Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane

Abstract The transfer of $ Cd^{2+} $, $ Pb^{2+} $, $ Hg^{2+} $, $ Pd^{2+} $, and $ Cu^{2+} $ ions across polarized nitrobenzene/water (NB/W) interface assisted by 1,4,7,10,13,16-hexathiacyclooctadecane (HTCO) present in NB-phase has been studied by means of cyclic voltammetry. Voltammograms of $ Cd^...
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Gespeichert in:

Autor*in:	Katano, Hajime [verfasserIn] Senda, Mitsugi

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	1999

Schlagwörter:	Voltammetry polythiaether assisted transfer heavy metal ion polarizable oil/water interface

Anmerkung:	© The Japan Society for Analytical Chemistry 1999

Übergeordnetes Werk:	Enthalten in: Analytical sciences - [Cham] : Springer International Publishing, 1985, 15(1999), 12 vom: Dez., Seite 1179-1184
Übergeordnetes Werk:	volume:15 ; year:1999 ; number:12 ; month:12 ; pages:1179-1184

Links:	Volltext

DOI / URN:	10.2116/analsci.15.1179

Katalog-ID:	SPR047394676

Internformat


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245	1	0	\|a Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane
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520			\|a Abstract The transfer of $ Cd^{2+} $, $ Pb^{2+} $, $ Hg^{2+} $, $ Pd^{2+} $, and $ Cu^{2+} $ ions across polarized nitrobenzene/water (NB/W) interface assisted by 1,4,7,10,13,16-hexathiacyclooctadecane (HTCO) present in NB-phase has been studied by means of cyclic voltammetry. Voltammograms of $ Cd^{2+} $ and $ Pb^{2+} $ ions can be interpreted as being due to the reversible transfer of the ions assisted by the formation of 1:1 metal(M)-HTCO complex in NB-phase. The formal formation constants of [PbHTCO]2+ and [CdHTCO]2+ complexes in NB-phase have been determined to be $ 10^{11.7±0.3} $ and $ 10^{7.9±0.3} $ $ M^{–1} $, respectively, using the formal potentials of non-assisted ion(M)-transfer at NB/W interface (DNWBfM0 ¢). The DNWBfM0 ¢’ s of $ Cd^{2+} $ and $ Pb^{2+} $ ions and $ Zn^{2+} $ and $ Tl^{+} $ ions as well have been determined on the basis of the tetraphenylarsonium-tetraphenylborate assumption and of the polarographic reversible half-wave potentials of the ions in NB- and W-media reported by previous authors. Voltammograms of $ Hg^{2+} $ and $ Pd^{2+} $ ions have been explained by that 1:1 M-HTCO complex is formed and soluble in both NB- and W-phases. The formal potentials of the transfer of [HgHTCO]2+ and [PdHTCO]2+ complex ions at NB/W interface have been determined. Voltammograms of $ Cu^{2+} $ ion are of irreversible nature.
650		4	\|a Voltammetry \|7 (dpeaa)DE-He213
650		4	\|a polythiaether \|7 (dpeaa)DE-He213
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650		4	\|a heavy metal ion \|7 (dpeaa)DE-He213
650		4	\|a polarizable oil/water interface \|7 (dpeaa)DE-He213
700	1		\|a Senda, Mitsugi \|4 aut
773	0	8	\|i Enthalten in \|t Analytical sciences \|d [Cham] : Springer International Publishing, 1985 \|g 15(1999), 12 vom: Dez., Seite 1179-1184 \|w (DE-627)300895925 \|w (DE-600)1483376-1 \|x 1348-2246 \|7 nnns
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912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_101
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_138
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2144
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2232
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912			\|a GBV_ILN_2470
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912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4012
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4328
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4336
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4367
912			\|a GBV_ILN_4393
912			\|a GBV_ILN_4700
951			\|a AR
952			\|d 15 \|j 1999 \|e 12 \|c 12 \|h 1179-1184

