Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances
As a new thermosetting resin, polybenzoxazine has attracted extensive attention because of its excellent properties. However, the biggest challenge of polybenzoxazine is the balance among impact strength, thermal stability, and processability. In this work, we first introduced a 2-ureido-4[1H]-pyrim...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhao, Sipei [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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| Anmerkung: |
© The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| Übergeordnetes Werk: |
Enthalten in: Advanced composites and hybrid materials - [Cham] : Springer International Publishing, 2017, 5(2022), 4 vom: 13. Sept., Seite 3057-3067 |
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| Übergeordnetes Werk: |
volume:5 ; year:2022 ; number:4 ; day:13 ; month:09 ; pages:3057-3067 |
| Links: |
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| DOI / URN: |
10.1007/s42114-022-00555-7 |
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SPR04849075X |
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| 520 | |a As a new thermosetting resin, polybenzoxazine has attracted extensive attention because of its excellent properties. However, the biggest challenge of polybenzoxazine is the balance among impact strength, thermal stability, and processability. In this work, we first introduced a 2-ureido-4[1H]-pyrimidone (UPy, containing quadruple hydrogen bonds) dimer into benzoxazine to tackle this challenge. In the blends containing 3 wt% UPy, its toughness and thermal properties have been simultaneously improved, while maintaining a high modulus and a negligible increasement in viscosity. The impact strength and the glass transition temperature (Tg) reach 16.39 kJ·$ m^{−2} $ and 221 °C, which are 172% and 10 °C higher than that of polybenzoxazine, respectively. Meanwhile, this strategy was extended to carbon fiber surface modification to enhance the interfacial adhesion between fibers and resins. The mechanical properties of modified fiber composites are significantly improved. Furthermore, we firstly designed the cyclic flexural experiment of material and tried to propose an effective method to verify the effect of hydrogen bond dynamics on flexural properties of polybenzoxazine. Here, we not only provide a new way to get a balance among different properties of polybenzoxazine but also give a broad insight on the application of additional hydrogen bonds in thermoset resins. Graphical Abstract The improved comprehensive performances of polybenzoxazine were realized by introducing quadruple hydrogen bond motif. | ||
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10.1007/s42114-022-00555-7 doi (DE-627)SPR04849075X (SPR)s42114-022-00555-7-e DE-627 ger DE-627 rakwb eng Zhao, Sipei verfasserin aut Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. As a new thermosetting resin, polybenzoxazine has attracted extensive attention because of its excellent properties. However, the biggest challenge of polybenzoxazine is the balance among impact strength, thermal stability, and processability. In this work, we first introduced a 2-ureido-4[1H]-pyrimidone (UPy, containing quadruple hydrogen bonds) dimer into benzoxazine to tackle this challenge. In the blends containing 3 wt% UPy, its toughness and thermal properties have been simultaneously improved, while maintaining a high modulus and a negligible increasement in viscosity. The impact strength and the glass transition temperature (Tg) reach 16.39 kJ·$ m^{−2} $ and 221 °C, which are 172% and 10 °C higher than that of polybenzoxazine, respectively. Meanwhile, this strategy was extended to carbon fiber surface modification to enhance the interfacial adhesion between fibers and resins. The mechanical properties of modified fiber composites are significantly improved. Furthermore, we firstly designed the cyclic flexural experiment of material and tried to propose an effective method to verify the effect of hydrogen bond dynamics on flexural properties of polybenzoxazine. Here, we not only provide a new way to get a balance among different properties of polybenzoxazine but also give a broad insight on the application of additional hydrogen bonds in thermoset resins. Graphical Abstract The improved comprehensive performances of polybenzoxazine were realized by introducing quadruple hydrogen bond motif. Polybenzoxazine (dpeaa)DE-He213 Toughening (dpeaa)DE-He213 Quadruple hydrogen bonds (dpeaa)DE-He213 Li, Shuiquan aut Liu, Huihui aut Jiang, Jin aut Wang, Meichen aut Liu, Haolang aut Wang, Weiwei aut Wang, Zhi (orcid)0000-0002-5701-2980 aut Enthalten in Advanced composites and hybrid materials [Cham] : Springer International Publishing, 2017 5(2022), 4 vom: 13. Sept., Seite 3057-3067 (DE-627)1004720920 (DE-600)2911408-1 2522-0136 nnns volume:5 year:2022 number:4 day:13 month:09 pages:3057-3067 https://dx.doi.org/10.1007/s42114-022-00555-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 5 2022 4 13 09 3057-3067 |
