Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays
Abstract Electron spin resonance techniques were employed to investigate the effects of the absorbed dose and post-irradiation conditions on the evolution and decay of free-radicals in cross-linked polytetrafluoroethylene (XPTFE), induced by γ-ray radiation. Chain-end free-radicals, chain alkyl free...
Ausführliche Beschreibung
Autor*in: |
Sha, Fei-Xiang [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2022 |
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Schlagwörter: |
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Anmerkung: |
© The Author(s), under exclusive licence to China Science Publishing & Media Ltd. (Science Press), Shanghai Institute of Applied Physics, the Chinese Academy of Sciences, Chinese Nuclear Society 2022 |
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Übergeordnetes Werk: |
Enthalten in: Nuclear science and techniques - Singapore : Springer, 2006, 33(2022), 5 vom: Mai |
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Übergeordnetes Werk: |
volume:33 ; year:2022 ; number:5 ; month:05 |
Links: |
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DOI / URN: |
10.1007/s41365-022-01039-5 |
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Katalog-ID: |
SPR047367059 |
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520 | |a Abstract Electron spin resonance techniques were employed to investigate the effects of the absorbed dose and post-irradiation conditions on the evolution and decay of free-radicals in cross-linked polytetrafluoroethylene (XPTFE), induced by γ-ray radiation. Chain-end free-radicals, chain alkyl free-radicals, and tertiary alkyl free-radicals were detected when XPTFE was irradiated under Ar atmosphere. The corresponding peroxy free-radicals were formed upon exposure of irradiated XPTFE to air; the free-radicals concentration first increased linearly with increasing absorbed dose and then gradually saturated. The free-radicals yield under air atmosphere was greater than that under Ar, and the peroxy free-radicals were preserved for a relatively long time when irradiated XPTFE was stored under air atmosphere. The chain alkyl free-radicals may be converted to chain end free-radicals by β-scission, while chain end free-radicals are more sensitive to oxygen than chain alkyl free-radicals. When the annealing temperature was raised above the α-transition temperature of XPTFE, the decay of the free-radicals was greatly affected and accelerated by the motion of the molecules over the long range. | ||
650 | 4 | |a Polytetrafluoroethylene |7 (dpeaa)DE-He213 | |
650 | 4 | |a Cross-linked polytetrafluoroethylene |7 (dpeaa)DE-He213 | |
650 | 4 | |a Electron spin resonance |7 (dpeaa)DE-He213 | |
650 | 4 | |a Decay |7 (dpeaa)DE-He213 | |
650 | 4 | |a Radiation |7 (dpeaa)DE-He213 | |
650 | 4 | |a γ-ray |7 (dpeaa)DE-He213 | |
700 | 1 | |a Cheng, Guo-Jun |4 aut | |
700 | 1 | |a Xuan, Zi-Yue |4 aut | |
700 | 1 | |a Liu, Yang |4 aut | |
700 | 1 | |a Liu, Wei-Hua |4 aut | |
700 | 1 | |a Zhang, Xiao-Dong |4 aut | |
700 | 1 | |a Tang, Zhong-Feng |0 (orcid)0000-0001-9135-7213 |4 aut | |
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10.1007/s41365-022-01039-5 doi (DE-627)SPR047367059 (SPR)s41365-022-01039-5-e DE-627 ger DE-627 rakwb eng Sha, Fei-Xiang verfasserin aut Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to China Science Publishing & Media Ltd. (Science Press), Shanghai Institute of Applied Physics, the Chinese Academy of Sciences, Chinese Nuclear Society 2022 Abstract Electron spin resonance techniques were employed to investigate the effects of the absorbed dose and post-irradiation conditions on the evolution and decay of free-radicals in cross-linked polytetrafluoroethylene (XPTFE), induced by γ-ray radiation. Chain-end free-radicals, chain alkyl free-radicals, and tertiary alkyl free-radicals were detected when XPTFE was irradiated under Ar atmosphere. The corresponding peroxy free-radicals were formed upon exposure of irradiated XPTFE to air; the free-radicals concentration first increased linearly with increasing absorbed dose and then gradually saturated. The free-radicals yield under air atmosphere was greater than that under Ar, and the peroxy free-radicals were preserved for a relatively long time when irradiated XPTFE was stored under air atmosphere. The chain alkyl free-radicals may be converted to