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author_variant	h k hk m s ms
matchkey_str	article:13482246:1999----::otmerctdoternfrfevmtlostirbneeaeitraesitdy4
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publishDate	1999
allfields	10.2116/analsci.15.1179 doi (DE-627)SPR047394676 (SPR)analsci.15.1179-e DE-627 ger DE-627 rakwb eng Katano, Hajime verfasserin aut Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane 1999 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1999 Abstract The transfer of $ Cd^{2+} $, $ Pb^{2+} $, $ Hg^{2+} $, $ Pd^{2+} $, and $ Cu^{2+} $ ions across polarized nitrobenzene/water (NB/W) interface assisted by 1,4,7,10,13,16-hexathiacyclooctadecane (HTCO) present in NB-phase has been studied by means of cyclic voltammetry. Voltammograms of $ Cd^{2+} $ and $ Pb^{2+} $ ions can be interpreted as being due to the reversible transfer of the ions assisted by the formation of 1:1 metal(M)-HTCO complex in NB-phase. The formal formation constants of [PbHTCO]2+ and [CdHTCO]2+ complexes in NB-phase have been determined to be $ 10^{11.7±0.3} $ and $ 10^{7.9±0.3} $ $ M^{–1} $, respectively, using the formal potentials of non-assisted ion(M)-transfer at NB/W interface (DNWBfM0 ¢). The DNWBfM0 ¢’ s of $ Cd^{2+} $ and $ Pb^{2+} $ ions and $ Zn^{2+} $ and $ Tl^{+} $ ions as well have been determined on the basis of the tetraphenylarsonium-tetraphenylborate assumption and of the polarographic reversible half-wave potentials of the ions in NB- and W-media reported by previous authors. Voltammograms of $ Hg^{2+} $ and $ Pd^{2+} $ ions have been explained by that 1:1 M-HTCO complex is formed and soluble in both NB- and W-phases. The formal potentials of the transfer of [HgHTCO]2+ and [PdHTCO]2+ complex ions at NB/W interface have been determined. Voltammograms of $ Cu^{2+} $ ion are of irreversible nature. Voltammetry (dpeaa)DE-He213 polythiaether (dpeaa)DE-He213 assisted transfer (dpeaa)DE-He213 heavy metal ion (dpeaa)DE-He213 polarizable oil/water interface (dpeaa)DE-He213 Senda, Mitsugi aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 15(1999), 12 vom: Dez., Seite 1179-1184 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:15 year:1999 number:12 month:12 pages:1179-1184 https://dx.doi.org/10.2116/analsci.15.1179 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 15 1999 12 12 1179-1184
spelling	10.2116/analsci.15.1179 doi (DE-627)SPR047394676 (SPR)analsci.15.1179-e DE-627 ger DE-627 rakwb eng Katano, Hajime verfasserin aut Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane 1999 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1999 Abstract The transfer of $ Cd^{2+} $, $ Pb^{2+} $, $ Hg^{2+} $, $ Pd^{2+} $, and $ Cu^{2+} $ ions across polarized nitrobenzene/water (NB/W) interface assisted by 1,4,7,10,13,16-hexathiacyclooctadecane (HTCO) present in NB-phase has been studied by means of cyclic voltammetry. Voltammograms of $ Cd^{2+} $ and $ Pb^{2+} $ ions can be interpreted as being due to the reversible transfer of the ions assisted by the formation of 1:1 metal(M)-HTCO complex in NB-phase. The formal formation constants of [PbHTCO]2+ and [CdHTCO]2+ complexes in NB-phase have been determined to be $ 10^{11.7±0.3} $ and $ 10^{7.9±0.3} $ $ M^{–1} $, respectively, using the formal potentials of non-assisted ion(M)-transfer at NB/W interface (DNWBfM0 ¢). The DNWBfM0 ¢’ s of $ Cd^{2+} $ and $ Pb^{2+} $ ions and $ Zn^{2+} $ and $ Tl^{+} $ ions as well have been determined on the basis of the tetraphenylarsonium-tetraphenylborate assumption and of the polarographic reversible half-wave potentials of the ions in NB- and W-media reported by previous authors. Voltammograms of $ Hg^{2+} $ and $ Pd^{2+} $ ions have been explained by that 1:1 M-HTCO complex is formed and soluble in both NB- and W-phases. The formal potentials of the transfer