Synthesis and properties of core–shell halloysite–polyaniline nanocomposites
Abstract We consider physico-chemical specificity (open circuit potential and pH changes) of the chemical oxidative aniline polymerization in the presence of halloysite nanotubes (HNTs) and morphology, structure and properties of the new nanocomposites of HNTs with polyaniline (PANI) doped by p-tolu...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Noskov, Yuriy [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2021 |
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| Schlagwörter: |
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| Anmerkung: |
© King Abdulaziz City for Science and Technology 2021 |
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| Übergeordnetes Werk: |
Enthalten in: Applied nanoscience - Berlin : Springer, 2011, 12(2021), 4 vom: 27. März, Seite 1285-1294 |
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| Übergeordnetes Werk: |
volume:12 ; year:2021 ; number:4 ; day:27 ; month:03 ; pages:1285-1294 |
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| DOI / URN: |
10.1007/s13204-021-01812-9 |
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SPR046623124 |
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| 520 | |a Abstract We consider physico-chemical specificity (open circuit potential and pH changes) of the chemical oxidative aniline polymerization in the presence of halloysite nanotubes (HNTs) and morphology, structure and properties of the new nanocomposites of HNTs with polyaniline (PANI) doped by p-toluenesulfonic acid. We find that specificity of the PANI properties in such nanocomposites appears obviously due to adsorption on the HNTs surface and specific interactions of all participants of the polymerization process. The study of the open circuit potential and pH changes in the polymerization system and properties of the synthesized HNT/PANI nanocomposites revealed the strong dependence of their morphology, molecular structure, conductivity, thermostability and sensor behavior on the contents of the doped PANI. These findings indicate existence of specific interactions between the PANI component and the HNT surface, which significantly improved properties of the PANI component in the synthesized HNT/PANI nanocomposites as compared with that of the pure PANI. The best thermostability and sensing behavior were found for the synthesized HNT/PANI nanocomposites with the lowest contents of the doped PANI. In particular, the strongest sensor responses to gaseous ammonia are observed in the case of HNT/PANI nanocomposite with lowering the doped PANI content. This work shows for the first time applicability of HNT/PANI nanocomposites for gas sensing. | ||
| 650 | 4 | |a Halloysite nanotubes |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Polyaniline |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Polymerization |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Nanocomposites |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Improved properties |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Ammonia gas sensing |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Ogurtsov, Nikolay |0 (orcid)0000-0002-5193-2276 |4 aut | |
| 700 | 1 | |a Bliznyuk, Valery |0 (orcid)0000-0002-3883-6941 |4 aut | |
| 700 | 1 | |a Lvov, Yuri |0 (orcid)0000-0003-0722-5643 |4 aut | |
| 700 | 1 | |a Myronyuk, Iryna |0 (orcid)0000-0002-0681-633X |4 aut | |
| 700 | 1 | |a Pud, Alexander |4 aut | |
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10.1007/s13204-021-01812-9 doi (DE-627)SPR046623124 (SPR)s13204-021-01812-9-e DE-627 ger DE-627 rakwb eng Noskov, Yuriy verfasserin (orcid)0000-0002-4192-1733 aut Synthesis and properties of core–shell halloysite–polyaniline nanocomposites 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © King Abdulaziz City for Science and Technology 2021 Abstract We consider physico-chemical specificity (open circuit potential and pH changes) of the chemical oxidative aniline polymerization in the presence of halloysite nanotubes (HNTs) and morphology, structure and properties of the new nanocomposites of HNTs with polyaniline (PANI) doped by p-toluenesulfonic acid. We find that specificity of the PANI properties in such nanocomposites appears obviously due to adsorption on the HNTs surface and specific interactions of all participants of the polymerization process. The study of the open circuit potential and pH changes in the polymerization system and properties of the synthesized HNT/PANI nanocomposites revealed the strong dependence of their morphology, molecular structure, conductivity, thermostability and sensor behavior on the contents of the doped PANI. These findings indicate existence of specific interactions between the PANI component and the HNT surface, which significantly improved properties of the PANI component in the synthesized HNT/PANI nanocomposites as compared with that of the pure PANI. The