chain end free-radicals by β-scission, while chain end free-radicals are more sensitive to oxygen than chain alkyl free-radicals. When the annealing temperature was raised above the α-transition temperature of XPTFE, the decay of the free-radicals was greatly affected and accelerated by the motion of the molecules over the long range. Polytetrafluoroethylene (dpeaa)DE-He213 Cross-linked polytetrafluoroethylene (dpeaa)DE-He213 Electron spin resonance (dpeaa)DE-He213 Decay (dpeaa)DE-He213 Radiation (dpeaa)DE-He213 γ-ray (dpeaa)DE-He213 Cheng, Guo-Jun aut Xuan, Zi-Yue aut Liu, Yang aut Liu, Wei-Hua aut Zhang, Xiao-Dong aut Tang, Zhong-Feng (orcid)0000-0001-9135-7213 aut Enthalten in Nuclear science and techniques Singapore : Springer, 2006 33(2022), 5 vom: Mai (DE-627)513219439 (DE-600)2238719-5 2210-3147 nnns volume:33 year:2022 number:5 month:05 https://dx.doi.org/10.1007/s41365-022-01039-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 33 2022 5 05 |
spelling |
10.1007/s41365-022-01039-5 doi (DE-627)SPR047367059 (SPR)s41365-022-01039-5-e DE-627 ger DE-627 rakwb eng Sha, Fei-Xiang verfasserin aut Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to China Science Publishing & Media Ltd. (Science Press), Shanghai Institute of Applied Physics, the Chinese Academy of Sciences, Chinese Nuclear Society 2022 Abstract Electron spin resonance techniques were employed to investigate the effects of the absorbed dose and post-irradiation conditions on the evolution and decay of free-radicals in cross-linked polytetrafluoroethylene (XPTFE), induced by γ-ray radiation. Chain-end free-radicals, chain alkyl free-radicals, and tertiary alkyl free-radicals were detected when XPTFE was irradiated under Ar atmosphere. The corresponding peroxy free-radicals were formed upon exposure of irradiated XPTFE to air; the free-radicals concentration first increased linearly with increasing absorbed dose and then gradually saturated. The free-radicals yield under air atmosphere was greater than that under Ar, and the peroxy free-radicals were preserved for a relatively long time when irradiated XPTFE was stored under air atmosphere. The chain alkyl free-radicals may be converted to chain end free-radicals by β-scission, while chain end free-radicals are more sensitive to oxygen than chain alkyl free-radicals. When the annealing temperature was raised above the α-transition temperature of XPTFE, the decay of the free-radicals was greatly affected and accelerated by the motion of the molecules over the long range. Polytetrafluoroethylene (dpeaa)DE-He213 Cross-linked polytetrafluoroethylene (dpeaa)DE-He213 Electron spin resonance (dpeaa)DE-He213 Decay (dpeaa)DE-He213 Radiation (dpeaa)DE-He213 γ-ray (dpeaa)DE-He213 Cheng, Guo-Jun aut Xuan, Zi-Yue aut Liu, Yang aut Liu, Wei-Hua aut Zhang, Xiao-Dong aut Tang, Zhong-Feng (orcid)0000-0001-9135-7213 aut Enthalten in Nuclear science and techniques Singapore : Springer, 2006 33(2022), 5 vom: Mai (DE-627)513219439 (DE-600)2238719-5 2210-3147 nnns volume:33 year:2022 number:5 month:05 https://dx.doi.org/10.1007/s41365-022-01039-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 33 2022 5 05 |
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10.1007/s41365-022-01039-5 doi (DE-627)SPR047367059 (SPR)s41365-022-01039-5-e DE-627 ger DE-627 rakwb eng Sha, Fei-Xiang verfasserin aut Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to China Science Publishing & Media Ltd. (Science Press), Shanghai Institute of Applied Physics, the Chinese Academy of Sciences, Chinese Nuclear Society 2022 Abstract Electron spin resonance techniques were employed to investigate the effects of the absorbed dose and post-irradiation conditions on the evolution and decay of free-radicals in cross-linked polytetrafluoroethylene (XPTFE), induced by γ-ray radiation. Chain-end free-radicals, chain alkyl free-radicals, and tertiary alkyl free-radicals were detected when XPTFE was irradiated under Ar atmosphere. The corresponding peroxy free-radicals were formed upon exposure of irradiated XPTFE to air; the free-radicals concentration first increased linearly with increasing absorbed dose and then gradually saturated. The free-radicals yield under air atmosphere was greater than that under Ar, and the peroxy free-radicals were preserved for a relatively long time when irradiated XPTFE was stored under air atmosphere. The chain alkyl free-radicals