Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst

CuO–$ CeO_{2} $ (Cu–Ce) catalyst with a CuO/$ CeO_{2} $ mass ratio of 1 prepared by a sol–gel method is used in the CO catalytic oxidation reaction in the actual industrial sulfur-containing atmosphere. At a reaction temperature of 200 °C, the catalyst exhibits quite different stability under sulfur...
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Autor*in:	Li, Zhiyu [verfasserIn] Chen, Jinding Jiang, Man Li, Linna Zhang, Jingyi Duan, Wenbiao Wen, Junjie Wang, Huimin Liu, Mo Zhang, Qiulin Chen, Jianjun Ning, Ping

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2021

Schlagwörter:	Sulfur poisoning CO catalytic oxidation Cu–Ce Cerium sulfate

Anmerkung:	© The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021

Übergeordnetes Werk:	Enthalten in: Catalysis letters - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988, 152(2021), 9 vom: 08. Nov., Seite 2729-2737
Übergeordnetes Werk:	volume:152 ; year:2021 ; number:9 ; day:08 ; month:11 ; pages:2729-2737

Links:	Volltext

DOI / URN:	10.1007/s10562-021-03846-8

Katalog-ID:	SPR047778873

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520			\|a CuO–$ CeO_{2} $ (Cu–Ce) catalyst with a CuO/$ CeO_{2} $ mass ratio of 1 prepared by a sol–gel method is used in the CO catalytic oxidation reaction in the actual industrial sulfur-containing atmosphere. At a reaction temperature of 200 °C, the catalyst exhibits quite different stability under sulfur-containing and sulfur-free conditions. When 30 ppm $ SO_{2} $ was added to the feed gas, the Cu–Ce catalyst had an initial CO conversion rate of 100%, gradually decreasing after 26 h, and this catalyst completely deactivated at about 50 h. However, the CO conversion rate of the catalyst under sulfur-free conditions could be nearly maintained at 100% within the measured time range (60 h). The results of IR, Raman, and XPS characterizations proved that the accumulation of cerium sulfate on the Cu–Ce catalyst would cover the active sites of the catalyst, eventually leading to the complete deactivation of the catalyst, which provides favorable evidence for the actual industrial anti-sulfur application. Graphical Abstract
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650		4	\|a CO catalytic oxidation \|7 (dpeaa)DE-He213
650		4	\|a Cu–Ce \|7 (dpeaa)DE-He213
650		4	\|a Cerium sulfate \|7 (dpeaa)DE-He213
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700	1		\|a Liu, Mo \|4 aut
700	1		\|a Zhang, Qiulin \|4 aut
700	1		\|a Chen, Jianjun \|4 aut
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allfields	10.1007/s10562-021-03846-8 doi (DE-627)SPR047778873 (SPR)s10562-021-03846-8-e DE-627 ger DE-627 rakwb eng Li, Zhiyu verfasserin aut Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021 CuO–$ CeO_{2} $ (Cu–Ce) catalyst with a CuO/$ CeO_{2} $ mass ratio of 1 prepared by a sol–gel method is used in the CO catalytic oxidation reaction in the actual industrial sulfur-containing atmosphere. At a reaction temperature of 200 °C, the catalyst exhibits quite different stability under sulfur-containing and sulfur-free conditions. When 30 ppm $ SO_{2} $ was added to the feed gas, the Cu–Ce catalyst had an initial CO conversion rate of 100%, gradually decreasing after 26 h, and this catalyst completely deactivated at about 50 h. However, the CO conversion rate of the catalyst under sulfur-free conditions could be nearly maintained at 100% within the measured time range (60 h). The results of IR, Raman, and XPS characterizations proved that the accumulation of cerium sulfate on the Cu–Ce catalyst would cover the active sites of the catalyst, eventually leading to the complete deactivation of the catalyst, which provides favorable evidence for the actual industrial anti-sulfur application. Graphical Abstract Sulfur poisoning (dpeaa)DE-He213 CO catalytic oxidation (dpeaa)DE-He213 Cu–Ce (dpeaa)DE-He213 Cerium sulfate (dpeaa)DE-He213 Chen, Jinding aut Jiang, Man aut Li, Linna aut Zhang, Jingyi aut Duan, Wenbiao aut Wen, Junjie aut Wang, Huimin aut Liu, Mo aut Zhang, Qiulin aut Chen, Jianjun aut Ning, Ping aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 152(2021), 9 vom: 08. Nov., Seite 2729-2737 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:152 year:2021 number:9 day:08 month:11 pages:2729-2737 https://dx.doi.org/10.1007/s10562-021-03846-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 152 2021 9 08 11 2729-2737