best thermostability and sensing behavior were found for the synthesized HNT/PANI nanocomposites with the lowest contents of the doped PANI. In particular, the strongest sensor responses to gaseous ammonia are observed in the case of HNT/PANI nanocomposite with lowering the doped PANI content. This work shows for the first time applicability of HNT/PANI nanocomposites for gas sensing. Halloysite nanotubes (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Polymerization (dpeaa)DE-He213 Nanocomposites (dpeaa)DE-He213 Improved properties (dpeaa)DE-He213 Ammonia gas sensing (dpeaa)DE-He213 Ogurtsov, Nikolay (orcid)0000-0002-5193-2276 aut Bliznyuk, Valery (orcid)0000-0002-3883-6941 aut Lvov, Yuri (orcid)0000-0003-0722-5643 aut Myronyuk, Iryna (orcid)0000-0002-0681-633X aut Pud, Alexander aut Enthalten in Applied nanoscience Berlin : Springer, 2011 12(2021), 4 vom: 27. März, Seite 1285-1294 (DE-627)658009001 (DE-600)2607723-1 2190-5517 nnns volume:12 year:2021 number:4 day:27 month:03 pages:1285-1294 https://dx.doi.org/10.1007/s13204-021-01812-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 12 2021 4 27 03 1285-1294 |
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10.1007/s13204-021-01812-9 doi (DE-627)SPR046623124 (SPR)s13204-021-01812-9-e DE-627 ger DE-627 rakwb eng Noskov, Yuriy verfasserin (orcid)0000-0002-4192-1733 aut Synthesis and properties of core–shell halloysite–polyaniline nanocomposites 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © King Abdulaziz City for Science and Technology 2021 Abstract We consider physico-chemical specificity (open circuit potential and pH changes) of the chemical oxidative aniline polymerization in the presence of halloysite nanotubes (HNTs) and morphology, structure and properties of the new nanocomposites of HNTs with polyaniline (PANI) doped by p-toluenesulfonic acid. We find that specificity of the PANI properties in such nanocomposites appears obviously due to adsorption on the HNTs surface and specific interactions of all participants of the polymerization process. The study of the open circuit potential and pH changes in the polymerization system and properties of the synthesized HNT/PANI nanocomposites revealed the strong dependence of their morphology, molecular structure, conductivity, thermostability and sensor behavior on the contents of the doped PANI. These findings indicate existence of specific interactions between the PANI component and the HNT surface, which significantly improved properties of the PANI component in the synthesized HNT/PANI nanocomposites as compared with that of the pure PANI. The best thermostability and sensing behavior were found for the synthesized HNT/PANI nanocomposites with the lowest contents of the doped PANI. In particular, the strongest sensor responses to gaseous ammonia are observed in the case of HNT/PANI nanocomposite with lowering the doped PANI content. This work shows for the first time applicability of HNT/PANI nanocomposites for gas sensing. Halloysite nanotubes (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Polymerization (dpeaa)DE-He213 Nanocomposites (dpeaa)DE-He213 Improved properties (dpeaa)DE-He213 Ammonia gas sensing (dpeaa)DE-He213 Ogurtsov, Nikolay (orcid)0000-0002-5193-2276 aut Bliznyuk, Valery (orcid)0000-0002-3883-6941 aut Lvov, Yuri (orcid)0000-0003-0722-5643 aut Myronyuk, Iryna (orcid)0000-0002-0681-633X aut Pud, Alexander aut Enthalten in Applied nanoscience Berlin : Springer, 2011 12(2021), 4 vom: 27. März, Seite 1285-1294 (DE-627)658009001 (DE-600)2607723-1 2190-5517 nnns volume:12 year:2021 number:4 day:27 month:03 pages:1285-1294 https://dx.doi.org/10.1007/s13204-021-01812-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 12 2021 4 27 03 1285-1294 |
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10.1007/s13204-021-01812-9 doi (DE-627)SPR046623124 (SPR)s13204-021-01812-9-e DE-627 ger DE-627 rakwb eng Noskov, Yuriy verfasserin (orcid)0000-0002-4192-1733 aut Synthesis and properties of core–shell halloysite–polyaniline nanocomposites 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © King Abdulaziz City for Science and Technology 2021 Abstract We consider physico-chemical specificity (open circuit potential and pH changes) of the chemical oxidative aniline polymerization in the presence of halloysite nanotubes (HNTs) and morphology, structure and properties of the new nanocomposites of HNTs with polyaniline (PANI) doped by p-toluenesulfonic acid. We find that specificity of the PANI properties in such nanocomposites appears obviously due to adsorption on the HNTs surface and specific interactions of all participants of the polymerization process. The study of the open circuit potential and pH changes in the polymerization system and properties of the synthesized HNT/PANI nanocomposites revealed the strong dependence of their morphology, molecular structure, conductivity, thermostability and sensor behavior on the contents of the