may be converted to chain end free-radicals by β-scission, while chain end free-radicals are more sensitive to oxygen than chain alkyl free-radicals. When the annealing temperature was raised above the α-transition temperature of XPTFE, the decay of the free-radicals was greatly affected and accelerated by the motion of the molecules over the long range. Polytetrafluoroethylene (dpeaa)DE-He213 Cross-linked polytetrafluoroethylene (dpeaa)DE-He213 Electron spin resonance (dpeaa)DE-He213 Decay (dpeaa)DE-He213 Radiation (dpeaa)DE-He213 γ-ray (dpeaa)DE-He213 Cheng, Guo-Jun aut Xuan, Zi-Yue aut Liu, Yang aut Liu, Wei-Hua aut Zhang, Xiao-Dong aut Tang, Zhong-Feng (orcid)0000-0001-9135-7213 aut Enthalten in Nuclear science and techniques Singapore : Springer, 2006 33(2022), 5 vom: Mai (DE-627)513219439 (DE-600)2238719-5 2210-3147 nnns volume:33 year:2022 number:5 month:05 https://dx.doi.org/10.1007/s41365-022-01039-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 33 2022 5 05 |
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10.1007/s41365-022-01039-5 doi (DE-627)SPR047367059 (SPR)s41365-022-01039-5-e DE-627 ger DE-627 rakwb eng Sha, Fei-Xiang verfasserin aut Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to China Science Publishing & Media Ltd. (Science Press), Shanghai Institute of Applied Physics, the Chinese Academy of Sciences, Chinese Nuclear Society 2022 Abstract Electron spin resonance techniques were employed to investigate the effects of the absorbed dose and post-irradiation conditions on the evolution and decay of free-radicals in cross-linked polytetrafluoroethylene (XPTFE), induced by γ-ray radiation. Chain-end free-radicals, chain alkyl free-radicals, and tertiary alkyl free-radicals were detected when XPTFE was irradiated under Ar atmosphere. The corresponding peroxy free-radicals were formed upon exposure of irradiated XPTFE to air; the free-radicals concentration first increased linearly with increasing absorbed dose and then gradually saturated. The free-radicals yield under air atmosphere was greater than that under Ar, and the peroxy free-radicals were preserved for a relatively long time when irradiated XPTFE was stored under air atmosphere. The chain alkyl free-radicals may be converted to chain end free-radicals by β-scission, while chain end free-radicals are more sensitive to oxygen than chain alkyl free-radicals. When the annealing temperature was raised above the α-transition temperature of XPTFE, the decay of the free-radicals was greatly affected and accelerated by the motion of the molecules over the long range. Polytetrafluoroethylene (dpeaa)DE-He213 Cross-linked polytetrafluoroethylene (dpeaa)DE-He213 Electron spin resonance (dpeaa)DE-He213 Decay (dpeaa)DE-He213 Radiation (dpeaa)DE-He213 γ-ray (dpeaa)DE-He213 Cheng, Guo-Jun aut Xuan, Zi-Yue aut Liu, Yang aut Liu, Wei-Hua aut Zhang, Xiao-Dong aut Tang, Zhong-Feng (orcid)0000-0001-9135-7213 aut Enthalten in Nuclear science and techniques Singapore : Springer, 2006 33(2022), 5 vom: Mai (DE-627)513219439 (DE-600)2238719-5 2210-3147 nnns volume:33 year:2022 number:5 month:05 https://dx.doi.org/10.1007/s41365-022-01039-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 33 2022 5 05 |
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10.1007/s41365-022-01039-5 doi (DE-627)SPR047367059 (SPR)s41365-022-01039-5-e DE-627 ger DE-627 rakwb eng Sha, Fei-Xiang verfasserin aut Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to China Science Publishing & Media Ltd. (Science Press), Shanghai Institute of Applied Physics, the Chinese Academy of Sciences, Chinese Nuclear Society 2022 Abstract Electron spin resonance techniques were employed to investigate the effects of the absorbed dose and post-irradiation conditions on the evolution and decay of free-radicals in cross-linked polytetrafluoroethylene (XPTFE), induced by γ-ray radiation. Chain-end free-radicals, chain alkyl free-radicals, and tertiary alkyl free-radicals were detected when XPTFE was irradiated under Ar atmosphere. The corresponding peroxy free-radicals were formed upon exposure of irradiated XPTFE to air; the free-radicals concentration first increased linearly with increasing absorbed dose and then gradually saturated. The free-radicals yield under air atmosphere was greater than that under Ar, and the peroxy free-radicals were preserved for a relatively long time when irradiated XPTFE