of [HgHTCO]2+ and [PdHTCO]2+ complex ions at NB/W interface have been determined. Voltammograms of $ Cu^{2+} $ ion are of irreversible nature. Voltammetry (dpeaa)DE-He213 polythiaether (dpeaa)DE-He213 assisted transfer (dpeaa)DE-He213 heavy metal ion (dpeaa)DE-He213 polarizable oil/water interface (dpeaa)DE-He213 Senda, Mitsugi aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 15(1999), 12 vom: Dez., Seite 1179-1184 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:15 year:1999 number:12 month:12 pages:1179-1184 https://dx.doi.org/10.2116/analsci.15.1179 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 15 1999 12 12 1179-1184
allfields_unstemmed	10.2116/analsci.15.1179 doi (DE-627)SPR047394676 (SPR)analsci.15.1179-e DE-627 ger DE-627 rakwb eng Katano, Hajime verfasserin aut Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane 1999 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1999 Abstract The transfer of $ Cd^{2+} $, $ Pb^{2+} $, $ Hg^{2+} $, $ Pd^{2+} $, and $ Cu^{2+} $ ions across polarized nitrobenzene/water (NB/W) interface assisted by 1,4,7,10,13,16-hexathiacyclooctadecane (HTCO) present in NB-phase has been studied by means of cyclic voltammetry. Voltammograms of $ Cd^{2+} $ and $ Pb^{2+} $ ions can be interpreted as being due to the reversible transfer of the ions assisted by the formation of 1:1 metal(M)-HTCO complex in NB-phase. The formal formation constants of [PbHTCO]2+ and [CdHTCO]2+ complexes in NB-phase have been determined to be $ 10^{11.7±0.3} $ and $ 10^{7.9±0.3} $ $ M^{–1} $, respectively, using the formal potentials of non-assisted ion(M)-transfer at NB/W interface (DNWBfM0 ¢). The DNWBfM0 ¢’ s of $ Cd^{2+} $ and $ Pb^{2+} $ ions and $ Zn^{2+} $ and $ Tl^{+} $ ions as well have been determined on the basis of the tetraphenylarsonium-tetraphenylborate assumption and of the polarographic reversible half-wave potentials of the ions in NB- and W-media reported by previous authors. Voltammograms of $ Hg^{2+} $ and $ Pd^{2+} $ ions have been explained by that 1:1 M-HTCO complex is formed and soluble in both NB- and W-phases. The formal potentials of the transfer of [HgHTCO]2+ and [PdHTCO]2+ complex ions at NB/W interface have been determined. Voltammograms of $ Cu^{2+} $ ion are of irreversible nature. Voltammetry (dpeaa)DE-He213 polythiaether (dpeaa)DE-He213 assisted transfer (dpeaa)DE-He213 heavy metal ion (dpeaa)DE-He213 polarizable oil/water interface (dpeaa)DE-He213 Senda, Mitsugi aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 15(1999), 12 vom: Dez., Seite 1179-1184 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:15 year:1999 number:12 month:12 pages:1179-1184 https://dx.doi.org/10.2116/analsci.15.1179 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 15 1999 12 12 1179-1184
allfieldsGer	10.2116/analsci.15.1179 doi (DE-627)SPR047394676 (SPR)analsci.15.1179-e DE-627 ger DE-627 rakwb eng Katano, Hajime verfasserin aut Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane 1999 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1999 Abstract The transfer of $ Cd^{2+} $, $ Pb^{2+} $, $ Hg^{2+} $, $ Pd^{2+} $, and $ Cu^{2+} $ ions across polarized nitrobenzene/water (NB/W) interface assisted by 1,4,7,10,13,16-hexathiacyclooctadecane (HTCO) present in NB-phase has been studied by means of cyclic voltammetry. Voltammograms of $ Cd^{2+} $ and $ Pb^{2+} $ ions can be interpreted as being due to the reversible transfer of the ions assisted by the formation of 1:1 metal(M)-HTCO complex in NB-phase. The formal formation constants of [PbHTCO]2+ and [CdHTCO]2+ complexes in NB-phase have been determined to be $ 10^{11.7±0.3} $ and $ 10^{7.9±0.3} $ $ M^{–1} $, respectively, using the formal potentials of non-assisted ion(M)-transfer at NB/W interface (DNWBfM0 ¢). The DNWBfM0 ¢’ s of $ Cd^{2+} $ and $ Pb^{2+} $ ions and $ Zn^{2+} $ and $ Tl^{+} $ ions as well have been determined on the basis of the tetraphenylarsonium-tetraphenylborate assumption and of the polarographic reversible half-wave potentials of the ions in NB- and W-media reported by previous authors. Voltammograms of $ Hg^{2+} $ and $ Pd^{2+} $ ions have been explained by that 1:1 M-HTCO complex is formed and soluble in both NB- and W-phases. The formal potentials of the transfer of [HgHTCO]2+ and [PdHTCO]2+ complex ions at NB/W interface have been determined. Voltammograms of $ Cu^{2+} $ ion are of irreversible nature. Voltammetry (dpeaa)DE-He213 polythiaether (dpeaa)DE-He213 assisted transfer (dpeaa)DE-He213 heavy metal ion (dpeaa)DE-He213 polarizable oil/water interface (dpeaa)DE-He213 Senda, Mitsugi aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 15(1999), 12 vom: Dez., Seite 1179-1184 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:15 year:1999 number:12 month:12 pages:1179-1184 https://dx.doi.org/10.2116/analsci.15.1179 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 15 1999 12 12 1179-1184
allfieldsSound	10.2116/analsci.15.1179 doi (DE-627)SPR047394676 (SPR)analsci.15.1179-e DE-627 ger DE-627 rakwb eng Katano, Hajime verfasserin aut Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane 1999 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1999 Abstract The transfer of $ Cd^{2+} $, $ Pb^{2+} $, $ Hg^{2+} $, $ Pd^{2+} $, and $ Cu^{2+} $ ions across polarized nitrobenzene/water (NB/W) interface assisted by 1,4,7,10,13,16-hexathiacyclooctadecane (HTCO) present in NB-phase has been studied by means of cyclic voltammetry. Voltammograms of $ Cd^{2+} $ and $ Pb^{2+} $ ions can be interpreted as being due to the reversible transfer of the ions assisted by the formation of 1:1 metal(M)-HTCO complex in NB-phase. The formal formation constants of [PbHTCO]2+ and [CdHTCO]2+ complexes in NB-phase have been determined to be $ 10^{11.7±0.3} $ and $ 10^{7.9±0.3} $ $ M^{–1} $, respectively, using the formal potentials of non-assisted ion(M)-transfer at NB/W interface (DNWBfM0 ¢). The DNWBfM0 ¢’ s of $ Cd^{2+} $ and $ Pb^{2+} $ ions and $ Zn^{2+} $ and $ Tl^{+} $ ions as well have been determined on the basis of the tetraphenylarsonium-tetraphenylborate assumption and of the polarographic reversible half-wave potentials of the ions in NB- and W-media reported by previous authors. Voltammograms of $ Hg^{2+} $ and $ Pd^{2+} $ ions have been explained by that 1:1 M-HTCO complex is formed and soluble in both NB- and W-phases. The formal potentials of the transfer of [HgHTCO]2+ and [PdHTCO]2+ complex ions at NB/W interface have been determined. Voltammograms of $ Cu^{2+} $ ion are of irreversible nature. Voltammetry (dpeaa)DE-He213 polythiaether (dpeaa)DE-He213 assisted transfer (dpeaa)DE-He213 heavy metal ion (dpeaa)DE-He213 polarizable oil/water interface (dpeaa)DE-He213 Senda, Mitsugi aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 15(1999), 12 vom: Dez., Seite 1179-1184 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:15 year:1999 number:12 month:12 pages:1179-1184 https://dx.doi.org/10.2116/analsci.15.1179 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 15 1999 12 12 1179-1184
language	English
source	Enthalten in Analytical sciences 15(1999), 12 vom: Dez., Seite 1179-1184 volume:15 year:1999 number:12 month:12 pages:1179-1184
sourceStr	Enthalten in Analytical sciences 15(1999), 12 vom: Dez., Seite 1179-1184 volume:15 year:1999 number:12 month:12 pages:1179-1184
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Voltammetry polythiaether assisted transfer heavy metal ion polarizable oil/water interface
isfreeaccess_bool	false
container_title	Analytical sciences
authorswithroles_txt_mv	Katano, Hajime @@aut@@ Senda, Mitsugi @@aut@@
publishDateDaySort_date	1999-12-01T00:00:00Z
hierarchy_top_id	300895925
