Sensitive Spectrophotometric Determination of Chromium with 2-(5-Chloro-2-pyridylazo)-5-dimethylaminophenol
Abstract The optimal conditions for the development of complexation reactions between Cr(III) and 2-(5-chloro-2-pyridylazo)-5-dimethylaminophenol (5.C1DMP AP) were studied. When a mixture of a hydroethanolic solution of the reagent and an aqueous solution of Cr(III) were heated, three different comp...
Ausführliche Beschreibung
Autor*in: |
Anton, Rosa [verfasserIn] |
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Englisch |
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1995 |
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Anmerkung: |
© The Japan Society for Analytical Chemistry 1995 |
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Übergeordnetes Werk: |
Enthalten in: Analytical sciences - [Cham] : Springer International Publishing, 1985, 11(1995), 3 vom: Juni, Seite 431-436 |
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Übergeordnetes Werk: |
volume:11 ; year:1995 ; number:3 ; month:06 ; pages:431-436 |
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DOI / URN: |
10.2116/analsci.11.431 |
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SPR047588977 |
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10.2116/analsci.11.431 doi (DE-627)SPR047588977 (SPR)analsci.11.431-e DE-627 ger DE-627 rakwb eng Anton, Rosa verfasserin aut Sensitive Spectrophotometric Determination of Chromium with 2-(5-Chloro-2-pyridylazo)-5-dimethylaminophenol 1995 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1995 Abstract The optimal conditions for the development of complexation reactions between Cr(III) and 2-(5-chloro-2-pyridylazo)-5-dimethylaminophenol (5.C1DMP AP) were studied. When a mixture of a hydroethanolic solution of the reagent and an aqueous solution of Cr(III) were heated, three different complex species were formed, depending on the composition and pH of the medium (ε=I.7× $ 10^{5} $1 $ mol^{-1} $ $ cm^{-1} $). All of them were hardly soluble when the proportion of organic solvent was low. The stoichiometry of the different complexes was determined, the formation mechanisms were elucidated and the respective constants were calculated. A useful absorptiometric method is proposed for Cr(III) in concentrations ranging from 15 to 400 ppb. The proper ways to reduce interferences produced by Fe(III), Nb<V), Ta(V), Ti(IV), V(V), Co(II), Zr(IV), Sn(II), A1(III), Mn(II) and Cu(II) are described. The methods were applied to chromium determination in water samples with very satisfactory results. Chromium (dpeaa)DE-He213 spectrophotometric determination (dpeaa)DE-He213 water sample (dpeaa)DE-He213 Marini, Héctor aut Olsina, Roberto aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 11(1995), 3 vom: Juni, Seite 431-436 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:11 year:1995 number:3 month:06 pages:431-436 https://dx.doi.org/10.2116/analsci.11.431 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_250 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 1995 3 06 431-436 |
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10.2116/analsci.11.431 doi (DE-627)SPR047588977 (SPR)analsci.11.431-e DE-627 ger DE-627 rakwb eng Anton, Rosa verfasserin aut Sensitive Spectrophotometric Determination of Chromium with 2-(5-Chloro-2-pyridylazo)-5-dimethylaminophenol 1995 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1995 Abstract The optimal conditions for the development of complexation reactions between Cr(III) and 2-(5-chloro-2-pyridylazo)-5-dimethylaminophenol (5.C1DMP AP) were studied. When a mixture of a hydroethanolic solution of the reagent and an aqueous solution of Cr(III) were heated, three different complex species were formed, depending on the composition and pH of the medium (ε=I.7× $ 10^{5} $1 $ mol^{-1} $ $ cm^{-1} $). All of them were hardly soluble when the proportion of organic solvent was low. The stoichiometry of the different complexes was determined, the formation mechanisms were elucidated and the respective constants were calculated. A useful absorptiometric method is proposed for Cr(III) in concentrations ranging from 15 to 400 ppb. The proper ways to reduce interferences produced by Fe(III), Nb<V), Ta(V), Ti(IV), V(V), Co(II), Zr(IV), Sn(II), A1(III), Mn(II) and Cu(II) are described. The methods were applied to chromium determination in water samples with very satisfactory results. Chromium (dpeaa)DE-He213 spectrophotometric determination (dpeaa)DE-He213 water sample (dpeaa)DE-He213 Marini, Héctor aut Olsina, Roberto aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 11(1995), 3 vom: Juni, Seite 431-436 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:11 year:1995 number:3 month:06 pages:431-436 https://dx.doi.org/10.2116/analsci.11.431 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_250 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 1995 3 06 431-436 |
