Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples
Abstract Herein, we developed an effervescent reaction-enhanced dispersive liquid–liquid microextraction method for the preconcentration/extraction of bisphenols (BPs) in milk and milky tea samples. This microextraction method was based on the utilization of acidic ionic liquid (AIL) and in situ met...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Gao, Ming [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022 |
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| Übergeordnetes Werk: |
Enthalten in: Food analytical methods - New York, NY : Springer, 2008, 15(2022), 7 vom: 26. März, Seite 2036-2047 |
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| Übergeordnetes Werk: |
volume:15 ; year:2022 ; number:7 ; day:26 ; month:03 ; pages:2036-2047 |
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| DOI / URN: |
10.1007/s12161-022-02263-w |
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| Katalog-ID: |
SPR047196017 |
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| 520 | |a Abstract Herein, we developed an effervescent reaction-enhanced dispersive liquid–liquid microextraction method for the preconcentration/extraction of bisphenols (BPs) in milk and milky tea samples. This microextraction method was based on the utilization of acidic ionic liquid (AIL) and in situ metathesis reaction (AI-EDLM). Compared to the traditional imidazolium-based ionic liquid, AIL can not only be used as an extractant, but also as an acidic source in the effervescent reaction. Under such a case, it can avoid the use of additional acidic source and also achieve a rapid dispersion effect due to vigorous $ CO_{2} $ bubbles, which simplify the experimental procedures and decrease the preparation cost of effervescent tablets. By employing the one-factor-at-a-time approach, the main parameters were optimized as follows: 400 mg of [BMIM][$ HSO_{4} $] as extractant, 100 mg of $ Na_{2} %$ CO_{3} $ as alkaline source, 400 mg of Li[NTf]2 as the ionic-exchange reagent, 4% of NaCl, 5 min of centrifugation and 1.5 mL of ether as the elution solvent. Under optimized conditions, the limits of detection ranged from 0.12 to 0.32 μg $ L^{−1} $, and the extraction recoveries for BPA, BPB, and BPAF spanned the range of 85.7–106.2% in five kinds of milk samples. Therefore, the AIL ([BMIM][$ HSO_{4} $]) played dual roles, i.e., extractant and pH regulator, in the AI-EDLM procedures. Overall, this proposed method is simple, quick, and environment-friendly with low detection limits and high recoveries for BPs, and thus has excellent application value in the sample pretreatment field in milk and milky tea samples. | ||
| 650 | 4 | |a Bisphenol |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Acidic ionic liquid |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Effervescent reaction-enhanced microextraction |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a In situ metathesis reaction |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Milk and milky tea samples |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Wang, Hui |4 aut | |
| 700 | 1 | |a Wang, Jun |4 aut | |
| 700 | 1 | |a Wang, Xuedong |0 (orcid)0000-0002-8343-0692 |4 aut | |
| 700 | 1 | |a Wang, Huili |4 aut | |
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10.1007/s12161-022-02263-w doi (DE-627)SPR047196017 (SPR)s12161-022-02263-w-e DE-627 ger DE-627 rakwb eng Gao, Ming verfasserin aut Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022 Abstract Herein, we developed an effervescent reaction-enhanced dispersive liquid–liquid microextraction method for the preconcentration/extraction of bisphenols (BPs) in milk and milky tea samples. This microextraction method was based on the utilization of acidic ionic liquid (AIL) and in situ metathesis reaction (AI-EDLM). Compared to the traditional imidazolium-based ionic liquid, AIL can not only be used as an extractant, but also as an acidic source in the effervescent reaction. Under such a case, it can avoid the use of additional acidic source and also achieve a rapid dispersion effect due to vigorous $ CO_{2} $ bubbles, which simplify the experimental procedures and decrease the preparation cost of effervescent tablets. By employing the one-factor-at-a-time approach, the main