spelling	10.1007/s10562-021-03846-8 doi (DE-627)SPR047778873 (SPR)s10562-021-03846-8-e DE-627 ger DE-627 rakwb eng Li, Zhiyu verfasserin aut Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021 CuO–$ CeO_{2} $ (Cu–Ce) catalyst with a CuO/$ CeO_{2} $ mass ratio of 1 prepared by a sol–gel method is used in the CO catalytic oxidation reaction in the actual industrial sulfur-containing atmosphere. At a reaction temperature of 200 °C, the catalyst exhibits quite different stability under sulfur-containing and sulfur-free conditions. When 30 ppm $ SO_{2} $ was added to the feed gas, the Cu–Ce catalyst had an initial CO conversion rate of 100%, gradually decreasing after 26 h, and this catalyst completely deactivated at about 50 h. However, the CO conversion rate of the catalyst under sulfur-free conditions could be nearly maintained at 100% within the measured time range (60 h). The results of IR, Raman, and XPS characterizations proved that the accumulation of cerium sulfate on the Cu–Ce catalyst would cover the active sites of the catalyst, eventually leading to the complete deactivation of the catalyst, which provides favorable evidence for the actual industrial anti-sulfur application. Graphical Abstract Sulfur poisoning (dpeaa)DE-He213 CO catalytic oxidation (dpeaa)DE-He213 Cu–Ce (dpeaa)DE-He213 Cerium sulfate (dpeaa)DE-He213 Chen, Jinding aut Jiang, Man aut Li, Linna aut Zhang, Jingyi aut Duan, Wenbiao aut Wen, Junjie aut Wang, Huimin aut Liu, Mo aut Zhang, Qiulin aut Chen, Jianjun aut Ning, Ping aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 152(2021), 9 vom: 08. Nov., Seite 2729-2737 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:152 year:2021 number:9 day:08 month:11 pages:2729-2737 https://dx.doi.org/10.1007/s10562-021-03846-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 152 2021 9 08 11 2729-2737
allfields_unstemmed	10.1007/s10562-021-03846-8 doi (DE-627)SPR047778873 (SPR)s10562-021-03846-8-e DE-627 ger DE-627 rakwb eng Li, Zhiyu verfasserin aut Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021 CuO–$ CeO_{2} $ (Cu–Ce) catalyst with a CuO/$ CeO_{2} $ mass ratio of 1 prepared by a sol–gel method is used in the CO catalytic oxidation reaction in the actual industrial sulfur-containing atmosphere. At a reaction temperature of 200 °C, the catalyst exhibits quite different stability under sulfur-containing and sulfur-free conditions. When 30 ppm $ SO_{2} $ was added to the feed gas, the Cu–Ce catalyst had an initial CO conversion rate of 100%, gradually decreasing after 26 h, and this catalyst completely deactivated at about 50 h. However, the CO conversion rate of the catalyst under sulfur-free conditions could be nearly maintained at 100% within the measured time range (60 h). The results of IR, Raman, and XPS characterizations proved that the accumulation of cerium sulfate on the Cu–Ce catalyst would cover the active sites of the catalyst, eventually leading to the complete deactivation of the catalyst, which provides favorable evidence for the actual industrial anti-sulfur application. Graphical Abstract Sulfur poisoning (dpeaa)DE-He213 CO catalytic oxidation (dpeaa)DE-He213 Cu–Ce (dpeaa)DE-He213 Cerium sulfate (dpeaa)DE-He213 Chen, Jinding aut Jiang, Man aut Li, Linna aut Zhang, Jingyi aut Duan, Wenbiao aut Wen, Junjie aut Wang, Huimin aut Liu, Mo aut Zhang, Qiulin aut Chen, Jianjun aut Ning, Ping aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 152(2021), 9 vom: 08. Nov., Seite 2729-2737 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:152 year:2021 number:9 day:08 month:11 pages:2729-2737 https://dx.doi.org/10.1007/s10562-021-03846-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 152 2021 9 08 11 2729-2737
allfieldsGer	10.1007/s10562-021-03846-8 doi (DE-627)SPR047778873 (SPR)s10562-021-03846-8-e DE-627 ger DE-627 rakwb eng Li, Zhiyu verfasserin aut Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021 CuO–$ CeO_{2} $ (Cu–Ce) catalyst with a CuO/$ CeO_{2} $ mass ratio of 1 prepared by a sol–gel method is used in the CO catalytic oxidation reaction in the actual industrial sulfur-containing atmosphere. At a reaction temperature of 200 °C, the catalyst exhibits quite different stability under sulfur-containing and sulfur-free conditions. When 30 ppm $ SO_{2} $ was added to the feed gas, the Cu–Ce catalyst had an initial CO conversion rate of 100%, gradually decreasing after 26 h, and this catalyst completely deactivated at about 50 h. However, the CO conversion rate of the catalyst under sulfur-free conditions could be nearly maintained at 100% within the measured time range (60 h). The results