The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction
Abstract Nowadays, tremendous effort has been made in searching clean, high-efficient and sustainable energy, and related energy conversion methods. Oxygen reduction reaction (ORR), as one of the fundamental reactions for energy utilization, has drawn a lot of attention. Understanding the reaction p...
Ausführliche Beschreibung
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Tao, Keyu [verfasserIn] |
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Englisch |
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2022 |
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© The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022 |
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Übergeordnetes Werk: |
Enthalten in: Journal of solid state electrochemistry - Berlin : Springer, 1997, 26(2022), 8 vom: 09. Juni, Seite 1693-1702 |
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Übergeordnetes Werk: |
volume:26 ; year:2022 ; number:8 ; day:09 ; month:06 ; pages:1693-1702 |
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DOI / URN: |
10.1007/s10008-022-05209-8 |
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SPR047550538 |
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245 | 1 | 4 | |a The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction |
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520 | |a Abstract Nowadays, tremendous effort has been made in searching clean, high-efficient and sustainable energy, and related energy conversion methods. Oxygen reduction reaction (ORR), as one of the fundamental reactions for energy utilization, has drawn a lot of attention. Understanding the reaction process and exploring the active sites are extremely important for designing new catalysts and improving the catalytic ability. In this paper, the interdigitated array (IDA) electrodes, which show high collection efficiency and sensitivity, are proposed to explore the catalytic ability and the reaction process. With this special tool, the in situ preparation of nitrogen-doped carbon (N/C) has been realized with the pyrolysis of polyaniline (PANI) on the IDA electrodes directly. Two things should be noticed: First, this method can be used as a simple way to obtain the N/C and be used as a potential substitution catalyst for the noble metal towards the ORR for its low cost and relatively high activity; Second, the in situ preparation of catalyst on the electrode surface largely eliminated the possible electron transfer barrier between the catalyst and the electrode surface, and the high collection efficiency of the IDA electrodes ensures the detection of species with low concentration or short lifetime, therefore, the sensitivity of detection is largely improved. It demonstrates that the polyaniline-derived N/C was successfully synthesized on the micron-sized electrode surface with precise control of boundaries. The electron transfer number and corresponding percentage yield of $ H_{2} %$ O_{2} $ were detected and calculated in real time. The catalyst prepared with 700 °C shows the highest electron transfer numbers in the reaction process and the lowest percentage yield of $ H_{2} %$ O_{2} $. The content of the pyridinic nitrogen may play a crucial role in catalyzing the ORR. The idea of in situ synthetization and investigation of reaction process with IDA electrodes can be applied to study other catalytic reactions and explore the catalytic reaction process as well. | ||
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10.1007/s10008-022-05209-8 doi (DE-627)SPR047550538 (SPR)s10008-022-05209-8-e DE-627 ger DE-627 rakwb eng Tao, Keyu verfasserin aut The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022 Abstract Nowadays, tremendous effort has been made in searching clean, high-efficient and sustainable energy, and related energy conversion methods. Oxygen reduction reaction (ORR), as one of the fundamental reactions for energy utilization, has drawn a lot of attention. Understanding the reaction process and exploring the active sites are extremely important for designing new catalysts and improving the catalytic ability. In this paper, the interdigitated array (IDA) electrodes, which show high collection efficiency and sensitivity, are proposed to explore the catalytic ability and the reaction process. With this special tool, the in situ preparation of nitrogen-doped carbon (N/C) has been realized with the pyrolysis of polyaniline (PANI) on the IDA electrodes directly. Two things should be noticed: First, this method can be used as a simple way to obtain the N/C and be used as a potential substitution catalyst for the noble metal towards the ORR for its low cost and relatively high activity; Second, the in situ preparation of catalyst on the electrode surface largely eliminated the possible electron transfer barrier