Time-Resolved Resonance Raman Spectroscopy Using a Fast Mixing Device
Abstract A new fast mixing device has been developed. Our attention has been paid to improving the apparatus design in order to decrease the mixing dead time and to enhance the mixing efficiency. We modified and, mainly, simplified the system proposed by Clegg. The new device comprises two concentri...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Paeng, Ki-jung [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1994 |
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| Schlagwörter: |
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| Anmerkung: |
© The Japan Society for Analytical Chemistry 1994 |
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| Übergeordnetes Werk: |
Enthalten in: Analytical sciences - [Cham] : Springer International Publishing, 1985, 10(1994), 1 vom: Feb., Seite 157-159 |
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| Übergeordnetes Werk: |
volume:10 ; year:1994 ; number:1 ; month:02 ; pages:157-159 |
| Links: |
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| DOI / URN: |
10.2116/analsci.10.157 |
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| 520 | |a Abstract A new fast mixing device has been developed. Our attention has been paid to improving the apparatus design in order to decrease the mixing dead time and to enhance the mixing efficiency. We modified and, mainly, simplified the system proposed by Clegg. The new device comprises two concentric tubes and a platinum spherical ball with a single piece of Teflon used as a support housing. Mixing is thus performed by the induced turbulent flow which can be generated by forcing a liquid stream to flow through channels between a Pt ball and a glass wall. This device offers many advantages relative to conventional mixing devices. The 99% mixing time for the device has been found to be 30 - 80 μs, which is at least a factor of 10 faster than the older devices. This technique can be applied using any type of fast reaction, solvent or laser. The stability of the stream and the excellent reproducibility allow measurements of the rate constants of very fast reactions. | ||
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10.2116/analsci.10.157 doi (DE-627)SPR047607254 (SPR)analsci.10.157-e DE-627 ger DE-627 rakwb eng Paeng, Ki-jung verfasserin aut Time-Resolved Resonance Raman Spectroscopy Using a Fast Mixing Device 1994 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1994 Abstract A new fast mixing device has been developed. Our attention has been paid to improving the apparatus design in order to decrease the mixing dead time and to enhance the mixing efficiency. We modified and, mainly, simplified the system proposed by Clegg. The new device comprises two concentric tubes and a platinum spherical ball with a single piece of Teflon used as a support housing. Mixing is thus performed by the induced turbulent flow which can be generated by forcing a liquid stream to flow through channels between a Pt ball and a glass wall. This device offers many advantages relative to conventional mixing devices. The 99% mixing time for the device has been found to be 30 - 80 μs, which is at least a factor of 10 faster than the older devices. This technique can be applied using any type of fast reaction, solvent or laser. The stability of the stream and the excellent reproducibility allow measurements of the rate constants of very fast reactions. Spherical tip mixer (dpeaa)DE-He213 fast mixing (dpeaa)DE-He213 time-resolved resonance Raman spectroscopy (dpeaa)DE-He213 Rhee Paeng, Insook aut Kincaid, James R. aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 10(1994), 1 vom: Feb., Seite 157-159 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:10 year:1994 number:1 month:02 pages:157-159 https://dx.doi.org/10.2116/analsci.10.157 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_250 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 1994 1 02 157-159 |
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10.2116/analsci.10.157 doi (DE-627)SPR047607254 (SPR)analsci.10.157-e DE-627 ger DE-627 rakwb eng Paeng, Ki-jung verfasserin aut Time-Resolved Resonance Raman Spectroscopy Using a Fast Mixing Device 1994 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1994 Abstract A new fast mixing device has been developed. Our attention has been paid to improving the apparatus design in order to decrease the mixing dead time and to enhance the mixing efficiency. We modified and, mainly, simplified the system proposed by Clegg. The new device comprises two concentric tubes and a platinum spherical ball with a single piece of Teflon used as a support housing. Mixing is thus performed by the induced turbulent flow which can be generated by forcing a liquid stream to flow through channels between a Pt ball and a glass wall. This device offers many advantages relative to conventional mixing devices. The 99% mixing