parameters were optimized as follows: 400 mg of [BMIM][$ HSO_{4} $] as extractant, 100 mg of $ Na_{2} %$ CO_{3} $ as alkaline source, 400 mg of Li[NTf]2 as the ionic-exchange reagent, 4% of NaCl, 5 min of centrifugation and 1.5 mL of ether as the elution solvent. Under optimized conditions, the limits of detection ranged from 0.12 to 0.32 μg $ L^{−1} $, and the extraction recoveries for BPA, BPB, and BPAF spanned the range of 85.7–106.2% in five kinds of milk samples. Therefore, the AIL ([BMIM][$ HSO_{4} $]) played dual roles, i.e., extractant and pH regulator, in the AI-EDLM procedures. Overall, this proposed method is simple, quick, and environment-friendly with low detection limits and high recoveries for BPs, and thus has excellent application value in the sample pretreatment field in milk and milky tea samples. Bisphenol (dpeaa)DE-He213 Acidic ionic liquid (dpeaa)DE-He213 Effervescent reaction-enhanced microextraction (dpeaa)DE-He213 In situ metathesis reaction (dpeaa)DE-He213 Milk and milky tea samples (dpeaa)DE-He213 Wang, Hui aut Wang, Jun aut Wang, Xuedong (orcid)0000-0002-8343-0692 aut Wang, Huili aut Enthalten in Food analytical methods New York, NY : Springer, 2008 15(2022), 7 vom: 26. März, Seite 2036-2047 (DE-627)566007320 (DE-600)2424728-5 1936-976X nnns volume:15 year:2022 number:7 day:26 month:03 pages:2036-2047 https://dx.doi.org/10.1007/s12161-022-02263-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 15 2022 7 26 03 2036-2047 |
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10.1007/s12161-022-02263-w doi (DE-627)SPR047196017 (SPR)s12161-022-02263-w-e DE-627 ger DE-627 rakwb eng Gao, Ming verfasserin aut Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022 Abstract Herein, we developed an effervescent reaction-enhanced dispersive liquid–liquid microextraction method for the preconcentration/extraction of bisphenols (BPs) in milk and milky tea samples. This microextraction method was based on the utilization of acidic ionic liquid (AIL) and in situ metathesis reaction (AI-EDLM). Compared to the traditional imidazolium-based ionic liquid, AIL can not only be used as an extractant, but also as an acidic source in the effervescent reaction. Under such a case, it can avoid the use of additional acidic source and also achieve a rapid dispersion effect due to vigorous $ CO_{2} $ bubbles, which simplify the experimental procedures and decrease the preparation cost of effervescent tablets. By employing the one-factor-at-a-time approach, the main parameters were optimized as follows: 400 mg of [BMIM][$ HSO_{4} $] as extractant, 100 mg of $ Na_{2} %$ CO_{3} $ as alkaline source, 400 mg of Li[NTf]2 as the ionic-exchange reagent, 4% of NaCl, 5 min of centrifugation and 1.5 mL of ether as the elution solvent. Under optimized conditions, the limits of detection ranged from 0.12 to 0.32 μg $ L^{−1} $, and the extraction recoveries for BPA, BPB, and BPAF spanned the range of 85.7–106.2% in five kinds of milk samples. Therefore, the AIL ([BMIM][$ HSO_{4} $]) played dual roles, i.e., extractant and pH regulator, in the AI-EDLM procedures. Overall, this proposed method is simple, quick, and environment-friendly with low detection limits and high recoveries for BPs, and thus has excellent application value in the sample pretreatment field in milk and milky tea samples. Bisphenol (dpeaa)DE-He213 Acidic ionic liquid (dpeaa)DE-He213 Effervescent reaction-enhanced microextraction (dpeaa)DE-He213 In situ metathesis reaction (dpeaa)DE-He213 Milk and milky tea samples (dpeaa)DE-He213 Wang, Hui aut Wang, Jun aut Wang, Xuedong (orcid)0000-0002-8343-0692 aut Wang, Huili aut Enthalten in Food analytical methods New York, NY : Springer, 2008 15(2022), 7 vom: 26. März, Seite 2036-2047 (DE-627)566007320 (DE-600)2424728-5 1936-976X nnns volume:15 year:2022 number:7 day:26 month:03 pages:2036-2047 https://dx.doi.org/10.1007/s12161-022-02263-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 15 2022 7 26 03 2036-2047 |