between the catalyst and the electrode surface, and the high collection efficiency of the IDA electrodes ensures the detection of species with low concentration or short lifetime, therefore, the sensitivity of detection is largely improved. It demonstrates that the polyaniline-derived N/C was successfully synthesized on the micron-sized electrode surface with precise control of boundaries. The electron transfer number and corresponding percentage yield of $ H_{2} %$ O_{2} $ were detected and calculated in real time. The catalyst prepared with 700 °C shows the highest electron transfer numbers in the reaction process and the lowest percentage yield of $ H_{2} %$ O_{2} $. The content of the pyridinic nitrogen may play a crucial role in catalyzing the ORR. The idea of in situ synthetization and investigation of reaction process with IDA electrodes can be applied to study other catalytic reactions and explore the catalytic reaction process as well. Polyaniline (dpeaa)DE-He213 Interdigitated array electrodes (dpeaa)DE-He213 Oxygen reduction reaction (dpeaa)DE-He213 Hao, Yanan aut He, Xinyu aut Liang, Yanping aut Liu, Fei (orcid)0000-0001-9550-759X aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 26(2022), 8 vom: 09. Juni, Seite 1693-1702 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:26 year:2022 number:8 day:09 month:06 pages:1693-1702 https://dx.doi.org/10.1007/s10008-022-05209-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 26 2022 8 09 06 1693-1702 |
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10.1007/s10008-022-05209-8 doi (DE-627)SPR047550538 (SPR)s10008-022-05209-8-e DE-627 ger DE-627 rakwb eng Tao, Keyu verfasserin aut The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022 Abstract Nowadays, tremendous effort has been made in searching clean, high-efficient and sustainable energy, and related energy conversion methods. Oxygen reduction reaction (ORR), as one of the fundamental reactions for energy utilization, has drawn a lot of attention. Understanding the reaction process and exploring the active sites are extremely important for designing new catalysts and improving the catalytic ability. In this paper, the interdigitated array (IDA) electrodes, which show high collection efficiency and sensitivity, are proposed to explore the catalytic ability and the reaction process. With this special tool, the in situ preparation of nitrogen-doped carbon (N/C) has been realized with the pyrolysis of polyaniline (PANI) on the IDA electrodes directly. Two things should be noticed: First, this method can be used as a simple way to obtain the N/C and be used as a potential substitution catalyst for the noble metal towards the ORR for its low cost and relatively high activity; Second, the in situ preparation of catalyst on the electrode surface largely eliminated the possible electron transfer barrier between the catalyst and the electrode surface, and the high collection efficiency of the IDA electrodes ensures the detection of species with low concentration or short lifetime, therefore, the sensitivity of detection is largely improved. It demonstrates that the polyaniline-derived N/C was successfully synthesized on the micron-sized electrode surface with precise control of boundaries. The electron transfer number and corresponding percentage yield of $ H_{2} %$ O_{2} $ were detected and calculated in real time. The catalyst prepared with 700 °C shows the highest electron transfer numbers in the reaction process and the lowest percentage yield of $ H_{2} %$ O_{2} $. The content of the pyridinic nitrogen may play a crucial role in catalyzing the ORR. The idea of in situ synthetization and investigation of reaction process with IDA electrodes can be applied to study other catalytic reactions and explore the catalytic reaction process as well. Polyaniline (dpeaa)DE-He213 Interdigitated array electrodes (dpeaa)DE-He213 Oxygen reduction reaction (dpeaa)DE-He213 Hao, Yanan aut He, Xinyu aut Liang, Yanping aut Liu, Fei (orcid)0000-0001-9550-759X aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 26(2022), 8 vom: 09. Juni, Seite 1693-1702 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:26 year:2022 number:8 day:09 month:06 pages:1693-1702 https://dx.doi.org/10.1007/s10008-022-05209-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 26 2022 8 09 06 1693-1702 |
