Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium
Abstract To investigate the effective separation of actinides (Ans) from lanthanides (Lns), single-stage batch extraction experiments were performed with a novel extractant, tetradodecyl-1,10-phenanthroline-2,9-diamide (TDdPTDA) with various diluents such as 3-nitrobenzotrifluoride (F-3), nitrobenze...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Tsutsui, Nao [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019 |
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| Schlagwörter: |
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| Anmerkung: |
© The Japan Society for Analytical Chemistry 2020 |
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| Übergeordnetes Werk: |
Enthalten in: Analytical sciences - [Cham] : Springer International Publishing, 1985, 36(2019), 2 vom: 27. Sept., Seite 241-245 |
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| Übergeordnetes Werk: |
volume:36 ; year:2019 ; number:2 ; day:27 ; month:09 ; pages:241-245 |
| Links: |
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| DOI / URN: |
10.2116/analsci.19P275 |
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| Katalog-ID: |
SPR047407662 |
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| 100 | 1 | |a Tsutsui, Nao |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium |
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| 520 | |a Abstract To investigate the effective separation of actinides (Ans) from lanthanides (Lns), single-stage batch extraction experiments were performed with a novel extractant, tetradodecyl-1,10-phenanthroline-2,9-diamide (TDdPTDA) with various diluents such as 3-nitrobenzotrifluoride (F-3), nitrobenzene, and n-dodecane for Am, Cm, and Lns. The extraction kinetics with TDdPTDA was rapid enough to perform continuous extraction experiments using mixer-settler extractors. The slopes of the distribution ratio versus the TDdPTDA concentration and the distribution ratio versus the nitric acid concentration were similar for F-3 and nitrobenzene systems, but different from the n-dodecane system. These differences were attributed to the characteristics of the diluents. This study revealed high distribution ratios of Am ($ D_{Am} $) and Cm ($ D_{Cm} $) for TDdPTDA, with the high separation factors (SFs) of Am from Lns enough for their separation. | ||
| 650 | 4 | |a Partitioning |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a 1,10-phenanthroline-2,9-dicarboxamide |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a minor actinide |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a americium |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a curium |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a lanthanide |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a solvent extraction |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a distribution ratio |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a separation factor |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Ban, Yasutoshi |4 aut | |
| 700 | 1 | |a Suzuki, Hideya |4 aut | |
| 700 | 1 | |a Nakase, Masahiko |4 aut | |
| 700 | 1 | |a Ito, Sayumi |4 aut | |
| 700 | 1 | |a Inaba, Yusuke |4 aut | |
| 700 | 1 | |a Matsumura, Tatsuro |4 aut | |
| 700 | 1 | |a Takeshita, Kenji |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Analytical sciences |d [Cham] : Springer International Publishing, 1985 |g 36(2019), 2 vom: 27. Sept., Seite 241-245 |w (DE-627)300895925 |w (DE-600)1483376-1 |x 1348-2246 |7 nnns |
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10.2116/analsci.19P275 doi (DE-627)SPR047407662 (SPR)analsci.19P275-e DE-627 ger DE-627 rakwb eng Tsutsui, Nao verfasserin aut Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 2020 Abstract To investigate the effective separation of actinides (Ans) from lanthanides (Lns), single-stage batch extraction experiments were performed with a novel extractant, tetradodecyl-1,10-phenanthroline-2,9-diamide (TDdPTDA) with various diluents such as 3-nitrobenzotrifluoride (F-3), nitrobenzene, and n-dodecane for Am, Cm, and Lns. The extraction kinetics with TDdPTDA was rapid enough to perform continuous extraction experiments using mixer-settler extractors. The slopes of the distribution ratio versus the TDdPTDA concentration and the distribution ratio versus the nitric acid concentration were similar for F-3 and nitrobenzene systems, but different from the n-dodecane system. These differences were attributed to the characteristics of the diluents. This study revealed high distribution ratios of Am ($ D_{Am} $) and Cm ($ D_{Cm} $) for TDdPTDA, with the high separation factors (SFs) of Am from Lns enough for their separation. Partitioning (dpeaa)DE-He213 1,10-phenanthroline-2,9-dicarboxamide (dpeaa)DE-He213 minor actinide (dpeaa)DE-He213 americium (dpeaa)DE-He213 curium (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 solvent extraction (dpeaa)DE-He213 distribution ratio (dpeaa)DE-He213 separation factor (dpeaa)DE-He213 Ban, Yasutoshi aut Suzuki, Hideya aut Nakase, Masahiko aut Ito, Sayumi aut Inaba, Yusuke aut Matsumura, Tatsuro aut Takeshita, Kenji aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 36(2019), 2 vom: 27. Sept., Seite 241-245 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:36 year:2019 number:2 day:27 month:09 pages:241-245 https://dx.doi.org/10.2116/analsci.19P275 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 36 2019 2 27 09 241-245 |