was stored under air atmosphere. The chain alkyl free-radicals may be converted to chain end free-radicals by β-scission, while chain end free-radicals are more sensitive to oxygen than chain alkyl free-radicals. When the annealing temperature was raised above the α-transition temperature of XPTFE, the decay of the free-radicals was greatly affected and accelerated by the motion of the molecules over the long range. Polytetrafluoroethylene (dpeaa)DE-He213 Cross-linked polytetrafluoroethylene (dpeaa)DE-He213 Electron spin resonance (dpeaa)DE-He213 Decay (dpeaa)DE-He213 Radiation (dpeaa)DE-He213 γ-ray (dpeaa)DE-He213 Cheng, Guo-Jun aut Xuan, Zi-Yue aut Liu, Yang aut Liu, Wei-Hua aut Zhang, Xiao-Dong aut Tang, Zhong-Feng (orcid)0000-0001-9135-7213 aut Enthalten in Nuclear science and techniques Singapore : Springer, 2006 33(2022), 5 vom: Mai (DE-627)513219439 (DE-600)2238719-5 2210-3147 nnns volume:33 year:2022 number:5 month:05 https://dx.doi.org/10.1007/s41365-022-01039-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 33 2022 5 05 |
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Enthalten in Nuclear science and techniques 33(2022), 5 vom: Mai volume:33 year:2022 number:5 month:05 |
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Enthalten in Nuclear science and techniques 33(2022), 5 vom: Mai volume:33 year:2022 number:5 month:05 |
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Polytetrafluoroethylene Cross-linked polytetrafluoroethylene Electron spin resonance Decay Radiation γ-ray |
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Sha, Fei-Xiang @@aut@@ Cheng, Guo-Jun @@aut@@ Xuan, Zi-Yue @@aut@@ Liu, Yang @@aut@@ Liu, Wei-Hua @@aut@@ Zhang, Xiao-Dong @@aut@@ Tang, Zhong-Feng @@aut@@ |
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(Science Press), Shanghai Institute of Applied Physics, the Chinese Academy of Sciences, Chinese Nuclear Society 2022</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Electron spin resonance techniques were employed to investigate the effects of the absorbed dose and post-irradiation conditions on the evolution and decay of free-radicals in cross-linked polytetrafluoroethylene (XPTFE), induced by γ-ray radiation. Chain-end free-radicals, chain alkyl free-radicals, and tertiary alkyl free-radicals were detected when XPTFE was irradiated under Ar atmosphere. The corresponding peroxy free-radicals were formed upon exposure of irradiated XPTFE to air; the free-radicals concentration first increased linearly with increasing absorbed dose and then gradually saturated. 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Sha, Fei-Xiang |
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Sha, Fei-Xiang misc Polytetrafluoroethylene misc Cross-linked polytetrafluoroethylene misc Electron spin resonance misc Decay misc Radiation misc γ-ray Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays |
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Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays Polytetrafluoroethylene (dpeaa)DE-He213 Cross-linked polytetrafluoroethylene (dpeaa)DE-He213 Electron spin resonance (dpeaa)DE-He213 Decay (dpeaa)DE-He213 Radiation (dpeaa)DE-He213 γ-ray (dpeaa)DE-He213 |
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misc Polytetrafluoroethylene misc Cross-linked polytetrafluoroethylene misc Electron spin resonance misc Decay misc Radiation misc γ-ray |
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Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays |
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Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays |
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free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays |
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Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays |
abstract |