id	SPR047394676
language_de	englisch
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author	Katano, Hajime
spellingShingle	Katano, Hajime misc Voltammetry misc polythiaether misc assisted transfer misc heavy metal ion misc polarizable oil/water interface Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane
authorStr	Katano, Hajime
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topic_title	Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane Voltammetry (dpeaa)DE-He213 polythiaether (dpeaa)DE-He213 assisted transfer (dpeaa)DE-He213 heavy metal ion (dpeaa)DE-He213 polarizable oil/water interface (dpeaa)DE-He213
topic	misc Voltammetry misc polythiaether misc assisted transfer misc heavy metal ion misc polarizable oil/water interface
topic_unstemmed	misc Voltammetry misc polythiaether misc assisted transfer misc heavy metal ion misc polarizable oil/water interface
topic_browse	misc Voltammetry misc polythiaether misc assisted transfer misc heavy metal ion misc polarizable oil/water interface
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
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title	Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane
ctrlnum	(DE-627)SPR047394676 (SPR)analsci.15.1179-e
title_full	Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane
author_sort	Katano, Hajime
journal	Analytical sciences
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author_browse	Katano, Hajime Senda, Mitsugi
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author-letter	Katano, Hajime
doi_str_mv	10.2116/analsci.15.1179
title_sort	voltammetric study of the transfer of heavy metal ions at nitrobenzene/water interface assisted by 1,4,7,10,13,16-hexathiacyclooctadecane
title_auth	Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane
abstract	Abstract The transfer of $ Cd^{2+} $, $ Pb^{2+} $, $ Hg^{2+} $, $ Pd^{2+} $, and $ Cu^{2+} $ ions across polarized nitrobenzene/water (NB/W) interface assisted by 1,4,7,10,13,16-hexathiacyclooctadecane (HTCO) present in NB-phase has been studied by means of cyclic voltammetry. Voltammograms of $ Cd^{2+} $ and $ Pb^{2+} $ ions can be interpreted as being due to the reversible transfer of the ions assisted by the formation of 1:1 metal(M)-HTCO complex in NB-phase. The formal formation constants of [PbHTCO]2+ and [CdHTCO]2+ complexes in NB-phase have been determined to be $ 10^{11.7±0.3} $ and $ 10^{7.9±0.3} $ $ M^{–1} $, respectively, using the formal potentials of non-assisted ion(M)-transfer at NB/W interface (DNWBfM0 ¢). The DNWBfM0 ¢’ s of $ Cd^{2+} $ and $ Pb^{2+} $ ions and $ Zn^{2+} $ and $ Tl^{+} $ ions as well have been determined on the basis of the tetraphenylarsonium-tetraphenylborate assumption and of the polarographic reversible half-wave potentials of the ions in NB- and W-media reported by previous authors. Voltammograms of $ Hg^{2+} $ and $ Pd^{2+} $ ions have been explained by that 1:1 M-HTCO complex is formed and soluble in both NB- and W-phases. The formal potentials of the transfer of [HgHTCO]2+ and [PdHTCO]2+ complex ions at NB/W interface have been determined. Voltammograms of $ Cu^{2+} $ ion are of irreversible nature. © The Japan Society for Analytical Chemistry 1999
abstractGer	Abstract The transfer of $ Cd^{2+} $, $ Pb^{2+} $, $ Hg^{2+} $, $ Pd^{2+} $, and $ Cu^{2+} $ ions across polarized nitrobenzene/water (NB/W) interface assisted by 1,4,7,10,13,16-hexathiacyclooctadecane (HTCO) present in NB-phase has been studied by means of cyclic voltammetry. Voltammograms of $ Cd^{2+} $ and $ Pb^{2+} $ ions can be interpreted as being due to the reversible transfer of the ions assisted by the formation of 1:1 metal(M)-HTCO complex in NB-phase. The formal formation constants of [PbHTCO]2+ and [CdHTCO]2+ complexes in NB-phase have been determined to be $ 10^{11.7±0.3} $ and $ 