time for the device has been found to be 30 - 80 μs, which is at least a factor of 10 faster than the older devices. This technique can be applied using any type of fast reaction, solvent or laser. The stability of the stream and the excellent reproducibility allow measurements of the rate constants of very fast reactions. Spherical tip mixer (dpeaa)DE-He213 fast mixing (dpeaa)DE-He213 time-resolved resonance Raman spectroscopy (dpeaa)DE-He213 Rhee Paeng, Insook aut Kincaid, James R. aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 10(1994), 1 vom: Feb., Seite 157-159 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:10 year:1994 number:1 month:02 pages:157-159 https://dx.doi.org/10.2116/analsci.10.157 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_250 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 1994 1 02 157-159 |
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10.2116/analsci.10.157 doi (DE-627)SPR047607254 (SPR)analsci.10.157-e DE-627 ger DE-627 rakwb eng Paeng, Ki-jung verfasserin aut Time-Resolved Resonance Raman Spectroscopy Using a Fast Mixing Device 1994 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1994 Abstract A new fast mixing device has been developed. Our attention has been paid to improving the apparatus design in order to decrease the mixing dead time and to enhance the mixing efficiency. We modified and, mainly, simplified the system proposed by Clegg. The new device comprises two concentric tubes and a platinum spherical ball with a single piece of Teflon used as a support housing. Mixing is thus performed by the induced turbulent flow which can be generated by forcing a liquid stream to flow through channels between a Pt ball and a glass wall. This device offers many advantages relative to conventional mixing devices. The 99% mixing time for the device has been found to be 30 - 80 μs, which is at least a factor of 10 faster than the older devices. This technique can be applied using any type of fast reaction, solvent or laser. The stability of the stream and the excellent reproducibility allow measurements of the rate constants of very fast reactions. Spherical tip mixer (dpeaa)DE-He213 fast mixing (dpeaa)DE-He213 time-resolved resonance Raman spectroscopy (dpeaa)DE-He213 Rhee Paeng, Insook aut Kincaid, James R. aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 10(1994), 1 vom: Feb., Seite 157-159 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:10 year:1994 number:1 month:02 pages:157-159 https://dx.doi.org/10.2116/analsci.10.157 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_250 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 1994 1 02 157-159 |
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10.2116/analsci.10.157 doi (DE-627)SPR047607254 (SPR)analsci.10.157-e DE-627 ger DE-627 rakwb eng Paeng, Ki-jung verfasserin aut Time-Resolved Resonance Raman Spectroscopy Using a Fast Mixing Device 1994 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1994 Abstract A new fast mixing device has been developed. Our attention has been paid to improving the apparatus design in order to decrease the mixing dead time and to enhance the mixing efficiency. We modified and, mainly, simplified the system proposed by Clegg. The new device comprises two concentric tubes and a platinum spherical ball with a single piece of Teflon used as a support housing. Mixing is thus performed by the induced turbulent flow which can be generated by forcing a liquid stream to flow through channels between a Pt ball and a glass wall. This device offers many advantages relative to conventional mixing devices. The 99% mixing time for the device has been found to be 30 - 80 μs, which is at least a factor of 10 faster than the older devices. This technique can be applied using any type of fast reaction, solvent or laser. The stability of the stream and the excellent reproducibility allow measurements of the rate constants of very fast reactions. Spherical tip mixer (dpeaa)DE-He213 fast mixing (dpeaa)DE-He213 time-resolved resonance Raman spectroscopy (dpeaa)DE-He213 Rhee Paeng, Insook aut Kincaid, James R. aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 10(1994), 1 vom: Feb., Seite 157-159 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:10 year:1994 number:1 month:02 pages:157-159 https://dx.doi.org/10.2116/analsci.10.157 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_250 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 1994 1 02 157-159 |