doped PANI. These findings indicate existence of specific interactions between the PANI component and the HNT surface, which significantly improved properties of the PANI component in the synthesized HNT/PANI nanocomposites as compared with that of the pure PANI. The best thermostability and sensing behavior were found for the synthesized HNT/PANI nanocomposites with the lowest contents of the doped PANI. In particular, the strongest sensor responses to gaseous ammonia are observed in the case of HNT/PANI nanocomposite with lowering the doped PANI content. This work shows for the first time applicability of HNT/PANI nanocomposites for gas sensing. Halloysite nanotubes (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Polymerization (dpeaa)DE-He213 Nanocomposites (dpeaa)DE-He213 Improved properties (dpeaa)DE-He213 Ammonia gas sensing (dpeaa)DE-He213 Ogurtsov, Nikolay (orcid)0000-0002-5193-2276 aut Bliznyuk, Valery (orcid)0000-0002-3883-6941 aut Lvov, Yuri (orcid)0000-0003-0722-5643 aut Myronyuk, Iryna (orcid)0000-0002-0681-633X aut Pud, Alexander aut Enthalten in Applied nanoscience Berlin : Springer, 2011 12(2021), 4 vom: 27. März, Seite 1285-1294 (DE-627)658009001 (DE-600)2607723-1 2190-5517 nnns volume:12 year:2021 number:4 day:27 month:03 pages:1285-1294 https://dx.doi.org/10.1007/s13204-021-01812-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 12 2021 4 27 03 1285-1294 |
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10.1007/s13204-021-01812-9 doi (DE-627)SPR046623124 (SPR)s13204-021-01812-9-e DE-627 ger DE-627 rakwb eng Noskov, Yuriy verfasserin (orcid)0000-0002-4192-1733 aut Synthesis and properties of core–shell halloysite–polyaniline nanocomposites 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © King Abdulaziz City for Science and Technology 2021 Abstract We consider physico-chemical specificity (open circuit potential and pH changes) of the chemical oxidative aniline polymerization in the presence of halloysite nanotubes (HNTs) and morphology, structure and properties of the new nanocomposites of HNTs with polyaniline (PANI) doped by p-toluenesulfonic acid. We find that specificity of the PANI properties in such nanocomposites appears obviously due to adsorption on the HNTs surface and specific interactions of all participants of the polymerization process. The study of the open circuit potential and pH changes in the polymerization system and properties of the synthesized HNT/PANI nanocomposites revealed the strong dependence of their morphology, molecular structure, conductivity, thermostability and sensor behavior on the contents of the doped PANI. These findings indicate existence of specific interactions between the PANI component and the HNT surface, which significantly improved properties of the PANI component in the synthesized HNT/PANI nanocomposites as compared with that of the pure PANI. The best thermostability and sensing behavior were found for the synthesized HNT/PANI nanocomposites with the lowest contents of the doped PANI. In particular, the strongest sensor responses to gaseous ammonia are observed in the case of HNT/PANI nanocomposite with lowering the doped PANI content. This work shows for the first time applicability of HNT/PANI nanocomposites for gas sensing. Halloysite nanotubes (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Polymerization (dpeaa)DE-He213 Nanocomposites (dpeaa)DE-He213 Improved properties (dpeaa)DE-He213 Ammonia gas sensing (dpeaa)DE-He213 Ogurtsov, Nikolay (orcid)0000-0002-5193-2276 aut Bliznyuk, Valery (orcid)0000-0002-3883-6941 aut Lvov, Yuri (orcid)0000-0003-0722-5643 aut Myronyuk, Iryna (orcid)0000-0002-0681-633X aut Pud, Alexander aut Enthalten in Applied nanoscience Berlin : Springer, 2011 12(2021), 4 vom: 27. März, Seite 1285-1294 (DE-627)658009001 (DE-600)2607723-1 2190-5517 nnns volume:12 year:2021 number:4 day:27 month:03 pages:1285-1294 https://dx.doi.org/10.1007/s13204-021-01812-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 12 2021 4 27 03 1285-1294 |
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10.1007/s13204-021-01812-9 doi (DE-627)SPR046623124 (SPR)s13204-021-01812-9-e DE-627 ger DE-627 rakwb eng Noskov, Yuriy verfasserin (orcid)0000-0002-4192-1733 aut Synthesis and properties of core–shell halloysite–polyaniline nanocomposites 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © King Abdulaziz City for Science and Technology 2021 Abstract We consider physico-chemical specificity (open circuit potential and pH changes) of the chemical oxidative aniline polymerization in the presence of halloysite nanotubes (HNTs) and morphology, structure and properties of the new nanocomposites of HNTs with polyaniline (PANI) doped by p-toluenesulfonic acid. We find that specificity of the PANI properties in such nanocomposites appears obviously due to adsorption on the HNTs surface and specific interactions of all participants of the polymerization process. The study of the open