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10.1007/s42114-022-00555-7 doi (DE-627)SPR04849075X (SPR)s42114-022-00555-7-e DE-627 ger DE-627 rakwb eng Zhao, Sipei verfasserin aut Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. As a new thermosetting resin, polybenzoxazine has attracted extensive attention because of its excellent properties. However, the biggest challenge of polybenzoxazine is the balance among impact strength, thermal stability, and processability. In this work, we first introduced a 2-ureido-4[1H]-pyrimidone (UPy, containing quadruple hydrogen bonds) dimer into benzoxazine to tackle this challenge. In the blends containing 3 wt% UPy, its toughness and thermal properties have been simultaneously improved, while maintaining a high modulus and a negligible increasement in viscosity. The impact strength and the glass transition temperature (Tg) reach 16.39 kJ·$ m^{−2} $ and 221 °C, which are 172% and 10 °C higher than that of polybenzoxazine, respectively. Meanwhile, this strategy was extended to carbon fiber surface modification to enhance the interfacial adhesion between fibers and resins. The mechanical properties of modified fiber composites are significantly improved. Furthermore, we firstly designed the cyclic flexural experiment of material and tried to propose an effective method to verify the effect of hydrogen bond dynamics on flexural properties of polybenzoxazine. Here, we not only provide a new way to get a balance among different properties of polybenzoxazine but also give a broad insight on the application of additional hydrogen bonds in thermoset resins. Graphical Abstract The improved comprehensive performances of polybenzoxazine were realized by introducing quadruple hydrogen bond motif. Polybenzoxazine (dpeaa)DE-He213 Toughening (dpeaa)DE-He213 Quadruple hydrogen bonds (dpeaa)DE-He213 Li, Shuiquan aut Liu, Huihui aut Jiang, Jin aut Wang, Meichen aut Liu, Haolang aut Wang, Weiwei aut Wang, Zhi (orcid)0000-0002-5701-2980 aut Enthalten in Advanced composites and hybrid materials [Cham] : Springer International Publishing, 2017 5(2022), 4 vom: 13. Sept., Seite 3057-3067 (DE-627)1004720920 (DE-600)2911408-1 2522-0136 nnns volume:5 year:2022 number:4 day:13 month:09 pages:3057-3067 https://dx.doi.org/10.1007/s42114-022-00555-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 5 2022 4 13 09 3057-3067 |
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10.1007/s42114-022-00555-7 doi (DE-627)SPR04849075X (SPR)s42114-022-00555-7-e DE-627 ger DE-627 rakwb eng Zhao, Sipei verfasserin aut Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. As a new thermosetting resin, polybenzoxazine has attracted extensive attention because of its excellent properties. However, the biggest challenge of polybenzoxazine is the balance among impact strength, thermal stability, and processability. In this work, we first introduced a 2-ureido-4[1H]-pyrimidone (UPy, containing quadruple hydrogen bonds) dimer into benzoxazine to tackle this challenge. In the blends containing 3 wt% UPy, its toughness and thermal properties have been simultaneously improved, while maintaining a high modulus and a negligible increasement in viscosity. The impact strength and the glass transition temperature (Tg) reach 16.39 kJ·$ m^{−2} $ and 221 °C, which are 172% and 10 °C higher than that of polybenzoxazine, respectively. Meanwhile, this strategy was extended to carbon fiber surface modification to enhance the interfacial adhesion between fibers and resins. The mechanical properties of modified fiber composites are significantly improved. Furthermore, we firstly designed the cyclic flexural experiment of material and tried to propose an effective method to verify the effect of hydrogen bond dynamics on flexural properties of polybenzoxazine. Here, we not only provide a new way to get a balance among different properties of polybenzoxazine but also give a broad insight on the application of additional hydrogen bonds in thermoset resins. Graphical Abstract The improved comprehensive performances of polybenzoxazine were realized by introducing quadruple hydrogen bond motif. Polybenzoxazine (dpeaa)DE-He213 Toughening (dpeaa)DE-He213 Quadruple hydrogen bonds (dpeaa)DE-He213 Li, Shuiquan aut Liu, Huihui aut Jiang, Jin aut Wang, Meichen aut Liu, Haolang aut Wang, Weiwei aut Wang, Zhi (orcid)0000-0002-5701-2980 aut Enthalten in Advanced composites and hybrid materials [Cham] : Springer International Publishing, 2017 5(2022), 4 vom: 13. Sept., Seite 3057-3067 (DE-627)1004720920 (DE-600)2911408-1 2522-0136 nnns volume:5 year:2022 number:4 day:13 month:09 pages:3057-3067 https://dx.doi.org/10.1007/s42114-022-00555-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 5 2022 4 13 09 3057-3067 |