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10.1007/s10008-022-05209-8 doi (DE-627)SPR047550538 (SPR)s10008-022-05209-8-e DE-627 ger DE-627 rakwb eng Tao, Keyu verfasserin aut The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022 Abstract Nowadays, tremendous effort has been made in searching clean, high-efficient and sustainable energy, and related energy conversion methods. Oxygen reduction reaction (ORR), as one of the fundamental reactions for energy utilization, has drawn a lot of attention. Understanding the reaction process and exploring the active sites are extremely important for designing new catalysts and improving the catalytic ability. In this paper, the interdigitated array (IDA) electrodes, which show high collection efficiency and sensitivity, are proposed to explore the catalytic ability and the reaction process. With this special tool, the in situ preparation of nitrogen-doped carbon (N/C) has been realized with the pyrolysis of polyaniline (PANI) on the IDA electrodes directly. Two things should be noticed: First, this method can be used as a simple way to obtain the N/C and be used as a potential substitution catalyst for the noble metal towards the ORR for its low cost and relatively high activity; Second, the in situ preparation of catalyst on the electrode surface largely eliminated the possible electron transfer barrier between the catalyst and the electrode surface, and the high collection efficiency of the IDA electrodes ensures the detection of species with low concentration or short lifetime, therefore, the sensitivity of detection is largely improved. It demonstrates that the polyaniline-derived N/C was successfully synthesized on the micron-sized electrode surface with precise control of boundaries. The electron transfer number and corresponding percentage yield of $ H_{2} %$ O_{2} $ were detected and calculated in real time. The catalyst prepared with 700 °C shows the highest electron transfer numbers in the reaction process and the lowest percentage yield of $ H_{2} %$ O_{2} $. The content of the pyridinic nitrogen may play a crucial role in catalyzing the ORR. The idea of in situ synthetization and investigation of reaction process with IDA electrodes can be applied to study other catalytic reactions and explore the catalytic reaction process as well. Polyaniline (dpeaa)DE-He213 Interdigitated array electrodes (dpeaa)DE-He213 Oxygen reduction reaction (dpeaa)DE-He213 Hao, Yanan aut He, Xinyu aut Liang, Yanping aut Liu, Fei (orcid)0000-0001-9550-759X aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 26(2022), 8 vom: 09. Juni, Seite 1693-1702 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:26 year:2022 number:8 day:09 month:06 pages:1693-1702 https://dx.doi.org/10.1007/s10008-022-05209-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 26 2022 8 09 06 1693-1702 |
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10.1007/s10008-022-05209-8 doi (DE-627)SPR047550538 (SPR)s10008-022-05209-8-e DE-627 ger DE-627 rakwb eng Tao, Keyu verfasserin aut The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022 Abstract Nowadays, tremendous effort has been made in searching clean, high-efficient and sustainable energy, and related energy conversion methods. Oxygen reduction reaction (ORR), as one of the fundamental reactions for energy utilization, has drawn a lot of attention. Understanding the reaction process and exploring the active sites are extremely important for designing new catalysts and improving the catalytic ability. In this paper, the interdigitated array (IDA) electrodes, which show high collection efficiency and sensitivity, are proposed to explore the catalytic ability and the reaction process. With this special tool, the in situ preparation of nitrogen-doped carbon (N/C) has been realized with the pyrolysis of polyaniline (PANI) on the IDA electrodes directly. Two things should be noticed: First, this method can be used as a simple way to obtain the N/C and be used as a potential substitution catalyst for the noble metal towards the ORR for its low cost and relatively high activity; Second, the in situ preparation of catalyst on the electrode surface largely eliminated the possible electron transfer barrier between the catalyst and the electrode surface, and the high collection efficiency of the IDA electrodes ensures the detection of species with low concentration or short lifetime, therefore, the sensitivity of detection is largely improved. It demonstrates that the polyaniline-derived N/C was successfully synthesized on the micron-sized electrode surface with precise control of boundaries. The electron transfer number and corresponding percentage yield of $ H_{2} %$ O_{2} $ were detected and calculated in real time. The catalyst prepared with 700 °C shows the highest electron transfer numbers in the reaction process and the lowest percentage yield of $ H_{2} %$ O_{2} $. The content of the pyridinic nitrogen may play a crucial role in catalyzing the ORR. The idea of in situ synthetization and investigation of reaction process with IDA electrodes can be applied to study other catalytic reactions and explore the catalytic reaction process as well. Polyaniline (dpeaa)DE-He213 Interdigitated array electrodes (dpeaa)DE-He213 Oxygen reduction reaction (dpeaa)DE-He213 Hao, Yanan aut He, Xinyu aut Liang, Yanping aut Liu, Fei (orcid)0000-0001-9550-759X aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 26(2022), 8 vom: 09. Juni, Seite 1693-1702 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:26 year:2022 number:8 day:09 month:06 pages:1693-1702 https://dx.doi.org/10.1007/s10008-022-05209-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 26 2022 8 09 06 1693-1702 |