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10.2116/analsci.19P275 doi (DE-627)SPR047407662 (SPR)analsci.19P275-e DE-627 ger DE-627 rakwb eng Tsutsui, Nao verfasserin aut Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 2020 Abstract To investigate the effective separation of actinides (Ans) from lanthanides (Lns), single-stage batch extraction experiments were performed with a novel extractant, tetradodecyl-1,10-phenanthroline-2,9-diamide (TDdPTDA) with various diluents such as 3-nitrobenzotrifluoride (F-3), nitrobenzene, and n-dodecane for Am, Cm, and Lns. The extraction kinetics with TDdPTDA was rapid enough to perform continuous extraction experiments using mixer-settler extractors. The slopes of the distribution ratio versus the TDdPTDA concentration and the distribution ratio versus the nitric acid concentration were similar for F-3 and nitrobenzene systems, but different from the n-dodecane system. These differences were attributed to the characteristics of the diluents. This study revealed high distribution ratios of Am ($ D_{Am} $) and Cm ($ D_{Cm} $) for TDdPTDA, with the high separation factors (SFs) of Am from Lns enough for their separation. Partitioning (dpeaa)DE-He213 1,10-phenanthroline-2,9-dicarboxamide (dpeaa)DE-He213 minor actinide (dpeaa)DE-He213 americium (dpeaa)DE-He213 curium (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 solvent extraction (dpeaa)DE-He213 distribution ratio (dpeaa)DE-He213 separation factor (dpeaa)DE-He213 Ban, Yasutoshi aut Suzuki, Hideya aut Nakase, Masahiko aut Ito, Sayumi aut Inaba, Yusuke aut Matsumura, Tatsuro aut Takeshita, Kenji aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 36(2019), 2 vom: 27. Sept., Seite 241-245 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:36 year:2019 number:2 day:27 month:09 pages:241-245 https://dx.doi.org/10.2116/analsci.19P275 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 36 2019 2 27 09 241-245 |
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10.2116/analsci.19P275 doi (DE-627)SPR047407662 (SPR)analsci.19P275-e DE-627 ger DE-627 rakwb eng Tsutsui, Nao verfasserin aut Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 2020 Abstract To investigate the effective separation of actinides (Ans) from lanthanides (Lns), single-stage batch extraction experiments were performed with a novel extractant, tetradodecyl-1,10-phenanthroline-2,9-diamide (TDdPTDA) with various diluents such as 3-nitrobenzotrifluoride (F-3), nitrobenzene, and n-dodecane for Am, Cm, and Lns. The extraction kinetics with TDdPTDA was rapid enough to perform continuous extraction experiments using mixer-settler extractors. The slopes of the distribution ratio versus the TDdPTDA concentration and the distribution ratio versus the nitric acid concentration were similar for F-3 and nitrobenzene systems, but different from the n-dodecane system. These differences were attributed to the characteristics of the diluents. This study revealed high distribution ratios of Am ($ D_{Am} $) and Cm ($ D_{Cm} $) for TDdPTDA, with the high separation factors (SFs) of Am from Lns enough for their separation. Partitioning (dpeaa)DE-He213 1,10-phenanthroline-2,9-dicarboxamide (dpeaa)DE-He213 minor actinide (dpeaa)DE-He213 americium (dpeaa)DE-He213 curium (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 solvent extraction (dpeaa)DE-He213 distribution ratio (dpeaa)DE-He213 separation factor (dpeaa)DE-He213 Ban, Yasutoshi aut Suzuki, Hideya aut Nakase, Masahiko aut Ito, Sayumi aut Inaba, Yusuke aut Matsumura, Tatsuro aut Takeshita, Kenji aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 36(2019), 2 vom: 27. Sept., Seite 241-245 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:36 year:2019 number:2 day:27 month:09 pages:241-245 https://dx.doi.org/10.2116/analsci.19P275 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 36 2019 2 27 09 241-245 |
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10.2116/analsci.19P275 doi (DE-627)SPR047407662 (SPR)analsci.19P275-e DE-627 ger DE-627 rakwb eng Tsutsui, Nao verfasserin aut Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 2020 Abstract To investigate the effective separation of actinides (Ans) from lanthanides (Lns), single-stage batch extraction experiments were performed with a novel extractant, tetradodecyl-1,10-phenanthroline-2,9-diamide (TDdPTDA) with various diluents such as 3-nitrobenzotrifluoride (F-3), nitrobenzene, and n-dodecane for Am, Cm, and Lns. The extraction kinetics with TDdPTDA was rapid enough to perform continuous extraction experiments using mixer-settler extractors. The slopes of the distribution ratio versus the TDdPTDA concentration and the distribution ratio versus the nitric acid concentration were similar for F-3 and nitrobenzene systems, but different from the n-dodecane system. These differences were attributed