liquid-like packing in the GPa pressure range. The corresponding coordination number is increased from 4.3 in the ambient condition to 9.7 at 4 GPa/600 K. The $ Ce^{3+} $–$ Cl^{−} $ association decreases with increasing pressure. Graphical abstract Cerium chloride (dpeaa)DE-He213 Ion solvation (dpeaa)DE-He213 Water structure (dpeaa)DE-He213 X-ray scattering (dpeaa)DE-He213 High pressure (dpeaa)DE-He213 EPSR (dpeaa)DE-He213 Fukuyama, Nami aut Yoshida, Koji aut Katayama, Yoshinori aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 38(2022), 2 vom: Feb., Seite 409-417 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:38 year:2022 number:2 month:02 pages:409-417 https://dx.doi.org/10.2116/analsci.21P297 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 38 2022 2 02 409-417 |
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10.2116/analsci.21P297 doi (DE-627)SPR046555234 (SPR)analsci.21P297-e DE-627 ger DE-627 rakwb eng Yamaguchi, Toshio verfasserin aut Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry 2022 X-ray diffraction measurements are performed on a 1 m (= mol $ kg^{−1} $) $ CeCl_{3} $ aqueous solution over a temperature range of 300–600 K and a pressure range of 0.1 MPa to 4 GPa. The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling. The $ Ce^{3+} $ coordinates water molecules in a tricapped trigonal prism configuration under the ambient condition. The number of water molecules around $ Ce^{3+} $ changes from 8.8 at 0.1 MPa/300 K to 11.5 at 4 GPa/600 K. The number of water molecules around $ Cl^{−} $ changes drastically from 10 under the ambient condition to 17 at 4 GPa/600 K. The tetrahedral-like network structure of water under the ambient condition is transformed toward a simple liquid-like packing in the GPa pressure range. The corresponding coordination number is increased from 4.3 in the ambient condition to 9.7 at 4 GPa/600 K. The $ Ce^{3+} $–$ Cl^{−} $ association decreases with increasing pressure. Graphical abstract Cerium chloride (dpeaa)DE-He213 Ion solvation (dpeaa)DE-He213 Water structure (dpeaa)DE-He213 X-ray scattering (dpeaa)DE-He213 High pressure (dpeaa)DE-He213 EPSR (dpeaa)DE-He213 Fukuyama, Nami aut Yoshida, Koji aut Katayama, Yoshinori aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 38(2022), 2 vom: Feb., Seite 409-417 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:38 year:2022 number:2 month:02 pages:409-417 https://dx.doi.org/10.2116/analsci.21P297 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 38 2022 2 02 409-417 |
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10.2116/analsci.21P297 doi (DE-627)SPR046555234 (SPR)analsci.21P297-e DE-627 ger DE-627 rakwb eng Yamaguchi, Toshio verfasserin aut Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry 2022 X-ray diffraction measurements are performed on a 1 m (= mol $ kg^{−1} $) $ CeCl_{3} $ aqueous solution over a temperature range of 300–600 K and a pressure range of 0.1 MPa to 4 GPa. The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling. The $ Ce^{3+} $ coordinates water molecules in a tricapped trigonal prism configuration under the ambient condition. The number of water molecules around $ Ce^{3+} $ changes from 8.8 at 0.1 MPa/300 K to 11.5 at 4 GPa/600 K. The number of water molecules around $ Cl^{−} $ changes drastically from 10 under the ambient condition to 17 at 4 GPa/600 K. The tetrahedral-like network structure of water under the ambient condition is transformed toward a simple liquid-like packing in the GPa pressure range. The corresponding coordination number is increased from 4.3 in the ambient condition to 9.7 at 4 GPa/600 K. The $ Ce^{3+} $–$ Cl^{−} $ association decreases with increasing pressure. Graphical abstract Cerium chloride (dpeaa)DE-He213 Ion solvation (dpeaa)DE-He213 Water structure (dpeaa)DE-He213 X-ray scattering (dpeaa)DE-He213 High pressure (dpeaa)DE-He213 EPSR (dpeaa)DE-He213 Fukuyama, Nami aut Yoshida, Koji aut Katayama, Yoshinori aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 38(2022), 2 vom: Feb., Seite 409-417 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:38 year:2022 number:2 month:02 pages:409-417 https://dx.doi.org/10.2116/analsci.21P297 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 38 2022 2 02 409-417 |
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10.2116/analsci.21P297 doi (DE-627)SPR046555234 (SPR)analsci.21P297-e DE-627 ger DE-627 rakwb eng Yamaguchi, Toshio verfasserin aut Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry 2022 X-ray diffraction measurements are performed on a 1 m (= mol $ kg^{−1} $) $ CeCl_{3} $ aqueous solution over a temperature range of 300–600 K and a pressure range of 0.1 MPa to 4 GPa. The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling. The $ Ce^{3+} $ coordinates water molecules in a tricapped trigonal prism configuration under the ambient condition. The number of water molecules around $ Ce^{3+} $ changes from 8.8 at 0.1 MPa/300 K to 11.5 at 4 GPa/600 K. The number of water molecules around $ Cl^{−} $ changes drastically from 10 under the ambient condition to 17 at 4 GPa/600 K. The tetrahedral-like network structure of water under the ambient condition is transformed toward a simple liquid-like packing in the GPa pressure range. The corresponding coordination number is increased from 4.3 in the ambient condition to 9.7 at 4 GPa/600 K. The $ Ce^{3+} $–$ Cl^{−} $ association decreases with increasing pressure. Graphical abstract Cerium chloride (dpeaa)DE-He213 Ion solvation (dpeaa)DE-He213 Water structure (dpeaa)DE-He213 X-ray scattering (dpeaa)DE-He213 High pressure (dpeaa)DE-He213 EPSR (dpeaa)DE-He213 Fukuyama, Nami aut Yoshida, Koji aut Katayama, Yoshinori aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 38(2022), 2 vom: Feb., Seite 409-417 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:38 year:2022 number:2 month:02 pages:409-417 https://dx.doi.org/10.2116/analsci.21P297 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 38 2022 2 02 409-417 |