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10.1007/s10008-022-05209-8 doi (DE-627)SPR047550538 (SPR)s10008-022-05209-8-e DE-627 ger DE-627 rakwb eng Tao, Keyu verfasserin aut The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022 Abstract Nowadays, tremendous effort has been made in searching clean, high-efficient and sustainable energy, and related energy conversion methods. Oxygen reduction reaction (ORR), as one of the fundamental reactions for energy utilization, has drawn a lot of attention. Understanding the reaction process and exploring the active sites are extremely important for designing new catalysts and improving the catalytic ability. In this paper, the interdigitated array (IDA) electrodes, which show high collection efficiency and sensitivity, are proposed to explore the catalytic ability and the reaction process. With this special tool, the in situ preparation of nitrogen-doped carbon (N/C) has been realized with the pyrolysis of polyaniline (PANI) on the IDA electrodes directly. Two things should be noticed: First, this method can be used as a simple way to obtain the N/C and be used as a potential substitution catalyst for the noble metal towards the ORR for its low cost and relatively high activity; Second, the in situ preparation of catalyst on the electrode surface largely eliminated the possible electron transfer barrier between the catalyst and the electrode surface, and the high collection efficiency of the IDA electrodes ensures the detection of species with low concentration or short lifetime, therefore, the sensitivity of detection is largely improved. It demonstrates that the polyaniline-derived N/C was successfully synthesized on the micron-sized electrode surface with precise control of boundaries. The electron transfer number and corresponding percentage yield of $ H_{2} %$ O_{2} $ were detected and calculated in real time. The catalyst prepared with 700 °C shows the highest electron transfer numbers in the reaction process and the lowest percentage yield of $ H_{2} %$ O_{2} $. The content of the pyridinic nitrogen may play a crucial role in catalyzing the ORR. The idea of in situ synthetization and investigation of reaction process with IDA electrodes can be applied to study other catalytic reactions and explore the catalytic reaction process as well. Polyaniline (dpeaa)DE-He213 Interdigitated array electrodes (dpeaa)DE-He213 Oxygen reduction reaction (dpeaa)DE-He213 Hao, Yanan aut He, Xinyu aut Liang, Yanping aut Liu, Fei (orcid)0000-0001-9550-759X aut Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 26(2022), 8 vom: 09. Juni, Seite 1693-1702 (DE-627)271175400 (DE-600)1478940-1 1433-0768 nnns volume:26 year:2022 number:8 day:09 month:06 pages:1693-1702 https://dx.doi.org/10.1007/s10008-022-05209-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_267 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 26 2022 8 09 06 1693-1702 |
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Enthalten in Journal of solid state electrochemistry 26(2022), 8 vom: 09. Juni, Seite 1693-1702 volume:26 year:2022 number:8 day:09 month:06 pages:1693-1702 |
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Tao, Keyu @@aut@@ Hao, Yanan @@aut@@ He, Xinyu @@aut@@ Liang, Yanping @@aut@@ Liu, Fei @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR047550538</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230507231335.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">220713s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10008-022-05209-8</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR047550538</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s10008-022-05209-8-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Tao, Keyu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="4"><subfield code="a">The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Nowadays, tremendous effort has been made in searching clean, high-efficient and sustainable energy, and related energy conversion methods. Oxygen reduction reaction (ORR), as one of the fundamental reactions for energy utilization, has drawn a lot of attention. Understanding the reaction process and exploring the active sites are extremely important for designing new catalysts and improving the catalytic ability. In this paper, the interdigitated array (IDA) electrodes, which show high collection efficiency and sensitivity, are proposed to explore the catalytic ability and the reaction process. With this special tool, the in situ preparation of nitrogen-doped carbon (N/C) has been realized