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10.2116/analsci.10.157 doi (DE-627)SPR047607254 (SPR)analsci.10.157-e DE-627 ger DE-627 rakwb eng Paeng, Ki-jung verfasserin aut Time-Resolved Resonance Raman Spectroscopy Using a Fast Mixing Device 1994 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Japan Society for Analytical Chemistry 1994 Abstract A new fast mixing device has been developed. Our attention has been paid to improving the apparatus design in order to decrease the mixing dead time and to enhance the mixing efficiency. We modified and, mainly, simplified the system proposed by Clegg. The new device comprises two concentric tubes and a platinum spherical ball with a single piece of Teflon used as a support housing. Mixing is thus performed by the induced turbulent flow which can be generated by forcing a liquid stream to flow through channels between a Pt ball and a glass wall. This device offers many advantages relative to conventional mixing devices. The 99% mixing time for the device has been found to be 30 - 80 μs, which is at least a factor of 10 faster than the older devices. This technique can be applied using any type of fast reaction, solvent or laser. The stability of the stream and the excellent reproducibility allow measurements of the rate constants of very fast reactions. Spherical tip mixer (dpeaa)DE-He213 fast mixing (dpeaa)DE-He213 time-resolved resonance Raman spectroscopy (dpeaa)DE-He213 Rhee Paeng, Insook aut Kincaid, James R. aut Enthalten in Analytical sciences [Cham] : Springer International Publishing, 1985 10(1994), 1 vom: Feb., Seite 157-159 (DE-627)300895925 (DE-600)1483376-1 1348-2246 nnns volume:10 year:1994 number:1 month:02 pages:157-159 https://dx.doi.org/10.2116/analsci.10.157 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_250 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 1994 1 02 157-159 |
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time-resolved resonance raman spectroscopy using a fast mixing device |
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Time-Resolved Resonance Raman Spectroscopy Using a Fast Mixing Device |
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Abstract A new fast mixing device has been developed. Our attention has been paid to improving the apparatus design in order to decrease the mixing dead time and to enhance the mixing efficiency. We modified and, mainly, simplified the system proposed by Clegg. The new device comprises two concentric tubes and a platinum spherical ball with a single piece of Teflon used as a support housing. Mixing is thus performed by the induced turbulent flow which can be generated by forcing a liquid stream to flow through channels between a Pt ball and a glass wall. This device offers many advantages relative to conventional mixing devices. The 99% mixing time for the device has been found to be 30 - 80 μs, which is at least a factor of 10 faster than the older devices. This technique can be applied using any type of fast reaction, solvent or laser. The stability of the stream and the excellent reproducibility allow measurements of the rate constants of very fast reactions. © The Japan Society for Analytical Chemistry 1994 |
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Abstract A new fast mixing device has been developed. Our attention has been paid to improving the apparatus design in order to decrease the mixing dead time and to enhance the mixing efficiency. We modified and, mainly, simplified the system proposed by Clegg. The new device comprises two concentric tubes and a platinum spherical ball with a single piece of Teflon used as a support housing. Mixing is thus performed by the induced turbulent flow which can be generated by forcing a liquid stream to flow through channels between a Pt ball and a glass wall. This device offers many advantages relative to conventional mixing devices. The 99% mixing time for the device has been found to be 30 - 80 μs, which is at least a factor of 10 faster than the older devices. This technique can be applied using any type of fast reaction, solvent or laser. The stability of the stream and the excellent reproducibility allow measurements of the rate constants of very fast reactions. © The Japan Society for Analytical Chemistry 1994 |
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Abstract A new fast mixing device has been developed. Our attention has been paid to improving the apparatus design in order to decrease the mixing dead time and to enhance the mixing efficiency. We modified and, mainly, simplified the system proposed by Clegg. The new device comprises two concentric tubes and a platinum spherical ball with a single piece of Teflon used as a support housing. Mixing is thus performed by the induced turbulent flow which can be generated by forcing a liquid stream to flow through channels between a Pt ball and a glass wall. This device offers many advantages relative to conventional mixing devices. The 99% mixing time for the device has been found to be 30 - 80 μs, which is at least a factor of 10 faster than the older devices. This technique can be applied using any type of fast reaction, solvent or laser. The stability of the stream and the excellent reproducibility allow measurements of the rate constants of very fast reactions. © The Japan Society for Analytical Chemistry 1994 |
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