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10.1007/s12161-022-02263-w doi (DE-627)SPR047196017 (SPR)s12161-022-02263-w-e DE-627 ger DE-627 rakwb eng Gao, Ming verfasserin aut Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022 Abstract Herein, we developed an effervescent reaction-enhanced dispersive liquid–liquid microextraction method for the preconcentration/extraction of bisphenols (BPs) in milk and milky tea samples. This microextraction method was based on the utilization of acidic ionic liquid (AIL) and in situ metathesis reaction (AI-EDLM). Compared to the traditional imidazolium-based ionic liquid, AIL can not only be used as an extractant, but also as an acidic source in the effervescent reaction. Under such a case, it can avoid the use of additional acidic source and also achieve a rapid dispersion effect due to vigorous $ CO_{2} $ bubbles, which simplify the experimental procedures and decrease the preparation cost of effervescent tablets. By employing the one-factor-at-a-time approach, the main parameters were optimized as follows: 400 mg of [BMIM][$ HSO_{4} $] as extractant, 100 mg of $ Na_{2} %$ CO_{3} $ as alkaline source, 400 mg of Li[NTf]2 as the ionic-exchange reagent, 4% of NaCl, 5 min of centrifugation and 1.5 mL of ether as the elution solvent. Under optimized conditions, the limits of detection ranged from 0.12 to 0.32 μg $ L^{−1} $, and the extraction recoveries for BPA, BPB, and BPAF spanned the range of 85.7–106.2% in five kinds of milk samples. Therefore, the AIL ([BMIM][$ HSO_{4} $]) played dual roles, i.e., extractant and pH regulator, in the AI-EDLM procedures. Overall, this proposed method is simple, quick, and environment-friendly with low detection limits and high recoveries for BPs, and thus has excellent application value in the sample pretreatment field in milk and milky tea samples. Bisphenol (dpeaa)DE-He213 Acidic ionic liquid (dpeaa)DE-He213 Effervescent reaction-enhanced microextraction (dpeaa)DE-He213 In situ metathesis reaction (dpeaa)DE-He213 Milk and milky tea samples (dpeaa)DE-He213 Wang, Hui aut Wang, Jun aut Wang, Xuedong (orcid)0000-0002-8343-0692 aut Wang, Huili aut Enthalten in Food analytical methods New York, NY : Springer, 2008 15(2022), 7 vom: 26. März, Seite 2036-2047 (DE-627)566007320 (DE-600)2424728-5 1936-976X nnns volume:15 year:2022 number:7 day:26 month:03 pages:2036-2047 https://dx.doi.org/10.1007/s12161-022-02263-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 15 2022 7 26 03 2036-2047 |
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10.1007/s12161-022-02263-w doi (DE-627)SPR047196017 (SPR)s12161-022-02263-w-e DE-627 ger DE-627 rakwb eng Gao, Ming verfasserin aut Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022 Abstract Herein, we developed an effervescent reaction-enhanced dispersive liquid–liquid microextraction method for the preconcentration/extraction of bisphenols (BPs) in milk and milky tea samples. This microextraction method was based on the utilization of acidic ionic liquid (AIL) and in situ metathesis reaction (AI-EDLM). Compared to the traditional imidazolium-based ionic liquid, AIL can not only be used as an extractant, but also as an acidic source in the effervescent reaction. Under such a case, it can avoid the use of additional acidic source and also achieve a rapid dispersion effect due to vigorous $ CO_{2} $ bubbles, which simplify the experimental procedures and decrease the preparation cost of effervescent tablets. By employing the one-factor-at-a-time approach, the main parameters were optimized as follows: 400 mg of [BMIM][$ HSO_{4} $] as extractant, 100 mg of $ Na_{2} %$ CO_{3} $ as alkaline source, 400 mg of Li[NTf]2 as the ionic-exchange reagent, 4% of NaCl, 5 min of centrifugation and 1.5 mL of ether as the elution solvent. Under optimized conditions, the limits of detection ranged from 0.12 to 0.32 μg $ L^{−1} $, and the extraction recoveries for BPA, BPB, and BPAF spanned the range of 85.7–106.2% in five kinds of milk samples. Therefore, the AIL ([BMIM][$ HSO_{4} $]) played dual roles, i.e., extractant and pH regulator, in the AI-EDLM procedures. Overall, this proposed method is simple, quick, and environment-friendly with low detection limits and high recoveries for BPs, and thus has excellent application value in the sample pretreatment field in milk and milky tea samples. Bisphenol (dpeaa)DE-He213 Acidic ionic liquid (dpeaa)DE-He213 Effervescent reaction-enhanced microextraction (dpeaa)DE-He213 In situ metathesis reaction (dpeaa)DE-He213 Milk and milky tea samples (dpeaa)DE-He213 Wang, Hui aut Wang, Jun aut Wang, Xuedong (orcid)0000-0002-8343-0692 aut Wang, Huili aut Enthalten in Food analytical methods New York, NY : Springer, 2008 15(2022), 7 vom: 26. März, Seite 2036-2047 (DE-627)566007320 (DE-600)2424728-5 1936-976X nnns volume:15 year:2022 number:7 day:26 month:03 pages:2036-2047 https://dx.doi.org/10.1007/s12161-022-02263-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 15 2022 7 26 03 2036-2047 |