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10.1007/s42114-022-00555-7 doi (DE-627)SPR04849075X (SPR)s42114-022-00555-7-e DE-627 ger DE-627 rakwb eng Zhao, Sipei verfasserin aut Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. As a new thermosetting resin, polybenzoxazine has attracted extensive attention because of its excellent properties. However, the biggest challenge of polybenzoxazine is the balance among impact strength, thermal stability, and processability. In this work, we first introduced a 2-ureido-4[1H]-pyrimidone (UPy, containing quadruple hydrogen bonds) dimer into benzoxazine to tackle this challenge. In the blends containing 3 wt% UPy, its toughness and thermal properties have been simultaneously improved, while maintaining a high modulus and a negligible increasement in viscosity. The impact strength and the glass transition temperature (Tg) reach 16.39 kJ·$ m^{−2} $ and 221 °C, which are 172% and 10 °C higher than that of polybenzoxazine, respectively. Meanwhile, this strategy was extended to carbon fiber surface modification to enhance the interfacial adhesion between fibers and resins. The mechanical properties of modified fiber composites are significantly improved. Furthermore, we firstly designed the cyclic flexural experiment of material and tried to propose an effective method to verify the effect of hydrogen bond dynamics on flexural properties of polybenzoxazine. Here, we not only provide a new way to get a balance among different properties of polybenzoxazine but also give a broad insight on the application of additional hydrogen bonds in thermoset resins. Graphical Abstract The improved comprehensive performances of polybenzoxazine were realized by introducing quadruple hydrogen bond motif. Polybenzoxazine (dpeaa)DE-He213 Toughening (dpeaa)DE-He213 Quadruple hydrogen bonds (dpeaa)DE-He213 Li, Shuiquan aut Liu, Huihui aut Jiang, Jin aut Wang, Meichen aut Liu, Haolang aut Wang, Weiwei aut Wang, Zhi (orcid)0000-0002-5701-2980 aut Enthalten in Advanced composites and hybrid materials [Cham] : Springer International Publishing, 2017 5(2022), 4 vom: 13. Sept., Seite 3057-3067 (DE-627)1004720920 (DE-600)2911408-1 2522-0136 nnns volume:5 year:2022 number:4 day:13 month:09 pages:3057-3067 https://dx.doi.org/10.1007/s42114-022-00555-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 5 2022 4 13 09 3057-3067 |
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10.1007/s42114-022-00555-7 doi (DE-627)SPR04849075X (SPR)s42114-022-00555-7-e DE-627 ger DE-627 rakwb eng Zhao, Sipei verfasserin aut Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. As a new thermosetting resin, polybenzoxazine has attracted extensive attention because of its excellent properties. However, the biggest challenge of polybenzoxazine is the balance among impact strength, thermal stability, and processability. In this work, we first introduced a 2-ureido-4[1H]-pyrimidone (UPy, containing quadruple hydrogen bonds) dimer into benzoxazine to tackle this challenge. In the blends containing 3 wt% UPy, its toughness and thermal properties have been simultaneously improved, while maintaining a high modulus and a negligible increasement in viscosity. The impact strength and the glass transition temperature (Tg) reach 16.39 kJ·$ m^{−2} $ and 221 °C, which are 172% and 10 °C higher than that of polybenzoxazine, respectively. Meanwhile, this strategy was extended to carbon fiber surface modification to enhance the interfacial adhesion between fibers and resins. The mechanical properties of modified fiber composites are significantly improved. Furthermore, we firstly designed the cyclic flexural experiment of material and tried to propose an effective method to verify the effect of hydrogen bond dynamics on flexural properties of polybenzoxazine. Here, we not only provide a new way to get a balance among different properties of polybenzoxazine but also give a broad insight on the application of additional hydrogen bonds in thermoset resins. Graphical Abstract The improved comprehensive performances of polybenzoxazine were realized by introducing quadruple hydrogen bond motif. Polybenzoxazine (dpeaa)DE-He213 Toughening (dpeaa)DE-He213 Quadruple hydrogen bonds (dpeaa)DE-He213 Li, Shuiquan aut Liu, Huihui aut Jiang, Jin aut Wang, Meichen aut Liu, Haolang aut Wang, Weiwei aut Wang, Zhi (orcid)0000-0002-5701-2980 aut Enthalten in Advanced composites and hybrid materials [Cham] : Springer International Publishing, 2017 5(2022), 4 vom: 13. Sept., Seite 3057-3067 (DE-627)1004720920 (DE-600)2911408-1 2522-0136 nnns volume:5 year:2022 number:4 day:13 month:09 pages:3057-3067 https://dx.doi.org/10.1007/s42114-022-00555-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 5 2022 4 13 09 3057-3067 |