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10.2116/analsci.11.431 doi (DE-627)SPR047588977 (SPR)analsci.11.431-e DE-627 ger DE-627 rakwb eng Anton, Rosa verfasserin aut Sensitive Spectrophotometric Determination of Chromium with 2-(5-Chloro-2-pyridylazo)-5-dimethylaminophenol 1995 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1995 Abstract The optimal conditions for the development of complexation reactions between Cr(III) and 2-(5-chloro-2-pyridylazo)-5-dimethylaminophenol (5.C1DMP AP) were studied. When a mixture of a hydroethanolic solution of the reagent and an aqueous solution of Cr(III) were heated, three different complex species were formed, depending on the composition and pH of the medium (ε=I.7× $ 10^{5} $1 $ mol^{-1} $ $ cm^{-1} $). All of them were hardly soluble when the proportion of organic solvent was low. The stoichiometry of the different complexes was determined, the formation mechanisms were elucidated and the respective constants were calculated. A useful absorptiometric method is proposed for Cr(III) in concentrations ranging from 15 to 400 ppb. The proper ways to reduce interferences produced by Fe(III), Nb<V), Ta(V), Ti(IV), V(V), Co(II), Zr(IV), Sn(II), A1(III), Mn(II) and Cu(II) are described. The methods were applied to chromium determination in water samples with very satisfactory results. Chromium (dpeaa)DE-He213 spectrophotometric determination (dpeaa)DE-He213 water sample (dpeaa)DE-He213 Marini, Héctor aut Olsina, Roberto aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 11(1995), 3 vom: Juni, Seite 431-436 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:11 year:1995 number:3 month:06 pages:431-436 https://dx.doi.org/10.2116/analsci.11.431 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_250 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 1995 3 06 431-436 |
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10.2116/analsci.11.431 doi (DE-627)SPR047588977 (SPR)analsci.11.431-e DE-627 ger DE-627 rakwb eng Anton, Rosa verfasserin aut Sensitive Spectrophotometric Determination of Chromium with 2-(5-Chloro-2-pyridylazo)-5-dimethylaminophenol 1995 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1995 Abstract The optimal conditions for the development of complexation reactions between Cr(III) and 2-(5-chloro-2-pyridylazo)-5-dimethylaminophenol (5.C1DMP AP) were studied. When a mixture of a hydroethanolic solution of the reagent and an aqueous solution of Cr(III) were heated, three different complex species were formed, depending on the composition and pH of the medium (ε=I.7× $ 10^{5} $1 $ mol^{-1} $ $ cm^{-1} $). All of them were hardly soluble when the proportion of organic solvent was low. The stoichiometry of the different complexes was determined, the formation mechanisms were elucidated and the respective constants were calculated. A useful absorptiometric method is proposed for Cr(III) in concentrations ranging from 15 to 400 ppb. The proper ways to reduce interferences produced by Fe(III), Nb<V), Ta(V), Ti(IV), V(V), Co(II), Zr(IV), Sn(II), A1(III), Mn(II) and Cu(II) are described. The methods were applied to chromium determination in water samples with very satisfactory results. Chromium (dpeaa)DE-He213 spectrophotometric determination (dpeaa)DE-He213 water sample (dpeaa)DE-He213 Marini, Héctor aut Olsina, Roberto aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 11(1995), 3 vom: Juni, Seite 431-436 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:11 year:1995 number:3 month:06 pages:431-436 https://dx.doi.org/10.2116/analsci.11.431 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_250 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 1995 3 06 431-436 |
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10.2116/analsci.11.431 doi (DE-627)SPR047588977 (SPR)analsci.11.431-e DE-627 ger DE-627 rakwb eng Anton, Rosa verfasserin aut Sensitive Spectrophotometric Determination of Chromium with 2-(5-Chloro-2-pyridylazo)-5-dimethylaminophenol 1995 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1995 Abstract The optimal conditions for the development of complexation reactions between Cr(III) and 2-(5-chloro-2-pyridylazo)-5-dimethylaminophenol (5.C1DMP AP) were studied. When a mixture of a hydroethanolic solution of the reagent and an aqueous solution of Cr(III) were heated, three different complex species were formed, depending on the composition and pH of the medium (ε=I.7× $ 10^{5} $1 $ mol^{-1} $ $ cm^{-1} $). All of them were hardly soluble when the proportion of organic solvent was low. The stoichiometry of the different complexes was determined, the formation mechanisms were elucidated and the respective constants were calculated. A useful absorptiometric method is proposed for Cr(III) in concentrations ranging from 15 to 400 ppb. The proper ways to reduce interferences produced by Fe(III), Nb<V), Ta(V), Ti(IV), V(V), Co(II), Zr(IV), Sn(II), A1(III), Mn(II) and Cu(II) are described. The methods were applied to chromium determination in water samples with very satisfactory results. Chromium (dpeaa)DE-He213 spectrophotometric determination (dpeaa)DE-He213 water sample (dpeaa)DE-He213 Marini, Héctor aut Olsina, Roberto aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 11(1995), 3 vom: Juni, Seite 431-436 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:11 year:1995 number:3 month:06 pages:431-436 https://dx.doi.org/10.2116/analsci.11.431 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_250 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 1995 3 06 431-436 |