to the characteristics of the diluents. This study revealed high distribution ratios of Am ($ D_{Am} $) and Cm ($ D_{Cm} $) for TDdPTDA, with the high separation factors (SFs) of Am from Lns enough for their separation. Partitioning (dpeaa)DE-He213 1,10-phenanthroline-2,9-dicarboxamide (dpeaa)DE-He213 minor actinide (dpeaa)DE-He213 americium (dpeaa)DE-He213 curium (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 solvent extraction (dpeaa)DE-He213 distribution ratio (dpeaa)DE-He213 separation factor (dpeaa)DE-He213 Ban, Yasutoshi aut Suzuki, Hideya aut Nakase, Masahiko aut Ito, Sayumi aut Inaba, Yusuke aut Matsumura, Tatsuro aut Takeshita, Kenji aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 36(2019), 2 vom: 27. Sept., Seite 241-245 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:36 year:2019 number:2 day:27 month:09 pages:241-245 https://dx.doi.org/10.2116/analsci.19P275 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 36 2019 2 27 09 241-245 |
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10.2116/analsci.19P275 doi (DE-627)SPR047407662 (SPR)analsci.19P275-e DE-627 ger DE-627 rakwb eng Tsutsui, Nao verfasserin aut Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 2020 Abstract To investigate the effective separation of actinides (Ans) from lanthanides (Lns), single-stage batch extraction experiments were performed with a novel extractant, tetradodecyl-1,10-phenanthroline-2,9-diamide (TDdPTDA) with various diluents such as 3-nitrobenzotrifluoride (F-3), nitrobenzene, and n-dodecane for Am, Cm, and Lns. The extraction kinetics with TDdPTDA was rapid enough to perform continuous extraction experiments using mixer-settler extractors. The slopes of the distribution ratio versus the TDdPTDA concentration and the distribution ratio versus the nitric acid concentration were similar for F-3 and nitrobenzene systems, but different from the n-dodecane system. These differences were attributed to the characteristics of the diluents. This study revealed high distribution ratios of Am ($ D_{Am} $) and Cm ($ D_{Cm} $) for TDdPTDA, with the high separation factors (SFs) of Am from Lns enough for their separation. Partitioning (dpeaa)DE-He213 1,10-phenanthroline-2,9-dicarboxamide (dpeaa)DE-He213 minor actinide (dpeaa)DE-He213 americium (dpeaa)DE-He213 curium (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 solvent extraction (dpeaa)DE-He213 distribution ratio (dpeaa)DE-He213 separation factor (dpeaa)DE-He213 Ban, Yasutoshi aut Suzuki, Hideya aut Nakase, Masahiko aut Ito, Sayumi aut Inaba, Yusuke aut Matsumura, Tatsuro aut Takeshita, Kenji aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 36(2019), 2 vom: 27. Sept., Seite 241-245 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:36 year:2019 number:2 day:27 month:09 pages:241-245 https://dx.doi.org/10.2116/analsci.19P275 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2360 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 36 2019 2 27 09 241-245 |
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Enthalten in Analytical sciences 36(2019), 2 vom: 27. Sept., Seite 241-245 volume:36 year:2019 number:2 day:27 month:09 pages:241-245 |
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Partitioning 1,10-phenanthroline-2,9-dicarboxamide minor actinide americium curium lanthanide solvent extraction distribution ratio separation factor |
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Tsutsui, Nao @@aut@@ Ban, Yasutoshi @@aut@@ Suzuki, Hideya @@aut@@ Nakase, Masahiko @@aut@@ Ito, Sayumi @@aut@@ Inaba, Yusuke @@aut@@ Matsumura, Tatsuro @@aut@@ Takeshita, Kenji @@aut@@ |
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The extraction kinetics with TDdPTDA was rapid enough to perform continuous extraction experiments using mixer-settler extractors. The slopes of the distribution ratio versus the TDdPTDA concentration and the distribution ratio versus the nitric acid concentration were similar for F-3 and nitrobenzene systems, but different from the n-dodecane system. These differences were attributed to the characteristics of the diluents. 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Tsutsui, Nao |
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Tsutsui, Nao misc Partitioning misc 1,10-phenanthroline-2,9-dicarboxamide misc minor actinide misc americium misc curium misc lanthanide misc solvent extraction misc distribution ratio misc separation factor Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium |
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Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium Partitioning (dpeaa)DE-He213 1,10-phenanthroline-2,9-dicarboxamide (dpeaa)DE-He213 minor actinide (dpeaa)DE-He213 americium (dpeaa)DE-He213 curium (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 solvent extraction (dpeaa)DE-He213 distribution ratio (dpeaa)DE-He213 separation factor (dpeaa)DE-He213 |
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misc Partitioning misc 1,10-phenanthroline-2,9-dicarboxamide misc minor actinide misc americium misc curium misc lanthanide misc solvent extraction misc distribution ratio misc separation factor |