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Enthalten in Analytical sciences 38(2022), 2 vom: Feb., Seite 409-417 volume:38 year:2022 number:2 month:02 pages:409-417 |
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Yamaguchi, Toshio @@aut@@ Fukuyama, Nami @@aut@@ Yoshida, Koji @@aut@@ Katayama, Yoshinori @@aut@@ |
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The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling. The $ Ce^{3+} $ coordinates water molecules in a tricapped trigonal prism configuration under the ambient condition. The number of water molecules around $ Ce^{3+} $ changes from 8.8 at 0.1 MPa/300 K to 11.5 at 4 GPa/600 K. The number of water molecules around $ Cl^{−} $ changes drastically from 10 under the ambient condition to 17 at 4 GPa/600 K. The tetrahedral-like network structure of water under the ambient condition is transformed toward a simple liquid-like packing in the GPa pressure range. The corresponding coordination number is increased from 4.3 in the ambient condition to 9.7 at 4 GPa/600 K. The $ Ce^{3+} $–$ Cl^{−} $ association decreases with increasing pressure. 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| author |
Yamaguchi, Toshio |
| spellingShingle |
Yamaguchi, Toshio misc Cerium chloride misc Ion solvation misc Water structure misc X-ray scattering misc High pressure misc EPSR Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range |
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Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range Cerium chloride (dpeaa)DE-He213 Ion solvation (dpeaa)DE-He213 Water structure (dpeaa)DE-He213 X-ray scattering (dpeaa)DE-He213 High pressure (dpeaa)DE-He213 EPSR (dpeaa)DE-He213 |
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misc Cerium chloride misc Ion solvation misc Water structure misc X-ray scattering misc High pressure misc EPSR |
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Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range |
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Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range |
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Yamaguchi, Toshio |
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Yamaguchi, Toshio Fukuyama, Nami Yoshida, Koji Katayama, Yoshinori |
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Yamaguchi, Toshio |
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10.2116/analsci.21P297 |
| title_sort |
ion solvation and association and water structure in an aqueous cerium (iii) chloride solution in the gigapascal pressure range |
| title_auth |
Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range |
| abstract |
X-ray diffraction measurements are performed on a 1 m (= mol $ kg^{−1} $) $ CeCl_{3} $ aqueous solution over a temperature range of 300–600 K and a pressure range of 0.1 MPa to 4 GPa. The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling. The $ Ce^{3+} $ coordinates water molecules in a tricapped trigonal prism configuration under the ambient condition. The number of water molecules around $ Ce^{3+} $ changes from 8.8 at 0.1 MPa/300 K to 11.5 at 4 GPa/600 K. The number of water molecules around $ Cl^{−} $ changes drastically from 10 under the ambient condition to 17 at 4 GPa/600 K. The tetrahedral-like network structure of water under the ambient condition is transformed toward a simple liquid-like packing in the GPa pressure range. The corresponding coordination number is increased from 4.3 in the ambient condition to 9.7 at 4 GPa/600 K. The $ Ce^{3+} $–$ Cl^{−} $ association decreases with increasing pressure. Graphical abstract © The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry 2022 |
| abstractGer |
X-ray diffraction measurements are performed on a 1 m (= mol $ kg^{−1} $) $ CeCl_{3} $ aqueous solution over a temperature range of 300–600 K and a pressure range of 0.1 MPa to 4 GPa. The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling. The $ Ce^{3+} $ coordinates water molecules in a tricapped trigonal prism configuration under the ambient condition. The number of water molecules around $ Ce^{3+} $ changes from 8.8 at 0.1 MPa/300 K to 11.5 at 4 GPa/600 K. The number of water molecules around $ Cl^{−} $ changes drastically from 10 under the ambient condition to 17 at 4 GPa/600 K. The tetrahedral-like network structure of water under the ambient condition is transformed toward a simple liquid-like packing in the GPa pressure range. The corresponding coordination number is increased from 4.3 in the ambient condition to 9.7 at 4 GPa/600 K. The $ Ce^{3+} $–$ Cl^{−} $ association decreases with increasing pressure. Graphical abstract © The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry 2022 |
| abstract_unstemmed |
X-ray diffraction measurements are performed on a 1 m (= mol $ kg^{−1} $) $ CeCl_{3} $ aqueous solution over a temperature range of 300–600 K and a pressure range of 0.1 MPa to 4 GPa. The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling. The $ Ce^{3+} $ coordinates water molecules in a tricapped trigonal prism configuration under the ambient condition. The number of water molecules around $ Ce^{3+} $ changes from 8.8 at 0.1 MPa/300 K to 11.5 at 4 GPa/600 K. The number of water molecules around $ Cl^{−} $ changes drastically from 10 under the ambient condition to 17 at 4 GPa/600 K. The tetrahedral-like network structure of water under the ambient condition is transformed toward a simple liquid-like packing in the GPa pressure range. The corresponding coordination number is increased from 4.3 in the ambient condition to 9.7 at 4 GPa/600 K. The $ Ce^{3+} $–$ Cl^{−} $ association decreases with increasing pressure. Graphical abstract © The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry 2022 |
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Ion solvation and association and water structure in an aqueous cerium (III) chloride solution in the gigapascal pressure range |
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Fukuyama, Nami Yoshida, Koji Katayama, Yoshinori |
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