circuit potential and pH changes in the polymerization system and properties of the synthesized HNT/PANI nanocomposites revealed the strong dependence of their morphology, molecular structure, conductivity, thermostability and sensor behavior on the contents of the doped PANI. These findings indicate existence of specific interactions between the PANI component and the HNT surface, which significantly improved properties of the PANI component in the synthesized HNT/PANI nanocomposites as compared with that of the pure PANI. The best thermostability and sensing behavior were found for the synthesized HNT/PANI nanocomposites with the lowest contents of the doped PANI. In particular, the strongest sensor responses to gaseous ammonia are observed in the case of HNT/PANI nanocomposite with lowering the doped PANI content. This work shows for the first time applicability of HNT/PANI nanocomposites for gas sensing. Halloysite nanotubes (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Polymerization (dpeaa)DE-He213 Nanocomposites (dpeaa)DE-He213 Improved properties (dpeaa)DE-He213 Ammonia gas sensing (dpeaa)DE-He213 Ogurtsov, Nikolay (orcid)0000-0002-5193-2276 aut Bliznyuk, Valery (orcid)0000-0002-3883-6941 aut Lvov, Yuri (orcid)0000-0003-0722-5643 aut Myronyuk, Iryna (orcid)0000-0002-0681-633X aut Pud, Alexander aut Enthalten in Applied nanoscience Berlin : Springer, 2011 12(2021), 4 vom: 27. März, Seite 1285-1294 (DE-627)658009001 (DE-600)2607723-1 2190-5517 nnns volume:12 year:2021 number:4 day:27 month:03 pages:1285-1294 https://dx.doi.org/10.1007/s13204-021-01812-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 12 2021 4 27 03 1285-1294 |
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English |
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Enthalten in Applied nanoscience 12(2021), 4 vom: 27. März, Seite 1285-1294 volume:12 year:2021 number:4 day:27 month:03 pages:1285-1294 |
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Enthalten in Applied nanoscience 12(2021), 4 vom: 27. März, Seite 1285-1294 volume:12 year:2021 number:4 day:27 month:03 pages:1285-1294 |
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Halloysite nanotubes Polyaniline Polymerization Nanocomposites Improved properties Ammonia gas sensing |
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Noskov, Yuriy @@aut@@ Ogurtsov, Nikolay @@aut@@ Bliznyuk, Valery @@aut@@ Lvov, Yuri @@aut@@ Myronyuk, Iryna @@aut@@ Pud, Alexander @@aut@@ |
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2021-03-27T00:00:00Z |
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We find that specificity of the PANI properties in such nanocomposites appears obviously due to adsorption on the HNTs surface and specific interactions of all participants of the polymerization process. The study of the open circuit potential and pH changes in the polymerization system and properties of the synthesized HNT/PANI nanocomposites revealed the strong dependence of their morphology, molecular structure, conductivity, thermostability and sensor behavior on the contents of the doped PANI. These findings indicate existence of specific interactions between the PANI component and the HNT surface, which significantly improved properties of the PANI component in the synthesized HNT/PANI nanocomposites as compared with that of the pure PANI. The best thermostability and sensing behavior were found for the synthesized HNT/PANI nanocomposites with the lowest contents of the doped PANI. 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Noskov, Yuriy |
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Noskov, Yuriy misc Halloysite nanotubes misc Polyaniline misc Polymerization misc Nanocomposites misc Improved properties misc Ammonia gas sensing Synthesis and properties of core–shell halloysite–polyaniline nanocomposites |
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Synthesis and properties of core–shell halloysite–polyaniline nanocomposites Halloysite nanotubes (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Polymerization (dpeaa)DE-He213 Nanocomposites (dpeaa)DE-He213 Improved properties (dpeaa)DE-He213 Ammonia gas sensing (dpeaa)DE-He213 |
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Synthesis and properties of core–shell halloysite–polyaniline nanocomposites |
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synthesis and properties of core–shell halloysite–polyaniline nanocomposites |
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Synthesis and properties of core–shell halloysite–polyaniline nanocomposites |
| abstract |