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10.1007/s12161-022-02263-w doi (DE-627)SPR047196017 (SPR)s12161-022-02263-w-e DE-627 ger DE-627 rakwb eng Gao, Ming verfasserin aut Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022 Abstract Herein, we developed an effervescent reaction-enhanced dispersive liquid–liquid microextraction method for the preconcentration/extraction of bisphenols (BPs) in milk and milky tea samples. This microextraction method was based on the utilization of acidic ionic liquid (AIL) and in situ metathesis reaction (AI-EDLM). Compared to the traditional imidazolium-based ionic liquid, AIL can not only be used as an extractant, but also as an acidic source in the effervescent reaction. Under such a case, it can avoid the use of additional acidic source and also achieve a rapid dispersion effect due to vigorous $ CO_{2} $ bubbles, which simplify the experimental procedures and decrease the preparation cost of effervescent tablets. By employing the one-factor-at-a-time approach, the main parameters were optimized as follows: 400 mg of [BMIM][$ HSO_{4} $] as extractant, 100 mg of $ Na_{2} %$ CO_{3} $ as alkaline source, 400 mg of Li[NTf]2 as the ionic-exchange reagent, 4% of NaCl, 5 min of centrifugation and 1.5 mL of ether as the elution solvent. Under optimized conditions, the limits of detection ranged from 0.12 to 0.32 μg $ L^{−1} $, and the extraction recoveries for BPA, BPB, and BPAF spanned the range of 85.7–106.2% in five kinds of milk samples. Therefore, the AIL ([BMIM][$ HSO_{4} $]) played dual roles, i.e., extractant and pH regulator, in the AI-EDLM procedures. Overall, this proposed method is simple, quick, and environment-friendly with low detection limits and high recoveries for BPs, and thus has excellent application value in the sample pretreatment field in milk and milky tea samples. Bisphenol (dpeaa)DE-He213 Acidic ionic liquid (dpeaa)DE-He213 Effervescent reaction-enhanced microextraction (dpeaa)DE-He213 In situ metathesis reaction (dpeaa)DE-He213 Milk and milky tea samples (dpeaa)DE-He213 Wang, Hui aut Wang, Jun aut Wang, Xuedong (orcid)0000-0002-8343-0692 aut Wang, Huili aut Enthalten in Food analytical methods New York, NY : Springer, 2008 15(2022), 7 vom: 26. März, Seite 2036-2047 (DE-627)566007320 (DE-600)2424728-5 1936-976X nnns volume:15 year:2022 number:7 day:26 month:03 pages:2036-2047 https://dx.doi.org/10.1007/s12161-022-02263-w lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 15 2022 7 26 03 2036-2047 |
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Enthalten in Food analytical methods 15(2022), 7 vom: 26. März, Seite 2036-2047 volume:15 year:2022 number:7 day:26 month:03 pages:2036-2047 |
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Bisphenol Acidic ionic liquid Effervescent reaction-enhanced microextraction In situ metathesis reaction Milk and milky tea samples |
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Gao, Ming @@aut@@ Wang, Hui @@aut@@ Wang, Jun @@aut@@ Wang, Xuedong @@aut@@ Wang, Huili @@aut@@ |
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This microextraction method was based on the utilization of acidic ionic liquid (AIL) and in situ metathesis reaction (AI-EDLM). Compared to the traditional imidazolium-based ionic liquid, AIL can not only be used as an extractant, but also as an acidic source in the effervescent reaction. Under such a case, it can avoid the use of additional acidic source and also achieve a rapid dispersion effect due to vigorous $ CO_{2} $ bubbles, which simplify the experimental procedures and decrease the preparation cost of effervescent tablets. By employing the one-factor-at-a-time approach, the main parameters were optimized as follows: 400 mg of [BMIM][$ HSO_{4} $] as extractant, 100 mg of $ Na_{2} %$ CO_{3} $ as alkaline source, 400 mg of Li[NTf]2 as the ionic-exchange reagent, 4% of NaCl, 5 min of centrifugation and 1.5 mL of ether as the elution solvent. Under optimized conditions, the limits of detection ranged from 0.12 to 0.32 μg $ L^{−1} $, and the extraction recoveries for BPA, BPB, and BPAF spanned the range of 85.7–106.2% in five kinds of milk samples. Therefore, the AIL ([BMIM][$ HSO_{4} $]) played dual roles, i.e., extractant and pH regulator, in the AI-EDLM procedures. Overall, this proposed method is simple, quick, and environment-friendly with low detection limits and high recoveries for BPs, and thus has excellent application value in the sample pretreatment field in milk and milky tea samples.