10^{7.9±0.3} $ $ M^{–1} $, respectively, using the formal potentials of non-assisted ion(M)-transfer at NB/W interface (DNWBfM0 ¢). The DNWBfM0 ¢’ s of $ Cd^{2+} $ and $ Pb^{2+} $ ions and $ Zn^{2+} $ and $ Tl^{+} $ ions as well have been determined on the basis of the tetraphenylarsonium-tetraphenylborate assumption and of the polarographic reversible half-wave potentials of the ions in NB- and W-media reported by previous authors. Voltammograms of $ Hg^{2+} $ and $ Pd^{2+} $ ions have been explained by that 1:1 M-HTCO complex is formed and soluble in both NB- and W-phases. The formal potentials of the transfer of [HgHTCO]2+ and [PdHTCO]2+ complex ions at NB/W interface have been determined. Voltammograms of $ Cu^{2+} $ ion are of irreversible nature. © The Japan Society for Analytical Chemistry 1999
abstract_unstemmed	Abstract The transfer of $ Cd^{2+} $, $ Pb^{2+} $, $ Hg^{2+} $, $ Pd^{2+} $, and $ Cu^{2+} $ ions across polarized nitrobenzene/water (NB/W) interface assisted by 1,4,7,10,13,16-hexathiacyclooctadecane (HTCO) present in NB-phase has been studied by means of cyclic voltammetry. Voltammograms of $ Cd^{2+} $ and $ Pb^{2+} $ ions can be interpreted as being due to the reversible transfer of the ions assisted by the formation of 1:1 metal(M)-HTCO complex in NB-phase. The formal formation constants of [PbHTCO]2+ and [CdHTCO]2+ complexes in NB-phase have been determined to be $ 10^{11.7±0.3} $ and $ 10^{7.9±0.3} $ $ M^{–1} $, respectively, using the formal potentials of non-assisted ion(M)-transfer at NB/W interface (DNWBfM0 ¢). The DNWBfM0 ¢’ s of $ Cd^{2+} $ and $ Pb^{2+} $ ions and $ Zn^{2+} $ and $ Tl^{+} $ ions as well have been determined on the basis of the tetraphenylarsonium-tetraphenylborate assumption and of the polarographic reversible half-wave potentials of the ions in NB- and W-media reported by previous authors. Voltammograms of $ Hg^{2+} $ and $ Pd^{2+} $ ions have been explained by that 1:1 M-HTCO complex is formed and soluble in both NB- and W-phases. The formal potentials of the transfer of [HgHTCO]2+ and [PdHTCO]2+ complex ions at NB/W interface have been determined. Voltammograms of $ Cu^{2+} $ ion are of irreversible nature. © The Japan Society for Analytical Chemistry 1999
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container_issue	12
title_short	Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane
url	https://dx.doi.org/10.2116/analsci.15.1179
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up_date	2024-07-04T02:58:40.146Z
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Voltammograms of $ Cd^{2+} $ and $ Pb^{2+} $ ions can be interpreted as being due to the reversible transfer of the ions assisted by the formation of 1:1 metal(M)-HTCO complex in NB-phase. The formal formation constants of [PbHTCO]2+ and [CdHTCO]2+ complexes in NB-phase have been determined to be $ 10^{11.7±0.3} $ and $ 10^{7.9±0.3} $ $ M^{–1} $, respectively, using the formal potentials of non-assisted ion(M)-transfer at NB/W interface (DNWBfM0 ¢). The DNWBfM0 ¢’ s of $ Cd^{2+} $ and $ Pb^{2+} $ ions and $ Zn^{2+} $ and $ Tl^{+} $ ions as well have been determined on the basis of the tetraphenylarsonium-tetraphenylborate assumption and of the polarographic reversible half-wave potentials of the ions in NB- and W-media reported by previous authors. Voltammograms of $ Hg^{2+} $ and $ Pd^{2+} $ ions have been explained by that 1:1 M-HTCO complex is formed and soluble in both NB- and W-phases. The formal potentials of the transfer of [HgHTCO]2+ and [PdHTCO]2+ complex ions at NB/W interface have been determined. 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Voltammetric Study of the Transfer of Heavy Metal Ions at Nitrobenzene/Water Interface Assisted by 1,4,7,10,13,16-Hexathiacyclooctadecane

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