Abstract We consider physico-chemical specificity (open circuit potential and pH changes) of the chemical oxidative aniline polymerization in the presence of halloysite nanotubes (HNTs) and morphology, structure and properties of the new nanocomposites of HNTs with polyaniline (PANI) doped by p-toluenesulfonic acid. We find that specificity of the PANI properties in such nanocomposites appears obviously due to adsorption on the HNTs surface and specific interactions of all participants of the polymerization process. The study of the open circuit potential and pH changes in the polymerization system and properties of the synthesized HNT/PANI nanocomposites revealed the strong dependence of their morphology, molecular structure, conductivity, thermostability and sensor behavior on the contents of the doped PANI. These findings indicate existence of specific interactions between the PANI component and the HNT surface, which significantly improved properties of the PANI component in the synthesized HNT/PANI nanocomposites as compared with that of the pure PANI. The best thermostability and sensing behavior were found for the synthesized HNT/PANI nanocomposites with the lowest contents of the doped PANI. In particular, the strongest sensor responses to gaseous ammonia are observed in the case of HNT/PANI nanocomposite with lowering the doped PANI content. This work shows for the first time applicability of HNT/PANI nanocomposites for gas sensing. © King Abdulaziz City for Science and Technology 2021 |
| abstractGer |
Abstract We consider physico-chemical specificity (open circuit potential and pH changes) of the chemical oxidative aniline polymerization in the presence of halloysite nanotubes (HNTs) and morphology, structure and properties of the new nanocomposites of HNTs with polyaniline (PANI) doped by p-toluenesulfonic acid. We find that specificity of the PANI properties in such nanocomposites appears obviously due to adsorption on the HNTs surface and specific interactions of all participants of the polymerization process. The study of the open circuit potential and pH changes in the polymerization system and properties of the synthesized HNT/PANI nanocomposites revealed the strong dependence of their morphology, molecular structure, conductivity, thermostability and sensor behavior on the contents of the doped PANI. These findings indicate existence of specific interactions between the PANI component and the HNT surface, which significantly improved properties of the PANI component in the synthesized HNT/PANI nanocomposites as compared with that of the pure PANI. The best thermostability and sensing behavior were found for the synthesized HNT/PANI nanocomposites with the lowest contents of the doped PANI. In particular, the strongest sensor responses to gaseous ammonia are observed in the case of HNT/PANI nanocomposite with lowering the doped PANI content. This work shows for the first time applicability of HNT/PANI nanocomposites for gas sensing. © King Abdulaziz City for Science and Technology 2021 |
| abstract_unstemmed |
Abstract We consider physico-chemical specificity (open circuit potential and pH changes) of the chemical oxidative aniline polymerization in the presence of halloysite nanotubes (HNTs) and morphology, structure and properties of the new nanocomposites of HNTs with polyaniline (PANI) doped by p-toluenesulfonic acid. We find that specificity of the PANI properties in such nanocomposites appears obviously due to adsorption on the HNTs surface and specific interactions of all participants of the polymerization process. The study of the open circuit potential and pH changes in the polymerization system and properties of the synthesized HNT/PANI nanocomposites revealed the strong dependence of their morphology, molecular structure, conductivity, thermostability and sensor behavior on the contents of the doped PANI. These findings indicate existence of specific interactions between the PANI component and the HNT surface, which significantly improved properties of the PANI component in the synthesized HNT/PANI nanocomposites as compared with that of the pure PANI. The best thermostability and sensing behavior were found for the synthesized HNT/PANI nanocomposites with the lowest contents of the doped PANI. In particular, the strongest sensor responses to gaseous ammonia are observed in the case of HNT/PANI nanocomposite with lowering the doped PANI content. This work shows for the first time applicability of HNT/PANI nanocomposites for gas sensing. © King Abdulaziz City for Science and Technology 2021 |
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| title_short |
Synthesis and properties of core–shell halloysite–polyaniline nanocomposites |
| url |
https://dx.doi.org/10.1007/s13204-021-01812-9 |
| remote_bool |
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| author2 |
Ogurtsov, Nikolay Bliznyuk, Valery Lvov, Yuri Myronyuk, Iryna Pud, Alexander |
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Ogurtsov, Nikolay Bliznyuk, Valery Lvov, Yuri Myronyuk, Iryna Pud, Alexander |
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10.1007/s13204-021-01812-9 |
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2024-07-03T23:35:44.331Z |
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| score |
7.399089 |