of IR, Raman, and XPS characterizations proved that the accumulation of cerium sulfate on the Cu–Ce catalyst would cover the active sites of the catalyst, eventually leading to the complete deactivation of the catalyst, which provides favorable evidence for the actual industrial anti-sulfur application. Graphical Abstract Sulfur poisoning (dpeaa)DE-He213 CO catalytic oxidation (dpeaa)DE-He213 Cu–Ce (dpeaa)DE-He213 Cerium sulfate (dpeaa)DE-He213 Chen, Jinding aut Jiang, Man aut Li, Linna aut Zhang, Jingyi aut Duan, Wenbiao aut Wen, Junjie aut Wang, Huimin aut Liu, Mo aut Zhang, Qiulin aut Chen, Jianjun aut Ning, Ping aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 152(2021), 9 vom: 08. Nov., Seite 2729-2737 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:152 year:2021 number:9 day:08 month:11 pages:2729-2737 https://dx.doi.org/10.1007/s10562-021-03846-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 152 2021 9 08 11 2729-2737
allfieldsSound	10.1007/s10562-021-03846-8 doi (DE-627)SPR047778873 (SPR)s10562-021-03846-8-e DE-627 ger DE-627 rakwb eng Li, Zhiyu verfasserin aut Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021 CuO–$ CeO_{2} $ (Cu–Ce) catalyst with a CuO/$ CeO_{2} $ mass ratio of 1 prepared by a sol–gel method is used in the CO catalytic oxidation reaction in the actual industrial sulfur-containing atmosphere. At a reaction temperature of 200 °C, the catalyst exhibits quite different stability under sulfur-containing and sulfur-free conditions. When 30 ppm $ SO_{2} $ was added to the feed gas, the Cu–Ce catalyst had an initial CO conversion rate of 100%, gradually decreasing after 26 h, and this catalyst completely deactivated at about 50 h. However, the CO conversion rate of the catalyst under sulfur-free conditions could be nearly maintained at 100% within the measured time range (60 h). The results of IR, Raman, and XPS characterizations proved that the accumulation of cerium sulfate on the Cu–Ce catalyst would cover the active sites of the catalyst, eventually leading to the complete deactivation of the catalyst, which provides favorable evidence for the actual industrial anti-sulfur application. Graphical Abstract Sulfur poisoning (dpeaa)DE-He213 CO catalytic oxidation (dpeaa)DE-He213 Cu–Ce (dpeaa)DE-He213 Cerium sulfate (dpeaa)DE-He213 Chen, Jinding aut Jiang, Man aut Li, Linna aut Zhang, Jingyi aut Duan, Wenbiao aut Wen, Junjie aut Wang, Huimin aut Liu, Mo aut Zhang, Qiulin aut Chen, Jianjun aut Ning, Ping aut Enthalten in Catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1988 152(2021), 9 vom: 08. Nov., Seite 2729-2737 (DE-627)306717638 (DE-600)1501518-X 1572-879X nnns volume:152 year:2021 number:9 day:08 month:11 pages:2729-2737 https://dx.doi.org/10.1007/s10562-021-03846-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 152 2021 9 08 11 2729-2737
language	English
source	Enthalten in Catalysis letters 152(2021), 9 vom: 08. Nov., Seite 2729-2737 volume:152 year:2021 number:9 day:08 month:11 pages:2729-2737
sourceStr	Enthalten in Catalysis letters 152(2021), 9 vom: 08. Nov., Seite 2729-2737 volume:152 year:2021 number:9 day:08 month:11 pages:2729-2737
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Sulfur poisoning CO catalytic oxidation Cu–Ce Cerium sulfate
isfreeaccess_bool	false
container_title	Catalysis letters
authorswithroles_txt_mv	Li, Zhiyu @@aut@@ Chen, Jinding @@aut@@ Jiang, Man @@aut@@ Li, Linna @@aut@@ Zhang, Jingyi @@aut@@ Duan, Wenbiao @@aut@@ Wen, Junjie @@aut@@ Wang, Huimin @@aut@@ Liu, Mo @@aut@@ Zhang, Qiulin @@aut@@ Chen, Jianjun @@aut@@ Ning, Ping @@aut@@
publishDateDaySort_date	2021-11-08T00:00:00Z
hierarchy_top_id	306717638
id	SPR047778873
language_de	englisch
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author	Li, Zhiyu
spellingShingle	Li, Zhiyu misc Sulfur poisoning misc CO catalytic oxidation misc Cu–Ce misc Cerium sulfate Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst
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topic_title	Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst Sulfur poisoning (dpeaa)DE-He213 CO catalytic oxidation (dpeaa)DE-He213 Cu–Ce (dpeaa)DE-He213 Cerium sulfate (dpeaa)DE-He213
topic	misc Sulfur poisoning misc CO catalytic oxidation misc Cu–Ce misc Cerium sulfate
topic_unstemmed	misc Sulfur poisoning misc CO catalytic oxidation misc Cu–Ce misc Cerium sulfate
topic_browse	misc Sulfur poisoning misc CO catalytic oxidation misc Cu–Ce misc Cerium sulfate
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title	Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst