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Sensitive Spectrophotometric Determination of Chromium with 2-(5-Chloro-2-pyridylazo)-5-dimethylaminophenol Chromium (dpeaa)DE-He213 spectrophotometric determination (dpeaa)DE-He213 water sample (dpeaa)DE-He213 |
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Sensitive Spectrophotometric Determination of Chromium with 2-(5-Chloro-2-pyridylazo)-5-dimethylaminophenol |
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Sensitive Spectrophotometric Determination of Chromium with 2-(5-Chloro-2-pyridylazo)-5-dimethylaminophenol |
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sensitive spectrophotometric determination of chromium with 2-(5-chloro-2-pyridylazo)-5-dimethylaminophenol |
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Sensitive Spectrophotometric Determination of Chromium with 2-(5-Chloro-2-pyridylazo)-5-dimethylaminophenol |
abstract |
Abstract The optimal conditions for the development of complexation reactions between Cr(III) and 2-(5-chloro-2-pyridylazo)-5-dimethylaminophenol (5.C1DMP AP) were studied. When a mixture of a hydroethanolic solution of the reagent and an aqueous solution of Cr(III) were heated, three different complex species were formed, depending on the composition and pH of the medium (ε=I.7× $ 10^{5} $1 $ mol^{-1} $ $ cm^{-1} $). All of them were hardly soluble when the proportion of organic solvent was low. The stoichiometry of the different complexes was determined, the formation mechanisms were elucidated and the respective constants were calculated. A useful absorptiometric method is proposed for Cr(III) in concentrations ranging from 15 to 400 ppb. The proper ways to reduce interferences produced by Fe(III), Nb<V), Ta(V), Ti(IV), V(V), Co(II), Zr(IV), Sn(II), A1(III), Mn(II) and Cu(II) are described. The methods were applied to chromium determination in water samples with very satisfactory results. © The Japan Society for Analytical Chemistry 1995 |
abstractGer |
Abstract The optimal conditions for the development of complexation reactions between Cr(III) and 2-(5-chloro-2-pyridylazo)-5-dimethylaminophenol (5.C1DMP AP) were studied. When a mixture of a hydroethanolic solution of the reagent and an aqueous solution of Cr(III) were heated, three different complex species were formed, depending on the composition and pH of the medium (ε=I.7× $ 10^{5} $1 $ mol^{-1} $ $ cm^{-1} $). All of them were hardly soluble when the proportion of organic solvent was low. The stoichiometry of the different complexes was determined, the formation mechanisms were elucidated and the respective constants were calculated. A useful absorptiometric method is proposed for Cr(III) in concentrations ranging from 15 to 400 ppb. The proper ways to reduce interferences produced by Fe(III), Nb<V), Ta(V), Ti(IV), V(V), Co(II), Zr(IV), Sn(II), A1(III), Mn(II) and Cu(II) are described. The methods were applied to chromium determination in water samples with very satisfactory results. © The Japan Society for Analytical Chemistry 1995 |
abstract_unstemmed |
Abstract The optimal conditions for the development of complexation reactions between Cr(III) and 2-(5-chloro-2-pyridylazo)-5-dimethylaminophenol (5.C1DMP AP) were studied. When a mixture of a hydroethanolic solution of the reagent and an aqueous solution of Cr(III) were heated, three different complex species were formed, depending on the composition and pH of the medium (ε=I.7× $ 10^{5} $1 $ mol^{-1} $ $ cm^{-1} $). All of them were hardly soluble when the proportion of organic solvent was low. The stoichiometry of the different complexes was determined, the formation mechanisms were elucidated and the respective constants were calculated. A useful absorptiometric method is proposed for Cr(III) in concentrations ranging from 15 to 400 ppb. The proper ways to reduce interferences produced by Fe(III), Nb<V), Ta(V), Ti(IV), V(V), Co(II), Zr(IV), Sn(II), A1(III), Mn(II) and Cu(II) are described. The methods were applied to chromium determination in water samples with very satisfactory results. © The Japan Society for Analytical Chemistry 1995 |
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Sensitive Spectrophotometric Determination of Chromium with 2-(5-Chloro-2-pyridylazo)-5-dimethylaminophenol |
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