with the pyrolysis of polyaniline (PANI) on the IDA electrodes directly. Two things should be noticed: First, this method can be used as a simple way to obtain the N/C and be used as a potential substitution catalyst for the noble metal towards the ORR for its low cost and relatively high activity; Second, the in situ preparation of catalyst on the electrode surface largely eliminated the possible electron transfer barrier between the catalyst and the electrode surface, and the high collection efficiency of the IDA electrodes ensures the detection of species with low concentration or short lifetime, therefore, the sensitivity of detection is largely improved. It demonstrates that the polyaniline-derived N/C was successfully synthesized on the micron-sized electrode surface with precise control of boundaries. The electron transfer number and corresponding percentage yield of $ H_{2} %$ O_{2} $ were detected and calculated in real time. The catalyst prepared with 700 °C shows the highest electron transfer numbers in the reaction process and the lowest percentage yield of $ H_{2} %$ O_{2} $. The content of the pyridinic nitrogen may play a crucial role in catalyzing the ORR. 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Tao, Keyu |
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Tao, Keyu misc Polyaniline misc Interdigitated array electrodes misc Oxygen reduction reaction The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction |
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The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction Polyaniline (dpeaa)DE-He213 Interdigitated array electrodes (dpeaa)DE-He213 Oxygen reduction reaction (dpeaa)DE-He213 |
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misc Polyaniline misc Interdigitated array electrodes misc Oxygen reduction reaction |
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misc Polyaniline misc Interdigitated array electrodes misc Oxygen reduction reaction |
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The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction |
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The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction |
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Tao, Keyu |
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Tao, Keyu Hao, Yanan He, Xinyu Liang, Yanping Liu, Fei |
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in situ investigation of the polyaniline-derived n-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction |
title_auth |
The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction |
abstract |
Abstract Nowadays, tremendous effort has been made in searching clean, high-efficient and sustainable energy, and related energy conversion methods. Oxygen reduction reaction (ORR), as one of the fundamental reactions for energy utilization, has drawn a lot of attention. Understanding the reaction process and exploring the active sites are extremely important for designing new catalysts and improving the catalytic ability. In this paper, the interdigitated array (IDA) electrodes, which show high collection efficiency and sensitivity, are proposed to explore the catalytic ability and the reaction process. With this special tool, the in situ preparation of nitrogen-doped carbon (N/C) has been realized with the pyrolysis of polyaniline (PANI) on the IDA electrodes directly. Two things should be noticed: First, this method can be used as a simple way to obtain the N/C and be used as a potential substitution catalyst for the noble metal towards the ORR for its low cost and relatively high activity; Second, the in situ preparation of catalyst on the electrode surface largely eliminated the possible electron transfer barrier between the catalyst and the electrode surface, and the high collection efficiency of the IDA electrodes ensures the detection of species with low concentration or short lifetime, therefore, the sensitivity of detection is largely improved. It demonstrates that the polyaniline-derived N/C was successfully synthesized on the micron-sized electrode surface with precise control of boundaries. The electron transfer number and corresponding percentage yield of $ H_{2} %$ O_{2} $ were detected and calculated in real time. The catalyst prepared with 700 °C shows the highest electron transfer numbers in the reaction process and the lowest percentage yield of $ H_{2} %$ O_{2} $. The content of the pyridinic nitrogen may play a crucial role in catalyzing the ORR. The idea of in situ synthetization and investigation of reaction process with IDA electrodes can be applied to study other catalytic reactions and explore the catalytic reaction process as well. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022 |
abstractGer |