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Enthalten in Advanced composites and hybrid materials 5(2022), 4 vom: 13. Sept., Seite 3057-3067 volume:5 year:2022 number:4 day:13 month:09 pages:3057-3067 |
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Zhao, Sipei @@aut@@ Li, Shuiquan @@aut@@ Liu, Huihui @@aut@@ Jiang, Jin @@aut@@ Wang, Meichen @@aut@@ Liu, Haolang @@aut@@ Wang, Weiwei @@aut@@ Wang, Zhi @@aut@@ |
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Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">As a new thermosetting resin, polybenzoxazine has attracted extensive attention because of its excellent properties. However, the biggest challenge of polybenzoxazine is the balance among impact strength, thermal stability, and processability. In this work, we first introduced a 2-ureido-4[1H]-pyrimidone (UPy, containing quadruple hydrogen bonds) dimer into benzoxazine to tackle this challenge. In the blends containing 3 wt% UPy, its toughness and thermal properties have been simultaneously improved, while maintaining a high modulus and a negligible increasement in viscosity. The impact strength and the glass transition temperature (Tg) reach 16.39 kJ·$ m^{−2} $ and 221 °C, which are 172% and 10 °C higher than that of polybenzoxazine, respectively. Meanwhile, this strategy was extended to carbon fiber surface modification to enhance the interfacial adhesion between fibers and resins. The mechanical properties of modified fiber composites are significantly improved. Furthermore, we firstly designed the cyclic flexural experiment of material and tried to propose an effective method to verify the effect of hydrogen bond dynamics on flexural properties of polybenzoxazine. Here, we not only provide a new way to get a balance among different properties of polybenzoxazine but also give a broad insight on the application of additional hydrogen bonds in thermoset resins. Graphical Abstract The improved comprehensive performances of polybenzoxazine were realized by introducing quadruple hydrogen bond motif.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polybenzoxazine</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Toughening</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Quadruple hydrogen bonds</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Shuiquan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Liu, Huihui</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Jiang, Jin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Meichen</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Liu, Haolang</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Weiwei</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Zhi</subfield><subfield code="0">(orcid)0000-0002-5701-2980</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Advanced composites and hybrid materials</subfield><subfield code="d">[Cham] : Springer International Publishing, 2017</subfield><subfield code="g">5(2022), 4 vom: 13. 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Zhao, Sipei |
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Zhao, Sipei misc Polybenzoxazine misc Toughening misc Quadruple hydrogen bonds Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances |
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Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances Polybenzoxazine (dpeaa)DE-He213 Toughening (dpeaa)DE-He213 Quadruple hydrogen bonds (dpeaa)DE-He213 |
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Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances |
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Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances |
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quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances |
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Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances |
| abstract |
As a new thermosetting resin, polybenzoxazine has attracted extensive attention because of its excellent properties. However, the biggest challenge of polybenzoxazine is the balance among impact strength, thermal stability, and processability. In this work, we first introduced a 2-ureido-4[1H]-pyrimidone (UPy, containing quadruple hydrogen bonds) dimer into benzoxazine to tackle this challenge. In the blends containing 3 wt% UPy, its toughness and thermal properties have been simultaneously improved, while maintaining a high modulus and a negligible increasement in viscosity. The impact strength and the glass transition temperature (Tg) reach 16.39 kJ·$ m^{−2} $ and 221 °C, which are 172% and 10 °C higher than that of