Abstract Electron spin resonance techniques were employed to investigate the effects of the absorbed dose and post-irradiation conditions on the evolution and decay of free-radicals in cross-linked polytetrafluoroethylene (XPTFE), induced by γ-ray radiation. Chain-end free-radicals, chain alkyl free-radicals, and tertiary alkyl free-radicals were detected when XPTFE was irradiated under Ar atmosphere. The corresponding peroxy free-radicals were formed upon exposure of irradiated XPTFE to air; the free-radicals concentration first increased linearly with increasing absorbed dose and then gradually saturated. The free-radicals yield under air atmosphere was greater than that under Ar, and the peroxy free-radicals were preserved for a relatively long time when irradiated XPTFE was stored under air atmosphere. The chain alkyl free-radicals may be converted to chain end free-radicals by β-scission, while chain end free-radicals are more sensitive to oxygen than chain alkyl free-radicals. When the annealing temperature was raised above the α-transition temperature of XPTFE, the decay of the free-radicals was greatly affected and accelerated by the motion of the molecules over the long range. © The Author(s), under exclusive licence to China Science Publishing & Media Ltd. (Science Press), Shanghai Institute of Applied Physics, the Chinese Academy of Sciences, Chinese Nuclear Society 2022 |
abstractGer |
Abstract Electron spin resonance techniques were employed to investigate the effects of the absorbed dose and post-irradiation conditions on the evolution and decay of free-radicals in cross-linked polytetrafluoroethylene (XPTFE), induced by γ-ray radiation. Chain-end free-radicals, chain alkyl free-radicals, and tertiary alkyl free-radicals were detected when XPTFE was irradiated under Ar atmosphere. The corresponding peroxy free-radicals were formed upon exposure of irradiated XPTFE to air; the free-radicals concentration first increased linearly with increasing absorbed dose and then gradually saturated. The free-radicals yield under air atmosphere was greater than that under Ar, and the peroxy free-radicals were preserved for a relatively long time when irradiated XPTFE was stored under air atmosphere. The chain alkyl free-radicals may be converted to chain end free-radicals by β-scission, while chain end free-radicals are more sensitive to oxygen than chain alkyl free-radicals. When the annealing temperature was raised above the α-transition temperature of XPTFE, the decay of the free-radicals was greatly affected and accelerated by the motion of the molecules over the long range. © The Author(s), under exclusive licence to China Science Publishing & Media Ltd. (Science Press), Shanghai Institute of Applied Physics, the Chinese Academy of Sciences, Chinese Nuclear Society 2022 |
abstract_unstemmed |
Abstract Electron spin resonance techniques were employed to investigate the effects of the absorbed dose and post-irradiation conditions on the evolution and decay of free-radicals in cross-linked polytetrafluoroethylene (XPTFE), induced by γ-ray radiation. Chain-end free-radicals, chain alkyl free-radicals, and tertiary alkyl free-radicals were detected when XPTFE was irradiated under Ar atmosphere. The corresponding peroxy free-radicals were formed upon exposure of irradiated XPTFE to air; the free-radicals concentration first increased linearly with increasing absorbed dose and then gradually saturated. The free-radicals yield under air atmosphere was greater than that under Ar, and the peroxy free-radicals were preserved for a relatively long time when irradiated XPTFE was stored under air atmosphere. The chain alkyl free-radicals may be converted to chain end free-radicals by β-scission, while chain end free-radicals are more sensitive to oxygen than chain alkyl free-radicals. When the annealing temperature was raised above the α-transition temperature of XPTFE, the decay of the free-radicals was greatly affected and accelerated by the motion of the molecules over the long range. © The Author(s), under exclusive licence to China Science Publishing & Media Ltd. (Science Press), Shanghai Institute of Applied Physics, the Chinese Academy of Sciences, Chinese Nuclear Society 2022 |
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title_short |
Free-radical evolution and decay in cross-linked polytetrafluoroethylene irradiated by gamma-rays |
url |
https://dx.doi.org/10.1007/s41365-022-01039-5 |
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Cheng, Guo-Jun Xuan, Zi-Yue Liu, Yang Liu, Wei-Hua Zhang, Xiao-Dong Tang, Zhong-Feng |
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Cheng, Guo-Jun Xuan, Zi-Yue Liu, Yang Liu, Wei-Hua Zhang, Xiao-Dong Tang, Zhong-Feng |
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doi_str |
10.1007/s41365-022-01039-5 |
up_date |
2024-07-04T02:53:14.756Z |
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|
score |
7.39935 |