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Bisphenol</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Acidic ionic liquid</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Effervescent reaction-enhanced microextraction</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">In situ metathesis reaction</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Milk and milky tea samples</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Hui</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Jun</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Xuedong</subfield><subfield code="0">(orcid)0000-0002-8343-0692</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Huili</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Food analytical methods</subfield><subfield code="d">New York, NY : Springer, 2008</subfield><subfield code="g">15(2022), 7 vom: 26. 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Gao, Ming |
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Gao, Ming misc Bisphenol misc Acidic ionic liquid misc Effervescent reaction-enhanced microextraction misc In situ metathesis reaction misc Milk and milky tea samples Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples |
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Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples Bisphenol (dpeaa)DE-He213 Acidic ionic liquid (dpeaa)DE-He213 Effervescent reaction-enhanced microextraction (dpeaa)DE-He213 In situ metathesis reaction (dpeaa)DE-He213 Milk and milky tea samples (dpeaa)DE-He213 |
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misc Bisphenol misc Acidic ionic liquid misc Effervescent reaction-enhanced microextraction misc In situ metathesis reaction misc Milk and milky tea samples |
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misc Bisphenol misc Acidic ionic liquid misc Effervescent reaction-enhanced microextraction misc In situ metathesis reaction misc Milk and milky tea samples |
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Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples |
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Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples |
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effervescence-enhanced microextraction based on acidic ionic liquids and in situ metathesis reaction for bisphenol detection in milk samples |
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Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples |
| abstract |
Abstract Herein, we developed an effervescent reaction-enhanced dispersive liquid–liquid microextraction method for the preconcentration/extraction of bisphenols (BPs) in milk and milky tea samples. This microextraction method was based on the utilization of acidic ionic liquid (AIL) and in situ metathesis reaction (AI-EDLM). Compared to the traditional imidazolium-based ionic liquid, AIL can not only be used as an extractant, but also as an acidic source in the effervescent reaction. Under such a case, it can avoid the use of additional acidic source and also achieve a rapid dispersion effect due to vigorous $ CO_{2} $ bubbles, which simplify the experimental procedures and decrease the preparation cost of effervescent tablets. By employing the one-factor-at-a-time approach, the main parameters were optimized as follows: 400 mg of [BMIM][$ HSO_{4} $] as extractant, 100 mg of $ Na_{2} %$ CO_{3} $ as alkaline source, 400 mg of Li[NTf]2 as the ionic-exchange reagent, 4% of NaCl, 5 min of centrifugation and 1.5 mL of ether as the elution solvent. Under optimized conditions, the limits of detection ranged from 0.12 to 0.32 μg $ L^{−1} $, and the extraction recoveries for BPA, BPB, and BPAF spanned the range of 85.7–106.2% in five kinds of milk samples. Therefore, the AIL ([BMIM][$ HSO_{4} $]) played dual roles, i.e., extractant and pH regulator, in the AI-EDLM procedures. Overall, this proposed method is simple, quick, and environment-friendly with low detection limits and high recoveries for BPs, and thus has excellent application value in the sample pretreatment field in milk and milky tea samples. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022 |