polybenzoxazine, respectively. Meanwhile, this strategy was extended to carbon fiber surface modification to enhance the interfacial adhesion between fibers and resins. The mechanical properties of modified fiber composites are significantly improved. Furthermore, we firstly designed the cyclic flexural experiment of material and tried to propose an effective method to verify the effect of hydrogen bond dynamics on flexural properties of polybenzoxazine. Here, we not only provide a new way to get a balance among different properties of polybenzoxazine but also give a broad insight on the application of additional hydrogen bonds in thermoset resins. Graphical Abstract The improved comprehensive performances of polybenzoxazine were realized by introducing quadruple hydrogen bond motif. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstractGer |
As a new thermosetting resin, polybenzoxazine has attracted extensive attention because of its excellent properties. However, the biggest challenge of polybenzoxazine is the balance among impact strength, thermal stability, and processability. In this work, we first introduced a 2-ureido-4[1H]-pyrimidone (UPy, containing quadruple hydrogen bonds) dimer into benzoxazine to tackle this challenge. In the blends containing 3 wt% UPy, its toughness and thermal properties have been simultaneously improved, while maintaining a high modulus and a negligible increasement in viscosity. The impact strength and the glass transition temperature (Tg) reach 16.39 kJ·$ m^{−2} $ and 221 °C, which are 172% and 10 °C higher than that of polybenzoxazine, respectively. Meanwhile, this strategy was extended to carbon fiber surface modification to enhance the interfacial adhesion between fibers and resins. The mechanical properties of modified fiber composites are significantly improved. Furthermore, we firstly designed the cyclic flexural experiment of material and tried to propose an effective method to verify the effect of hydrogen bond dynamics on flexural properties of polybenzoxazine. Here, we not only provide a new way to get a balance among different properties of polybenzoxazine but also give a broad insight on the application of additional hydrogen bonds in thermoset resins. Graphical Abstract The improved comprehensive performances of polybenzoxazine were realized by introducing quadruple hydrogen bond motif. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
| abstract_unstemmed |
As a new thermosetting resin, polybenzoxazine has attracted extensive attention because of its excellent properties. However, the biggest challenge of polybenzoxazine is the balance among impact strength, thermal stability, and processability. In this work, we first introduced a 2-ureido-4[1H]-pyrimidone (UPy, containing quadruple hydrogen bonds) dimer into benzoxazine to tackle this challenge. In the blends containing 3 wt% UPy, its toughness and thermal properties have been simultaneously improved, while maintaining a high modulus and a negligible increasement in viscosity. The impact strength and the glass transition temperature (Tg) reach 16.39 kJ·$ m^{−2} $ and 221 °C, which are 172% and 10 °C higher than that of polybenzoxazine, respectively. Meanwhile, this strategy was extended to carbon fiber surface modification to enhance the interfacial adhesion between fibers and resins. The mechanical properties of modified fiber composites are significantly improved. Furthermore, we firstly designed the cyclic flexural experiment of material and tried to propose an effective method to verify the effect of hydrogen bond dynamics on flexural properties of polybenzoxazine. Here, we not only provide a new way to get a balance among different properties of polybenzoxazine but also give a broad insight on the application of additional hydrogen bonds in thermoset resins. Graphical Abstract The improved comprehensive performances of polybenzoxazine were realized by introducing quadruple hydrogen bond motif. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. |
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| title_short |
Quadruple hydrogen bond motif-toughened polybenzoxazine with improved comprehensive performances |
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https://dx.doi.org/10.1007/s42114-022-00555-7 |
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Li, Shuiquan Liu, Huihui Jiang, Jin Wang, Meichen Liu, Haolang Wang, Weiwei Wang, Zhi |
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Li, Shuiquan Liu, Huihui Jiang, Jin Wang, Meichen Liu, Haolang Wang, Weiwei Wang, Zhi |
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10.1007/s42114-022-00555-7 |
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2024-07-03T19:32:53.397Z |
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|
| score |
7.399967 |