Abstract Nowadays, tremendous effort has been made in searching clean, high-efficient and sustainable energy, and related energy conversion methods. Oxygen reduction reaction (ORR), as one of the fundamental reactions for energy utilization, has drawn a lot of attention. Understanding the reaction process and exploring the active sites are extremely important for designing new catalysts and improving the catalytic ability. In this paper, the interdigitated array (IDA) electrodes, which show high collection efficiency and sensitivity, are proposed to explore the catalytic ability and the reaction process. With this special tool, the in situ preparation of nitrogen-doped carbon (N/C) has been realized with the pyrolysis of polyaniline (PANI) on the IDA electrodes directly. Two things should be noticed: First, this method can be used as a simple way to obtain the N/C and be used as a potential substitution catalyst for the noble metal towards the ORR for its low cost and relatively high activity; Second, the in situ preparation of catalyst on the electrode surface largely eliminated the possible electron transfer barrier between the catalyst and the electrode surface, and the high collection efficiency of the IDA electrodes ensures the detection of species with low concentration or short lifetime, therefore, the sensitivity of detection is largely improved. It demonstrates that the polyaniline-derived N/C was successfully synthesized on the micron-sized electrode surface with precise control of boundaries. The electron transfer number and corresponding percentage yield of $ H_{2} %$ O_{2} $ were detected and calculated in real time. The catalyst prepared with 700 °C shows the highest electron transfer numbers in the reaction process and the lowest percentage yield of $ H_{2} %$ O_{2} $. The content of the pyridinic nitrogen may play a crucial role in catalyzing the ORR. The idea of in situ synthetization and investigation of reaction process with IDA electrodes can be applied to study other catalytic reactions and explore the catalytic reaction process as well. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022 |
abstract_unstemmed |
Abstract Nowadays, tremendous effort has been made in searching clean, high-efficient and sustainable energy, and related energy conversion methods. Oxygen reduction reaction (ORR), as one of the fundamental reactions for energy utilization, has drawn a lot of attention. Understanding the reaction process and exploring the active sites are extremely important for designing new catalysts and improving the catalytic ability. In this paper, the interdigitated array (IDA) electrodes, which show high collection efficiency and sensitivity, are proposed to explore the catalytic ability and the reaction process. With this special tool, the in situ preparation of nitrogen-doped carbon (N/C) has been realized with the pyrolysis of polyaniline (PANI) on the IDA electrodes directly. Two things should be noticed: First, this method can be used as a simple way to obtain the N/C and be used as a potential substitution catalyst for the noble metal towards the ORR for its low cost and relatively high activity; Second, the in situ preparation of catalyst on the electrode surface largely eliminated the possible electron transfer barrier between the catalyst and the electrode surface, and the high collection efficiency of the IDA electrodes ensures the detection of species with low concentration or short lifetime, therefore, the sensitivity of detection is largely improved. It demonstrates that the polyaniline-derived N/C was successfully synthesized on the micron-sized electrode surface with precise control of boundaries. The electron transfer number and corresponding percentage yield of $ H_{2} %$ O_{2} $ were detected and calculated in real time. The catalyst prepared with 700 °C shows the highest electron transfer numbers in the reaction process and the lowest percentage yield of $ H_{2} %$ O_{2} $. The content of the pyridinic nitrogen may play a crucial role in catalyzing the ORR. The idea of in situ synthetization and investigation of reaction process with IDA electrodes can be applied to study other catalytic reactions and explore the catalytic reaction process as well. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022 |
collection_details |
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8 |
title_short |
The in situ investigation of the polyaniline-derived N-doped carbon with the interdigitated array electrodes towards the oxygen reduction reaction |
url |
https://dx.doi.org/10.1007/s10008-022-05209-8 |
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author2 |
Hao, Yanan He, Xinyu Liang, Yanping Liu, Fei |
author2Str |
Hao, Yanan He, Xinyu Liang, Yanping Liu, Fei |
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doi_str |
10.1007/s10008-022-05209-8 |
up_date |
2024-07-03T13:28:44.370Z |
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|
score |
7.399585 |