| abstractGer |
Abstract Herein, we developed an effervescent reaction-enhanced dispersive liquid–liquid microextraction method for the preconcentration/extraction of bisphenols (BPs) in milk and milky tea samples. This microextraction method was based on the utilization of acidic ionic liquid (AIL) and in situ metathesis reaction (AI-EDLM). Compared to the traditional imidazolium-based ionic liquid, AIL can not only be used as an extractant, but also as an acidic source in the effervescent reaction. Under such a case, it can avoid the use of additional acidic source and also achieve a rapid dispersion effect due to vigorous $ CO_{2} $ bubbles, which simplify the experimental procedures and decrease the preparation cost of effervescent tablets. By employing the one-factor-at-a-time approach, the main parameters were optimized as follows: 400 mg of [BMIM][$ HSO_{4} $] as extractant, 100 mg of $ Na_{2} %$ CO_{3} $ as alkaline source, 400 mg of Li[NTf]2 as the ionic-exchange reagent, 4% of NaCl, 5 min of centrifugation and 1.5 mL of ether as the elution solvent. Under optimized conditions, the limits of detection ranged from 0.12 to 0.32 μg $ L^{−1} $, and the extraction recoveries for BPA, BPB, and BPAF spanned the range of 85.7–106.2% in five kinds of milk samples. Therefore, the AIL ([BMIM][$ HSO_{4} $]) played dual roles, i.e., extractant and pH regulator, in the AI-EDLM procedures. Overall, this proposed method is simple, quick, and environment-friendly with low detection limits and high recoveries for BPs, and thus has excellent application value in the sample pretreatment field in milk and milky tea samples. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022 |
| abstract_unstemmed |
Abstract Herein, we developed an effervescent reaction-enhanced dispersive liquid–liquid microextraction method for the preconcentration/extraction of bisphenols (BPs) in milk and milky tea samples. This microextraction method was based on the utilization of acidic ionic liquid (AIL) and in situ metathesis reaction (AI-EDLM). Compared to the traditional imidazolium-based ionic liquid, AIL can not only be used as an extractant, but also as an acidic source in the effervescent reaction. Under such a case, it can avoid the use of additional acidic source and also achieve a rapid dispersion effect due to vigorous $ CO_{2} $ bubbles, which simplify the experimental procedures and decrease the preparation cost of effervescent tablets. By employing the one-factor-at-a-time approach, the main parameters were optimized as follows: 400 mg of [BMIM][$ HSO_{4} $] as extractant, 100 mg of $ Na_{2} %$ CO_{3} $ as alkaline source, 400 mg of Li[NTf]2 as the ionic-exchange reagent, 4% of NaCl, 5 min of centrifugation and 1.5 mL of ether as the elution solvent. Under optimized conditions, the limits of detection ranged from 0.12 to 0.32 μg $ L^{−1} $, and the extraction recoveries for BPA, BPB, and BPAF spanned the range of 85.7–106.2% in five kinds of milk samples. Therefore, the AIL ([BMIM][$ HSO_{4} $]) played dual roles, i.e., extractant and pH regulator, in the AI-EDLM procedures. Overall, this proposed method is simple, quick, and environment-friendly with low detection limits and high recoveries for BPs, and thus has excellent application value in the sample pretreatment field in milk and milky tea samples. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022 |
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| title_short |
Effervescence-Enhanced Microextraction Based on Acidic Ionic Liquids and In Situ Metathesis Reaction for Bisphenol Detection in Milk Samples |
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https://dx.doi.org/10.1007/s12161-022-02263-w |
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Wang, Hui Wang, Jun Wang, Xuedong Wang, Huili |
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| score |
7.400141 |