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misc Partitioning misc 1,10-phenanthroline-2,9-dicarboxamide misc minor actinide misc americium misc curium misc lanthanide misc solvent extraction misc distribution ratio misc separation factor |
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Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium |
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(DE-627)SPR047407662 (SPR)analsci.19P275-e |
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Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium |
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Tsutsui, Nao |
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Tsutsui, Nao Ban, Yasutoshi Suzuki, Hideya Nakase, Masahiko Ito, Sayumi Inaba, Yusuke Matsumura, Tatsuro Takeshita, Kenji |
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Tsutsui, Nao |
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10.2116/analsci.19P275 |
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effects of diluents on the separation of minor actinides from lanthanides with tetradodecyl-1,10-phenanthroline-2,9-diamide from nitric acid medium |
| title_auth |
Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium |
| abstract |
Abstract To investigate the effective separation of actinides (Ans) from lanthanides (Lns), single-stage batch extraction experiments were performed with a novel extractant, tetradodecyl-1,10-phenanthroline-2,9-diamide (TDdPTDA) with various diluents such as 3-nitrobenzotrifluoride (F-3), nitrobenzene, and n-dodecane for Am, Cm, and Lns. The extraction kinetics with TDdPTDA was rapid enough to perform continuous extraction experiments using mixer-settler extractors. The slopes of the distribution ratio versus the TDdPTDA concentration and the distribution ratio versus the nitric acid concentration were similar for F-3 and nitrobenzene systems, but different from the n-dodecane system. These differences were attributed to the characteristics of the diluents. This study revealed high distribution ratios of Am ($ D_{Am} $) and Cm ($ D_{Cm} $) for TDdPTDA, with the high separation factors (SFs) of Am from Lns enough for their separation. © The Japan Society for Analytical Chemistry 2020 |
| abstractGer |
Abstract To investigate the effective separation of actinides (Ans) from lanthanides (Lns), single-stage batch extraction experiments were performed with a novel extractant, tetradodecyl-1,10-phenanthroline-2,9-diamide (TDdPTDA) with various diluents such as 3-nitrobenzotrifluoride (F-3), nitrobenzene, and n-dodecane for Am, Cm, and Lns. The extraction kinetics with TDdPTDA was rapid enough to perform continuous extraction experiments using mixer-settler extractors. The slopes of the distribution ratio versus the TDdPTDA concentration and the distribution ratio versus the nitric acid concentration were similar for F-3 and nitrobenzene systems, but different from the n-dodecane system. These differences were attributed to the characteristics of the diluents. This study revealed high distribution ratios of Am ($ D_{Am} $) and Cm ($ D_{Cm} $) for TDdPTDA, with the high separation factors (SFs) of Am from Lns enough for their separation. © The Japan Society for Analytical Chemistry 2020 |
| abstract_unstemmed |
Abstract To investigate the effective separation of actinides (Ans) from lanthanides (Lns), single-stage batch extraction experiments were performed with a novel extractant, tetradodecyl-1,10-phenanthroline-2,9-diamide (TDdPTDA) with various diluents such as 3-nitrobenzotrifluoride (F-3), nitrobenzene, and n-dodecane for Am, Cm, and Lns. The extraction kinetics with TDdPTDA was rapid enough to perform continuous extraction experiments using mixer-settler extractors. The slopes of the distribution ratio versus the TDdPTDA concentration and the distribution ratio versus the nitric acid concentration were similar for F-3 and nitrobenzene systems, but different from the n-dodecane system. These differences were attributed to the characteristics of the diluents. This study revealed high distribution ratios of Am ($ D_{Am} $) and Cm ($ D_{Cm} $) for TDdPTDA, with the high separation factors (SFs) of Am from Lns enough for their separation. © The Japan Society for Analytical Chemistry 2020 |
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2 |
| title_short |
Effects of Diluents on the Separation of Minor Actinides from Lanthanides with Tetradodecyl-1,10-phenanthroline-2,9-diamide from Nitric Acid Medium |
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https://dx.doi.org/10.2116/analsci.19P275 |
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true |
| author2 |
Ban, Yasutoshi Suzuki, Hideya Nakase, Masahiko Ito, Sayumi Inaba, Yusuke Matsumura, Tatsuro Takeshita, Kenji |
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Ban, Yasutoshi Suzuki, Hideya Nakase, Masahiko Ito, Sayumi Inaba, Yusuke Matsumura, Tatsuro Takeshita, Kenji |
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| doi_str |
10.2116/analsci.19P275 |
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2024-07-04T03:01:18.714Z |
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| score |
7.3995914 |