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title_full	Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst
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author_browse	Li, Zhiyu Chen, Jinding Jiang, Man Li, Linna Zhang, Jingyi Duan, Wenbiao Wen, Junjie Wang, Huimin Liu, Mo Zhang, Qiulin Chen, Jianjun Ning, Ping
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author-letter	Li, Zhiyu
doi_str_mv	10.1007/s10562-021-03846-8
title_sort	study on $ so_{2} $ poisoning mechanism of co catalytic oxidation reaction on copper–cerium catalyst
title_auth	Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst
abstract	CuO–$ CeO_{2} $ (Cu–Ce) catalyst with a CuO/$ CeO_{2} $ mass ratio of 1 prepared by a sol–gel method is used in the CO catalytic oxidation reaction in the actual industrial sulfur-containing atmosphere. At a reaction temperature of 200 °C, the catalyst exhibits quite different stability under sulfur-containing and sulfur-free conditions. When 30 ppm $ SO_{2} $ was added to the feed gas, the Cu–Ce catalyst had an initial CO conversion rate of 100%, gradually decreasing after 26 h, and this catalyst completely deactivated at about 50 h. However, the CO conversion rate of the catalyst under sulfur-free conditions could be nearly maintained at 100% within the measured time range (60 h). The results of IR, Raman, and XPS characterizations proved that the accumulation of cerium sulfate on the Cu–Ce catalyst would cover the active sites of the catalyst, eventually leading to the complete deactivation of the catalyst, which provides favorable evidence for the actual industrial anti-sulfur application. Graphical Abstract © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021
abstractGer	CuO–$ CeO_{2} $ (Cu–Ce) catalyst with a CuO/$ CeO_{2} $ mass ratio of 1 prepared by a sol–gel method is used in the CO catalytic oxidation reaction in the actual industrial sulfur-containing atmosphere. At a reaction temperature of 200 °C, the catalyst exhibits quite different stability under sulfur-containing and sulfur-free conditions. When 30 ppm $ SO_{2} $ was added to the feed gas, the Cu–Ce catalyst had an initial CO conversion rate of 100%, gradually decreasing after 26 h, and this catalyst completely deactivated at about 50 h. However, the CO conversion rate of the catalyst under sulfur-free conditions could be nearly maintained at 100% within the measured time range (60 h). The results of IR, Raman, and XPS characterizations proved that the accumulation of cerium sulfate on the Cu–Ce catalyst would cover the active sites of the catalyst, eventually leading to the complete deactivation of the catalyst, which provides favorable evidence for the actual industrial anti-sulfur application. Graphical Abstract © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021
abstract_unstemmed	CuO–$ CeO_{2} $ (Cu–Ce) catalyst with a CuO/$ CeO_{2} $ mass ratio of 1 prepared by a sol–gel method is used in the CO catalytic oxidation reaction in the actual industrial sulfur-containing atmosphere. At a reaction temperature of 200 °C, the catalyst exhibits quite different stability under sulfur-containing and sulfur-free conditions. When 30 ppm $ SO_{2} $ was added to the feed gas, the Cu–Ce catalyst had an initial CO conversion rate of 100%, gradually decreasing after 26 h, and this catalyst completely deactivated at about 50 h. However, the CO conversion rate of the catalyst under sulfur-free conditions could be nearly maintained at 100% within the measured time range (60 h). The results of IR, Raman, and XPS characterizations proved that the accumulation of cerium sulfate on the Cu–Ce catalyst would cover the active sites of the catalyst, eventually leading to the complete deactivation of the catalyst, which provides favorable evidence for the actual industrial anti-sulfur application. Graphical Abstract © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021
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container_issue	9
title_short	Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst
url	https://dx.doi.org/10.1007/s10562-021-03846-8
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author2	Chen, Jinding Jiang, Man Li, Linna Zhang, Jingyi Duan, Wenbiao Wen, Junjie Wang, Huimin Liu, Mo Zhang, Qiulin Chen, Jianjun Ning, Ping
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Study on $ SO_{2} $ Poisoning Mechanism of CO Catalytic Oxidation Reaction on Copper–Cerium Catalyst

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